EP0645781A1 - Energiekabel mit verbesserter dielektrischen Festigkeit - Google Patents
Energiekabel mit verbesserter dielektrischen Festigkeit Download PDFInfo
- Publication number
- EP0645781A1 EP0645781A1 EP94402053A EP94402053A EP0645781A1 EP 0645781 A1 EP0645781 A1 EP 0645781A1 EP 94402053 A EP94402053 A EP 94402053A EP 94402053 A EP94402053 A EP 94402053A EP 0645781 A1 EP0645781 A1 EP 0645781A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- dielectric layer
- polymer
- insulating
- core
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B9/00—Power cables
- H01B9/02—Power cables with screens or conductive layers, e.g. for avoiding large potential gradients
- H01B9/027—Power cables with screens or conductive layers, e.g. for avoiding large potential gradients composed of semi-conducting layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B9/00—Power cables
- H01B9/02—Power cables with screens or conductive layers, e.g. for avoiding large potential gradients
Definitions
- the present invention relates to high voltage power cables and direct or alternating current. It relates more particularly to such an energy cable with improved dielectric strength.
- This power cable includes a polymeric insulation, preferably extruded.
- the insulation covers an internal semiconductor screen, itself covering the conductive core of the cable, and is covered with an external semiconductor screen.
- This polymeric insulator has a high intrinsic dielectric strength. Its practical dielectric strength, obtained on the cable, is less than its intrinsic stiffness. This difference is mainly due to the presence of impurities or cavities, which are introduced or formed before and / or during the use of the insulation on the cable, give rise to local concentrations of electric field in the insulation and are the source of possible electrical faults through the cable insulation.
- Document JP-A-2-18811 describes an energy cable with polymeric insulation containing from 0.2 to 1.5% by mass of carbon black.
- the insulation thus modified can be implemented directly on the conductive core of the cable.
- the small quantity of carbon black which it contains reduces the risks of electrical faults which may be due to peripheral irregularities of the core and to impurities or internal cavities of the insulator, by improving the homogeneity of distribution of the electric field and therefore cable reliability. It gives the insulator a slight electrical conductivity, as such weak but not zero.
- This conductivity is constant and directly linked to the intrinsic electrical conductivity of carbon black, typically from 10 to 100 S / cm, contained in the insulator. It promotes leakage currents in the insulation and increases its dielectric losses. It reduces the intrinsic dielectric strength of the insulation thus modified and by there its practical dielectric rigidity on the cable, this independently of the presence or not of irregularities or internal cavities.
- the present invention aims to produce an energy cable whose polymeric insulation is of high dielectric strength, which only adapts locally to possible impurities or cavities.
- a direct current energy cable with improved dielectric strength comprising an electrical core and a first polymeric dielectric layer for insulating said core, characterized in that said first dielectric layer is constituted by an insulating polymer matrix containing at least one conductive polymer, incorporated in said polymer matrix with a mass rate such that the electrical conductivity resulting from said first dielectric layer is less than 10 ⁇ 14 S / cm.
- an AC power cable with improved dielectric strength comprising an electrical core and a first polymeric dielectric layer for insulating said core, characterized in that said first dielectric layer is constituted by an insulating polymer matrix containing at least one conductive polymer, incorporated in said polymer matrix with a mass rate such that the electrical conductivity resulting from said first dielectric layer is less than 10 ⁇ 10 S / cm.
- the cable shown in Figure 1 has a conductive core 1, formed by a conductive strand but can also be formed by a single conductor, which is surrounded by an internal semiconductor screen 2, itself surrounded by a layer insulating dielectric 3, in turn surrounded by an external semiconductor screen 4.
- a protective sheath 5 surrounds the external semiconductor screen 4 and ensures the protection of the cable. It is in particular made of lead or a lead alloy. It can be insulating and then preferably associated with a directly underlying metallic mass screen.
- the insulating dielectric layer 3 is constituted by an insulating polymer matrix in which is incorporated at least one conductive polymer, with a mass rate such that the electrical conductivity resulting from the dielectric layer 3 is lower. at 10 ⁇ 14 S / cm in direct current, and at 10 ⁇ 10 S / cm in alternating current.
- the electrical conductivity or the dielectric constant of the layer 3 in the cable according to the invention increases substantially locally, in the presence of a defect at any point, by being variable from one point to another depending on the faults at these points.
- the dielectric layer 3 is therefore said to be self-adapting locally according to the various defects it presents. It thus makes it possible to homogenize the distribution of the electric field through it over the entire length of the cable, reducing the risks of breakdown due to these faults.
- the conductive polymer may for example be an undoped, dedoped or autodoped polymer.
- an undoped conductive polymer is a polymer whose synthesis does not require the introduction of dopant, such as the polyaniline obtained by polycondensation reaction of aniline and quinone, or polyacetylene, the polymerization of which was started using a Ziegler-Natta type catalyst.
- dopant such as the polyaniline obtained by polycondensation reaction of aniline and quinone, or polyacetylene, the polymerization of which was started using a Ziegler-Natta type catalyst.
- a self-doping conductive polymer is a polymer obtained by grafting a dopant during its synthesis, such as for example polyaniline grafted by a sulfonic group on the cycle.
- a dedoped conductive polymer is a polymer doped during its synthesis, like polyaniline treated by hydrochloric acid, then dedoped by elimination of this acid by an appropriate means.
- the mass rate in the dielectric layer 3 is at most about 2% by mass, both for direct current and current use.
- its mass content in layer 3 will preferably be at most equal to approximately 5% by mass, both for direct current and alternating current use.
- One or each of the internal 2 and external 4 semiconductor screens is advantageously of the type described in document EP-A-0507676, which consists of an insulating polymer matrix and at least one conductive polymer, the latter being chosen among undoped polymers and doped polymers then dedoped, and being incorporated into the polymer matrix with a rate of 5 to 70% by mass, and preferably from 20 to 30%, to obtain a conductivity of the semiconductor screens lower or equal to 1 S / cm.
- one or each of these semiconductor screens consists of an insulating polymer matrix and at least one conductive polymer autodoped in particular of the type described in document EP-A-0512926, which is incorporated with a mass content greater than 5% by mass, and preferably between 10 and 40% by mass in the polymer matrix.
- the polymer matrix of the dielectric layer 3 comprises, like that of the semiconductor screens 2 and 4, at least one thermoplastic polymer, chosen from acrylic, styrenic, vinyl and cellulosic resins, polyolefins, fluorinated polymers, polyethers, polyimides, polycarbonates, polyurethanes, silicones, their copolymers, and mixtures between homopolymers and between homopolymers and copolymers.
- thermoplastic polymer chosen from acrylic, styrenic, vinyl and cellulosic resins, polyolefins, fluorinated polymers, polyethers, polyimides, polycarbonates, polyurethanes, silicones, their copolymers, and mixtures between homopolymers and between homopolymers and copolymers.
- thermoplastic polymer is chosen from polypropylene (PP), polyethylene (PE), the copolymer of ethylene and vinyl acetate (EVA), ethylene-proprylene-diene-monomer (EPDM), fluorinated polyvinylidene (PVDF), ethylene-butylacrylate (EBA), alone or as a mixture.
- PP polypropylene
- PE polyethylene
- EVA ethylene-proprylene-diene-monomer
- PVDF fluorinated polyvinylidene
- EBA ethylene-butylacrylate
- the polymer matrix comprises at least one thermosetting polymer chosen from polyesters, epoxy resins and phenolic resins.
- the undoped or doped polymer (s) then doped of the dielectric layer 3, like that or those possible of the semiconductor screens 2 and 4, are chosen from the group comprising polyaniline, polythiophene, polypyrrole, polyacetylene, polyparaphenylene, polyalkylthiophenes, their derivatives and mixtures.
- undoped and dedoped polymers do not contain ionic groups. Their intrinsic electrical conductivity, measured in direct current, is very low and of the order of 10 ⁇ 10 to 10 ⁇ 9 S / cm.
- the conductivity of the dielectric layer 3, containing at most 5% of the undoped or dedoped polymer, is of the order and even less than 10 ⁇ 14 S / cm for use in direct current and at low electric fields, and less than 10 ⁇ 10 S / cm for use in alternating current and at low electric fields, that is to say in the absence of faults or in the presence of faults negligible, which does not degrade the high dielectric strength of this layer.
- the self-doped polymer or polymers of the dielectric layer 3, like that or those possible of the semiconductor screens 2 and 4, are chosen from self-doped polyanilines having benzene or benzene and quinone nuclei, which carry grafts consisting, for one hydrocarbon radical, comprising from 2 to 8 carbon atoms and interrupted by at least one hetero atom, and for the others by a strong acid function or one of its salts, said hetero atom being itself chosen from O and S and the strong acid function among the residues of sulfonic, phosphonic and phosphoric acids or their salts.
- the intrinsic electrical conductivity, measured in direct current, of these self-doped polymers is on the order of 10 ⁇ 3 to 10 ⁇ 2 S / cm on average. It is also adjustable as desired between 10 ⁇ 5 and 1 S / cm, by varying the molecular ratio of the two types of grafts.
- the electrical conductivity of the dielectric layer 3, constituted by the above polymer matrix to which is added at most 2% by mass of this self-doped polymer, is itself adjustable and of the order or less than 10 ⁇ 14 S / cm for use at low electric fields in direct current, and of the order or less than 10 ⁇ 10 S / cm for use in alternating current at low electric fields. This dielectric strength decreases with the increase of the electric field.
- the electrical conductivity and the dielectric constant of such a dielectric layer strongly increase with the electric field and then make it possible to support without problem a significant local concentration of space charges and to distribute these charges.
- the above-mentioned dielectric layer 3 directly surrounds the cable core and is directly covered by the protective sheath 5, the two internal and external semiconductor screens being eliminated.
- the cable shown in this FIG. 2 comprises an internal dielectric layer 7, between the conductive core 1 and the dielectric layer 3, and an external dielectric layer 8, between the dielectric layer 3 and the protective sheath 5.
- Each of these two dielectric layers 7 and 8 consists of at least one of the polymers of the above-mentioned insulating polymer matrix and at least one conductive polymer incorporated in this matrix, with a content of 5 to 20% by mass.
- Its conductive polymer is at least one of the three types of conductive polymers mentioned above, but is preferably chosen from only non-doped or dedoped polymers. It is added to the polymer matrix of the dielectric layer at a rate less than or equal to 20% by mass and greater than 5% by mass.
- the resulting electrical conductivity of layers 7 and 8 is 10 ⁇ 14 to 1 S / cm for use in direct current, and 10 ⁇ 10 to 1 S / cm for use in alternating current.
- the cable comprises two semiconductor screens as in FIG. 1, the internal screen being covered by the internal dielectric layer 7 and the external screen covering the external dielectric layer 8.
- one or each of the internal 7 and external dielectric layers 8 is divided into several elementary layers, such as 7A and 7B and 8A and 8B, having a mass content of conductive polymer which remains between 5 and 20% but is different from one elementary layer to another.
- This conductive polymer content of the elementary layers of the internal layer 7 decreases successively, from the innermost elementary layer 7A in contact with the core.
- it is increasing in the outer layer 8 from the innermost elementary layer 8A in contact with the dielectric layer 3 to the outermost elementary layer 8B in contact with the protective sheath 5.
- the internal 7 and external 8 dielectric layers or their possible elementary layers play the role of internal and external semiconductor screens when they are subjected to high electric fields, which are due to their internal faults and in addition to peripheral irregularities of the conductive core or to faults in the protective sheath. They play the role of dielectric layer at low electric fields.
- the electrical conductivity of layer 7A is between 10 ⁇ 9 and 1 S / cm, that of layer 7B between 10 ⁇ 14 and 10 ⁇ 9 S / cm, that of layer 8A between 10 ⁇ 14 and 10 ⁇ 9 S / cm, and that of layer 8B between 10 ⁇ 9 and 1 S / cm.
- the electrical conductivity of layer 7A is between 10 ⁇ 5 and 1 S / cm, that of layer 7B between 10 ⁇ 10 and 10 ⁇ 5 S / cm, that of layer 8A between 10 ⁇ 10 and 10 ⁇ 5 S / cm, and that of layer 8B between 10 ⁇ 5 and 1 S / cm.
- the cable according to the invention comprises semiconductor screens as such
- the latter can be made either of the materials described above, or of the conventional materials used for semiconductor screens in cables of the art prior.
- the cables according to the invention can be produced using the conventional methods of manufacturing this type of cable.
Landscapes
- Conductive Materials (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9311117 | 1993-09-17 | ||
FR9311117A FR2710184B1 (fr) | 1993-09-17 | 1993-09-17 | Câble d'énergie à rigidité diélectrique améliorée. |
FR9312227 | 1993-10-14 | ||
FR9312227A FR2710183B3 (fr) | 1993-09-17 | 1993-10-14 | Câble d'énergie à rigidité diélectrique améliorée. |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0645781A1 true EP0645781A1 (de) | 1995-03-29 |
EP0645781B1 EP0645781B1 (de) | 1997-04-09 |
EP0645781B2 EP0645781B2 (de) | 2000-06-07 |
Family
ID=26230605
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94402053A Expired - Lifetime EP0645781B2 (de) | 1993-09-17 | 1994-09-14 | Energiekabel mit verbesserter dielektrischen Festigkeit |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0645781B2 (de) |
JP (1) | JP4040114B2 (de) |
KR (1) | KR100323178B1 (de) |
CN (1) | CN1124868A (de) |
AU (1) | AU683076B2 (de) |
DE (1) | DE69402494T3 (de) |
DK (1) | DK0645781T4 (de) |
FR (1) | FR2710183B3 (de) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0961302A2 (de) * | 1998-05-27 | 1999-12-01 | Alcatel | Elektrische Spule, Transformator, und Elektromotor mit solcher Spule |
EP2752448A1 (de) | 2013-01-02 | 2014-07-09 | Nexans | Feldabstufungsschicht |
EP2784787A1 (de) | 2013-03-29 | 2014-10-01 | Nexans | Elektrisches Kabel, das eine Schicht mit elektrischem Eigenschaftsgradienten umfasst |
WO2016061230A1 (en) * | 2014-10-17 | 2016-04-21 | 3M Innovative Properties Company | Dielectric material with enhanced breakdown strength |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2827999B1 (fr) * | 2001-07-25 | 2003-10-17 | Nexans | Ecran semi-conducteur pour cable d'energie |
CN104332220B (zh) * | 2014-11-12 | 2017-07-21 | 远东电缆有限公司 | 一种柔软性抗核电磁脉冲智慧信息系统用电缆 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3666876A (en) * | 1970-07-17 | 1972-05-30 | Exxon Research Engineering Co | Novel compositions with controlled electrical properties |
US3792192A (en) * | 1972-12-29 | 1974-02-12 | Anaconda Co | Electrical cable |
JPH0218811A (ja) | 1988-07-05 | 1990-01-23 | Fujikura Ltd | 直流電力ケーブル |
EP0507676A2 (de) | 1991-04-02 | 1992-10-07 | Alcatel Cable | Material für Halbleiter-Abschirmung |
EP0512926A1 (de) | 1991-05-07 | 1992-11-11 | Alcatel N.V. | Leitfähige selbstdopierte Polyaniline und Verfahren zu ihrer Herstellung |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1135021B (it) † | 1981-01-14 | 1986-08-20 | Pirelli Cavi Spa | Cavo elettrico perfezionato |
DE3248088A1 (de) † | 1982-12-24 | 1984-06-28 | Brown, Boveri & Cie Ag, 6800 Mannheim | Verfahren zur herstellung eines polymers |
GB8425377D0 (en) † | 1984-10-08 | 1984-11-14 | Ass Elect Ind | High voltage cables |
DE3509168A1 (de) † | 1985-03-14 | 1986-09-18 | Brown, Boveri & Cie Ag, 6800 Mannheim | Kabel |
-
1993
- 1993-10-14 FR FR9312227A patent/FR2710183B3/fr not_active Expired - Fee Related
-
1994
- 1994-09-14 DK DK94402053T patent/DK0645781T4/da active
- 1994-09-14 EP EP94402053A patent/EP0645781B2/de not_active Expired - Lifetime
- 1994-09-14 AU AU72967/94A patent/AU683076B2/en not_active Ceased
- 1994-09-14 DE DE69402494T patent/DE69402494T3/de not_active Expired - Fee Related
- 1994-09-16 JP JP22210394A patent/JP4040114B2/ja not_active Expired - Fee Related
- 1994-09-16 CN CN94118002A patent/CN1124868A/zh active Pending
- 1994-09-16 KR KR1019940023607A patent/KR100323178B1/ko not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3666876A (en) * | 1970-07-17 | 1972-05-30 | Exxon Research Engineering Co | Novel compositions with controlled electrical properties |
US3792192A (en) * | 1972-12-29 | 1974-02-12 | Anaconda Co | Electrical cable |
JPH0218811A (ja) | 1988-07-05 | 1990-01-23 | Fujikura Ltd | 直流電力ケーブル |
EP0507676A2 (de) | 1991-04-02 | 1992-10-07 | Alcatel Cable | Material für Halbleiter-Abschirmung |
EP0512926A1 (de) | 1991-05-07 | 1992-11-11 | Alcatel N.V. | Leitfähige selbstdopierte Polyaniline und Verfahren zu ihrer Herstellung |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0961302A2 (de) * | 1998-05-27 | 1999-12-01 | Alcatel | Elektrische Spule, Transformator, und Elektromotor mit solcher Spule |
EP0961302A3 (de) * | 1998-05-27 | 2000-04-19 | Alcatel | Elektrische Spule, Transformator, und Elektromotor mit solcher Spule |
EP2752448A1 (de) | 2013-01-02 | 2014-07-09 | Nexans | Feldabstufungsschicht |
EP2784787A1 (de) | 2013-03-29 | 2014-10-01 | Nexans | Elektrisches Kabel, das eine Schicht mit elektrischem Eigenschaftsgradienten umfasst |
WO2016061230A1 (en) * | 2014-10-17 | 2016-04-21 | 3M Innovative Properties Company | Dielectric material with enhanced breakdown strength |
US10121570B2 (en) | 2014-10-17 | 2018-11-06 | 3M Innovative Properties Company | Dielectric material with enhanced breakdown strength |
Also Published As
Publication number | Publication date |
---|---|
FR2710183B3 (fr) | 1995-10-13 |
DE69402494D1 (de) | 1997-05-15 |
DE69402494T2 (de) | 1997-07-17 |
DE69402494T3 (de) | 2000-08-31 |
CN1124868A (zh) | 1996-06-19 |
JPH07169339A (ja) | 1995-07-04 |
EP0645781B1 (de) | 1997-04-09 |
DK0645781T3 (de) | 1997-05-05 |
JP4040114B2 (ja) | 2008-01-30 |
AU683076B2 (en) | 1997-10-30 |
AU7296794A (en) | 1995-03-30 |
KR100323178B1 (ko) | 2002-05-13 |
EP0645781B2 (de) | 2000-06-07 |
FR2710183A1 (fr) | 1995-03-24 |
KR950009751A (ko) | 1995-04-24 |
DK0645781T4 (da) | 2000-10-09 |
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