EP0699157A1 - Verpackungssystem für nahrungsmittel mit erhöhter haltbarkeit - Google Patents

Verpackungssystem für nahrungsmittel mit erhöhter haltbarkeit

Info

Publication number
EP0699157A1
EP0699157A1 EP94918018A EP94918018A EP0699157A1 EP 0699157 A1 EP0699157 A1 EP 0699157A1 EP 94918018 A EP94918018 A EP 94918018A EP 94918018 A EP94918018 A EP 94918018A EP 0699157 A1 EP0699157 A1 EP 0699157A1
Authority
EP
European Patent Office
Prior art keywords
die
package
apparams
trays
tray
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP94918018A
Other languages
English (en)
French (fr)
Other versions
EP0699157B1 (de
Inventor
Michael P. Gorlich
Robert F. Mcpherson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
World Class Packaging Systems Inc
Original Assignee
World Class Packaging Systems Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/064,700 external-priority patent/US5348752A/en
Priority claimed from US08/098,530 external-priority patent/US5419096A/en
Priority claimed from US08/154,756 external-priority patent/US5419097A/en
Priority claimed from US08/221,194 external-priority patent/US5439132A/en
Application filed by World Class Packaging Systems Inc filed Critical World Class Packaging Systems Inc
Priority to EP99109931A priority Critical patent/EP0949147A1/de
Priority to EP98122058A priority patent/EP0899209B1/de
Publication of EP0699157A1 publication Critical patent/EP0699157A1/de
Application granted granted Critical
Publication of EP0699157B1 publication Critical patent/EP0699157B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • B65D81/245Internal membrane, floating cover or the like isolating the contents from the ambient atmosphere
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B25/00Packaging other articles presenting special problems
    • B65B25/06Packaging slices or specially-shaped pieces of meat, cheese, or other plastic or tacky products
    • B65B25/065Packaging slices or specially-shaped pieces of meat, cheese, or other plastic or tacky products of meat
    • B65B25/067Packaging slices or specially-shaped pieces of meat, cheese, or other plastic or tacky products of meat combined with its conservation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B31/00Packaging articles or materials under special atmospheric or gaseous conditions; Adding propellants to aerosol containers
    • B65B31/02Filling, closing, or filling and closing, containers or wrappers in chambers maintained under vacuum or superatmospheric pressure or containing a special atmosphere, e.g. of inert gas
    • B65B31/025Filling, closing, or filling and closing, containers or wrappers in chambers maintained under vacuum or superatmospheric pressure or containing a special atmosphere, e.g. of inert gas specially adapted for rigid or semi-rigid containers
    • B65B31/028Filling, closing, or filling and closing, containers or wrappers in chambers maintained under vacuum or superatmospheric pressure or containing a special atmosphere, e.g. of inert gas specially adapted for rigid or semi-rigid containers closed by a lid sealed to the upper rim of the container, e.g. tray-like container
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B7/00Closing containers or receptacles after filling
    • B65B7/16Closing semi-rigid or rigid containers or receptacles not deformed by, or not taking-up shape of, contents, e.g. boxes or cartons
    • B65B7/168Closing semi-rigid or rigid containers or receptacles not deformed by, or not taking-up shape of, contents, e.g. boxes or cartons by applying and securing double closures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D51/00Closures not otherwise provided for
    • B65D51/18Arrangements of closures with protective outer cap-like covers or of two or more co-operating closures
    • B65D51/185Arrangements of closures with protective outer cap-like covers or of two or more co-operating closures the outer closure being a foil membrane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D77/00Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
    • B65D77/10Container closures formed after filling
    • B65D77/20Container closures formed after filling by applying separate lids or covers, i.e. flexible membrane or foil-like covers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D77/00Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
    • B65D77/22Details
    • B65D77/30Opening or contents-removing devices added or incorporated during filling or closing of containers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/18Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
    • B65D81/20Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas
    • B65D81/2069Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas in a special atmosphere
    • B65D81/2076Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas in a special atmosphere in an at least partially rigid container
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2251/00Details relating to container closures
    • B65D2251/0003Two or more closures
    • B65D2251/0006Upper closure
    • B65D2251/0031Membrane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2251/00Details relating to container closures
    • B65D2251/0003Two or more closures
    • B65D2251/0068Lower closure
    • B65D2251/0093Membrane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2565/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D2565/38Packaging materials of special type or form
    • B65D2565/381Details of packaging materials of special type or form
    • B65D2565/388Materials used for their gas-permeability

Definitions

  • This invention relates to machines for packaging food products, packages and related methods such that the packaged product may be maintained in one condition under certain circumstances and then converted to another condition.
  • the food package might maintain an inert gaseous atmosphere and then, when the package reaches a supermarket or other retail outlet, the food package will permit exposure of the food product to the ambient atmosphere.
  • it is particularly advantageous in connection with the packaging of meat in a modified atmosphere package such that the meat may be transported in a relatively inert atmosphere and then caused to bloom when it reaches a retail outlet by exposure to oxygen.
  • the upper cover is gas impermeable and may be removed to expose a lower cover that is air permeable.
  • the package may be shipped with the upper cover intact so that a inert gaseous atmosphere may be maintained within the package during shipping.
  • the upper cover may be removed at the supermarket leaving the lower cover. Since the lower cover is oxygen permeable, it allows the meat to bloom in the presence of oxygen.
  • Domed meat packages have been used in the past to contain large cuts of meats such as chickens or roasts. However, these packages have suffered from a number of drawbacks.
  • the shelf life of the food product can be extended from a few days to as long as two weeks or more perhaps.
  • the customer In order to make the customer feel comfortable with the food packaging, the customer should be able to view a substantial portion of the food product. In order to maintain a desired atmosphere around the package, a package which is somewhat larger than the food product is required. However, with a large, relatively heavy meat product it is difficult to allow for spacing around the food product and yet maintain the product in an attractive fashion within the container.
  • the spacing becomes visible to the consumer. The consumer may believe that the package is too large and wasteful. Moreover, if the product is substantially larger than the food product, the food product may move around during transportation and handling, and the package itself may be indented or otherwise damaged.
  • deep draw packages may have been used for this type of packaging.
  • deep draw packages become difficult to form at large sizes and may experience significant deformation of the packaging material.
  • These packages are particularly susceptible to the formation of thin spots and to the indenting and collapsing of the corner regions.
  • the present applicant has appreciated that it would be desirable to form a domed package rather than to use the deep draw plastic forming technique.
  • the product may protrude above the sealing flanges that connect the upper and lower package portions.
  • the package portions may be formed from different materials adapted to particular packaging needs. For example, it may be desirable to form the bottom portion out of foam material and the top out of transparent plastic.
  • an apparatus for making modified atmosphere packages that includes a plurality of packaging stations. Among these stations is at least one station for loading a food product into a tray. A rotary conveyor moves the trays from one station to the next. The rotary conveyor includes a platform for carrying a plurality of trays. One of the packaging stations is adapted to load the trays on the platform. Another one of the stations is adapted to unload the trays from the platform. An apparatus is included for replacing die ambient atmosphere in the trays with an atmosphere reduced in oxygen content before covering the trays with a packaging film.
  • a method for making modified atmosphere packaging includes the step of loading a plurality of trays onto a rotary conveyor.
  • the trays are indexed between a plurality of stations arranged in a circular path.
  • the atmosphere within a tray is withdrawn after a food product has been added.
  • the tray is covered with a film to maintain an atmosphere reduced in oxygen content within the tray.
  • the trays are thereafter unloaded from the rotary conveyor.
  • a pliant first membrane is sealed to a tray.
  • a pliant second membrane is sealed to the tray over the first membrane.
  • the membranes are secured to the tray at separate locations on the tray.
  • the membranes are substantially coplanar with one another and are removable from the tray independently of each other.
  • Figure 1 is a plan view of one embodiment of a package 10 in accordance with the present invention.
  • Figure 2 is an enlarged side cross-sectional view of the package 10, taken along the line 2-2 of Figure 1;
  • Figure 3 is a plan view of another embodiment of the package 10 in accordance with the present invention.
  • Figure 4 is an enlarged side cross-sectional view of the package 10, taken along the line 3-3 of Figure 3;
  • Figure 5 is a schematic view showing a method for assembling the package 10 of Figure 1;
  • Figure 6 is a cross-sectional view taken generally along the line 6-6 in Figure 7;
  • Figure 7 is a front elevational view of the embodiment shown in Figure 6;
  • Figure 8 is an enlarged top plan view of a portion of the embodiment shown in Figure 6, showing the loading area receiving trays to be packaged;
  • Figure 9 is a front elevational view of the portion shown in Figure 8.
  • Figure 10 is a front elevational view corresponding to that shown in Figure 9 after a row of trays has been positioned atop a receiving platform;
  • Figure 11 is a top plan view of the portion shown in Figure 10;
  • Figure 12 is a vertical, cross-sectional view partially broken away so as to show two rather than four stations and with vacuum and gas supplying means removed;
  • Figure 13 is a view corresponding to Figure 12 after the platform has been removed from the rotary arms;
  • Figure 14 is an enlarged, plan view of d e quick disconnect tooling at the station 122c;
  • Figure 15 is an enlarged, cross-sectional view taken generally along the line 15-15 in Figure 14;
  • Figure 16 is a partial, side elevational view of the unloading station
  • Figure 17 is a partial, side elevational view of the unloading station after a platform has been raised to an "up" position;
  • Figure 18 is a top plan view of the embodiment shown in Figure 17 after the trays have been pushed onto the unloading conveyor;
  • Figure 19 is an enlarged, partial, cross-sectional view of the bottom of the surge tank
  • Figure 20 is a simplified cross-sectional view showing three stages in one embodiment of a packaging process in accordance with the present invention.
  • Figure 21 is a partial, enlarged, top plan view of the package shown in Figure 20a;
  • Figure 22 is a partial, enlarged, top plan view of d e package shown in Figure 20b;
  • Figure 23 is an enlarged, cross-sectional view of one embodiment of a packaging apparatus for accomplishing the process steps shown in Figure 20b;
  • Figure 24 is an enlarged, cross-sectional view of the packaging apparatus of Figure 23, shown in position to accomplish the process steps shown in Figure 20c; and Figure 25 is an enlarged, top plan view of anotiier embodiment of me package shown in the position illustrated in Figure 20b.
  • a package 10 for containing one or more food products "A" is shown ( Figures 1-2).
  • the package 10 is especially advantageous for containing red meat.
  • the package 10 includes a relatively rigid tray 12, a more permeable membrane 14, and a less permeable membrane 16.
  • the membranes 14 and 16 are peripherally connected to the tray 12.
  • the tray 12 may be made of a relatively rigid plastic, formed by thermomolding or the like.
  • the tray is preferably made of a material which is gas impermeable, and may be composed of a single polymeric sheet such as poly vinyl chloride, nylon, fluorohalocarbon, polyurethane or a composite of polymeric materials including: PVC; PVC and polyolefin; PVC and saran; PVC and saran and polyolefin; PVC, saran, ethylenevinylacetate copolymer; polystyrene, saran and polyolefin; polystyrene, saran and copolymer; nylon, saran, polyolefin; polyolefin, saran and polyethylene; polyester, saran, polyolefin; polycarbonate, saran and polyolefin; or many other materials which are well known in the art.
  • the tray 12 is preferably formed of a material that forms
  • the tray 12 is shown in the illustrated embodiment as being generally rectangular, other shapes of the tray 12, such as a round form (not shown), are contemplated in accordance with the invention.
  • the tray 12 includes a curved base 18 which defines a cavity for receiving the food product A, and a double flanged edge 20 which extends around die periphery of the base 18.
  • the double flanged edge 20 defines a pair of ledges 22 and 24 separated by a trough 26.
  • the outermost edge 28 of the flange 20 may be turned downwardly.
  • the base 18 and the flange 20 may be molded as a single piece.
  • upper surfaces of me ledges 22 and 24 may be positioned in a single plane, such mat the ledges 22 and 24 and die membranes 14 and 16 provide a substantially flat surface on top of the package 10.
  • the tray 12 may be formed from a porous, foam-like material that is heat pressed to ensure uniformity in the height of the ledges 22, 24 and die thickness of the tray 12.
  • the more permeable layer 14 preferably comprises a flexible, resilient material such as a pliant plastic substance, to permit gaseous exchange therethrough as required by the particular application. In connection with the blooming of red meat, it is generally desirable that the more permeable membrane 14 be highly transmissive of ambient atmosphere.
  • materials are capable of acting as the membrane 14, including polyvinyl chloride, polycarbonate, cellophane, polypropylene, poly ethy lene, polyethylene copolymers, ionomer film or any other gas permeable materials which are well known in the art.
  • the membrane 14 may also be constructed of microporous films which have holes formed either chemically or mechanically. The membrane 14 need only be sufficiently strong to prevent perforation in use.
  • the membrane 14 is secured to me tray 12 at the inner ledge 24.
  • me film is "sealed" to me tray, signifying that it is heat fused or adhesively secured to d e tray as opposed to being frictionally connected diereto.
  • a trough 26 is defined between the ledges 22 and 24, a trough 26 is defined. The trough 26 aids in securing the membrane 14 to the inner ledge 24.
  • tiiat the trough 26 may assume a "V"-shape, a semi-circular shape, a rectangular shape, or another suitable shape that may be desired for aesmetic, functional, or other reasons.
  • the less permeable membrane 16 also preferably comprises a flexible, resilient material such as a pliant plastic substance.
  • the membrane 16 is preferably selected from a group of materials that are relatively less gas permeable, such as polyester, nylon, cellophane, polypropylene, polyvinyl acetate, saran, or combinations of these materials.
  • the less permeable membrane 16 is impermeable to gases.
  • the less permeable membrane 16 is removably secured to me outer ledge 22, again by heat sealing, adhesive techniques, or omer techniques known in the art.
  • the membrane 16 may be trimmed by moving a cutting press downward tiirough the membrane 16, at a position outward from the outermost edge 28 as explained later.
  • me membrane 16 may be trimmed before sealing it to the outer ledge 22.
  • the membrane 16 is preferably trimmed to leave an overhang 19, to facilitate later removal of the membrane 16 by lifting the overhang 19 and peeling the membrane 16 back from its connection to the outer ledge 22.
  • the less permeable membrane 16, when secured to the ledge 22, is totally free of any connection to the more permeable membrane 14, except frictional connection or indirect connection through the tray 12. This facilitates the convenient removal of the less permeable membrane 16 from the package while leaving the more permeable membrane 14 in place and undisturbed. Aldiough the membranes 14, 16 are not connected to each other, the membranes 14, 16 are substantially coplanar to each other, in face to face abutment, each advantageously being under slight resilient tension. After both the membranes 14 and 16 are secured to the tray 12, a desirable atmosphere may be maintained witi in the package 10 for the benefit of the food product A contained therein. This may be done by sealing the package closed in me desired atmosphere.
  • the initial atmosphere in some embodiments may contain a relatively low concentration of oxygen.
  • gases including substantial concentrations of carbon dioxide or nitrogen may be maintained with the package to reduce the exposure of the food product A to oxygen.
  • the package 10 exists wid out the less permeable membrane 16, and includes only die more permeable membrane 14 and me tray 12.
  • the red meat product A can be caused to turn red or bloom in me presence of a higher concentration of oxygen.
  • bom membranes 14, 16 may be formed from substantially impermeable materials, for use in certain applications. This arrangement may be useful, for example, to provide alternative labeling schemes. Wim such an embodiment, me lower membrane may contain a label of a supermarket or other retail store, such as an advertising label; the upper membrane, on me other hand, may display a label from an initial meat packer, providing instructions to the retail butcher ra ier man the ultimate buyer of me meat. Then the outer membrane 16 may be easily removed relative to me inner membrane 14.
  • mis embodiment contemplates a ledge 52, surrounded by a recessed lip 54 having an outermost edge 56.
  • die more permeable membrane 14 is first secured to die ledge 52, and men trimmed by moving a cutting press downwardly d rough the membrane 14 at a position radially outward from the ledge 52, as permitted by the recessed lip 54.
  • the less permeable membrane 16 is stretched over die tray 12 and adhered to d e lip 54.
  • the less permeable membrane 16 is trimmed by moving a cutting press (not shown) downward dirough die membrane 16 at a position outward from die outermost edge 56.
  • d e less permeable membrane 16 is provided witii a larger surface area than the more permeable membrane 14, such that die membrane 16 overlaps the membrane 14.
  • the membrane 16 may be cut to provide an overhang 58, such mat die less permeable membrane 16 may be easily removed by lifting die overhang 58 and peeling the membrane 16 back from its connection wim the edge 56.
  • d e membranes 14, 16 are substantially coplanar with each other, in face to face abutment, each being under slight resilient tension.
  • me desired atmosphere may be maintained witiiin the package 10, in the same manner as described above in conjunction wim die previous embodiment.
  • the less permeable membrane 16 may be removed by conveniendy grasping the overhang 58 of die membrane 16 in pulling it upward. Thereafter, the package 10 exists without the less permeable membrane 16 and includes only the more permeable membrane 14 and die tray 12, as with me embodiment described previously.
  • FIG 5 an exemplary process for forming the package 10 will be explained. Starting at the right side of Figure 5, a tray 12, held from below in a rigid conforming carrier 60, is filled in a conventional fashion with a food product A.
  • the package 10 is evacuated of oxygen and gas back-filled widi a transportation gas which is lower in oxygen content.
  • a web 70 of the more permeable membrane 14 is unwound from a pair of rolls 62 and 64 and positioned over the tray 12.
  • the more permeable web 70 is secured to die inner ledge 24, for example by a heat sealing machine 66.
  • a conventional cutting press 68 is used to cut die web 70.
  • the web 70 is cut at a position adjacent to die trough 26.
  • the web 70 is cut at a position over the recessed lip 54, d e lip itself acting as a trough or depression.
  • me trough 26 or lip 54 facilitates the removal or cutting of the membrane 14 from the web 70 in place on d e package 10.
  • the web 70 may also be severed by using heat or ultrasonic energy or the like.
  • a web 76 of the less permeable material 16 is unrolled from a pair of rolls 72, 74 so that die less permeable web 76 may be positioned on me package 10.
  • die less permeable web 76 is secured to d e ledge 22.
  • the less permeable web 76 is secured to die outermost edge 56.
  • d is securing is performed using conventional techniques, such as using a heat sealing machine 42.
  • d e transportation gas is sealed inside the package 10.
  • the web 76 is cut by conventional cutting equipment 78. In me embodiment of Figures 1-2, the cutting occurs slightly outward from the edge 28.
  • the cutting occurs slightly outward from the outer edge 56. This leaves an overhanging piece 19 or 58 of me less permeable material 16 which may be grasped by the user to remove the membrane 16 when desired.
  • the package may be shipped to locations for retail sale. At the retail establishment, the package is held until the package is ready to be displayed. At tiiat point, the less permeable membrane 16 is peeled away and discarded. After a short holding period, d e package may be displayed for retail sale. The holding period is necessary to allow die package to absorb oxygen through the more permeable membrane 14. After the meat product has bloomed, it can be displayed for retail sale.
  • botii membranes 14, 16 may be attached to d e same tray 12 in a fashion that permits high speed manufacture. While the simplified process depicted in Figure 5 suggests that d e material may be packaged in a serial fashion, mis approach would likewise apply to conventional packaging equipment.
  • die more permeable membrane is sufficient to maintain the desired gaseous environment in the package until die less permeable membrane is in place. This is especially true with high speed systems. However, in some circumstances it may be useful to provide a particular gaseous atmosphere between the stations where the more permeable and less permeable membranes are applied.
  • a packaging machine 120 includes four stations 122. While the machine is illustrated in a four-station embodiment, it should be understood that one or more of the indicated stations may be unused and diat in any particular embodiment it may be possible or desirable to have more or less than four stations.
  • the four stations 122 operate on packages which are moved circularly from one station to the next.
  • the packages to be produced are held on a platform 124 which in the illustrated embodiment includes slots 126 to receive four package trays.
  • a variety of package types may be utilized including diose described herein.
  • the platforms 124 are carried on mounting arms 128 which in turn connect to rotatable ring 130.
  • the ring 130 is driven by the mechanism 132 which may be of any conventional type but is illustrated as being a drive chain and motor arrangement.
  • Base 134 also supports a surge tank 138, which in mm supports a hanger assembly 140.
  • the surge tank 138 provides a central support for mounting the ring 130 and drive mechanism 132.
  • the base 134 and hanger assembly 140 may be utilized to support various equipment positioned at die stations 122 for operating on the food trays contained witinin the platform 124.
  • a tray load mechanism 142 is associated witii the station 122a and supported on die base 134.
  • a tooling assembly 144 includes an upper portion 146 mounted on die hanger 140 and a lower portion 148 mounted on die base 134.
  • the upper portion 146 includes a housing or chamber 147 and die lower portion 148 includes a housing or chamber 149.
  • the tray load mechanism 142 includes a tray conveyor 150 and a tray loader 152.
  • the conveyor 150 may be a conventional belt conveyor wherein the trays 155 are motioned onto die tray conveyor 150. They are aligned by a stop bar 154 powered by a cylinder 156. At me appropriate interval, the trays 155 may be advanced to a second stop bar 158 so mat the position previously occupied by the trays 155 may be filled by additional trays.
  • the stop bar 158 is controlled by a second cylinder 160.
  • the trays 155 may be pre-loaded widi d e food product to be packaged. Below the platform 124a, there is a cylinder 162 diat powers a bed 164 upwardly and downwardly.
  • the bed 164 includes a stop 166 on its inward end. Each bed 164 is designed to receive a tray 155 from the tray conveyor 150 and to lower it into a platform slot 126. Thus, mere would be a plurality of mechamsms 160 and 164, one for each of d e slots 126 in a platform 124a.
  • me station 122b is an inactive station which is not used. However, in me other applications, it may be desirable or necessary to perform all or part of the operation which is done at anodier station at the station 122b.
  • the station 122b could be used, for example, to load die food product into the trays 155.
  • the station 122c includes a tooling assembly 144 made up of an upper portion 146 and a lower portion 148.
  • me upper chamber 147 is mounted on a mechanism 168 which allows it to be raised and lowered towards and away from the platform 124.
  • me lower chamber 149 is mounted on a mechanism 170 which raises and lowers die lower portion 148 towards the underside of die platform 124. If desired, eidier die upper chamber 147 or lower chamber 149 may be stationary.
  • FIG. 12 The mounting of a platform 124 on die arms 128 is shown in Figures 12 and 13. As shown in Figure 12, the platform 124 is mounted on me arms 128 by a plurality of upstanding pins 172. Each pin 172 includes a tapered upper portion 174 which fits in a mating tapered portion 176 in the underside of die platform 124. Thus, me platform 124 is removably located on d e arms 128 by way of the pins 172.
  • the lower chamber 149 includes a pair of upstanding pins 178 with tapered portions 180 which mate in holes 182 in the platform 124. Thus, when me lower chamber 149 moves upwardly to engage me platform 124, the tapered portions
  • the configuration of the upper and lower portions 146 and 148 of die tooling assembly 144, shown in Figure 15, includes a sealer 186, a cutter 188, and a web winding system 190.
  • the web 192 may be unrolled from a roll 194, processed inside d e tooling assembly 144 and transferred to a waste roll 196.
  • the film 192 may be made of any plastic film used for food packaging including composite films of plastic, aluminum foil, paper, or cardboard.
  • Wim me film 192 positioned over die tray 155 it may be sealed by the sealer 186 which is mounted on a shaft 208.
  • the seal bar may be telescopically reciprocated up and down at die appropriate times in order to seal the film 192 to the tray 155.
  • a wide variety of sealers 186 may be utilized, however one conventional sealer uses electrical resistance heaters 200 in order to heat seal the film to the tray 155.
  • the extent of upward and downward movement of the shaft 208 is controlled by the medial stops 202 under me influence of a conventional fluid energy source.
  • the medial stops 202 are part of a tube 198 which is sealing secured to d e shaft 208.
  • the sealer 186 may be removed from the mechanism for repair or cleaning when desired simply by unthreading die nut 206. When diis is done, die shaft 208 and sealer 186 may be removed downwardly from the mechanism.
  • the cutter 188 includes a pair of blades 210 positioned to enter die recess 212 in the platform 124. These blades cut me film 192 completely around d e upper circumference of the tray so that it conforms to the configuration of the tray
  • the cutter 188 reciprocates upwardly and downwardly around die sealer 186. It is controlled by stops 214 on arms 216 under die influence of a conventional fluid energy source.
  • the cutter 188 also includes an internal coolant circulation passage 218. Connected to a source of external cooling liquid, the passage 218 provides a medium for cooling the cutter 188.
  • the cutter 188 in close proximity to the sealer 186, is subject to possible heat related malfunctions. By cooling die cutter 188, die precision of the cutting operation may be maintained even in a relatively hot environment.
  • the lower chamber 149 contains a gas exchange passage 230 in its lower surface, while the upper chamber 147 includes a gas exchange passage 232 in its side wall.
  • the lower portion 148 may include filler 234.
  • Each platform 124 includes a plurality of gas exchange passages 236.
  • the gas exchange passage 232 communicates wim a vacuum source by way of me quick disconnect device 238, shown in Figure 14. That device is secured to d e upper chamber 146 by threaded knobs 240. Similarly, device 242 is connected by d readed knobs 244 to lower chamber 149 to provide gas exchange via opening 230.
  • connection to the upper and lower portions 146 and 148 are all of the quick disconnect variety so that die machinery associated widi any particular station 122 may be readily removed from the remainder of die machine 120.
  • connections for power and fluid may likewise be of the quick disconnect variety.
  • die connections such as those shown at 220 may be disconnected by simply pulling mem apart or unscrewing them and dien the mechanisms 246 holding d e upper and lower chambers 147 and 149 may be disconnected in the same fashion so mat me upper and lower chambers 147 and 149 may be quickly removed.
  • the unloading station 122d shown in Figure 16, includes an unloading conveyor 226 and a tray pusher 228.
  • the trays 155 in a platform 124 are pushed upwardly by the cylinder 230 of d e pusher 228. Then the trays are pushed laterally by die slider 232 powered by cylinder 234. The trays are pushed onto die conveyor 226 as indicated in Figure 13.
  • the machine is operated generally as follows. Initially, a plurality of trays 155 are organized on d e conveyor 150 of the tray load assembly 142. As indicated in Figures 8 and 9, die trays are formed into two rows of four trays through the operation of the stop bars 154 and 158. Trays are originally allowed to ride up against stop bar 158 so mat tiiey slide relative to the rotating conveyor 150. A second row of trays dien back up to the first row of trays.
  • the second stop bar 158 is lowered allowing me first row of trays to pass on to the bed 164.
  • Each bed 164 is tiiereafter lowered so diat each tray 155 is held in a slot 126 in the platform 124.
  • the platform 124 is rotated 90 degrees to die station 122b. Thereafter, me stop bar 158 is operated to allow die second row of trays 155 to be loaded into a subsequent platform 124 rotated into station 122a from station 122d. From station 122b, die platform 124 rotates into die station 122c as shown in Figure 6.
  • This atmosphere is preferably one which is reduced in oxygen content to extend die life of die packaged food product.
  • die film 192 may be heat sealed to die tray 155 using d e sealer 186.
  • This operation may be a conventional heat sealing operation.
  • the sealer 186 reciprocates downwardly under die control of the stops 202 in response to changing fluid pressure in die chamber 203.
  • die film is cut by cutter 188.
  • the cutter 188 reciprocates downwardly to cut die film 192, eventually entering the recess 212.
  • the movement of me cutter 188 is controlled by d e fluid pressure in the chamber 217.
  • die desired atmosphere may be sealed into d e package.
  • odier gas exchange techniques may be utilized as well.
  • die atmosphere inside die assembly 144 is reduced in oxygen content so that the food product will have a longer useful life.
  • the operation of the cutter 188 may be adversely affected by die ambient heat within me assembly 144 which is greatly augmented by die heat created by die heat sealing operation. This heat may distort the cutting blades and cause inaccuracies therein. For this reason, a source of cooling fluid, for example water, may be circulated through the passage 218 so as to cool die cutter 188.
  • a source of cooling fluid for example water
  • Trays 155 are then advanced to d e next station 126d.
  • the trays 155 are positioned over the tray pushers 228 and cylinders 230. At die appropriate time, one or more trays 155 are pushed upwardly dirough the action of die cylinders 230 and pushers 228 as shown in Figure 17. Thereafter, me trays may be pushed laterally by the slider 232 and its cylinder 234 as shown in Figure 18. Then the trays may be taken away from the rotary conveyor by the unloading conveyor 226.
  • the rotary arrangement die central area may be occupied by die conveniently located surge tank 138.
  • This tank supplies a source of fluid pressure for die various operations in the surrounding rotary conveying apparams.
  • the tank 138 is normally closed by caps 254 on botii ends. As shown in Figure
  • a drain 252 is provided at die bottom of the surge tank 138 for releasing a sanitizing solution.
  • the drain may be closed by a removable cover 256.
  • the interior of the tank 138 may be washed widi the bacteriostatic solution to minimize bacteria transfer to the packaging.
  • the tank 138 also provides die support for the drive mechanism 132 and rotatable ring 130.
  • any particular station may be easily accessed for removal from the rest of die machine. Any particular station may be easily replaced with a more appropriate station for any particular operation. Also, a malfunctioning apparatus may be replaced wi i a working apparams. Because of me rotary arrangement, access to die individual stations for repair is facilitated.
  • Repair and replacement is also facilitated by making the various connections to the stations for electrical and fluid power of the quick disconnect variety. Moreover, by making the means of attachment of the particular apparams to each station of a quick disconnect variety it is possible to change stations quickly to convert die machine for other uses or to replace a broken piece of equipment.
  • step a the food product "A" is shown contained within a dish-shaped plastic package portion 310 which is supported by a peripheral flange 312 on a member 314.
  • the package portion 310 may be formed of a variety of conventional materials including any known plastic packaging material. In many instances, it may be desirable to form the lower package portion 310 of molded foamed plastic so that the package portion will be relatively rigid.
  • an upper package portion 318 is shown in spaced relation to die lower package portion 310 over the food product "A".
  • the package portion 318 is domed and includes a peripheral flange 320.
  • the upper package portion 318 may be formed of a variety of conventional plastic materials. However, in many instances, it may be desirable to form the upper package portion 318 out of relatively rigid, molded transparent plastic material. This allows the food product "A" to be viewed widiin d e food package.
  • botii die portions 310 and 318 are preformed of relatively rigid, molded plastic material.
  • me upper and lower package portions 318 and 310 may be joined along their peripheral flanges 320 and 312 by an apparams 322 which presses die flanges 320 of the portion 318 downwardly onto die flanges 312 of die package portion 310.
  • die apparams 322 may be a heat seal machine which causes heat sealing of me juxtaposed flange portions thereby connecting the materials.
  • the advantage of holding the upper domed portions 318 in spaced juxtaposition witii the lower portion 310 is tiiat die gaseous environment within die package may be transformed prior to die sealing step c shown in Figure 20.
  • the air inside die package may be exhausted, and a desired gas may be supplied in its place.
  • the desired gas may be one which is relatively low in oxygen content so that die shelf life of die food product may be extended.
  • the gas may be relatively higher in either carbon dioxide and/or nitrogen than normal atmospheric air in order to prevent or diminish the oxidation processes that shorten the life of the meat product "A".
  • me lower package portion 310 may be maintained in a desired arrangement by a set of two pairs of opposed guides 324.
  • Each of the guides 324 is arranged in a substantially tangential arrangement to die curved sides of die lower package portion 310 so as to abut wid die sealing region 326.
  • the sealing region 326 provides die point of attachment to me upper package portion 318.
  • the lower package portion 310 may include an outwardly extending flange portion 328 on either of two opposed ends of d e package 310. While die package 310 shown in Figure 21 has an oblong configuration, the cross-sectional configuration of the package may assume one of a variety of different shapes.
  • Figure 22 shows the positioning of die upper package portion 318 over the lower package portion 310.
  • the upper package portion 318 includes a pair of opposed bluntly pointed end flanges 334 which interact with and are constrained between each set of guides 324.
  • the outwardly extending flange portions 334 extend over the tubes 330 such that die tubes 330 do not generally guide die positioning of the upper package portion 318 in die horizontal plane. This accomplished substantially by die guides 324.
  • die flanges 334 extend past die edges 332 of die flanges 328 so diat there is a region of overhang of the flange 334 over the lower package portion 310.
  • Figure 23 shows a packaging machine for achieving die package operation shown in Figure 20.
  • die package 338 shown in Figure 23 is of a slightly different shape dian the package shown in Figure 20.
  • me lower package portion 310 is deeper than die package portion 310 shown in Figure 20, and me abruptness of both the lower and d e upper package portions 318 and 310 is greater in the embodiment shown in Figure 23.
  • the lower package portion 310 rests in a conforming tray 340 which conforms to its outside configuration and supports the flange 312.
  • the upper package portion 318 has its flange portion 336 resting atop the filling mbe 330.
  • the filling mbe 330 is reciprocal up and down widiin a slot 342. However, the extent of its upward extension is controlled by die overhanging edge 344 of die adjacent guide 324.
  • Each mbe 330 includes an outer cylinder 330a and an inner cylinder 330b.
  • the outer cylinder 330a includes a set of "O" rings 346 which prevent leakage around d e mbe 330.
  • a pin 348 is provided to control the extent of downward movement of the mbe 330 and to prevent its rotation about its lengthwise axis.
  • Widiin the center of die mbe 330 is a bore 350 which is capable of conveying gas to or from the interior of me package to or from the passageway 352. Thus, gas may pass via the passageway 352 to or from the interior of me package shown in d e configuration of Figure 23.
  • a pressurized gas supply passageway 372 is connected to a source (not shown) of pressurized gas.
  • pressurized gas may be communicated via the passageway 372 to act on d e lower end of d e outer cylinder 330a. This causes the mbe 330 to move to its upper position shown in Figure 23.
  • Juxtaposed over die upper pi , ⁇ age portion 318 is a pusher bar 354 and a sealing bar 356.
  • the sealing bar 356 may be a conventional heat sealing bar which heat seals die flanges of me upper package portion 318 to those of die lower package portion 310.
  • the vacuum chamber cover 390 seals to the lower chamber 392 through inner and outer peripheral seals 394 and 396 and die abutment of gasket 398 on the lower chamber 392.
  • a valved passage 400 is provided for pulling a vacuum inside die chamber defined by die cover 390.
  • Figure 25 shows an alternate embodiment in which a gas exchange system is provided on die upper package portion 318.
  • the gas exchange portion 358 is constructed generally as described previously.
  • the portion 358 includes one or more holes 360 formed in the package portion 318. These holes are covered by a first circular plastic film layer 362 which may be permeable to atmospheric air.
  • the layer 362 is sealed to die package portion 318 at 364. Attached over die portion 362 is an upper fluid impermeable plastic film 366 which is sealed at 368 to the upper package portion 318. When desired, the layer 366 may be peeled away to allow gas exchange dirough the lower layer 362 via die holes 360.
  • the method and apparams of the present invention may be implemented in die following fashion.
  • the lower package portion 310, loaded into the conforming tray 340, is supported by its flanges 312.
  • a meat product "A” if not already loaded, may be loaded inside die package portion 310.
  • the relatively rigid top or upper portion 318 is aligned over die lower package portion 310 but resting on the top of die filling tubes 330 as shown in Figure 23.
  • the air within the package is exhausted through both the passage 400 and die bore 350 to the passageway 352.
  • a desired gaseous environment is passed dirough die passageway 352 and die bore 350 into the package.
  • This gaseous environment may be one which is relatively poor in its concentration of oxygen and relatively higher (wid respect to normal ambient atmosphere) with respect to its carbon dioxide and/or nitrogen content.
  • the result of such an environment is to extend die shelf life of a meat product. This is because die presence of oxygen causes the meat product to age and discolor.
  • die gas filling tubes 330 are pushed downwardly by d e pusher bar 354 into their passageways 342 until die pins 348 engage the top of die slots 380.
  • the upper package portion 318 is in abutment wim the lower package portion 310.
  • die sealing regions 326 are likewise in abutment.
  • the package is thereafter sealed along d e regions 326 of die upper and lower package portions 310 and 318 to provide an air tight seal between the two package portions.
  • dirough die sealing bar 356 which may, in one advantageous embodiment, cause heat sealing of me components togemer.
  • the sealing bar 356 reciprocates with d e pusher bar 354.
  • die pusher bar 354 pushes the mbes 330 below the flanges to insure that, regardless of the package thickness, the mbes 330 do not interfere with the sealing process.
  • the completed package 338 may be removed by raising the cover 390 with die sealing bar 356 and pusher bar 354.
  • the package 338 may be removed from the conforming carrier 340. This may be accomplished in batch or continuous fashion as desired.
  • the cycle may be repeated after die gas mbes 330 are reciprocated to d eir upper position. This is achieved by supplying air pressure to die upper cylinders 330a. The air pressure is released dirough a relief valve (not shown) when the mbes 330 are pushed downwardly by die pusher bar 354.
  • the lower package portion 310 is inserted into me conforming carrier 340, guided by mbes 330 and guides 324. Then, die upper package portion 318 is located on die mbes 330, positioned by die guides 324. Thereafter, the cover 390 is closed and the process may be repeated.
  • the package with its low oxygen environment will cause the meat to have a purplish color.
  • the upper fluid impermeable film 366 may be peeled back. This allows ambient atmosphere to enter the package so that d e meat will take on a reddish color.
  • the provision of the overhang 336 of die upper package portion 318 over d e lower package portion 310 facilitates die removal of the domed upper package portion 318 in use. Moreover, me concealed location of die overhang 336 diminishes the possibility of accidental opening.
  • diat tiiere has been provided, in accordance with the invention, a package, a method, and a packaging apparams that satisfies the aims, objects, and advantages set forth above. While die invention has been described in conjunction with specific embodiments thereof, it is evident diat many alternatives, modifications, and variations will be apparent to those skilled in the art in light of die foregoing description. Accordingly, it is intended to embrace all such embodiments, alternatives, modifications, and variations tiiat fall within die spirit and broad scope of die appended claims.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Food Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Vacuum Packaging (AREA)
  • Packages (AREA)
  • Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Preparation Of Fruits And Vegetables (AREA)
  • Freezing, Cooling And Drying Of Foods (AREA)
  • Packaging Frangible Articles (AREA)
EP94918018A 1993-05-20 1994-05-16 Verpackung für nahrungsmittel mit erhöhter haltbarkeit Expired - Lifetime EP0699157B1 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP99109931A EP0949147A1 (de) 1993-05-20 1994-05-16 Verpackungsanlagen zum Erhöhen der Haltbarkeit von Lebensmitteln
EP98122058A EP0899209B1 (de) 1993-05-20 1994-05-16 Verpackung für Nahrungsmittel und entsprechendes Verfahren

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US08/064,700 US5348752A (en) 1993-05-20 1993-05-20 Dual state food packaging
US64700 1993-05-20
US98530 1993-07-08
US08/098,530 US5419096A (en) 1993-07-28 1993-07-28 Packaging method and apparatus for packaging large meat products in a desired gaseous atmosphere
US154756 1993-11-18
US08/154,756 US5419097A (en) 1993-11-18 1993-11-18 Method and apparatus for packaging food
US221194 1994-03-31
US08/221,194 US5439132A (en) 1993-05-20 1994-03-31 Dual cover package
PCT/US1994/005525 WO1994027868A2 (en) 1993-05-20 1994-05-16 Packaging systems for increased food product shelf life

Related Child Applications (2)

Application Number Title Priority Date Filing Date
EP98122058A Division EP0899209B1 (de) 1993-05-20 1994-05-16 Verpackung für Nahrungsmittel und entsprechendes Verfahren
EP99109931A Division EP0949147A1 (de) 1993-05-20 1994-05-16 Verpackungsanlagen zum Erhöhen der Haltbarkeit von Lebensmitteln

Publications (2)

Publication Number Publication Date
EP0699157A1 true EP0699157A1 (de) 1996-03-06
EP0699157B1 EP0699157B1 (de) 2000-01-12

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EP98122058A Expired - Lifetime EP0899209B1 (de) 1993-05-20 1994-05-16 Verpackung für Nahrungsmittel und entsprechendes Verfahren
EP94918018A Expired - Lifetime EP0699157B1 (de) 1993-05-20 1994-05-16 Verpackung für nahrungsmittel mit erhöhter haltbarkeit
EP99109931A Withdrawn EP0949147A1 (de) 1993-05-20 1994-05-16 Verpackungsanlagen zum Erhöhen der Haltbarkeit von Lebensmitteln

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JP (2) JPH08510708A (de)
KR (1) KR100320356B1 (de)
AT (2) ATE247028T1 (de)
AU (1) AU688329B2 (de)
CA (1) CA2163230C (de)
DE (2) DE69422620T2 (de)
NZ (1) NZ267278A (de)
WO (1) WO1994027868A2 (de)

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Also Published As

Publication number Publication date
DE69422620T2 (de) 2000-05-31
WO1994027868A3 (en) 1995-02-09
EP0699157B1 (de) 2000-01-12
JP2001294278A (ja) 2001-10-23
EP0899209A2 (de) 1999-03-03
KR100320356B1 (ko) 2002-01-15
AU688329B2 (en) 1998-03-12
ATE247028T1 (de) 2003-08-15
AU6952094A (en) 1994-12-20
EP0949147A1 (de) 1999-10-13
DE69422620D1 (de) 2000-02-17
JPH08510708A (ja) 1996-11-12
DE69433041T2 (de) 2004-05-27
EP0899209B1 (de) 2003-08-13
NZ267278A (en) 1997-11-24
ATE188660T1 (de) 2000-01-15
EP0899209A3 (de) 1999-04-14
DE69433041D1 (de) 2003-09-18
WO1994027868A2 (en) 1994-12-08
CA2163230C (en) 1999-11-02
CA2163230A1 (en) 1994-12-08

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