EP0679760B1 - Procédé pour le blanchiment de pâte à papier contenant de la lignocellulose - Google Patents
Procédé pour le blanchiment de pâte à papier contenant de la lignocellulose Download PDFInfo
- Publication number
- EP0679760B1 EP0679760B1 EP94203640A EP94203640A EP0679760B1 EP 0679760 B1 EP0679760 B1 EP 0679760B1 EP 94203640 A EP94203640 A EP 94203640A EP 94203640 A EP94203640 A EP 94203640A EP 0679760 B1 EP0679760 B1 EP 0679760B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pulp
- magnesium
- calcium
- compound
- chlorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/16—Bleaching ; Apparatus therefor with per compounds
- D21C9/163—Bleaching ; Apparatus therefor with per compounds with peroxides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1005—Pretreatment of the pulp, e.g. degassing the pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1026—Other features in bleaching processes
- D21C9/1036—Use of compounds accelerating or improving the efficiency of the processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
- D21C9/153—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications with ozone
Claims (9)
- Procédé de délignification et de blanchiment de pâte à papier contenant de la lignocellulose, qui a été soumise à une digestion par voie chimique, procédé dans lequel on traite la pâte avec un acide, à un pH compris dans l'intervalle allant d'environ 1 à environ 6, et on lave la pâte après le traitement par un acide, caractérisé en ce que l'on ajoute ensuite un mélange soluble dans l'eau d'un dérivé du magnésium et d'un dérivé du calcium, à un pH compris dans l'intervalle allant d'environ 1 à environ 7 et en une quantité comprise entre environ 0,5 et environ 10 kg par tonne de pâte sèche, ladite quantité étant calculée en magnésium et en calcium, et en ce que la pâte est ensuite délignifiée et blanchie au moyen d'un agent de blanchiment exempt de chlore, renfermant du peroxyde d'hydrogène, à un pH compris dans l'intervalle allant d'environ 8 à environ 12.
- Procédé selon la revendication 1, caractérisé en ce que le mélange soluble dans l'eau d'un dérivé du magnésium et d'un dérivé du calcium est ajouté en une quantité comprise entre environ 2 et environ 10 kg par tonne de pâte sèche, ladite quantité étant calculée en magnésium et en calcium.
- Procédé selon la revendication 1, caractérisé en ce que la pâte qui a été soumise à une digestion par voie chimique, est une pâte au sulfate.
- Procédé selon la revendication 1, caractérisé en ce que le mélange soluble dans l'eau d'un dérivé du magnésium et d'un dérivé du calcium est ajouté à un pH compris entre 2 et 6.
- Procédé selon la revendication 1, caractérisé en ce que le dérivé du calcium est le chlorure de calcium ou l'oxyde de calcium.
- Procédé selon la revendication 1 ou 5, caractérisé en ce que le dérivé du magnésium est le sulfate de magnésium ou le chlorure de magnésium.
- Procédé selon la revendication 1, caractérisé en ce que l'agent de blanchiment exempt de chlore est constitué d'oxygène et de peroxyde d'hydrogène.
- Procédé selon la revendication 7, caractérisé en ce que, après le traitement, la pâte est soumise à un blanchiment final par l'ozone, en une ou plusieurs étapes.
- Procédé selon l'une quelconque des revendications 1 à 8, caractérisé en ce que l'on réalise le traitement par un acide à une température comprise dans l'intervalle allant d'environ 10 à environ 95 °C, pendant une durée allant d'environ 1 à environ 120 minutes, en ce que le mélange d'un dérivé du magnésium et d'un dérivé du calcium est ajouté à une température comprise dans l'intervalle allant d'environ 10 à environ 95 °C, en un laps de temps allant d'environ 1 à environ 180 minutes et en une quantité comprise dans l'intervalle allant de 0,5 à 5 kg par tonne de pâte sèche, ladite quantité étant calculée en magnésium et en calcium et la pâte traitée ayant une concentration d'environ 3 à environ 35 % en poids, et en ce que la pâte est blanchie et délignifiée au moyen de peroxyde d'hydrogène, à un pH compris dans l'intervalle allant d'environ 8 à environ 12.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE9101301A SE470065C (sv) | 1991-04-30 | 1991-04-30 | Behandling av kemisk massa med en syra och därefter en magnesium- och kalciumförening vid klorfri blekning |
SE9101301 | 1991-04-30 | ||
EP92201005A EP0511695B2 (fr) | 1991-04-30 | 1992-04-08 | Procédé pour le blanchiment de pâte à papier contenant de la lignocellulose |
Related Parent Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92201005A Division EP0511695B2 (fr) | 1991-04-30 | 1992-04-08 | Procédé pour le blanchiment de pâte à papier contenant de la lignocellulose |
EP92201005.3 Division | 1992-04-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0679760A1 EP0679760A1 (fr) | 1995-11-02 |
EP0679760B1 true EP0679760B1 (fr) | 1998-11-18 |
Family
ID=20382601
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94203640A Expired - Lifetime EP0679760B1 (fr) | 1991-04-30 | 1992-04-08 | Procédé pour le blanchiment de pâte à papier contenant de la lignocellulose |
EP92201005A Expired - Lifetime EP0511695B2 (fr) | 1991-04-30 | 1992-04-08 | Procédé pour le blanchiment de pâte à papier contenant de la lignocellulose |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92201005A Expired - Lifetime EP0511695B2 (fr) | 1991-04-30 | 1992-04-08 | Procédé pour le blanchiment de pâte à papier contenant de la lignocellulose |
Country Status (14)
Country | Link |
---|---|
EP (2) | EP0679760B1 (fr) |
JP (1) | JP2592747B2 (fr) |
AT (2) | ATE173518T1 (fr) |
BR (1) | BR9201554A (fr) |
CA (1) | CA2067296C (fr) |
DE (2) | DE69227640T2 (fr) |
ES (1) | ES2091395T3 (fr) |
FI (1) | FI111964B (fr) |
MX (1) | MX9201966A (fr) |
NO (1) | NO180495C (fr) |
NZ (1) | NZ242465A (fr) |
RU (1) | RU2039141C1 (fr) |
SE (1) | SE470065C (fr) |
ZA (1) | ZA923073B (fr) |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI89516B (fi) | 1989-05-10 | 1993-06-30 | Ahlstroem Oy | Foerfarande foer blekning av cellulosamassa med otson |
US6398908B1 (en) | 1991-04-30 | 2002-06-04 | Eka Nobel Ab | Process for acid bleaching of lignocellulose-containing pulp with a magnesium compound |
SE500353C2 (sv) * | 1992-10-26 | 1994-06-06 | Sca Wifsta Oestrand Ab | Peroxidblekning av sulfatmassa med tillsats av magnesium före blekningen |
SE512137C2 (sv) * | 1992-10-29 | 2000-01-31 | Eka Chemicals Ab | Förfarande för blekning av lignocellulosahaltig massa |
SE9203366L (sv) * | 1992-11-11 | 1994-05-12 | Mo Och Domsjoe Ab | Förfarande vid delignifiering och/eller blekning av cellulosamassa |
US6007678A (en) * | 1992-11-27 | 1999-12-28 | Eka Nobel Ab | Process for delignification of lignocellulose-containing pulp with an organic peracid or salts thereof |
EP0622491B2 (fr) * | 1993-04-20 | 2002-07-17 | Eka Chemicals AB | Procédé pour le blanchiment de pâte à papier contenant de la lignocellulose |
SE500616C2 (sv) * | 1993-06-08 | 1994-07-25 | Kvaerner Pulping Tech | Blekning av kemisk massa med peroxid vid övertryck |
US6605181B1 (en) * | 1993-10-01 | 2003-08-12 | Kvaerner Pulping Aktiebolag | Peroxide bleach sequence including an acidic bleach stage and including a wash stage |
BE1007757A3 (fr) * | 1993-11-10 | 1995-10-17 | Solvay Interox | Procede pour le blanchiment d'une pate a papier chimique. |
FI102301B1 (fi) * | 1994-10-13 | 1998-11-13 | Ahlstrom Machinery Oy | Menetelmä selluloosamassojen käsittelemiseksi |
US6776876B1 (en) | 1994-10-13 | 2004-08-17 | Andritz Oy | Method of treating cellulosic pulp to remove hexenuronic acid |
DE19516151A1 (de) | 1995-05-03 | 1996-11-07 | Sven Siegle | Verfahren zur Herstellung einer Pulpe aus zellulosehaltigem Material, die Pulpe selbst und deren Verwendung |
FI105701B (fi) | 1995-10-20 | 2000-09-29 | Ahlstrom Machinery Oy | Menetelmä ja laitteisto massan käsittelemiseksi |
JPH108092A (ja) * | 1996-06-21 | 1998-01-13 | Mitsubishi Paper Mills Ltd | 過酸化物漂白用安定化剤及びそれを用いた繊維系物質の漂白方法 |
BE1010679A3 (fr) * | 1996-10-11 | 1998-11-03 | Solvay Interox | Procede de delignification et de blanchiment de pate a papier chimique. |
ID23571A (id) * | 1997-08-25 | 2000-05-04 | Praxair Technology Inc | Metoda penerapan ozon dalam pemutihan ecf |
JP2002266272A (ja) * | 2001-03-12 | 2002-09-18 | Nippon Paper Industries Co Ltd | セルロース質繊維材料パルプの漂白方法 |
US6743332B2 (en) * | 2001-05-16 | 2004-06-01 | Weyerhaeuser Company | High temperature peroxide bleaching of mechanical pulps |
KR100547491B1 (ko) * | 2005-04-27 | 2006-01-31 | 이권혁 | 대나무를 이용하여 생산하는 섬유용 펄프의 제조방법 및 그 펄프 |
US9511167B2 (en) | 2009-05-28 | 2016-12-06 | Gp Cellulose Gmbh | Modified cellulose from chemical kraft fiber and methods of making and using the same |
US8778136B2 (en) | 2009-05-28 | 2014-07-15 | Gp Cellulose Gmbh | Modified cellulose from chemical kraft fiber and methods of making and using the same |
US9512237B2 (en) | 2009-05-28 | 2016-12-06 | Gp Cellulose Gmbh | Method for inhibiting the growth of microbes with a modified cellulose fiber |
US9512563B2 (en) | 2009-05-28 | 2016-12-06 | Gp Cellulose Gmbh | Surface treated modified cellulose from chemical kraft fiber and methods of making and using same |
JP6254078B2 (ja) | 2011-05-23 | 2017-12-27 | ゲーペー ツェルローゼ ゲーエムベーハー | 白色度および明度が改善された針葉樹クラフト繊維、ならびにそれを作製する方法および使用する方法 |
KR102093167B1 (ko) | 2012-01-12 | 2020-03-26 | 게페 첼루로제 게엠베하 | 황변 성질이 감소된 저 점성 크래프트 섬유 및 그의 제조 및 사용 방법 |
RU2636306C2 (ru) | 2012-04-18 | 2017-11-21 | ДжиПи СЕЛЛЬЮЛОУС ГМБХ | Использование поверхностно-активного вещества для обработки пульпы и улучшение введения крафт-пульпы в волокно для получения вискозы и других вторичных волокнистых продуктов |
JP6129323B2 (ja) * | 2012-09-27 | 2017-05-17 | アンドリッツ インコーポレーテッド | リグノセルロース系繊維束材料の化学的処理並びにそれに関する方法及びシステム |
MX365675B (es) | 2013-02-08 | 2019-06-10 | Gp Cellulose Gmbh | Fibra kraft de madera blanda que tiene un contenido mejorado de a-celulosa, y su uso en la produccion de productos de celulosa quimica. |
WO2014140852A2 (fr) | 2013-03-14 | 2014-09-18 | Gp Cellulose Gmbh | Procédé de fabrication d'une fibre kraft extrêmement fonctionnelle et de viscosité faible, en utilisant une séquence de blanchiment acide, et fibre fabriquée par ce procédé |
BR112015020000A2 (pt) | 2013-03-15 | 2017-07-18 | Gp Cellulose Gmbh | fibra kraft quimicamente modificada e métodos de fabricação da mesma |
WO2017055504A1 (fr) * | 2015-09-30 | 2017-04-06 | Imerys Minerals Limited | Procédés de blanchiment de pâtes aqueuses, et compositions destinées à être utilisées dans ces procédés |
CA3040734A1 (fr) | 2016-11-16 | 2018-05-24 | Gp Cellulose Gmbh | Cellulose modifiee a base de fibres chimiques et procedes de fabrication et d'utilisation de ladite cellulose modifiee |
WO2021209586A1 (fr) * | 2020-04-16 | 2021-10-21 | Bim Kemi Ab | Procédé de délignification |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1206704A (fr) * | 1982-01-28 | 1986-07-02 | Dominique Lachenal | Procede pour le traitement de pates papetieres chimiques |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3507744A (en) * | 1966-04-01 | 1970-04-21 | Kimberly Clark Co | Wood pulp bleaching process utilizing peroxide pyrophosphate high concentration compositions |
SE335053B (fr) * | 1969-05-13 | 1971-05-10 | Mo Och Domsjoe Ab | |
DE2742262C2 (de) * | 1977-09-20 | 1982-06-09 | Degussa Ag, 6000 Frankfurt | Verfahren zur Herstellung eines mittel- bis hochviskosen Nadelholz-Sulfitzellstoffs |
FR2557605B1 (fr) * | 1983-12-29 | 1987-12-11 | Atochem | Procede de blanchiment de pates papetieres par le peroxyde d'hydrogene |
JPH0364589A (ja) * | 1989-07-28 | 1991-03-19 | Mitsubishi Gas Chem Co Inc | 化学パルプの漂白方法 |
-
1991
- 1991-04-30 SE SE9101301A patent/SE470065C/sv not_active IP Right Cessation
-
1992
- 1992-04-08 DE DE69227640T patent/DE69227640T2/de not_active Expired - Fee Related
- 1992-04-08 AT AT94203640T patent/ATE173518T1/de not_active IP Right Cessation
- 1992-04-08 EP EP94203640A patent/EP0679760B1/fr not_active Expired - Lifetime
- 1992-04-08 EP EP92201005A patent/EP0511695B2/fr not_active Expired - Lifetime
- 1992-04-08 ES ES92201005T patent/ES2091395T3/es not_active Expired - Lifetime
- 1992-04-08 AT AT92201005T patent/ATE141971T1/de not_active IP Right Cessation
- 1992-04-08 DE DE69213080T patent/DE69213080D1/de not_active Expired - Lifetime
- 1992-04-23 NZ NZ242465A patent/NZ242465A/en unknown
- 1992-04-27 FI FI921886A patent/FI111964B/fi active
- 1992-04-27 CA CA002067296A patent/CA2067296C/fr not_active Expired - Fee Related
- 1992-04-28 BR BR929201554A patent/BR9201554A/pt not_active IP Right Cessation
- 1992-04-28 JP JP4134325A patent/JP2592747B2/ja not_active Expired - Fee Related
- 1992-04-28 ZA ZA923073A patent/ZA923073B/xx unknown
- 1992-04-28 MX MX9201966A patent/MX9201966A/es unknown
- 1992-04-29 RU SU925011770A patent/RU2039141C1/ru not_active IP Right Cessation
- 1992-04-29 NO NO19921671A patent/NO180495C/no not_active IP Right Cessation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1206704A (fr) * | 1982-01-28 | 1986-07-02 | Dominique Lachenal | Procede pour le traitement de pates papetieres chimiques |
Non-Patent Citations (1)
Title |
---|
J.P. CASEY: "Pulp and Paper; Chemistry and Chemical Technology, 3rd edition, vol. I, page 651", JOHN WILEY & SONS, NEW YORK * |
Also Published As
Publication number | Publication date |
---|---|
SE470065C (sv) | 1995-10-12 |
EP0511695B2 (fr) | 2004-06-02 |
FI921886A0 (fi) | 1992-04-27 |
ATE173518T1 (de) | 1998-12-15 |
RU2039141C1 (ru) | 1995-07-09 |
ZA923073B (en) | 1992-12-30 |
DE69227640T2 (de) | 1999-05-06 |
ATE141971T1 (de) | 1996-09-15 |
NO180495C (no) | 2003-06-06 |
EP0511695A1 (fr) | 1992-11-04 |
EP0511695B1 (fr) | 1996-08-28 |
SE9101301L (sv) | 1992-10-31 |
BR9201554A (pt) | 1992-12-01 |
JP2592747B2 (ja) | 1997-03-19 |
SE470065B (sv) | 1993-11-01 |
FI921886A (fi) | 1992-10-31 |
ES2091395T3 (es) | 1996-11-01 |
SE9101301D0 (sv) | 1991-04-30 |
DE69213080D1 (de) | 1996-10-02 |
JPH05148784A (ja) | 1993-06-15 |
MX9201966A (es) | 1992-11-01 |
FI111964B (fi) | 2003-10-15 |
NZ242465A (en) | 1993-12-23 |
AU651192B2 (en) | 1994-07-14 |
NO921671L (no) | 1992-11-02 |
AU1514992A (en) | 1993-03-11 |
CA2067296C (fr) | 1997-03-04 |
NO180495B (no) | 1997-01-20 |
CA2067296A1 (fr) | 1992-10-31 |
EP0679760A1 (fr) | 1995-11-02 |
DE69227640D1 (de) | 1998-12-24 |
NO921671D0 (no) | 1992-04-29 |
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