EP0710508A1 - Procédé pour fabriquer des revêtments ayant des effets optiques tri-dimensionnels - Google Patents
Procédé pour fabriquer des revêtments ayant des effets optiques tri-dimensionnels Download PDFInfo
- Publication number
- EP0710508A1 EP0710508A1 EP95116928A EP95116928A EP0710508A1 EP 0710508 A1 EP0710508 A1 EP 0710508A1 EP 95116928 A EP95116928 A EP 95116928A EP 95116928 A EP95116928 A EP 95116928A EP 0710508 A1 EP0710508 A1 EP 0710508A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- transfer medium
- magnetic
- configuration
- electromagnet
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/20—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by magnetic fields
- B05D3/207—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by magnetic fields post-treatment by magnetic fields
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
- B05D5/061—Special surface effect
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F7/00—Designs imitating three-dimensional effects
Definitions
- the present invention relates to a new process for producing coatings having three-dimensional optical effects by aligning magnetically orientable, platelet-shaped pigments.
- Prints or varnishes that show three-dimensional optical characteristics are not only suitable for decorative purposes, but are also of particular interest for the production of counterfeit-proof materials, in particular for security printing, since they cannot be photocopied and therefore can be easily distinguished from the original and enable counterfeiting.
- Such three-dimensional optical effects can advantageously be generated by aligning magnetic, platelet-shaped pigments in the still liquid application medium under the influence of a magnetic field and fixed by subsequent curing of the application medium.
- DE-A-39 38 055 discloses various methods for producing three-dimensional patterns by orienting magnetizable, platelet-shaped pigments, in particular mica and aluminum platelets, which are coated with a magnetic layer or are mixed with magnetic material.
- One of these methods is that the desired pattern is applied to a mumetal foil by punching or cutting, the layer to be aligned is placed on this foil and a magnetic field of a suitable size is generated under the foil, whereby the magnetic pigment particles should be aligned according to the desired pattern.
- the disadvantage here is that an optimal, ie complete, field configuration of the magnetic particles is not achieved via the mumetal foil and that a new mummetal foil has to be prepared for each pattern.
- a lettering is written directly into a moist print by moving a permanent magnet along it.
- a certain exposure time of the magnetic field i.e. a slow movement of the magnet is necessary, which is why the layer has partially dried before the "writing" process has ended.
- a third method combines magnetic field treatment with UV light treatment to harden the layer.
- the moist layer is exposed through a photomask, then the pigment particles in the still moist areas are magnetically aligned, and then the entire layer is cured by UV light.
- the object of the invention was to remedy the deficiencies mentioned and to provide a practical alignment method.
- Plastic films in which hard magnetic particles are incorporated are particularly suitable as a magnetizing sheet-like transfer medium for the method according to the invention, but other sheet-like magnetic designs could also be used.
- the plastic films can be placed on a thin support, e.g. an adhesive film, be applied, but preferably it is carrier-free materials, especially magnetic films or magnetic adhesive films or magnetic tapes, as are generally available commercially.
- the thickness of these materials is usually 0.1 to 5 mm.
- the hard magnetic particles contained in the plastic films can consist, for example, of the following hard magnetic materials:
- Hard ferrites such as barium and strontium ferrite; Rare earth alloys such as samarium / cobalt alloys; the AlNiCo group; Metal oxides used for magnetic information storage such as cobalt-containing ⁇ -iron (III) oxide, chromium dioxide or pure iron particles.
- Typical dimensions of the hard magnetic particles are generally from a few 10 ⁇ m down to 10 to 20 nm.
- the production of the magnetic particles can be carried out in the usual way, e.g. by sintering or rapid quenching and subsequent comminution.
- the magnetic properties of the transfer medium do not have to meet any special requirements, but materials with high saturation magnetization are generally advantageous. It is also advantageous if the coercive field strength is approximately the same as the magnetization of the entire transfer medium, but this is not a requirement.
- the thickness of the transfer medium preferably corresponds to 0.3 to 3 times the resolution desired in the finished effect coating.
- the desired three-dimensional optical effects are transferred via the magnetic field of the previously configured transfer medium to the magnetically orientable platelet-shaped pigments in the still moist coating (e.g. printing or painting).
- the subsequent configuration of the transfer medium i.e.
- the targeted remagnetization of the partial magnets, for writing in the desired information or the three-dimensional pattern, can be particularly advantageous by relative movement of the transfer medium either to (between) the pole pieces of a two-sided electromagnet or to the pole piece of a one-sided pole shoe equipped on one side only, pin-like electromagnets.
- FIGS. 1 and 2 Preferred configurations of the two-sided and the one-sided embodiment are shown schematically in FIGS. 1 and 2.
- FIG. 1 shows the preferred vertical arrangement of the movable transfer medium (T) in the gap of an electromagnet equipped with pole shoes (P) on both sides.
- FIG. 2 shows the preferred vertical arrangement of the transfer medium (T), which in turn is movable, to the pole shoe (P) of the one-sided, pin-like electromagnet.
- T transfer medium
- P pole shoe
- W soft magnetic plate
- the coils (S) can be oriented at other points in the magnetic circuit or can be completely or partially replaced by permanent magnets.
- the diameter in the pole shoe tip depends on the desired spatial resolution in the effect coating and is usually about 0.3 to 3 times this resolution.
- the field strength in the gap of the two-sided electromagnet or the field strength in front of the pole of the one-sided electromagnet (pin) preferably corresponds to the coercive field strength of the transfer medium.
- the two-sided design of the electromagnet usually results in a better resolution of the inscribed three-dimensional pattern.
- the one-sided, pen-like design is easier to handle.
- one or the other version will be preferred.
- the configured transfer medium is made possible completely and evenly with the still wet coating (printing or painting), in which the pigment particles are still mobile.
- the coated material is preferably simply placed on the transfer medium.
- all magnetically orientable, platelet-shaped pigments can be easily and specifically aligned.
- examples include the ferromagnetic metal platelets listed in US Pat. No. 2,570,856 and the mica and aluminum platelets listed in DE-A-39 38 055, which are coated with magnetite, and those in DE-A-43 13 541 and the unpublished DE-A-43 40 141 aluminum platelets described, which with an inner iron, cobalt, nickel or ⁇ -iron (III) oxide (maghemite) containing layer, another non-ferromagnetic metal oxide layer and / or an outer passivating phosphate, chromate - and / or a layer containing vanadium are occupied.
- A iron, cobalt, nickel, magnetite and / or ⁇ -Fe2O3,
- B silicon oxide and / or aluminum oxide
- C Have metal and / or non-selectively absorbing metal oxide.
- the exposure times for aligning the pigment particles are only 1 to 100 seconds, regardless of the complexity of the pattern.
- the subsequent drying process after which the pigment particles and hence the three-dimensional optical effects are fixed, can be accelerated by additional UV radiation.
- three-dimensional optical effects can advantageously be achieved by simply adapting the method parameters (pole shoe diameter and field strength of the magnet, contact time, thickness and coercive field strength of the transfer medium) safely and with the desired (good) resolution, ie with the desired contrast and the desired strength.
- magnetically orientable coatings containing platelet-shaped pigments, such as prints or coatings in magnetically orientable coatings containing platelet-shaped pigments, such as prints or coatings.
- the present method is characterized by its low time requirement (short registration times and short transmission times), the reusability of the transfer medium, which can be magnetized uniformly at any time with the help of a strong permanent magnet and is then available again for further enrollment processes, and the possibility of automation by computer control, particularly due to its economy.
- a commercially available 1 mm thick barium ferrite-containing magnetic adhesive film (from IBS, Berlin) was repeated after complete magnetization with a strong permanent magnet (Nd2Fe14B) while moving at a speed of about 1 cm / sec using an electromagnet equipped with pole shoes on both sides ( Pole shoe spacing about 1 mm, 2 coils with 480 turns each) described with a zigzag pattern.
- the pole shoe diameter and current were varied as indicated in the table.
- a still moist screen print was then placed on the magnetic film described for 60 seconds.
- the screen prints used for this were each made by printing (49 screen) a screen printing ink, the 20 g magnetizable pigment (Example 1 of DE-A-43 13 541) in 80 g of a commercially available binder solution (copolymer based on vinyl chloride and vinyl isobutyl ether ⁇ Laroflex® MP45 / acetate / aliphates) applied to paper or foil.
- a commercially available binder solution copolymer based on vinyl chloride and vinyl isobutyl ether ⁇ Laroflex® MP45 / acetate / aliphates
- the zigzag pattern was clearly visible in the dried print in all cases and could not be copied unchanged.
Landscapes
- Paints Or Removers (AREA)
- Printing Methods (AREA)
- Magnetic Record Carriers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4439455 | 1994-11-04 | ||
DE19944439455 DE4439455A1 (de) | 1994-11-04 | 1994-11-04 | Verfahren zur Herstellung von dreidimensionale optische Effekte aufweisenden Beschichtungen |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0710508A1 true EP0710508A1 (fr) | 1996-05-08 |
Family
ID=6532503
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95116928A Withdrawn EP0710508A1 (fr) | 1994-11-04 | 1995-10-27 | Procédé pour fabriquer des revêtments ayant des effets optiques tri-dimensionnels |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0710508A1 (fr) |
CA (1) | CA2161816A1 (fr) |
DE (1) | DE4439455A1 (fr) |
FI (1) | FI955264A (fr) |
Cited By (74)
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WO2003000801A2 (fr) | 2001-04-27 | 2003-01-03 | Flex Products, Inc. | Pigments et films magnetiques multicouches |
WO2003029018A1 (fr) * | 2001-10-01 | 2003-04-10 | Paradigma S.R.L. | Transfert d'image avec encre de sublimation et support en forme de feuille pour l'executer |
WO2003053593A2 (fr) * | 2001-12-20 | 2003-07-03 | Honeywell International Inc | Encres et revetements a coloration physique |
EP1398296A2 (fr) * | 2002-09-06 | 2004-03-17 | C.R.F. Società Consortile per Azioni | Procédé de production d'une microstructure ou nanostructure tridimensionnelle |
WO2004024836A2 (fr) * | 2002-09-13 | 2004-03-25 | Jds Uniphase Corporation | Paillettes pigmentaires de diffraction d'alignement |
EP1412096A2 (fr) | 2001-05-07 | 2004-04-28 | Flex Products, Inc. | Procedes de production d'articles revetus comportant des images dans lesquels on utilise des pigments magnetiques |
WO2005000585A1 (fr) * | 2003-06-30 | 2005-01-06 | Kba-Giori S.A. | Machine d'impression |
US7047883B2 (en) | 2002-07-15 | 2006-05-23 | Jds Uniphase Corporation | Method and apparatus for orienting magnetic flakes |
WO2006061301A1 (fr) | 2004-12-09 | 2006-06-15 | Sicpa Holding S.A. | Element de securite a aspect dependant de l'angle de vision |
DE102005017544A1 (de) * | 2005-04-16 | 2006-10-19 | Balda Solutions Deutschland Gmbh | Verfahren und Vorrichtung zur Herstellung eines Kunstoffbauteils |
WO2006114289A1 (fr) * | 2005-04-27 | 2006-11-02 | Leonhard Kurz Gmbh & Co. Kg | Procede pour produire des elements createurs d'effet de couleurs |
US7169472B2 (en) | 2003-02-13 | 2007-01-30 | Jds Uniphase Corporation | Robust multilayer magnetic pigments and foils |
EP1787728A1 (fr) | 2005-11-18 | 2007-05-23 | JDS Uniphase Corporation | Plaque magnétique pour imprimer des effets optiques |
US7241489B2 (en) | 2002-09-13 | 2007-07-10 | Jds Uniphase Corporation | Opaque flake for covert security applications |
WO2007089708A2 (fr) * | 2006-02-01 | 2007-08-09 | Basf Catalysts Llc | article plastique comprenant des pigments magnétisables à effet orienté |
US7258915B2 (en) | 2003-08-14 | 2007-08-21 | Jds Uniphase Corporation | Flake for covert security applications |
US7258900B2 (en) | 2002-07-15 | 2007-08-21 | Jds Uniphase Corporation | Magnetic planarization of pigment flakes |
EP1908598A1 (fr) * | 2006-10-04 | 2008-04-09 | Sang Broli Company Limited | Procédé et matériau pour la production de motifs imprimés avec effect tridimensionnel |
US7517578B2 (en) | 2002-07-15 | 2009-04-14 | Jds Uniphase Corporation | Method and apparatus for orienting magnetic flakes |
US7604855B2 (en) | 2002-07-15 | 2009-10-20 | Jds Uniphase Corporation | Kinematic images formed by orienting alignable flakes |
US7667895B2 (en) | 1999-07-08 | 2010-02-23 | Jds Uniphase Corporation | Patterned structures with optically variable effects |
US7674501B2 (en) | 2002-09-13 | 2010-03-09 | Jds Uniphase Corporation | Two-step method of coating an article for security printing by application of electric or magnetic field |
US7691468B2 (en) | 2003-07-03 | 2010-04-06 | Sicpa Holding S.A. | Method and means for producing a magnetically induced design in a coating containing magnetic particles |
US7729026B2 (en) | 2002-09-13 | 2010-06-01 | Jds Uniphase Corporation | Security device with metameric features using diffractive pigment flakes |
WO2010115928A2 (fr) | 2009-04-07 | 2010-10-14 | Sicpa Holding Sa | Element piézochrome de sécurité |
US7876481B2 (en) | 1999-07-08 | 2011-01-25 | Jds Uniphase Corporation | Patterned optical structures with enhanced security feature |
WO2011012520A2 (fr) | 2009-07-28 | 2011-02-03 | Sicpa Holding Sa | Feuille de transfert comprenant un pigment magnétique optiquement variable, procédé de fabrication, utilisation dune feuille de transfert, et article ou document la comprenant |
EP2314386A1 (fr) | 2009-10-22 | 2011-04-27 | manroland AG | Dispositif et procédé de revêtement |
US7934451B2 (en) | 2002-07-15 | 2011-05-03 | Jds Uniphase Corporation | Apparatus for orienting magnetic flakes |
WO2011107527A1 (fr) | 2010-03-03 | 2011-09-09 | Sicpa Holding Sa | Filet ou bande de sécurité comprenant des particules magnétiques orientées dans de l'encre et procédé et moyen permettant de produire le filet ou la bande de sécurité |
US8025952B2 (en) | 2002-09-13 | 2011-09-27 | Jds Uniphase Corporation | Printed magnetic ink overt security image |
US8118963B2 (en) | 2002-09-13 | 2012-02-21 | Alberto Argoitia | Stamping a coating of cured field aligned special effect flakes and image formed thereby |
US8246735B2 (en) | 2006-05-12 | 2012-08-21 | Sicpa Holding Sa | Coating composition for producing magnetically induced images |
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US8343615B2 (en) | 2002-07-15 | 2013-01-01 | Jds Uniphase Corporation | Dynamic appearance-changing optical devices (DACOD) printed in a shaped magnetic field including printable fresnel structures |
US8557403B2 (en) | 2006-10-17 | 2013-10-15 | Sicpa Holding S.A. | Method and means for magnetically transferring indicia to a coating composition applied on a substrate |
WO2014086556A1 (fr) | 2012-12-07 | 2014-06-12 | Sicpa Holding Sa | Compositions d'encre à séchage par oxydation |
US8999616B2 (en) | 2002-09-13 | 2015-04-07 | Jds Uniphase Corporation | Taggent flakes for covert security applications having a selected shape |
WO2015086257A1 (fr) | 2013-12-13 | 2015-06-18 | Sicpa Holding Sa | Procédé de production de couches à effets |
US9102195B2 (en) | 2012-01-12 | 2015-08-11 | Jds Uniphase Corporation | Article with curved patterns formed of aligned pigment flakes |
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WO2016016028A1 (fr) | 2014-07-30 | 2016-02-04 | Sicpa Holding Sa | Procédés commandés par courroie permettant de produire des couches à effet optique |
WO2016026896A1 (fr) | 2014-08-22 | 2016-02-25 | Sicpa Holding Sa | Appareil et procédé de production de couches à effet optique |
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US11768321B2 (en) | 2000-01-21 | 2023-09-26 | Viavi Solutions Inc. | Optically variable security devices |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19860093B4 (de) * | 1998-12-23 | 2008-10-09 | Giesecke & Devrient Gmbh | Echtheitsmerkmalskombination für Wertdokumente |
DE102010009977A1 (de) * | 2010-03-03 | 2011-09-08 | Giesecke & Devrient Gmbh | Sicherheitselement mit ausgerichteten Magnetpigmenten |
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DE3938055A1 (de) | 1989-11-16 | 1991-05-23 | Merck Patent Gmbh | Mit plaettchenfoermigen pigmenten beschichtete materialien |
EP0556449A1 (fr) * | 1992-02-21 | 1993-08-25 | Hashimoto Forming Industry Co., Ltd. | Peinture avec dessins faits magnétiquement et objets peints ayant des dessins formés magnétiquement |
DE4313541A1 (de) | 1993-04-24 | 1994-10-27 | Basf Ag | Magnetisierbare Glanzpigmente |
DE4340141A1 (de) | 1993-11-25 | 1995-06-01 | Basf Ag | Magnetisierbare Glanzpigmente |
DE4419173A1 (de) | 1994-06-01 | 1995-12-07 | Basf Ag | Magnetisierbare mehrfach beschichtete metallische Glanzpigmente |
-
1994
- 1994-11-04 DE DE19944439455 patent/DE4439455A1/de not_active Withdrawn
-
1995
- 1995-10-27 EP EP95116928A patent/EP0710508A1/fr not_active Withdrawn
- 1995-10-31 CA CA 2161816 patent/CA2161816A1/fr not_active Abandoned
- 1995-11-02 FI FI955264A patent/FI955264A/fi unknown
Patent Citations (13)
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US2570856A (en) | 1947-03-25 | 1951-10-09 | Du Pont | Process for obtaining pigmented films |
BE678945A (fr) * | 1965-04-15 | 1966-10-04 | ||
FR2069355A5 (fr) * | 1969-11-14 | 1971-09-03 | Emi Ltd | |
DE2006848A1 (en) * | 1970-02-14 | 1971-09-02 | Magnetfabrik Bonn GmbH, vormals Gewerkschaft Windhorst, 5300 Bonn Bad Godesberg, Weilburger Lackfabrik, J Grebe, 6290 Weilburg | Magnetic loaded varnish for prodn of pat-terns |
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Also Published As
Publication number | Publication date |
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FI955264A (fi) | 1996-05-05 |
DE4439455A1 (de) | 1996-05-09 |
CA2161816A1 (fr) | 1996-05-05 |
FI955264A0 (fi) | 1995-11-02 |
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