EP0617785A1 - Verfahren und regenerator für die wiederaufheizung von gasen - Google Patents

Verfahren und regenerator für die wiederaufheizung von gasen

Info

Publication number
EP0617785A1
EP0617785A1 EP93923585A EP93923585A EP0617785A1 EP 0617785 A1 EP0617785 A1 EP 0617785A1 EP 93923585 A EP93923585 A EP 93923585A EP 93923585 A EP93923585 A EP 93923585A EP 0617785 A1 EP0617785 A1 EP 0617785A1
Authority
EP
European Patent Office
Prior art keywords
regenerator
cold
hot
gas
grid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP93923585A
Other languages
English (en)
French (fr)
Other versions
EP0617785B1 (de
Inventor
Hans-Georg Fassbinder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Publication of EP0617785A1 publication Critical patent/EP0617785A1/de
Application granted granted Critical
Publication of EP0617785B1 publication Critical patent/EP0617785B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D17/00Regenerative heat-exchange apparatus in which a stationary intermediate heat-transfer medium or body is contacted successively by each heat-exchange medium, e.g. using granular particles
    • F28D17/005Regenerative heat-exchange apparatus in which a stationary intermediate heat-transfer medium or body is contacted successively by each heat-exchange medium, e.g. using granular particles using granular particles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D17/00Regenerative heat-exchange apparatus in which a stationary intermediate heat-transfer medium or body is contacted successively by each heat-exchange medium, e.g. using granular particles
    • F28D17/02Regenerative heat-exchange apparatus in which a stationary intermediate heat-transfer medium or body is contacted successively by each heat-exchange medium, e.g. using granular particles using rigid bodies, e.g. of porous material

Definitions

  • the present invention relates to a method of reheating gas in a regenerator with a mass of heat accumulation made up of bulk material arranged in a ring between two coaxial cylindrical grids, a hot collection chamber, surrounded by the internal hot grid, for the hot gases and a cold collection chamber, enclosed between the external cold grid on the one hand and the external wall of the regenerator on the other hand, for cold gases, as well as a regenerator of this type.
  • the hot gases respectively the cold gases are led in the radial direction through the mass of heat accumulation, unlike otherwise usual air heaters, and in fact during the heating phase, from the chamber hot collection inside the regenerator to the external cold collection chamber, and in the opposite direction during the cold blowing of the regenerator.
  • the gases to be heated can also be gas mixtures, which also contain parts of vapors, in particular water vapor.
  • the object of the invention is therefore to improve the process mentioned in the introduction as well as the regenerator described above, by avoiding the drawbacks caused by the chimney effect and in particular by increasing the power of the regenerator for a height significantly less construction of it.
  • this objective is achieved by the fact that the increase in the pressure drop during the heating phase is at least 5 times as great as the product pgH, in which H is the height of the regenerator , p is the density of the gas at a temperature of 20 ° C and g is the acceleration of gravity, and that the gas flow is at least 300 m 3 N / hm 2 of surface of the hot grate at normal pressure .
  • the cold phase that is to say the cold blowing, is carried out with an overpressure.
  • the flow of gas to be heated increases in the P / P 2 ratio, without the heat transfer being degraded.
  • the flow rate can reach 5000 m 3 N / hm 2 , respectively 2500 kW / m 2 .
  • a regenerator having a grid area of 20 m 2 , it is possible to produce a flow of hot wind of 100,000 m 3 N / h.
  • the grain size of the bulk material is chosen to be less than 15 mm.
  • the heating phase when operating at partial load, is carried out at full power, and breaks are observed after the cold blowing phase.
  • This implementation of the process makes it possible to work with the desired constricted power, and the thermal equilibrium of the two phases is then established by the breaks after the cold blowing, and also to use for heating the regenerator a burner which has only a very limited range of adjustment, unlike the burners used until now in conventional wind heaters.
  • the other objective fixed to the invention is, in a regenerator intended for the implementation of the method, achieved by the fact that the outside diameter of the annular mass of heat accumulation is at most double the inside diameter .
  • the regenerator is heated with a premix burner.
  • FIG. 2 An exemplary embodiment of the burner is shown in FIG. 2 and will be explained in detail below.
  • the regenerator 1 intended for implementing the method of the invention has an enclosure 2 having the shape of an upright cylinder, which can for example be supported by means of pillars 3.
  • the interior space of the enclosure 2 is essentially divided by two grids 4 and 5 of cylindrical shape and arranged concentrically at a distance from one another, into a hot collecting chamber 6 internal cylindrical, an intermediate annular chamber 7 containing the mass of heat accumulation consisting of bulk material, and a cold external annular collection chamber 8 formed by the wall of the enclosure 2 with the grid 5.
  • inlets 10 are provided for the heating gases, which are produced by a premix burner 11, which in turn is supplied by a gas mixing tube - air 12.
  • the hot internal collection chamber 6 ends in the upper region of the enclosure 2 of the regenerator 1 by a hot wind outlet 13, the external collection chamber 8 is connected to a chimney 14 for evacuating gases from which the heating gases can escape after they have passed through the heat storage agent in the intermediate chamber 7.
  • the gas-air mixing tube 12 is connected to a fan 15, which produces both the air for the heating phase and for the cold blowing phase. In the heating phase, the air is led through the gas-air mixing tube 12 and mixed with heating gas, which has been introduced by the gas injector 16 into the gas-air mixing tube 12.
  • valves 17, 18 and 19 are closed, the valve 20 as well as the outlet 13 are instead open, so that the cold blowing phase can then begin.
  • the open fittings are closed again and the previously closed valves are opened, so that the heating phase can start again.
  • the bulk material of the heat accumulating mass consists of a charge of granules with a grain size which does not exceed 15 mm, and the outside diameter of the annular heat accumulating mass is not greater than double the inside diameter.
  • This minimum flow corresponds to a power of 300 m 3 N / hm 2 .
  • the S profile of the temperature is more and more clearly raised.
  • a particularly advantageous operating point has appeared for a flow capacity of 1000 m 3 N / hm 2 , a pressure drop of 1000 to 1600 Pascal.
  • An increase in the flow rate up to 2000 m 3 N / hm 2 is possible without reducing the heat transfer, taking into account a pressure drop from 3000 to 5000 Pascal.
  • This power limit is applicable to walking at normal pressure.
  • the operation under increased pressure has shown the surprising result, that the flow rate can be further increased, in fact in proportion to the absolute pressure, without the heat transfer data being degraded. If, for example, a blast furnace wind at 5 bar is produced, the flow rate can reach 5000 m 3 N / hm 2 , respectively 2500 kW / m 2 . It is thus possible to produce a flow of hot wind of 100,000 m 3 N / h with a regenerator having a grid surface of 20 m 2 .
  • regenerator Since heating of the regenerator is in fact generally carried out at normal pressure, three generators must be heated simultaneously, so that a total of four regenerators are required to ensure continuous operation for the production of hot gases. These regenerators only have a diameter of 4 m for a height of 5 m, while the air heaters of the same power used until now have a diameter of 8 m and a height of 30 m.

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Drying Of Solid Materials (AREA)
  • Air Supply (AREA)
  • Furnace Details (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Air Bags (AREA)
  • Gas Burners (AREA)
EP93923585A 1992-10-29 1993-10-19 Verfahren und regenerator für die wiederaufheizung von gasen Expired - Lifetime EP0617785B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4236619A DE4236619C2 (de) 1992-10-29 1992-10-29 Verfahren und Regenerator zum Aufheizen von Gasen
DE4236619 1992-10-29
PCT/FR1993/001025 WO1994010519A1 (fr) 1992-10-29 1993-10-19 Procede et regenerateur pour le rechauffage de gaz

Publications (2)

Publication Number Publication Date
EP0617785A1 true EP0617785A1 (de) 1994-10-05
EP0617785B1 EP0617785B1 (de) 2003-08-13

Family

ID=6471695

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93923585A Expired - Lifetime EP0617785B1 (de) 1992-10-29 1993-10-19 Verfahren und regenerator für die wiederaufheizung von gasen

Country Status (10)

Country Link
US (2) US5547016A (de)
EP (1) EP0617785B1 (de)
JP (1) JPH07502804A (de)
KR (1) KR100317968B1 (de)
CN (1) CN1072793C (de)
AT (1) ATE247271T1 (de)
CA (1) CA2126993C (de)
DE (1) DE4236619C2 (de)
ES (1) ES2202314T3 (de)
WO (1) WO1994010519A1 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4236619C2 (de) * 1992-10-29 1996-11-28 Air Liquide Verfahren und Regenerator zum Aufheizen von Gasen
DE4317947C1 (de) * 1993-05-28 1994-06-23 Atz Evus Verfahren und Vorrichtungen zur Umwandlung thermischer Energie eines Mediums in mechanische Arbeit
DE19521673C2 (de) * 1995-06-14 1998-07-02 Atz Evus Applikations & Tech Verfahren zur regenerativen Abluftreinigung
US6631754B1 (en) 2000-03-14 2003-10-14 L'air Liquide Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Regenerative heat exchanger and method for heating a gas therewith
US6389776B1 (en) 2000-03-14 2002-05-21 L'air Liquide Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Gas permeable refractory brick for use in regenerative heat exchanger and hot grid formed therefrom
DE10039246C2 (de) 2000-08-11 2002-06-13 Atz Evus Verfahren zur Umwandlung von thermischer Energie in mechanische Arbeit
DE102004026646B4 (de) * 2004-06-01 2007-12-13 Applikations- Und Technikzentrum Für Energieverfahrens-, Umwelt- Und Strömungstechnik (Atz-Evus) Verfahren zur thermischen Entsorgung schadstoffhaltiger Substanzen
DE102007050566A1 (de) 2007-10-23 2009-05-07 Stevanović, Dragan, Dr. Verfahren und Vorrichtung zur Vergasung von kohlenstoffhaltigen Rohstoffen
DE102008014297A1 (de) 2007-11-16 2009-05-20 Krones Ag Verfahren und Vorrichtung zur Umwandlung kohlenstoffhaltiger Rohstoffe
AT506477B1 (de) 2008-02-21 2010-07-15 Schweighofer Franz Wärmespeichereinrichtung
NZ587568A (en) * 2008-02-28 2012-11-30 Krones Ag Method and device for converting carbonaceous raw materials
DE102009011358A1 (de) 2009-03-05 2010-09-16 Krones Ag Verfahren und Vorrichtung zur Verwertung von Biomasse in einem Biomassen-Vergasungsprozess
DE102009038323A1 (de) 2009-08-21 2011-02-24 Krones Ag Verfahren und Vorrichtung zur Verwertung von Biomasse
DE102009038322A1 (de) 2009-08-21 2011-02-24 Krones Ag Verfahren und Vorrichtung zur Umwandlung thermischer Energie aus Biomasse in mechanische Arbeit
US20110127004A1 (en) * 2009-11-30 2011-06-02 Freund Sebastian W Regenerative thermal energy storage apparatus for an adiabatic compressed air energy storage system
DE102013017010A1 (de) 2013-10-14 2015-04-16 Karl Brotzmann Consulting Gmbh Stromspeicherung über thermische Speicher und Luftturbine
CA2982255A1 (en) 2015-04-13 2016-10-20 Karl Brotzmann Consulting Gmbh Energy storage via thermal reservoirs and air turbines
DE102021108719A1 (de) 2021-04-08 2022-10-13 HiTES Holding GmbH Verfahren und Vorrichtung zur Umsetzung chemischer Energie eines Brennstoffes in Wärme und elektrische Energie
DE102021129812A1 (de) 2021-11-16 2023-05-17 HiTES Holding GmbH Verfahren und Vorrichtung zum Erzeugen von Wasserstoff
DE102021129804A1 (de) 2021-11-16 2023-05-17 HiTES Holding GmbH Verfahren und Vorrichtung zum Erzeugen von Wasserstoff
DE102021129810A1 (de) 2021-11-16 2023-05-17 HiTES Holding GmbH Verfahren und Vorrichtung zum Erzeugen von Wasserstoff
DE102022118858A1 (de) 2022-07-27 2024-02-01 HiTES Holding GmbH Thermisches Cracking von Methan oder Erdgas

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1940371A (en) * 1930-05-06 1933-12-19 Research Corp Apparatus for heating gases
GB387070A (en) * 1930-11-22 1933-02-02 Dougree Marihaye Sa Honeycomb structure for heat recuperating apparatus of the cowper type
US2272108A (en) * 1940-01-19 1942-02-03 Research Corp Regenerative stove
JPS5776078A (en) * 1980-10-29 1982-05-12 Agency Of Ind Science & Technol Heat accumulator utilizing latent heat
DE8718031U1 (de) * 1987-03-27 1993-01-14 Zeuna-Staerker Gmbh & Co Kg, 8900 Augsburg, De
DE3831831C1 (de) * 1988-09-20 1989-11-02 Skw Trostberg Ag, 8223 Trostberg, De
DE3841708C1 (de) * 1988-12-10 1989-12-28 Kloeckner Cra Patent Gmbh, 4100 Duisburg, De
DE4108744C1 (en) * 1991-03-18 1992-08-27 Atz Energie Umwelt Stroemungstechnik Gas heating jacketed regenerator with heat storage medium - has central chamber surrounded by layer of pebbles or granular material
DE4236619C2 (de) * 1992-10-29 1996-11-28 Air Liquide Verfahren und Regenerator zum Aufheizen von Gasen

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9410519A1 *

Also Published As

Publication number Publication date
WO1994010519A1 (fr) 1994-05-11
CN1086895A (zh) 1994-05-18
DE4236619C2 (de) 1996-11-28
CA2126993C (fr) 2004-12-21
JPH07502804A (ja) 1995-03-23
US5547016A (en) 1996-08-20
CN1072793C (zh) 2001-10-10
ATE247271T1 (de) 2003-08-15
EP0617785B1 (de) 2003-08-13
KR100317968B1 (ko) 2002-04-22
US5690164A (en) 1997-11-25
DE4236619A1 (de) 1994-05-05
ES2202314T3 (es) 2004-04-01
CA2126993A1 (fr) 1994-05-11
KR940703990A (ko) 1994-12-12

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