EP0687966B1 - Controlled atmosphere system for a refrigerated container - Google Patents

Controlled atmosphere system for a refrigerated container Download PDF

Info

Publication number
EP0687966B1
EP0687966B1 EP95630062A EP95630062A EP0687966B1 EP 0687966 B1 EP0687966 B1 EP 0687966B1 EP 95630062 A EP95630062 A EP 95630062A EP 95630062 A EP95630062 A EP 95630062A EP 0687966 B1 EP0687966 B1 EP 0687966B1
Authority
EP
European Patent Office
Prior art keywords
level
oxygen
carbon dioxide
sensor
nitrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP95630062A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0687966A2 (en
EP0687966A3 (en
Inventor
Barry P. Cahill-O'brien
Michael P. Nevin
Richard L. Martin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Carrier Corp
Original Assignee
Carrier Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carrier Corp filed Critical Carrier Corp
Publication of EP0687966A2 publication Critical patent/EP0687966A2/en
Publication of EP0687966A3 publication Critical patent/EP0687966A3/en
Application granted granted Critical
Publication of EP0687966B1 publication Critical patent/EP0687966B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/144Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • A23B7/148Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F11/00Control or safety arrangements
    • F24F11/30Control or safety arrangements for purposes related to the operation of the system, e.g. for safety or monitoring
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F11/00Control or safety arrangements
    • F24F11/30Control or safety arrangements for purposes related to the operation of the system, e.g. for safety or monitoring
    • F24F11/32Responding to malfunctions or emergencies
    • F24F11/38Failure diagnosis
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F11/00Control or safety arrangements
    • F24F11/50Control or safety arrangements characterised by user interfaces or communication
    • F24F11/52Indication arrangements, e.g. displays
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F11/00Control or safety arrangements
    • F24F11/62Control or safety arrangements characterised by the type of control or by internal processing, e.g. using fuzzy logic, adaptive control or estimation of values
    • F24F11/63Electronic processing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D17/00Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
    • F25D17/04Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
    • F25D17/042Air treating means within refrigerated spaces
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05DSYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
    • G05D21/00Control of chemical or physico-chemical variables, e.g. pH value
    • G05D21/02Control of chemical or physico-chemical variables, e.g. pH value characterised by the use of electric means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F2110/00Control inputs relating to air properties
    • F24F2110/50Air quality properties
    • F24F2110/65Concentration of specific substances or contaminants
    • F24F2110/70Carbon dioxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F2110/00Control inputs relating to air properties
    • F24F2110/50Air quality properties
    • F24F2110/65Concentration of specific substances or contaminants
    • F24F2110/76Oxygen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/70Efficient control or regulation technologies, e.g. for control of refrigerant flow, motor or heating

Definitions

  • This invention relates to a method of controlling operation of a controlled atmosphere system. Specifically, the invention relates to a controlled atmosphere system for a refrigerated container and specifically to a system for regulating the amount of nitrogen, oxygen, and carbon dioxide inside a refrigerated container resulting in an atmospheric composition that extends post harvest shelf life/or quality of fruits and vegetables.
  • Controlled atmosphere containers for the post-harvest transport and storage of agricultural commodities are well known in the art. Such systems are usually used in conjunction with a refrigeration unit designed to lower the temperature of the interior of the container to a desired optimum temperature for the load being shipped therein. It has been established that temperature is the most important factor in controlling the rate of deterioration of fruits and vegetables. A controlled atmosphere system is considered as a supplement to proper temperature and humidity control.
  • the purpose of a controlled atmosphere system is to control the amount of oxygen and carbon dioxide inside the refrigerated container to change the rate of ripening of the produce stored in the container.
  • the system controls the amount of oxygen (O 2 ) and carbon dioxide (CO 2 ) by replacing them with nitrogen (N 2 ).
  • the controlled atmosphere system In such systems it is desirable for the controlled atmosphere system to be more widely used by unskilled operators. In order to facilitate this goal it is desirable to have a microprocessor controlled system which provides enhanced system performance, ease of setup and use and self-diagnostics. To this end it is particularly desirable to have a controller which operates according to a specific control algorithm including algorithms which energize the compressor, the heater, the system control valves and other system components in order to maintain the gas concentration inside the container box.
  • the method for controlling operation of a controlled atmosphere system of the invention comprises the features claimed in claim 1.
  • a method for controlling operation of a controlled atmosphere system for controlling the atmosphere within a confined space.
  • the system has an electrical control which has a display and electrically controlled components.
  • the components include in serial relationship, an air compressor, a filter having a drain valve, an air heater, a nonelectric separator for dividing air into separate streams comprising its principal constituents of oxygen and nitrogen, and, two or more flow control valves in parallel flow relationship for varying the purity of the nitrogen stream.
  • the system also includes temperature sensors for indicating the temperature leaving the heater and the temperature of the atmosphere within the confined space.
  • a system pressure sensor for providing the pressure upstream of the control valves is included.
  • the system further includes an oxygen sensor for generating an output indicating oxygen level in a gas and a carbon dioxide sensor for indicating carbon dioxide level in a gas.
  • the method includes the steps of energizing the controlled atmosphere system and simultaneously operating the electrical control to perform the steps of: (1) operating the compressor to an on or off position responsive to inputs from the oxygen sensor and the carbon dioxide sensor; (2) operating the flow control to achieve setpoint oxygen and carbon dioxide levels in the atmosphere, in response to inputs from the oxygen sensor and the carbon dioxide sensor; (3) operating a control for the air heater to maintain the output therefrom at a preset value; (4) monitoring the oxygen sensor, and, automatically compensating the output when a predetermined temperature of the atmosphere is indicated; (5) monitoring the carbon dioxide sensor, and, automatically compensating the output when a predetermined change in the temperature of the carbon dioxide sensor occurs; and (6) monitoring the status of certain system components relative to safety and other operating parameters, and, indicating on the display when said parameters are unsafe or out of an expected range.
  • a refrigerated container 10 which has associated therewith an integrated electrically operated refrigeration system, comprising several components 12, and, a controlled atmosphere system, a part of which 14 is shown.
  • the refrigeration system 12 and the controlled atmosphere system are mounted at one end of the container and are adapted to regulate the temperature, and the atmosphere, respectively within the container 10.
  • the prior art refrigeration system 12 comprises a vapor compression refrigeration system which is well known in the prior art for such application.
  • the system includes an electrical power cord 16, providing electrical power to a refrigeration system controller 18.
  • the controller 18 is preferably a programmed microprocessor which is adapted to receive inputs from the system operator and from various sensors in the refrigeration system and thereby control the operation of the refrigeration system components, in a manner which is well known in the art.
  • the refrigeration system comprises a refrigeration circuit including an electrically driven compressor 20 communicating in turn with an evaporator coil 22, and a condenser coil 24.
  • Appropriate evaporator fans 26 are provided to recirculate the atmosphere within the container 10 over the evaporator coil 22 and into the container where it is appropriately circulated and returned to the evaporator coil for further cooling, again as is conventional.
  • a condenser fan 28 is provided to direct a cooling flow of atmospheric air over the condenser coil 24 to facilitate rejection of heat removed from the container 10.
  • the refrigeration system controller 18 operates the various components, to maintain a selected set point temperature within the container as is conventional.
  • the controlled atmosphere system 14 is illustrated in more detail in Figure 3.
  • the basic components of the controlled atmosphere system are an air compressor 30, a filter 32, an air heater 34, a nitrogen separation membrane 36, a system of metering valves 38, gas sensors 40 and a controller 50.
  • the purpose of the controlled atmosphere system is to control the amount of oxygen and carbon dioxide inside the refrigerated container 10 to change the rate of ripening of produce stored in the container.
  • the system controls the amount of oxygen (O 2 ) and carbon dioxide (CO 2 ) by replacing it with nitrogen generated from the membrane 36.
  • a normally closed drain valve 48 is provided on the filter 32.
  • the drain valve 48 is adapted to be electrically opened when energized by the controlled atmosphere system controller 50.
  • the controller is programmed to periodically open the drain value 48, for a short time, to remove residue which may build up in the filter 32.
  • High pressure air from the filter 32 passes to the air heater 34 where it is heated to the optimum operating temperature for the membrane 36 being used in the system.
  • the heater output is controlled to 55° C/131° F. This is the optimum operating temperature for a membrane separator 36 available as a Model 4241 Permeator from a company known as MEDAL MEMBRANE SEPARATION SYSTEMS DUPONT AIRLIQUIDE.
  • the controlled atmosphere controller 50 receives inputs from a temperature sensor 52 and controls energerization of a heater switch 54 to maintain the temperature of the compressed air leaving the air heater.
  • the warmed, high pressure air passing from the heater 34 enters the membrane 36, where it is separated into high purity nitrogen, which passes from the nitrogen outlet 56, and oxygen/and other gases which are passed to the oxygen outlet 58.
  • the rate of separation occurring in the membrane separator 36 depends on the flow of air through the membrane. This flow rate is controlled by the pressure in the nitrogen outlet 56. The higher the pressure in the nitrogen outlet 56, the higher the nitrogen purity generated, and the lower the flow rate of nitrogen.
  • the membrane 36 is capable of generating nitrogen purity levels greater than 99 percent. As the pressure in the nitrogen outlet 56 falls, the purity level of the nitrogen falls, and the flow rate increases.
  • the nitrogen enriched gas passing from the membrane through the outlet 56 passes to the flow control valves 38.
  • the oxygen/other gasses from the oxygen outlet 58 are exhausted to the outside air.
  • the pressure on the nitrogen outlet 56 of the membrane 36 is regulated by the aforementioned flow control valves 38.
  • the controller 50 is programmed to cycle the flow control valves 38 to increase or decrease the amount of nitrogen in the container as required.
  • the controller 50 may also add CO 2 from an external CO 2 source 65 if desired.
  • the controller 50 monitors the amount of oxygen and carbon dioxide in the container, using oxygen and carbon dioxide gas concentration sensors 40 via a sample line 64. Periodic calibration of the sensors to correct drifts with time and temperature require sampling outside air via line 66.
  • the refrigeration system controller 18 In normal operation, following loading of the container, and connection of the power cord 16 to an appropriate power source the refrigeration system controller 18 is energized and programmed to a desired set point temperature for the load. At the same time the controller 50 for the controlled atmosphere system is energized and set for the desired oxygen and carbon dioxide ranges for the load.
  • the refrigeration system 12 and the controlled atmosphere system 14 With both the refrigeration system 12 and the controlled atmosphere system 14 energized and suitably programmed the refrigeration system will begin immediate operation according to its programmed operation.
  • the controlled atmosphere system 14 will begin operation only when a controlled atmosphere enable switch 70 located in the refrigeration controller 18 is closed.
  • the enable switch 70 is closed by the refrigeration system controller 18 when it determines that the operating conditions of the refrigeration system, and conditions within the refrigerated container 10 are such that it is acceptable to allow the controlled atmosphere machine to operate.
  • FIG. 4 a schematic diagram of a controlled atmosphere system according to the present invention as installed in a container refrigeration unit will now be described in detail.
  • the broken lines in the schematic are used to generally define different parts of the refrigerated/controlled atmosphere refrigeration container unit and thus are useful in describing the location of various components with respect to these parts of the unit.
  • First the enclosed portion defined by the broken line 68 on the left hand portion represent the interior of the refrigerated container box 10.
  • the portion to the right of the interior of the box, identified by numeral 70, represents the evaporator section of the combined refrigeration/ controlled atmosphere unit mounted to the end of the container. It should be appreciated that the atmosphere in the evaporator section 70 is the same as the atmosphere within the container box as the circulating fans 26 of the refrigeration unit 12 recirculate the air between these sections.
  • the right hand portion of the schematic as defined by the lines 72 is the condenser section of the combined container refrigeration controlled atmosphere unit.
  • the condenser section is in direct contact with the normal atmosphere, with the condenser section 72 and the evaporator section 70 are separated by a substantially fluid tight barrier represented by line 74.
  • the intake air filter 46 is located in the condenser section 72 so as to receive outside atmospheric air.
  • An appropriate inlet conduit 76 is in fluid communication with a two cylinder air compressor 30 which has an outlet conduit 78 for high pressure compressed air discharged therefrom.
  • An overtemperature switch 80 is provided on the air compressor motor to direct a signal to the controlled atmosphere controller 50 should the compressor reach an unsafe temperature.
  • the outlet conduit 78 from the compressor communicates with a tortuously shaped condensing coil 81 which serves to cool the high pressure high temperature air discharged from the compressor and to condense moisture contained therein to a liquid state.
  • conduit 82 passes from the evaporator section through barrier 74 into the condenser section 72.
  • Schrader valve 84 Located in the conduit 82 is a Schrader valve 84 which facilities servicing of the system as for example conducting a pressurized leak check.
  • a pressure relief valve 86 located in conduit 82 is also located in conduit 82 a pressure relief valve 86 designed to protect the air compressor should a high back pressure develop in the system which could damage the compressor 30.
  • the air filter 32 Downstream from the pressure relief valve 86, in conduit 82, is the air filter 32 for filtering the high pressure air discharged from the compressor 30.
  • this filter is actually two separate filters, a primary discharge air filter 90 for large contaminants and a secondary discharge air filter 92 for fine particulate contaminants.
  • Each of the filters 90 and 92 is provided with a filter media which is replaceable on a periodic schedule.
  • Each filter 90, 92 is also provided with a drain solenoid valve 94. These electrically operated valves are normally closed and are adapted to be periodically opened by the controlled atmosphere controller 50 on a periodic schedule, for a short period of time, to remove residue built up in the filter.
  • Conduit 96 communicates the outlet of filter 92 with the inlet of the air heater 34.
  • the air heater is controlled by the system controller 50 to maintain the optimum temperature for the membrane separator 36 utilized in the system.
  • Heater operation is controlled by the system controller by way of a program which uses inputs from the desired set point temperature and from an air temperature sensor 52 which is located in the conduit 100 which communicates the outlet of the air heater 34 with the inlet of the membrane 36.
  • Air heater temperature control inputs from the controller 50 cycle a solid state heater switch 54 located adjacent to the heater. As will be seen, the heater 54 is on whenever the compressor 30 is on.
  • the actual heater control output is determined by a "Fuzzy logic" algorithm 156 which responds to inputs from the sensor 52 as shown at step 158.
  • the membrane separator 36 has an oxygen outlet 58 which extends from the separator through the barrier 74 to discharge oxygen and other gases to the outside atmosphere.
  • the nitrogen outlet 56 also extends through the barrier 74 into the condenser section 72 where it communicates with the flow control or metering valve system 38.
  • Located in the nitrogen outlet conduit 56 is a pressure transducer 98 which provides a pressure input to the controlled atmosphere controller 50.
  • An air pressure gage 102 is also illustrated in the nitrogen outlet line 56 to provide a visual reading of nitrogen pressure in the outlet line 56.
  • the flow control valve system 38 comprises three separate metering devices arranged in a parallel fluid flow relationship. As will be seen, these devices cooperate to control the flow of nitrogen to a nitrogen delivery line 106 which passes through the barrier 74 into the evaporator section 70. The nitrogen delivered by line 106 is then circulated by the fans 26 of the refrigeration system to the interior 68 of the container box 10. A flow meter 108 is shown in the nitrogen delivery line which will provide a visually perceptible reading of the nitrogen flow from the flow control valve system 38 to the container.
  • the flow control valve system comprises two solenoid valves designated A and B and a fixed orifice 104, which in the preferred embodiment is a capillary tube.
  • the flow control solenoid valves A and B are normally closed and are selectively opened and closed in response to the control algorithm from the controlled atmosphere system controller 50 to adjust the purity of nitrogen generated by the membrane 36.
  • valves A and B open, flow is through all three metering devices and the membrane will produce an output of approximately 15 percent oxygen and 85 percent nitrogen. This is defined as the low purity, high flow condition. With one valve, (A or B) open the system will produce approximately 5 percent oxygen and 95 percent nitrogen. This is defined as the medium purity, medium flow condition. With both valves A and B closed, the system will produce approximately 0.5 percent oxygen and 99.5 percent nitrogen. This is defined as the high purity, low flow condition. As will be seen, the control algorithm uses this for the system oxygen value as its primary control input.
  • the gas sensors 40 include an oxygen sensor 110 which is used to measure the concentration of oxygen inside the container.
  • the oxygen sensor used in a preferred embodiment of the system is a galvanic fuel cell. When a gas sample is passed through the galvanic cell, oxygen reacts with the cell to produce a small voltage. The voltage output is directly proportional to the oxygen concentration.
  • the controller 50 converts the voltage output to a percent oxygen readout on the digital display which will be described hereinbelow.
  • a model KE-50C Galvanic cell oxygen sensor available from the Japan Storage Battery Company, Ltd. is used in a preferred embodiment of the system.
  • a CO 2 sensor 112 which is used to measure the concentration of carbon dioxide inside the container.
  • the CO 2 sensor is what is known as a non dispersive infrared (NDIR microbench CO 2 sensor, available as part number 032 from Sensors Inc.
  • the CO 2 sensor has an internal temperature sensor which generates a signal which is also delivered to the controller.
  • the sensor generates a signal which is converted by the controller 50 to a percent CO 2 readout on the digital display.
  • the O 2 and CO 2 sensors 110, 112 are in serial fluid flow relationship in a gas sampling line 114. Downstream from the sensors is a discharge line 115 open to the evaporator section of the unit, while upstream is a gas sample filter 116.
  • solenoid valves may be selectively actuated to provide the desired gas sample flow to the inlet line 117 to the sensors 40.
  • a first solenoid valve 118 is located in an air sample line 120 which is adapted to deliver a sample of the warm air from the inlet line 100 to the membrane 36.
  • a capillary tube or other pressure drop device 123 is provided in this line as the air supply line is at high pressure.
  • a second solenoid valve 122 is positioned in a nitrogen sample supply line 124 which communicates with the nitrogen delivery line 106.
  • a third solenoid valve 126 is located in a calibration gas delivery line 128.
  • the calibration gas delivery line communicates with a suitable gas fitting 130 located on the outside of the condenser section 72. It is adapted to be connected with a calibration gas tank 131 which contains a calibration gas made up of 5 percent CO 2 and 95 percent nitrogen.
  • a pressure relief valve 132 is provided in the calibration gas line 128.
  • the fourth solenoid valve 134 is located in the sample line 64 which is adapted to deliver a sample of the gas within the container 10 to the gas sensors.
  • each of these solenoid valves is selectively actuated by the control atmosphere system controller 50.
  • the outputs from the O 2 sensor 110 and the CO 2 sensor 112 are delivered to the system controller to monitor the operation and performance of the system as will be appreciated.
  • the system is provided with a CO 2 supply system generally identified by reference numeral 65.
  • the system includes a CO 2 delivery line 138 which has a normally closed electrically actuated solenoid valve 140 positioned therein.
  • a pressure relief valve 142 is also provided in the CO 2 supply line 138.
  • two locations for CO 2 supply bottles are shown. The first is in the interior 68 of the container box wherein a CO 2 bottle 144 is shown in communication with an appropriate fitting 146 and a supply line 148 to the CO 2 system.
  • a second CO 2 bottle 150 located outside of the entire unit communicating through a fitting 152 and a line 154 to the CO 2 system 65.
  • the CO 2 supply system is physically separate from the rest of the controlled atmosphere system and is actuated as needed by the control atmosphere controller 50 by selective actuation of the solenoid valve 140.
  • Located within the interior 68 of the container 10 is a door safety interlock solenoid 156. This solenoid is associated with an interlock mechanism which will prevent the doors to the container form being opened when the oxygen level in the container falls below a predetermined value.
  • controller 18 of the refrigeration system and the controller of the controlled atmosphere system 50 be able to communicate electronically with one another.
  • One example of such communication is the over riding control of the refrigeration controller 18 by the enable switch 70, briefly described hereinabove, which is the subject of EP-A-0 692 199 published on January 17, 1996.
  • This relationship between the controllers 18 and 50 is shown schematically in Figure 5 wherein the solid arrows 155 interconnecting the controllers and electronic data recorder 156 are meant to illustrate the ability of these components to electronically communicate with one another.
  • the data recorder 156 serves to periodically record, for future reference, information from both the refrigeration controller and the controlled atmosphere controller.
  • Information recorded from the refrigeration controller typically includes temperature of supply and return air being circulated.
  • Information recorded from the controlled atmosphere controller includes O 2 and CO 2 levels, the result of pre-trip tests, alarm activity, and the state of the enable switch 70.
  • Figure 6 generally illustrates the controller 50 and the inputs and outputs thereto/therefrom. Each of the inputs is identified and the corresponding reference numeral in Figure 4 is also used.
  • the container atmosphere temperature input is derived from a temperature sensor 157, not previously mentioned, located within the enclosed space 68 of the container 10.
  • the key pad 160 inputs will be described below in connection with Figure 7. All of the other inputs have been discussed above in connection with the description of the system shown in Figure 4.
  • the outputs from the controlled atmosphere controller 50 are likewise each described along with the relevant reference numeral used in Figure 4. Again each of these components has been described previously and will not be further elaborated upon at this time.
  • Figure 7 illustrates the appearance of the key pad 160 which provides operator inputs to the controller 50. Most of the input buttons on the key pad 160 are not necessary to an understanding of the present invention and will not be described herein. When deemed necessary for a full understanding of a function, the buttons will be described at that time.
  • Figure 8 represents the display 170 of the controlled atmosphere controller 50. Across the top of the display are a series of seven indicator lights 174 useful in conveying information to the operator during operation of the system. At the bottom of the display are two alphanumeric LCD visual display regions. The left hand display 171 and the right hand display 173 are useful in conveying information to the operator as will be appreciated.
  • the controlled atmosphere control 18 then continuously monitors the input from the controlled atmosphere enable switch 70. If this switch 70 is closed the controlled atmosphere system will operate, if it opens, the system will immediately enter a stand-by mode. At this time the stand-by light 162 on the display 170 will be illuminated.
  • the controlled atmosphere control 50 When in the stand-by mode, the controlled atmosphere control 50 continuously monitors the status of the controlled atmosphere enable input 71. All outputs from the controller 50 as illustrated in Figure 6 are turned off, and the display 171, 173 is blank. On the other hand, when the CA control indicates, through the signal 71, that the controlled atmosphere system may operate the system operates according to the main controlled atmosphere algorithm 160 of Figure 9.
  • the air heater control system 164 has already been briefly described hereinabove, and, as indicated is used to maintain the temperature of the air leaving the heater 34 at 55°C. The heater is on whenever the compressor 30 is operating.
  • control logic for the compressor control system 166 is entered at point 170 wherein the inquiry is made as to whether the CA enable switch 70 is closed. If the switch is not closed, at step 172, no further action will be taken and the system will remain in stand-by until it is determined that the CA enable switch is closed at which point the logic will pass via the "Yes" branch 174 to evaluate the O 2 and CO 2 concentrations at steps 176 and 178 respectively. In each of these comparison steps the actual gas concentration is compared to a control band above and below the setpoint programmed into the controller for the particular gas.
  • step 176 when the controller determines that the CO 2 level is above the control band the CA air compressor 30 will be started at step 180, via the "Yes" branch 182. If step 178 indicates that the oxygen level is either above or below, i.e. "outside” the control band the air compressor 30 will be started, via the "Yes” branch 184. If neither of the conditions of step 176 or 178 are met the controller will loop, following the "No" branches, 186, 188 respectively until the conditions of steps 172, 176 and 178 result in starting of the CA air compressor at 180.
  • the system again evaluates, at step 190 the status of the enable switch 70. If the enable switch is open the compressor is stopped, at step 200, via the "No" branch 192. If the enable switch is closed the controller then evaluates the oxygen level at step 194. If the O 2 level is within the control band the controller then evaluates, via the "Yes” branch 195, the CO 2 level at step 196. If the CO 2 level is below the setpoint the controller stops the compressor, via the "Yes” branch 198, at step 200. This is done because operation of the compressor has no effect on "raising" the CO 2 level within the container.
  • the controller Upon stopping the compressor, at step 200, the controller returns via 202 to the entry point 170 of the compressor control algorithm. It should be appreciated that, following starting of the compressor at step 180, the status of the CA enable switch 70 is continuously evaluated via the "No" branches 204 and 206 respectively of steps 194 and 196 by returning to step 190. As a result the air compressor 13 stopped at step 200, via the "No" branch 192, at any time that the CA enable switch 70 is opened and the controller 50 places the controlled atmosphere system into a stand-by mode.
  • the flow control valve system Whenever the compressor 30 is actuated as described above, the flow control valve system, previously described, operates, according to its control algorithm 168, to bring the oxygen level and the carbon dioxide level to their programmed setpoints.
  • the algorithm uses the oxygen value as its primary control input.
  • the algorithm attempts to control CO 2 .
  • CO 2 concentration is increased by opening the CO 2 solenoid valve 140, which adds CO 2 from an external tank 146 or 150. CO 2 concentration is reduced by adding nitrogen from the membrane to displace the CO 2 in the container 10.
  • control algorithm will maintain the oxygen level within the control band until the CO 2 level is at or below the set level. It will be noted however that the CO 2 control does not become active until the oxygen setpoint is achieved.
  • Flow control algorithm 168 will first be described, and then the specific programming of the controller for adding nitrogen, at the three different levels of purity, will be described in connection with different setpoint ranges as shown in Figures 13 and 14.
  • the O 2 /CO 2 flow control algorithm is entered at point 208 and the controller evaluates at step 210 whether the oxygen level in the container is at the programmed setpoint. If it is, the controller moves through the "Yes" branch 212 to ask, at step 214, whether the CO 2 level is at or below the programmed setpoint. If it is not the controller moves through the "No" branch 216 to step 218 where, if the compressor 30 is not already running it is started and the CO 2 level is reduced by adding nitrogen to the container thereby displacing CO 2 . This condition is illustrated in the left hand portion of the graph shown in Figure 15.
  • step 220 With the compressor operating to decrease the CO 2 level the controller moves to step 220 where, if the CO 2 level is at the programmed setpoint, it moves through the "Yes" branch 222 to stop the air compressor at 224 and returns to the beginning 208 of the flow control algorithm. If the CO 2 level, at step 220, is not at setpoint the controller moves through the "No" branch 226 returning to the starting point 208.
  • step 214 if the CO 2 level is at or below setpoint the controller moves through the "Yes" branch 228 to stop the compressor at step 230, and, to increase the CO 2 level by adding CO 2 as at step 232.
  • the addition of CO 2 as previously described and as illustrated in the right hand portion of Figure 15 is achieved by the controller opening the CO 2 valve 140 until the CO 2 value reaches setpoint at which time the CO 2 valve 140 is closed.
  • step 210 if the O 2 level is not at setpoint the controller moves through the "No" branch 234 to step 236 where the controller asks whether the O 2 level is within the control band of the programmed O 2 level. If the O 2 is in the control band the controller then moves through the "Yes" branch 238 of step 236 to step 218. At step 218 the system will operate to control the O 2 level and as previously described the CO 2 control system will also be active.
  • step 236 If at step 236 it is determined that the O 2 level is not within the control band the controller will move through the "No" branch 240 to step 242 and commence oxygen control by adding nitrogen with the CO 2 control system not enabled. During such operation the controller continues to evaluate via branch 244; the oxygen and CO 2 levels relative to their setpoints and control bands to determine the best mode of operation of the system.
  • valves A and B open produce 15% oxygen and 85% nitrogen. This has been defined as the low purity, high flow condition.
  • FIG 13 the operation of the controller to operate the valves in response to the sensed oxygen level within the container is shown for setpoints between 0% and 5% oxygen.
  • This drawing illustrates operation of the system to bring the oxygen level down from the approximately 20.8% oxygen contained in atmospheric air to the desired setpoint value.
  • time 0 the system begins operation with the compressor operating and both valves A and B open, and operates, as seen at segment 246, until the oxygen level has been brought down to approximately 15%.
  • valve B is closed and the system moves to the medium purity, medium flow condition as represented by segment 248 until the oxygen level reaches the 5% value.
  • valve A is closed, and the system operates as represented by segment 250, in the high purity, low flow condition until it reaches the lower end 252 of the control band.
  • control valve A is again opened and the system returns, as represented by segment 254, to a medium purity, medium flow condition until the upper range of the control band is reached, as at 256, whereupon valve A is again closed and the system returns to high purity, low flow.
  • Such alternating opening and closing of valve A continues in order to maintain the oxygen level within the container within the control band.
  • Figure 14 illustrates the operation of the system where the oxygen setpoint is between 5% and 15%.
  • the system begins operation in the low purity, high flow mode with valves A and B open as indicated by segment 258 in Figure 14. Again, when the sensor determines that the oxygen level has reached 15% valve B is closed and it shifts to the medium purity, medium flow condition as indicated at segment 260. Valve B is then alternately opened and closed as the oxygen value hunts between the set value within the control band.
  • step 242 of Figure 12 is being carried out the controller, via branch 244 is continuously evaluating the O 2 value to determine the optimum system mode of operation.
  • the automatic compensation and calibration of the oxygen sensor 110 is also programmed into the controlled atmosphere controller 50 and is referred to in the main algorithm as reference numeral 266.
  • the oxygen sensor 110 is used to measure the concentration of oxygen within the container 10. Opening of the sample valve 134 will allow atmosphere from the container to pass over the sensor 110.
  • the oxygen sensor 110 produces a small voltage output which is directly proportional to the oxygen concentration of the gas it is sensing.
  • the microprocessor of the controlled atmosphere controller 50 converts the voltage output to a percent oxygen readout which is shown on the digital display 173.
  • the microprocessor is programmed with the sensor specifications for a range of oxygen measurements from 0 to 20.9%, and the expected rating for this range of oxygen levels.
  • the span of the oxygen sensor is defined as the difference between the voltage reading from the oxygen sensor at its maximum level less the reading at its minimum level.
  • the span and linearity of the oxygen sensor are sensitive to temperature and aging. As an example, the span with time may decrease to the point where the sensor is not capable of producing a voltage output which matches the sensor specification for 20.9% oxygen.
  • the controlled atmosphere controller 50 is programmed as illustrated in Figure 16.
  • the oxygen sensor compensation and calibration program 266 is entered at point 268 where the controller 50 first ascertains the temperature of the air returning from the interior of the container as measured by temperature sensor 158, at step 270. If this temperature is below 5°C, the output of the sensor is compensated at step 272 using a compensation curve, which has been programmed into the controller 50. If the air temperature is not below 5°C the controller moves through the "No" branch 274. From step 272, or from the "No" branch 274, the controller then considers whether one or the other of two events 276 or 278 have occurred.
  • step 276 two hours after power has been turned on to the CA system, as at step 276, or after 24 hours have elapsed since the last calibration, as at step 278, the span of the oxygen sensor will be calibrated by passing outside air (20.8% oxygen) through the oxygen sensor 110. As indicated this occurs whenever the "Yes" branch of step 276 or 278, collectively 280, is followed.
  • the controller Before initiating the test the controller ascertains, at step 282, whether the controlled atmosphere compressor 30 is on. Operation of the compressor is necessary in order to get a reliable air sample for the calibration and therefore if it is not on the controller will pass through the "No" branch 284 until the compressor is activated.
  • the compressor is on calibration is initiated via the "Yes" branch 286 at step 288 where the controller closes the nitrogen valve 122, the sample valve 134 and calibration gas valve 126, and opens the air valve 118 to thereby provide a flow of outside air across the sensor.
  • the output is then sensed and compared, at step 290, to determine if it is within the expected range of the sensor.
  • step 294 the value is recorded at step 294 and is used to set the span of the oxygen sensor, and the system returns, via 296, to the starting point 268. If in step 290 the sensor is not within the expected range the controller passes, via the "No” branch 298, to display a "fault” result, at step 300, on the display 171. The system will then use the previous O 2 sensor span value, as at step 302, and return to start 268.
  • the span and zero point of the carbon dioxide sensor 112 are sensitive to temperature and thus the controller is programmed, as shown in this Figure, to compensate and/or calibrate the CO 2 sensor in a manner which will now be described.
  • the CO 2 sensor temperature compensation/calibration algorithm 304 is shown generally as it relates to the other control algorithms continuously operating in the controlled atmosphere system in Figure 9 and in detail in Figure 17.
  • the CO 2 sensor algorithm 304 is entered at 306 and at step 308 the controller determines using the input from the CO 2 sensors 112 internal temperature sensor whether the sensor temperature is less than 25°C. If it is, the controller will move through the "Yes" branch 309 to step 310 where the output of the CO 2 sensor is compensated using a temperature compensation curve which is programmed into the CA controller 50. From the temperature compensation step 310, or via the "No" branch 312 of step 308, the controller then determines whether one or more of three conditions exist which will result in CO 2 sensor calibration. These events, as indicated at steps 314, 316 and 318 are: “Is it two hours after system start"? "Has there been a 5°C.
  • a yes answer to any of these inquiries results in moving, via the "Yes” branch 320, to initiation of CO 2 , sensor calibration at step 322.
  • a "No” result to each of the inquiries 314, 316 and 318 results in a return to the start 306 via the "No" branches 324.
  • CO 2 sensor calibration is initiated by determining at 322 whether the CA compressor 30 is on to assure a reliable flow of gas through the CO 2 sensor 112. If the compressor is not on the test will not continue as evidenced by the "No" branch 326 result. Assuming the compressor is on the controller next opens the nitrogen solenoid valve 122, and closes the air, sample and calibration gas solenoids 118, 134 and 126. The controller also closes both nitrogen flow control valves A and B. The controller then goes into a nine minute delay period to allow system conditions to stabilize with the highest purity nitrogen passing over the CO 2 sensor, all as indicated at step 328.
  • the CO 2 sensor is read, and, if it is the first calibration attempt, as at step 330, the first zero point value is stored, and, via the "Yes" branch 332, the controller shifts the system into a normal control mode of operation as at 336 for fifteen minutes.
  • a counter within the controller 50 is set at "10" at this time.
  • the controller After the fifteen minutes of normal control operation the controller returns to step 328 and 330 where it generates a second zero point value which is compared to the first zero point value at step 338. If at step 338 the controller finds that both zero points are within 50m v of each other, the second determined zero point is stored, via the "Yes" branch 340, at step 342. The control then returns to the start point 306 via branch 344 and the new zero value is used until the control decides that compensation or calibration is again necessary.
  • step 338 the controller moves through the "No" branch to step 348 wherein the counter 334 number is reduced by one and the new count is evaluated. If the new count is not "zero" the control passes, via the "No" branch 350, to step 336 and the process continues until a new zero value is determined, or, until the count at step 348 equals "zero". At this point the controller will move through the y branch 350 from step 348 and display a fault, as at 352, on the controller display 171. The controller 50 will then use the previous valid carbon dioxide zero point as at step 354 for system control.
  • controller 50 programmed into the controlled atmosphere controller 50 is used to detect major faults in the system and to shut the system down or put it into a safe operating mode if one occurs. It also accumulates the amount of operating time for the system. After fixed operating intervals the control will display at 171, a service alarm, indicating it is time to service certain components of the unit. Specifically, a service alarm appears upon 5000 lapsed hours for the filters 90 and 92 and a compressor service alarm appears at 14,000 hours. After servicing the unit, the operator resets the timer for the particular component using the keyboard 162.
  • alarm/fault system 356 includes the following: (1) Monitoring the status of the compressor overtemperature switch 80. If this switch opens the compressor 30 will be shut down and the display will indicate a fault. (2) Monitoring of the status of the system fuse (not shown) and should it open the system will enter a stand-by mode as indicated by illumination of the light 162 on the display 170. (3) Monitoring the status of the heater overtemperature switch 99. If this switch opens, the heater 34 will be shut down and the display 171 will indicate a fault. (4) Monitors the output of the oxygen sensor 110 and the CO 2 sensor 112. If these sensors read outside their expected range as described above or fail to calibrate, the control will indicate a fault on the display 170.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Signal Processing (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Human Computer Interaction (AREA)
  • Fuzzy Systems (AREA)
  • Mathematical Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Automation & Control Theory (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Devices That Are Associated With Refrigeration Equipment (AREA)
  • Storage Of Harvested Produce (AREA)
  • Storage Of Fruits Or Vegetables (AREA)
EP95630062A 1994-06-15 1995-06-12 Controlled atmosphere system for a refrigerated container Expired - Lifetime EP0687966B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/259,840 US5457963A (en) 1994-06-15 1994-06-15 Controlled atmosphere system for a refrigerated container
US259840 1994-06-15

Publications (3)

Publication Number Publication Date
EP0687966A2 EP0687966A2 (en) 1995-12-20
EP0687966A3 EP0687966A3 (en) 1996-11-13
EP0687966B1 true EP0687966B1 (en) 2002-01-16

Family

ID=22986633

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95630062A Expired - Lifetime EP0687966B1 (en) 1994-06-15 1995-06-12 Controlled atmosphere system for a refrigerated container

Country Status (8)

Country Link
US (1) US5457963A (ja)
EP (1) EP0687966B1 (ja)
JP (1) JP2635536B2 (ja)
CN (1) CN1060131C (ja)
AU (1) AU681273B2 (ja)
DE (1) DE69524993T2 (ja)
DK (1) DK0687966T3 (ja)
NZ (1) NZ272173A (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013205867A1 (de) 2013-04-03 2014-10-09 BSH Bosch und Siemens Hausgeräte GmbH Behältervorrichtung für ein Haushaltskältegerät, Haushaltskältegerät und Verfahren zum Herstellen einer Behältervorrichtung
DE102013205865A1 (de) 2013-04-03 2014-10-09 BSH Bosch und Siemens Hausgeräte GmbH Behältervorrichtung für ein Haushaltskältegerät, Haushaltskältegerät und entsprechendes Verfahren
DE102013205866A1 (de) 2013-04-03 2014-10-09 BSH Bosch und Siemens Hausgeräte GmbH Behältervorrichtung für ein Haushaltskältegerät, Haushaltskältegerät und entsprechendes Verfahren
EP3677115B1 (en) * 2017-09-29 2023-12-06 Daikin Industries, Ltd. Internal air adjustment device

Families Citing this family (121)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5623105A (en) * 1992-10-21 1997-04-22 Prolong Systems, Inc. Oxygen/carbon dioxide sensor and controller for a refrigerated controlled atmosphere shipping container
NL9402111A (nl) * 1994-12-13 1996-07-01 Inst Voor Agrotech Onderzoek Stelsel voor het regelen van de luchtsamenstelling binnen een bewaarruimte voor ademende plantaardige produkten.
FR2730790B1 (fr) * 1995-02-17 1997-05-23 Air Liquide Procede d'introduction d'un gaz de remplissage dans une enceinte et installation de mise en oeuvre
US5649995A (en) * 1995-03-09 1997-07-22 Nitec, Inc. Nitrogen generation control systems and methods for controlling oxygen content in containers for perishable goods
US5669225A (en) * 1996-06-27 1997-09-23 York International Corporation Variable speed control of a centrifugal chiller using fuzzy logic
US5732558A (en) * 1996-11-25 1998-03-31 Eisele; Hugh Controlled atmosphere system
US5718118A (en) * 1996-11-25 1998-02-17 Eisele; Hugh Controlled atmosphere system
US5791982A (en) * 1997-04-16 1998-08-11 Alliedsignal Inc. System for improving the well-being of humans in a commercial aircraft
US6251344B1 (en) * 1997-06-27 2001-06-26 Quantum Group, Inc. Air quality chamber: relative humidity and contamination controlled systems
GB9713989D0 (en) * 1997-07-02 1997-09-10 Boc Group Plc Controlling atmospheres in containers
US6131399A (en) * 1997-12-04 2000-10-17 Hall; Donald M. Refrigerated vending machine
US5960635A (en) * 1998-03-03 1999-10-05 Dakhil; Farouk Air conditioning apparatus using liquid nitrogen
US6209329B1 (en) * 1998-04-24 2001-04-03 Dippin' Dots, Inc. Cryogenic processor for liquid feed preparation of a free-flowing frozen product
US6012384A (en) * 1998-05-01 2000-01-11 Trans Tech Holdings Group Mobile ripening container
EP1175353B1 (en) 1998-10-19 2006-12-20 Mitsubishi Australia Ltd Apparatus for controlled venting of a chamber
AU1920500A (en) * 1998-11-25 2000-06-13 Thermo King Corporation Automatic ambient air control system and method for refrigerated container
USRE43429E1 (en) 1998-11-25 2012-05-29 Thermo King Corporation Automatic ambient air control system and method for refrigerated container
US6471136B1 (en) 1999-06-29 2002-10-29 Carrier Corporation Biosensors for monitoring air conditioning and refrigeration processes
DE19948654C1 (de) * 1999-10-08 2001-08-23 Integral Energietechnik Gmbh Verfahren zur Klimaregelung eines Raums
GB2361307A (en) * 2000-04-14 2001-10-17 Dominic Adam Simler Air conditioning systems
AUPQ721500A0 (en) * 2000-05-01 2000-05-25 Mitsubishi Australia Limited Apparatus and methods for controlled venting of a chamber
KR20020006854A (ko) * 2000-07-13 2002-01-26 김강권 원예산물의 공기조절 저장을 위한 저비용 간이 공기조절시스템
US6369716B1 (en) * 2000-12-01 2002-04-09 Johnson Controls Technology Company System and method for controlling air quality in a room
US6430944B1 (en) * 2001-04-13 2002-08-13 Smc Kabushiki Kaisha Remote maintenance system and method for chiller units
US6405644B1 (en) * 2001-10-10 2002-06-18 Robert J. Windecker Environmentally controlled storage and ripening apparatus
US6431060B1 (en) * 2002-02-01 2002-08-13 Carrier Corporation Container for cooling perishable goods
US6443056B1 (en) * 2002-02-27 2002-09-03 Carrier Corporation Remote fan pods for side-to-side airflow on a refrigerated container
US6457402B1 (en) * 2002-02-27 2002-10-01 Carrier Corporation Automated fresh air exchanger for mobile container
GB0210975D0 (en) * 2002-05-14 2002-06-19 Domnick Hunter Ltd Air treatment system
FR2855956B1 (fr) * 2003-06-12 2005-08-26 Thermagen Condenseur pour appareil de cuisson
EP1691980A4 (en) * 2003-12-03 2009-05-27 Commw Scient Ind Res Org METHODS FOR PRODUCING PACKAGING MATERIAL FOR TRANSPORTING AND STORING PERISHABLE GOODS
US7089751B2 (en) * 2004-04-23 2006-08-15 Carrier Corporation Automatic fresh air exchange system
US7171821B2 (en) * 2004-04-30 2007-02-06 Thermo King Corporation Temperature control unit having a vent arrangement
CN100516808C (zh) * 2005-04-22 2009-07-22 中国科学院力学研究所 空气加热系统
US20060260329A1 (en) * 2005-05-17 2006-11-23 Rampersad Bryce M Cryogenic biological preservation unit with integrated cryocooler and nitrogen supply
DE102005045760B4 (de) * 2005-09-23 2008-12-24 Hoffmann Consorten Hamburg Gmbh Verfahren und Vorrichtung zur Herstellung einer konditionierten Atmosphäre
ITMI20051789A1 (it) * 2005-09-27 2007-03-28 Finanziaria Unterland S P A Impianto frigorifero di conservazione particolarmente per uso domestico
US7665314B2 (en) * 2005-10-31 2010-02-23 Carrier Corporation Intermodal air compressor water separator and heat exchanger
TWI389829B (zh) * 2006-06-30 2013-03-21 Global Fresh Foods 用於運輸或貯存可氧化分解之食品的系統及方法
US7581427B2 (en) * 2006-11-14 2009-09-01 Mocon, Inc. Workspace analyte sensing system and method using a fan to move samples from the workspace to the sensor
US20080146137A1 (en) * 2006-12-18 2008-06-19 Mark Anthony Mosunic Multi Purpose Refrigerated Box Hold and Container Cargo Carrier with One or More Cargo Holds
CN101210103B (zh) * 2006-12-29 2010-12-29 佛山市顺德区汉达精密电子科技有限公司 聚碳酸酯/丙烯腈-丁二烯-苯乙烯共聚物次料回收配方
JP2008180614A (ja) * 2007-01-25 2008-08-07 Daikin Ind Ltd センサー較正装置
CN101280991B (zh) * 2007-04-05 2010-05-26 深圳清华大学研究院 一种自动调节冷藏集装箱箱体内外气压平衡的装置及其方法
US20090090112A1 (en) * 2007-09-06 2009-04-09 John Martin Girard System and method for cryogenic enhancement to mechanical freezers
US20090064690A1 (en) * 2007-09-06 2009-03-12 John Martin Girard System and method for cryogenic enhancement to mechanical freezers
DK2229579T3 (en) 2008-01-17 2018-12-17 Carrier Corp Detection of CO2 emissions in a container
EP2092831A1 (de) * 2008-01-25 2009-08-26 Cargofresh AG System zur Überwachung und Steuerung der Atmosphärenzusammensetzung in einem Container zum Transport von Lebensmitteln oder anderen empfindlichen Produkten
US8020360B2 (en) * 2008-03-12 2011-09-20 Whirlpool Corporation Device to produce a modified atmosphere for food preservation
GB0818048D0 (en) * 2008-10-03 2008-11-05 Rolls Royce Plc Compressor for pressurising carbon dioxide
WO2010055681A1 (ja) * 2008-11-13 2010-05-20 ダイキン工業株式会社 冷凍装置
US9874158B2 (en) 2009-09-04 2018-01-23 Lg Fuel Cell Systems, Inc Engine systems and methods of operating an engine
US9178235B2 (en) 2009-09-04 2015-11-03 Lg Fuel Cell Systems, Inc. Reducing gas generators and methods for generating a reducing gas
US9118048B2 (en) 2009-09-04 2015-08-25 Lg Fuel Cell Systems Inc. Engine systems and methods of operating an engine
US9083020B2 (en) 2009-09-04 2015-07-14 Lg Fuel Cell Systems Inc. Reducing gas generators and methods for generating reducing gas
US8668752B2 (en) * 2009-09-04 2014-03-11 Rolls-Royce Fuel Cell Systems (Us) Inc. Apparatus for generating a gas which may be used for startup and shutdown of a fuel cell
US9140220B2 (en) 2011-06-30 2015-09-22 Lg Fuel Cell Systems Inc. Engine systems and methods of operating an engine
US8597841B2 (en) 2009-09-04 2013-12-03 Lg Fuel Cell Systems Inc. Method for generating a gas which may be used for startup and shutdown of a fuel cell
CN102575886B (zh) 2009-10-23 2015-08-19 开利公司 制冷剂蒸气压缩系统的运行
NZ599192A (en) 2009-10-30 2014-01-31 Global Fresh Foods Systems and methods for maintaining perishable foods
US9468220B2 (en) * 2009-10-30 2016-10-18 Global Fresh Foods System and method for maintaining perishable foods
US8877271B2 (en) * 2009-10-30 2014-11-04 Global Fresh Foods Perishable food storage units
US9004369B2 (en) * 2010-03-24 2015-04-14 Whirlpool Corporation Systems and methods for multi-sense control algorithm for atomizers in refrigerators
SG184085A1 (en) 2010-04-13 2012-10-30 Carrier Corp Controlled atmosphere systems and methods
JP5625582B2 (ja) * 2010-07-26 2014-11-19 ダイキン工業株式会社 冷凍装置
US20120330596A1 (en) * 2011-06-21 2012-12-27 General Electric Company Self-calibrating sensor, system, and computer program product
CN102871208B (zh) * 2011-07-15 2016-02-10 湖南华望熏蒸消毒有限公司 一种烟叶快速降氧杀虫方法
DK2734048T3 (en) 2011-07-18 2017-06-19 Carrier Corp MANAGING ATMOSPHERE IN A CLOSED ENVIRONMENT.
EP2734285B1 (en) 2011-07-18 2018-06-13 Carrier Corporation Scrubber system with moving adsorbent bed
EP2734284B1 (en) 2011-07-18 2019-09-04 Carrier Corporation Refrigerated transport container
US20130025467A1 (en) * 2011-07-25 2013-01-31 Schroeder Industries, Inc. D/B/A Schroeder America Hot tea dispenser
CN102561778B (zh) * 2012-03-21 2013-10-30 山东理工大学 容积可调式自发气调库
KR101406931B1 (ko) * 2012-09-10 2014-06-13 경남대학교 산학협력단 기체조성 감지를 통한 통기구 개폐제어에 의해 적정 변형 기체의 농도를 유지하는 농산물 신선도 유지 장치, 및 방법
EP2914915B1 (en) 2012-10-30 2018-01-10 Carrier Corporation Drying a refrigerated cargo box following wash out prior to loading
US20140141139A1 (en) 2012-11-19 2014-05-22 Membrane Technology And Research, Inc. Membrane Separation Process for Controlling Gas Concentrations Within Produce Shipping or Storage Containers
US8877274B2 (en) * 2013-01-30 2014-11-04 Fresh Food Solutions Llc Modified and controlled atmosphere system and method
JP2015072103A (ja) * 2013-10-03 2015-04-16 ダイキン工業株式会社 コンテナ用冷凍装置
CN106104181B (zh) * 2014-03-31 2018-10-02 大金工业株式会社 集装箱用冷冻装置
US10905141B2 (en) 2014-06-11 2021-02-02 Thermo King Corporation Controlled atmosphere system and method for controlling the same
JP6459355B2 (ja) * 2014-09-30 2019-01-30 ダイキン工業株式会社 庫内空気調節装置及びそれを備えたコンテナ用冷凍装置
WO2016108953A1 (en) * 2014-12-31 2016-07-07 Thermo King Corporation Methods and systems for monitoring a leak rate of a transport unit
US20170355518A1 (en) * 2014-12-31 2017-12-14 Thermo King Corporation Carbon dioxide injection in a transport unit
JP5943106B1 (ja) * 2015-02-27 2016-06-29 ダイキン工業株式会社 ガス供給装置及びそれを備えたコンテナ用冷凍装置
WO2016136125A1 (ja) * 2015-02-27 2016-09-01 ダイキン工業株式会社 コンテナ用冷凍装置
US11015855B2 (en) * 2015-02-27 2021-05-25 Daikin Industries, Ltd. Refrigeration apparatus for containers
JP6056923B1 (ja) * 2015-08-28 2017-01-11 ダイキン工業株式会社 コンテナ用冷凍装置
JP6137249B2 (ja) * 2015-08-28 2017-05-31 ダイキン工業株式会社 庫内空気調節装置及びそれを備えたコンテナ用冷凍装置
JP6567945B2 (ja) * 2015-10-09 2019-08-28 青島海爾股▲フン▼有限公司 冷蔵庫
US11761703B2 (en) 2015-11-09 2023-09-19 Carrier Corporation Parallel loop intermodal container
EP3374703B1 (en) 2015-11-09 2022-03-09 Carrier Corporation Series loop intermodal container
JP6721327B2 (ja) * 2015-12-16 2020-07-15 旭化成株式会社 青果物の保存装置及び保存方法
JP6296090B2 (ja) * 2016-04-15 2018-03-20 ダイキン工業株式会社 庫内空気調節装置及びそれを備えたコンテナ用冷凍装置
DE102016221446A1 (de) * 2016-11-02 2018-05-03 BSH Hausgeräte GmbH Kalibrieren eines Sauerstoffsensors eines Haushaltsgeräts
WO2018102934A1 (es) * 2016-12-05 2018-06-14 Liventus Chile S.A. Método de instalación y de operación de un sistema de control atmosférico dentro de un contenedor de transporte de carga con un dispositivo de control de atmósfera
JP7014959B2 (ja) * 2017-03-10 2022-02-02 ダイキン工業株式会社 庫内空気調節装置及びそれを備えたコンテナ用冷凍装置
US10551081B1 (en) * 2017-07-17 2020-02-04 John Miller-Russell Air conditioner with safety device
CN107758130A (zh) * 2017-09-18 2018-03-06 北京卫星环境工程研究所 一体化航天器运输包装箱监控舱
EP3919826A3 (en) * 2017-09-29 2022-07-27 Daikin Industries, Ltd. Air composition adjusting device
EP3677114B1 (en) * 2017-09-29 2023-11-29 Daikin Industries, Ltd. Compartment interior air-conditioning device
WO2019065872A1 (ja) * 2017-09-29 2019-04-04 ダイキン工業株式会社 庫内空気調節装置
EP3692314B1 (en) 2017-10-06 2024-06-12 Carrier Corporation Environmental control unit
CN108099748B (zh) * 2018-02-12 2024-03-01 深圳市德塔防爆电动汽车有限公司 智能冷控厢以及冷藏运输车
DK3753395T3 (en) * 2018-02-27 2022-04-25 Daikin Ind Ltd Indvendigt luftstyringssystem
WO2019167768A1 (ja) * 2018-02-27 2019-09-06 ダイキン工業株式会社 庫内空気調節装置及びそれを備えたコンテナ用冷凍装置
WO2019199932A1 (en) 2018-04-11 2019-10-17 Carrier Corporation Pressure controlled cargo container for controlled atmosphere applications
SG11202100526VA (en) * 2018-07-20 2021-02-25 Daikin Ind Ltd Storage system
JP6687091B1 (ja) * 2018-11-14 2020-04-22 ダイキン工業株式会社 庫内空気調節装置
EP3673747B1 (en) 2018-12-30 2023-11-15 Thermo King LLC Controlled atmosphere systems
ES2963593T3 (es) 2018-12-30 2024-04-01 Thermo King Llc Sistemas activos de atmósfera controlada
EP3722710A1 (en) * 2019-04-12 2020-10-14 Carrier Corporation Refrigeration unit with atmosphere control system
EP3721714A1 (en) * 2019-04-12 2020-10-14 Carrier Corporation Method of controlling atmosphere in a refrigerated container
CN109990525B (zh) * 2019-04-30 2020-09-01 广西壮族自治区农业科学院 一种可移动式果蔬气调库
CN110094922B (zh) * 2019-05-17 2021-07-13 广州美的华凌冰箱有限公司 制冷设备
JP7417255B6 (ja) * 2020-01-09 2024-01-30 ヤマハファインテック株式会社 水素ガス混合装置
JP7440057B2 (ja) * 2020-01-09 2024-02-28 ヤマハファインテック株式会社 水素ガス混合装置
CN111762456B (zh) * 2020-06-22 2022-07-22 中国科学院电工研究所 一种氮气定向控温的电气设备密封舱系统
JP7168868B2 (ja) 2020-06-29 2022-11-10 ダイキン工業株式会社 空気組成調整装置、輸送用冷凍装置、及び輸送用コンテナ
EP4184089A4 (en) 2020-08-31 2023-12-27 Daikin Industries, Ltd. AIR COMPOSITION ADJUSTMENT DEVICE, REFRIGERATION DEVICE AND TRANSPORT CONTAINER
CN115183525B (zh) * 2021-04-02 2023-10-24 青岛海尔电冰箱有限公司 储物装置及冰箱
DK202200427A1 (en) * 2022-05-05 2024-02-13 Maersk Container Ind A/S Testing for an air leak in a controlled atmosphere container
CN114779865B (zh) * 2022-06-22 2022-09-13 深圳市华图测控系统有限公司 一种低氧气调系统的控制方法以及低氧气调系统

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3307618A (en) * 1964-03-09 1967-03-07 Whirlpool Co Temperature controlled storage unit
NZ205453A (en) * 1983-09-01 1988-03-30 New Zealand Shipping Transporting respiring comestibles while monitoring and adjusting oxygen and carbon dioxide levels
AT384668B (de) * 1985-11-28 1987-12-28 Welz Franz Transporte Transportabler kuehlcontainer
EP0252988A4 (en) * 1985-12-28 1992-07-08 Mitsui & Co., Ltd. Method of storing perishable goods and device therefor
KR950007612B1 (ko) * 1987-05-18 1995-07-13 노오링 스이산쇼오 노오교오 세이부쓰시겐 겐큐쇼 과실 및 야채의 저장방법
US4817391A (en) * 1987-11-02 1989-04-04 Elman Roe Method and apparatus for producing a controlled atmosphere
US4961322A (en) * 1987-12-28 1990-10-09 Aisin Seiki Kabushiki Kuisha Fresh food storing device
NZ225620A (en) * 1988-07-29 1991-12-23 Transfresh Corp Transporting comestibles in computer controlled atmosphere of reduced oxygen level
AT391756B (de) * 1988-08-04 1990-11-26 Welz Franz Transporte Kuehlbehaelter
NZ226929A (en) * 1988-11-11 1992-02-25 Transphere Systems Ltd Storing produce in container with controlled atmosphere: carbon dioxide supplied from store of dry ice
US5167243A (en) * 1991-02-28 1992-12-01 Lorillard Tobacco Company Disinfestation system for agricultural products
US5332547A (en) * 1991-04-16 1994-07-26 Prolong Systems, Inc. Controlled atmosphere storage container
US5355781A (en) * 1992-02-28 1994-10-18 Prolong Systems, Inc. Controlled atmosphere storage system

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013205867A1 (de) 2013-04-03 2014-10-09 BSH Bosch und Siemens Hausgeräte GmbH Behältervorrichtung für ein Haushaltskältegerät, Haushaltskältegerät und Verfahren zum Herstellen einer Behältervorrichtung
DE102013205865A1 (de) 2013-04-03 2014-10-09 BSH Bosch und Siemens Hausgeräte GmbH Behältervorrichtung für ein Haushaltskältegerät, Haushaltskältegerät und entsprechendes Verfahren
DE102013205866A1 (de) 2013-04-03 2014-10-09 BSH Bosch und Siemens Hausgeräte GmbH Behältervorrichtung für ein Haushaltskältegerät, Haushaltskältegerät und entsprechendes Verfahren
DE102013205865B4 (de) 2013-04-03 2020-07-16 BSH Hausgeräte GmbH Behältervorrichtung für ein Haushaltskältegerät, Haushaltskältegerät und entsprechendes Verfahren
EP3677115B1 (en) * 2017-09-29 2023-12-06 Daikin Industries, Ltd. Internal air adjustment device

Also Published As

Publication number Publication date
JP2635536B2 (ja) 1997-07-30
EP0687966A2 (en) 1995-12-20
DE69524993T2 (de) 2002-07-04
NZ272173A (en) 1997-02-24
US5457963A (en) 1995-10-17
EP0687966A3 (en) 1996-11-13
DE69524993D1 (de) 2002-02-21
CN1118759A (zh) 1996-03-20
JPH08168A (ja) 1996-01-09
CN1060131C (zh) 2001-01-03
AU681273B2 (en) 1997-08-21
DK0687966T3 (da) 2002-05-06
AU2058995A (en) 1995-12-21

Similar Documents

Publication Publication Date Title
EP0687966B1 (en) Controlled atmosphere system for a refrigerated container
EP0688508B1 (en) Method for automatically checking function and performance of a controlled atmosphere system
EP0692199B1 (en) Refrigeration controller for refrigerated container with enabling system for a atmosphere controller
DK2558803T3 (en) MANAGED ATMOSPHERE SYSTEMS AND PROCEDURES
US5332547A (en) Controlled atmosphere storage container
CA1268049A (en) Transportable refrigerating container
US5623105A (en) Oxygen/carbon dioxide sensor and controller for a refrigerated controlled atmosphere shipping container
EP1756479B1 (en) Automatic fresh air exchange system
US5355781A (en) Controlled atmosphere storage system
US6041605A (en) Compressor protection
EP3240979B1 (en) Method for controlling, transport unit
US20230180776A1 (en) Ripening chamber and method for ripening fruit
US5901559A (en) Electromechanical regulator
US6595847B1 (en) Automatic ambient air control system and method for refrigerated container
CN101013790A (zh) 气体激光振荡器以及测定激光气体置换量的方法
Waelti Microprocessor monitoring and control for controlled atmosphere treefruit storages

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): DE DK NL

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): DE DK NL

17P Request for examination filed

Effective date: 19970428

17Q First examination report despatched

Effective date: 19990322

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE DK NL

REF Corresponds to:

Ref document number: 69524993

Country of ref document: DE

Date of ref document: 20020221

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DK

Payment date: 20080508

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20080530

Year of fee payment: 14

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 20100101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100101

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090630

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20130605

Year of fee payment: 19

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 69524993

Country of ref document: DE

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 69524993

Country of ref document: DE

Effective date: 20150101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150101