EP0675979A1 - Adjuvants pour fibres - Google Patents

Adjuvants pour fibres

Info

Publication number
EP0675979A1
EP0675979A1 EP94903762A EP94903762A EP0675979A1 EP 0675979 A1 EP0675979 A1 EP 0675979A1 EP 94903762 A EP94903762 A EP 94903762A EP 94903762 A EP94903762 A EP 94903762A EP 0675979 A1 EP0675979 A1 EP 0675979A1
Authority
EP
European Patent Office
Prior art keywords
carbon atoms
methyl
hydrogen
fatty acid
acyl radical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP94903762A
Other languages
German (de)
English (en)
Inventor
Joaquim Bigorra Llosas
Maria Dolors L Pez G Mez
Antoni Soler Codina
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0675979A1 publication Critical patent/EP0675979A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C219/00—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C219/02—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C219/04—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C219/06—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having the hydroxy groups esterified by carboxylic acids having the esterifying carboxyl groups bound to hydrogen atoms or to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C219/00—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C219/02—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C219/04—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C219/08—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having at least one of the hydroxy groups esterified by a carboxylic acid having the esterifying carboxyl group bound to an acyclic carbon atom of an acyclic unsaturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/16—Anti-static materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Definitions

  • the invention relates to auxiliaries for synthetic fibers which contain quaternized fatty acid triethanolamine ester salts and to the use of these salts for the preparation of the agents mentioned.
  • spin finishes In addition to the smoothness and the thread closure, the fiber manufacturers generally place further requirements on spin finishes, of which the reduction in friction, the softening of the fiber filaments and the compatibility with Dyes are the main ones. In addition to the requirements mentioned, spin finishes must be temperature-resistant and non-corrosive, easy to remove from the fiber and physiologically harmless. Cationic surfactants, in particular of the quaternized fatty amine type, are usually used for this purpose. However, these show the disadvantage of a biodegradability which is not satisfactory in all cases.
  • the object of the invention was to provide new auxiliaries for the production of synthetic fibers which have improved biodegradability.
  • the invention relates to fiber auxiliaries which contain quaternized fatty acid triethanolamine ester salts of the formula (I) as active component,
  • R --- CO is an acyl radical having 6 to 22 carbon atoms
  • R and R 2 independently of one another are hydrogen or R --- CO
  • R 1 is an alkyl radical having 1 to 10 carbon atoms
  • x, y and z are 1 or numbers from 2 to 30
  • X is a halide or alkyl sulfate.
  • the salts according to the invention reduce the electrostatic charge on synthetic fibers. They also have fiber-enhancing properties, are stable at high temperatures, readily biodegradable and physiologically harmless.
  • the quaternized fatty acid triethanolamine ester salts are known substances which can be obtained by the relevant methods of preparative organic chemistry.
  • a process for their preparation as described in international patent application WO 91/1295 (Henkel), consists in esterifying fatty acids with triethanolamine in the presence of hypophosphorous acid and the technical fatty acid ester mixture, the mono-, di- and tri - contains ester, then quaternize with methyl chloride or diethyl sulfate.
  • polyglycol ether group-containing, ie ethoxylated, quaternized fatty acid triethanolamine ester salts are the subject of a previously unpublished application by the applicant.
  • ethoxylated triethanolamine which in turn is esterified and quaternized in a known manner. In this case, you usually add an average of 2 to 30, preferably 2 to 10 moles of ethylene oxide of triethanolamine in the esterification.
  • quaternized fatty acid triethanolamine ester salts are used for the preparation of the antistatic agents, fatty acid and triethanolamine or triethanolamine ethoxylate in a molar ratio of 1.2: 1 to 2.1: 1, preferably 1.64: 1 to 1.92: 1 have been used.
  • Fiber auxiliaries with particularly advantageous technical properties are obtained if quaternized fatty acid triethanola ester salts of the formula (I) are used in which
  • R ⁇ O is an acyl radical having 16 to 18 carbon atoms
  • R2 and R3 is hydrogen
  • R 4 is methyl
  • x, y and z are each 1
  • X is chloride or methyl sulfate
  • R - CO is an acyl radical with 16 to 18 carbon atoms
  • R2 and R3 are hydrogen
  • R 4 is methyl
  • x, y and z are numbers from 2 to 30
  • X is chloride or methyl sulfate
  • Quaternized fatty acid triethanolamine ester salts reduce the electrostatic charge on fibers and reduce the friction between the filaments. They have revitalizing properties, are temperature-stable and easily biodegradable.
  • Another object of the invention therefore relates to the use of the quaternized fatty acid triethanolamine ester salts for the production of spin finishes and finishing agents for synthetic fibers, in particular acrylic and polyester fibers.
  • the spin finishes or finishing agents are applied in the form of aqueous dispersions to the synthetic fibers immediately after they emerge from the spinneret.
  • the agents which have a temperature between 18 and 60 ° C, z. B. applied by application rollers or dosing pumps via suitable applicators.
  • the agents are preferably used in the form of their aqueous dispersions, which have a solids content of 3 to 40, preferably 5 to 30,% by weight and, in addition to the quaternized fatty acid triethanolamine ester salts, also other customary ingredients, such as, for example, synthetic ester oils , Sorbitan esters, silicones, polyethers, phosphoric acid esters, fatty acid alkanolamines, ethoxylated fatty acids and block polymers of ethylene and propylene oxide ("Pluronic types”) and the like.
  • the proportion of quaternized fatty acid triethanolamine ester salts in the compositions can be 1 to 100, preferably 30 to 70% by weight, based on the solids content.
  • the application amount of the spin finishes or finishing agents in the form of their aqueous dispersions is in the range customary for the fiber industry between 0.1 and 30, preferably 1 to 20% by weight, based on the weight of the fibers.
  • Base tallow acid unhardened
  • Base coconut fatty acid unhardened
  • Base tallow acid hardened
  • Base tallow acid 50% hardened
  • Dye bleeding (dye: cationic black) visual assessment:

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

L'invention concerne des sels quaternaires d'esters de triéthanolamine d'acide gras de la formule (I) dans laquelle R1CO désigne un reste acyle ayant 6 à 22 atomes de carbone, R¿2? et R3 désigent indépendamment l'un de l'autre hydrogène ou R?1CO, R4¿ désigne un reste alkyle ayant 1 à 10 atomes de carbone, x, y et z valent 1 ou des nombres compris entre 2 et 30 et X représente un haloïde ou un sulfate d'alkyle. Ces sels quaternaires d'esters de triéthanolamine d'acide gras sont appropriés pour être utilisés dans la fabrication d'adjuvants pour fibres synthétiques.
EP94903762A 1992-12-22 1993-12-13 Adjuvants pour fibres Withdrawn EP0675979A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19924243550 DE4243550C1 (de) 1992-12-22 1992-12-22 Faserhilfsmittel und deren Verwendung
DE4243550 1992-12-22
PCT/EP1993/003518 WO1994015011A1 (fr) 1992-12-22 1993-12-13 Adjuvants pour fibres

Publications (1)

Publication Number Publication Date
EP0675979A1 true EP0675979A1 (fr) 1995-10-11

Family

ID=6476170

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94903762A Withdrawn EP0675979A1 (fr) 1992-12-22 1993-12-13 Adjuvants pour fibres

Country Status (3)

Country Link
EP (1) EP0675979A1 (fr)
DE (1) DE4243550C1 (fr)
WO (1) WO1994015011A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19714044C1 (de) * 1997-04-05 1998-04-16 Henkel Kgaa Hydrophile Avivagemittel sowie Verwendung von Mischungen, enthaltend Esterquats und Siliconverbindungen zur Herstellung derselben
DE19829788A1 (de) * 1998-07-03 2000-01-05 Henkel Kgaa Verwendung von Esterquats als Antistatika
DE19903715C2 (de) 1999-01-30 2002-12-05 Cognis Deutschland Gmbh Verwendung von Fettsäurealkanolaminestern als interne Antistatika für thermoplastische Kunststoffe
DE10054020B4 (de) * 2000-11-01 2007-04-26 Cognis Ip Management Gmbh Verwendung von Mischungen als Textilbehandlungsmittel

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1469399A1 (de) * 1965-07-01 1968-12-12 Henkel & Cie Gmbh Weichmachungsmittel fuer Textilien
DE1619058A1 (de) * 1967-12-01 1971-01-28 Hoechst Ag Mittel zur Behandlung von Textilien
DE1935499A1 (de) * 1969-07-12 1971-01-14 Basf Ag Avivagemittel
DE2525610C2 (de) * 1975-06-09 1985-04-11 Henkel KGaA, 4000 Düsseldorf Kationische Avivagemittel mit verbesserter Kaltwasserlöslichkeit
DE69121887T2 (de) * 1991-07-29 1997-04-03 Kao Corp Verfahren zur Herstellung von quartären Verbindungen
DE4135115A1 (de) * 1991-10-24 1993-04-29 Trigon Chemie Gmbh Kationaktive tenside
DE4203489A1 (de) * 1992-02-07 1993-08-12 Henkel Kgaa Verfahren zur herstellung niedrigviskoser waessriger esterquat-konzentrate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9415011A1 *

Also Published As

Publication number Publication date
WO1994015011A1 (fr) 1994-07-07
DE4243550C1 (de) 1994-06-01

Similar Documents

Publication Publication Date Title
EP0614349B1 (fr) Utilisation de sels d'esters de trialkanolamines d'acides gras quaternises et d'alcools gras et/ou d'esters polyglycoliques d'alcools gras pour la production de compositions pour les soins des cheveux
EP0583446B1 (fr) Dispersions de cire, leur preparation et utilisation
DE4334365A1 (de) Quaternierte Fettsäuretriethanolaminester-Salze mit verbesserter Wasserlöslichkeit
DE3501293C2 (fr)
EP0729450B1 (fr) Procede de preparation d'esters quaternaires solides
EP0741774B1 (fr) Melanges detergents
DE4243547C2 (de) Quaternierte Fettsäure-triethanolaminester-Salze
DE4243550C1 (de) Faserhilfsmittel und deren Verwendung
EP0918901B1 (fr) Usage d'apprets pour textile
DE2812443A1 (de) Alkylpolyglykolmischformale als faserpraeparationsmittel
DE68911493T2 (de) Schlichtemittel für Glasfasern.
EP0075261B1 (fr) Agent pour préparer des fibres
EP0331030A1 (fr) Phosphates d'imidazolinium quaternaires
EP1282739B1 (fr) Utilisation des melanges tensioactifs pour la preparation de fibres textiles produites a grande vitesse
EP0869168A2 (fr) Composition pour rendre les textiles hydrophiles
DE2415651C2 (de) Schmälze für Textilfasern
DE10054020B4 (de) Verwendung von Mischungen als Textilbehandlungsmittel
DE3732378A1 (de) Praeparationsmittel fuer stapelfasern aus synthetischen polymeren
EP0674699B1 (fr) Agents d'avivage actifs anioniques sans azote
EP0470102B1 (fr) Utilisation de la Triacetine dans des Lubrifiants Textiles
JP2669561B2 (ja) 高速用紡績油剤
AT254122B (de) Verfahren zum Präparieren von Polyesterfäden
DE2447410B2 (de) Praeparationsmittel zur herstellung von synthetischen stapelfasern mit ausgepraegter oeffnungswilligkeit
DE3851748T2 (de) Schmiermittelzusammensetzung für spinnfasern.
JPH02175966A (ja) 合成繊維用処理剤

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19950613

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): DE ES GB IT

17Q First examination report despatched

Effective date: 19960925

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN

18W Application withdrawn

Withdrawal date: 19970113