EP0677580B1 - Waschmittelzusammensetzungen mit Zusätzen zur Verhinderung der Farbstoffübertragung sowie Verfahren zur deren Herstellung - Google Patents

Waschmittelzusammensetzungen mit Zusätzen zur Verhinderung der Farbstoffübertragung sowie Verfahren zur deren Herstellung Download PDF

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Publication number
EP0677580B1
EP0677580B1 EP94302676A EP94302676A EP0677580B1 EP 0677580 B1 EP0677580 B1 EP 0677580B1 EP 94302676 A EP94302676 A EP 94302676A EP 94302676 A EP94302676 A EP 94302676A EP 0677580 B1 EP0677580 B1 EP 0677580B1
Authority
EP
European Patent Office
Prior art keywords
weight
vinylpyrrolidone
vinylimidazole
free
polyamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP94302676A
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English (en)
French (fr)
Other versions
EP0677580A1 (de
Inventor
Scott John Donoghue
Koen Mariette Albert Schamp
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DK94302676T priority Critical patent/DK0677580T3/da
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to DE69431652T priority patent/DE69431652T2/de
Priority to PT94302676T priority patent/PT677580E/pt
Priority to EP94302676A priority patent/EP0677580B1/de
Priority to ES94302676T priority patent/ES2183828T3/es
Priority to AT94302676T priority patent/ATE227333T1/de
Priority to PCT/US1995/004210 priority patent/WO1995028462A1/en
Priority to US08/727,558 priority patent/US5849684A/en
Priority to CA002187439A priority patent/CA2187439C/en
Priority to JP7526999A priority patent/JPH09512051A/ja
Priority to CN95193437A priority patent/CN1077135C/zh
Publication of EP0677580A1 publication Critical patent/EP0677580A1/de
Application granted granted Critical
Publication of EP0677580B1 publication Critical patent/EP0677580B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C11D17/065—High-density particulate detergent compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3792—Amine oxide containing polymers

Definitions

  • US4414130 discloses a "readily disintegrable, insoluble, detergent builder particulate agglomerate comprising [aluminosilicate] held together by a water soluble binder.”
  • a binder which is mentioned is Polyclar ®, a PVP supplied by GAF.
  • Methods of manufacturing agglomerates include the use of a fine spray of water to promote adhesion.
  • Example 2(B) discloses a solution of polyvinyl pyrollidone and polyvinyl alcohol which is agglomerated with zeolite. This patent is not, however, concerned with the problems of formulating and processing dye transfer inhibiting agents.
  • GB-A-1 348 212 relates to detergent compositions with improved dye-transfer control characteristics comprising 60 to 95 % by weight of nonionic detergent and a homopolymer of vinylpyrrolidone or a copolymer of vinylpyrrolidone and a suitable comonomer.
  • polyvinyl pyrrolidone is useful as a dye transfer inhibitor, other polymers are being sought which are even more effective.
  • a more effective polymer is one which can be used in smaller quantities than polyvinyl pyrollidone to achieve the same effect, and which is cheaper.
  • the present invention provides a high density agglomerate which comprises copolymers of N-vinylpyrrolidone and N-vinylimidazole, at levels of 5% to 50% by weight, comprising very low levels of surfactant, ie. less than 2 % by weight.
  • the present invention also provides a process in which a premix of specific hygroscopic dye transfer inhibition polymer with zeolite (or other powder) is prepared prior to agglomeration.
  • the present invention provides a free-flowing powder having a bulk density of at least 600 g/l comprising:
  • the free-flowing powder comprises (a) from 50% to 75% by weight (on anhydrous basis) of aluminosilicate and (b) a mixture of polyamine N-oxide and copolymer of N-vinylpyrrolidone and N-vinylimidazole, the total polymer level being from 10% to 30% by weight of the powder.
  • the mixture of polyamine N-oxide and copolymers of N-vinylpyrrolidone and N-vinylimidazole is typically in the ratio of from 5:1 to 1:5, and is preferably about 1:1.
  • the present invention provides a process for making free-flowing particles comprising hygroscopic powders of polymers comprising the steps of:
  • the aqueous binder in step (b) is preferably an aqueous solution of polyamine N-oxide. Again, less than 2 % by weight of surfactant is present.
  • step of (c) drying the mixture of the premix and aqueous solution of binder to form the free-flowing particles may also be included in the process.
  • the aluminosilicate, and any other salt present is usually fully hydrated prior to the high shear mixer.
  • An essential ingredient of the free-flowing powders of the present invention is a copolymer of N-vinylpyrrolidone and N-vinylimidazole dye transfer inhibiting agent.
  • Polymeric dye transfer inhibiting agents are normally incorporated into detergent compositions in order to inhibit the transfer of dyes from colored fabrics onto fabrics washed therewith. These polymers have the ability to complex or adsorb the fugitive dyes washed out of dyed fabrics before the dyes have the opportunity to become attached to other articles in the wash.
  • further polymeric dye transfer inhibiting agents are polyamine N-oxide polymers, polyvinylpyrrolidone polymers, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof.
  • polyamine N-oxide polymers suitable for use contain units having the following structure formula :
  • the N-O group can be part of the polymerisable unit (P) or can be attached to the polymeric backbone or a combination of both.
  • Suitable polyamine N-oxides wherein the N-O group forms part of the polymerisable unit comprise polyamine N-oxides wherein R is selected from aliphatic, aromatic, alicyclic or heterocyclic groups.
  • R is selected from aliphatic, aromatic, alicyclic or heterocyclic groups.
  • One class of said polyamine N-oxides comprises the group of polyamine N-oxides wherein the nitrogen of the N-O group forms part of the R-group.
  • Preferred polyamine N-oxides are those wherein R is a heterocyclic group such as pyrridine, pyrrole, imidazole, pyrrolidine, piperidine, quinoline, acridine and derivatives thereof.
  • Another class of said polyamine N-oxides comprises the group of polyamine N-oxides wherein the nitrogen of the N-O group is attached to the R-group.
  • polyamine N-oxides are the polyamine oxides whereto the N-O group is attached to the polymerisable unit.
  • Preferred class of these polyamine N-oxides are the polyamine N-oxides having the general formula (I) wherein R is an aromatic, heterocyclic or alicyclic groups wherein the nitrogen of the N-0 functional group is part of said R group.
  • the polyamine oxides can be obtained in almost any degree of polymerisation.
  • the degree of polymerisation is not critical provided the material has the desired water-solubility and dye-suspending power.
  • the average molecular weight is within the range of 500 to 1000,000; preferably from 1,000 to 50,000, more preferably from 2,000 to 30,000, most preferably from 3,000 to 20,000.
  • the N-vinylimidazole N-vinylpyrrolidone polymers used in the present invention have an average molecular weight range from 5,000-1,000,000, preferably from 20,000-200,000.
  • Highly preferred polymers for use in detergent compositions according to the present invention comprise a polymer selected from N-vinylimidazole N-vinylpyrrolidone copolymers wherein said polymer has an average molecular weight range from 5,000 to 50,000 more preferably from 8,000 to 30,000, most preferably from 10,000 to 20,000.
  • the average molecular weight range was determined by light scattering as described in Barth H.G. and Mays J.W. Chemical Analysis Vol 113,"Modern Methods of Polymer Characterization".
  • N-vinylimidazole N-vinylpyrrolidone copolymers have an average molecular weight range from 5,000 to 50,000; more preferably from 8,000 to 30,000; most preferably from 10,000 to 20,000.
  • Sodium aluminosilicate may take many forms.
  • One example is crystalline aluminosilicate ion exchange material of the formula Na z [(AlO 2 ) z ⁇ (SiO 2 ) y ] ⁇ xH 2 O wherein z and y are at least about 6, the molar ratio of z to y is from about 1.0 to about 0.4 and z is from about 10 to about 264.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Coloring (AREA)

Claims (8)

  1. Freifließendes Pulver mit einer Schüttdichte von mindestens 600 g/l, umfassend:
    (a) 20 bis 95 Gew.-% (auf wasserfreier Basis) eines Reinigungsmittelbestandteils, gewählt aus der Gruppe, bestehend aus Aluminosilicat, Citrat, Silica, Carbonat, Bicarbonat, Silicat, Sulfat, Phoshpat, wasserlösliches Polymer und Mischungen hiervon;
    (b). 5 bis 50 Gew.-% eines Copolymeren von N-Vinylpyrrolidon und N-Vinylimidazol mit einem Durchschnittsmolekulargewichtsbereich von 5.000 bis 1.000.000 und einem Molverhältnis von N-Vinylimidazol zu N-Vinylpyrrolidon von 1 bis 0,2; und
    dadurch gekennzeichnet, daß der Gehalt an Tensid weniger als 2 Gew.-% beträgt.
  2. Freifließendes Pulver nach Anspruch 1, umfassend:
    (a) 50 bis 75 Gew.-% (auf wasserfreier Basis) Aluminosilicat;
    (b) 10 bis 30 Gew.-% einer Mischung aus Polyamin-N-oxid und einem Copolymer von N-Vinylpyrrolidon und N-Vinylimidazol.
  3. Freifließendes Pulver nach Anspruch 2, umfassend eine Mischung aus Polyamin-N-oxid (i) und einem Copolymer von N-Vinylpyrrolidon und N-Vinylimidazol (ii), wobei das Verhältnis von (i) zu (ii) 5:1 bis 1:5 beträgt, und vorzugsweise etwa 1:1 ist.
  4. Verfahren zur Herstellung freifließender Teilchen, umfassend hygroskopische Pulver von Polymeren, umfassend die Schritte:
    (a) Mischen eines pulverförmigen Polymeren mit zusätzlichen Pulvern, wobei die zusätzlichen Pulver aus der Gruppe gewählt sind, bestehend aus Aluminosilicat, Citrat, Silica, Carbonat, Bicarbonat, Silicat, Sulfat, Phosphat, wasserlösliches Polymer und Mischungen hiervon, um eine Pulvervormischung zu bilden;
    (b) Vermischen der Vormischung mit einer wäßrigen Lösung eines Bindemittels in einem Hochschermischer, um freifließende Teilchen zu bilden.
    dadurch gekennzeichnet, daß das pulverförmige Polymer in Schritt (a) ein Copolymer von N-Vinylpyrrolidon und N-Vinylimidazol mit einem Durchschnittsmolekulargewichtsbereich von 5.000 bis 1.000.000 und einem Molverhältnis von N-Vinylimidazol zu N-Vinylpyrrolidon von 1 bis 0,2 umfaßt, die wäßrige Lösung eines Bindemittels in Schritt (b) eine wäßrige Lösung eines Polyamin-N-oxid-Polymeren ist, und weniger als 2% Tensid in den Teilchen vorliegen.
  5. Verfahren nach Anspruch 4, wobei das pulverförmige Polymer in Schritt (a) ein Copolymer von N-Vinylpyrrolidon und N-Vinylimidazol ist, und die wäßrige Lösung eines Bindemittels in Schritt (b) eine wäßrige Lösung von Polyamin-N-oxid ist.
  6. Verfahren nach Anspruch 5, umfassend die Schritte:
    (a) Mischen von 5 bis 25 Gew.-% eines pulverförmigen Copolymeren von N-Vinylpyrrolidon und N-Vinylimidazol mit 50 bis 75 Gew.-% (auf wasserfreier Basis) Natriumaluminosilicat, zur Bildung einer Vormischung, und
    (b) Vermischen der Vormischung mit 5 bis 25 Gew.-% (auf Wirkstoffbasis) einer wäßrigen Lösung von Polyamin-N-oxid in einem Hochschermischer zur Bildung freifließender Teilchen.
  7. Verfahren nach mindestens einem der Ansprüche 4 bis 6, umfassend weiterhin den Schritt
    (c) Trocknen der Mischung aus der Vormischung und der wäßrigen Bindemittellösung zur Bildung der freifließenden Teilchen.
  8. Verfahren nach Anspruch 4, wobei das Aluminosilicat und irgendein anderes vorliegendes Salz vor dem Hochschermischen vollständig hydratisiert wird.
EP94302676A 1994-04-14 1994-04-14 Waschmittelzusammensetzungen mit Zusätzen zur Verhinderung der Farbstoffübertragung sowie Verfahren zur deren Herstellung Expired - Lifetime EP0677580B1 (de)

Priority Applications (11)

Application Number Priority Date Filing Date Title
DE69431652T DE69431652T2 (de) 1994-04-14 1994-04-14 Waschmittelzusammensetzungen mit Zusätzen zur Verhinderung der Farbstoffübertragung sowie Verfahren zur deren Herstellung
PT94302676T PT677580E (pt) 1994-04-14 1994-04-14 Composicoes detergentes compreendendo inibidores de transferencia de corantes e processo para a sua producao
EP94302676A EP0677580B1 (de) 1994-04-14 1994-04-14 Waschmittelzusammensetzungen mit Zusätzen zur Verhinderung der Farbstoffübertragung sowie Verfahren zur deren Herstellung
ES94302676T ES2183828T3 (es) 1994-04-14 1994-04-14 Composiciones detergentes que comprenden inhibidores de la transferencia de colorante, y procedimientos para obtenerlas.
AT94302676T ATE227333T1 (de) 1994-04-14 1994-04-14 Waschmittelzusammensetzungen mit zusätzen zur verhinderung der farbstoffübertragung sowie verfahren zur deren herstellung
DK94302676T DK0677580T3 (da) 1994-04-14 1994-04-14 Detergentsammensætning omfattende farveoverføringsinhibitorer og fremgangsmåde til fremstilling deraf
PCT/US1995/004210 WO1995028462A1 (en) 1994-04-14 1995-04-03 Detergent compositions comprising dye transfer inhibitors, and process for making them
US08/727,558 US5849684A (en) 1994-04-14 1995-04-03 Detergent additives comprising dye transfer inhibitors, and process for making them
CA002187439A CA2187439C (en) 1994-04-14 1995-04-03 Detergent compositions comprising dye transfer inhibitors, and process for making them
JP7526999A JPH09512051A (ja) 1994-04-14 1995-04-03 移染防止剤を含んでなる洗剤組成物およびその製造方法
CN95193437A CN1077135C (zh) 1994-04-14 1995-04-03 包含染料转移抑制剂的洗涤剂组合物及其生产方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP94302676A EP0677580B1 (de) 1994-04-14 1994-04-14 Waschmittelzusammensetzungen mit Zusätzen zur Verhinderung der Farbstoffübertragung sowie Verfahren zur deren Herstellung

Publications (2)

Publication Number Publication Date
EP0677580A1 EP0677580A1 (de) 1995-10-18
EP0677580B1 true EP0677580B1 (de) 2002-11-06

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EP94302676A Expired - Lifetime EP0677580B1 (de) 1994-04-14 1994-04-14 Waschmittelzusammensetzungen mit Zusätzen zur Verhinderung der Farbstoffübertragung sowie Verfahren zur deren Herstellung

Country Status (10)

Country Link
EP (1) EP0677580B1 (de)
JP (1) JPH09512051A (de)
CN (1) CN1077135C (de)
AT (1) ATE227333T1 (de)
CA (1) CA2187439C (de)
DE (1) DE69431652T2 (de)
DK (1) DK0677580T3 (de)
ES (1) ES2183828T3 (de)
PT (1) PT677580E (de)
WO (1) WO1995028462A1 (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9523571D0 (en) * 1995-11-17 1996-01-17 Unilever Plc Detergent compositions
US6133224A (en) * 1996-12-20 2000-10-17 The Procter & Gamble Company Process for making a free-flowing particulate dye transfer inhibiting detergent admix
GB9814819D0 (en) * 1998-07-08 1998-09-09 Unilever Plc Dye-transfer-inhibiting compositions and particulate detergent compositions containing them
GB9814822D0 (en) 1998-07-08 1998-09-09 Unilever Plc Dye-transfer-inhibiting compositions and particulate detergent compositions containing them
EP1201814A1 (de) * 2000-10-27 2002-05-02 The Procter & Gamble Company Behandlung von Geweben im Haushalt mit filmbildenden Materialien und Schäumungsmitteln
MY164215A (en) 2010-10-14 2017-11-30 Unilever Nv Laundry detergent particles
EP2627750B1 (de) 2010-10-14 2015-04-08 Unilever PLC Herstellung von waschmitteln in form von beschichteten partikeln
EP2627760B1 (de) 2010-10-14 2016-08-10 Unilever PLC Waschmittelteilchen
MX340440B (es) 2010-10-14 2016-07-08 Unilever N V * Particula de detergente para lavanderia.
EP2627757B1 (de) 2010-10-14 2016-11-02 Unilever PLC Waschmittelpartikel
MX2013003963A (es) * 2010-10-14 2013-06-28 Unilever Nv Particulas de detergente para lavanderia.
WO2012117024A1 (de) * 2011-03-01 2012-09-07 Basf Se Farbübertragungsinhibierend wirkende polymere mit verbesserter lagerstabilität und verarbeitbarkeit für wasch- und reinigungsmittel
CN106049106B (zh) * 2016-07-01 2018-06-19 施海峰 一种蒙脱土匀染剂及其制备方法
EP3802938A1 (de) 2018-05-25 2021-04-14 The Procter & Gamble Company Verfahren zur herstellung eines vliesstoffes und dafür geeignete vorrichtung
EP3802939A1 (de) * 2018-05-25 2021-04-14 The Procter & Gamble Company Vliesstoff und verfahren und vorrichtung zur herstellung davon

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1348212A (en) * 1971-07-02 1974-03-13 Procter & Gamble Detergent composition with dye-transfer control characteristics

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Publication number Priority date Publication date Assignee Title
DE2814287A1 (de) * 1978-04-03 1979-10-11 Henkel Kgaa Waschmittel mit einem gehalt an verfaerbungsinhibierenden zusaetzen
DE3803630A1 (de) * 1988-02-06 1989-08-17 Henkel Kgaa Waschmittelzusatz
EP0367339B1 (de) * 1988-11-02 1996-03-13 Unilever N.V. Verfahren zur Herstellung einer körnigen Reinigungsmittelzusammensetzung mit hoher Schüttdichte
GB9016504D0 (en) * 1990-07-27 1990-09-12 Warwick Int Ltd Granular bleach activator compositions
ATE172749T1 (de) * 1992-07-15 1998-11-15 Procter & Gamble Waschmittelzusammensetzungen zur verhinderung der farbstoffübertragung
EP0581751B1 (de) * 1992-07-15 1998-12-09 The Procter & Gamble Company Enzym enthaltende Waschmittelzusammensetzungen zur Verhinderung der Farbstoffübertragung
DE4235798A1 (de) * 1992-10-23 1994-04-28 Basf Ag Verwendung von Vinylpyrrolidon- und Vinylimidazol-Copolymerisaten als Waschmitteladditiv, neue Polymerisate des Vinylpyrrolidons und des Vinylimidazols und Verfahren zu ihrer Herstellung

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1348212A (en) * 1971-07-02 1974-03-13 Procter & Gamble Detergent composition with dye-transfer control characteristics

Also Published As

Publication number Publication date
ES2183828T3 (es) 2003-04-01
PT677580E (pt) 2003-03-31
WO1995028462A1 (en) 1995-10-26
DE69431652T2 (de) 2003-09-18
EP0677580A1 (de) 1995-10-18
DK0677580T3 (da) 2002-11-25
CN1149885A (zh) 1997-05-14
CA2187439C (en) 2001-01-16
JPH09512051A (ja) 1997-12-02
ATE227333T1 (de) 2002-11-15
DE69431652D1 (de) 2002-12-12
CN1077135C (zh) 2002-01-02
CA2187439A1 (en) 1995-10-26

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