EP0609257A1 - Verfahren zur herstellung von eisenerzkonzentraten durch flotation. - Google Patents
Verfahren zur herstellung von eisenerzkonzentraten durch flotation.Info
- Publication number
- EP0609257A1 EP0609257A1 EP92920650A EP92920650A EP0609257A1 EP 0609257 A1 EP0609257 A1 EP 0609257A1 EP 92920650 A EP92920650 A EP 92920650A EP 92920650 A EP92920650 A EP 92920650A EP 0609257 A1 EP0609257 A1 EP 0609257A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkyl
- collector
- flotation
- formula
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012141 concentrate Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims description 19
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 title description 5
- 238000009291 froth flotation Methods 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 47
- 238000005188 flotation Methods 0.000 claims abstract description 41
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 29
- 229910052742 iron Inorganic materials 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 125000000129 anionic group Chemical group 0.000 claims abstract description 9
- -1 ether amines Chemical class 0.000 claims description 84
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 25
- 229910019142 PO4 Inorganic materials 0.000 claims description 17
- 235000021317 phosphate Nutrition 0.000 claims description 17
- 229920000151 polyglycol Polymers 0.000 claims description 14
- 239000010695 polyglycol Substances 0.000 claims description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 13
- 150000002170 ethers Chemical class 0.000 claims description 13
- 239000000194 fatty acid Substances 0.000 claims description 13
- 229930195729 fatty acid Natural products 0.000 claims description 13
- 150000004665 fatty acids Chemical class 0.000 claims description 13
- 150000002191 fatty alcohols Chemical class 0.000 claims description 10
- 150000001412 amines Chemical class 0.000 claims description 9
- 239000006260 foam Substances 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000011574 phosphorus Substances 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- 125000002252 acyl group Chemical group 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 4
- 235000003704 aspartic acid Nutrition 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 239000003208 petroleum Substances 0.000 claims description 3
- 229920001522 polyglycol ester Polymers 0.000 claims description 3
- 150000003871 sulfonates Chemical class 0.000 claims description 3
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
- 229910000805 Pig iron Inorganic materials 0.000 claims 1
- 238000000746 purification Methods 0.000 abstract description 3
- 125000001931 aliphatic group Chemical group 0.000 abstract description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000000126 substance Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 9
- 238000007792 addition Methods 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 6
- 229910021653 sulphate ion Inorganic materials 0.000 description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229910052586 apatite Inorganic materials 0.000 description 4
- 229910052595 hematite Inorganic materials 0.000 description 4
- 239000011019 hematite Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 4
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 4
- 150000004760 silicates Chemical class 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 229930182470 glycoside Natural products 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- SLRMQYXOBQWXCR-UHFFFAOYSA-N 2154-56-5 Chemical compound [CH2]C1=CC=CC=C1 SLRMQYXOBQWXCR-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229920002261 Corn starch Polymers 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000008120 corn starch Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Substances OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- DFQDHMNSUGBBCW-UHFFFAOYSA-N 1,4-diamino-1,4-dioxobutane-2-sulfonic acid Chemical class NC(=O)CC(C(N)=O)S(O)(=O)=O DFQDHMNSUGBBCW-UHFFFAOYSA-N 0.000 description 1
- IBUPNDMHIOTKBL-UHFFFAOYSA-N 1,5-diaminopentan-2-ol Chemical compound NCCCC(O)CN IBUPNDMHIOTKBL-UHFFFAOYSA-N 0.000 description 1
- WHJDTUHLRPOPSK-UHFFFAOYSA-N 4-amino-4-oxo-3-sulfobutanoic acid Chemical class NC(=O)C(S(O)(=O)=O)CC(O)=O WHJDTUHLRPOPSK-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- HVWGGPRWKSHASF-UHFFFAOYSA-N Sulfuric acid, monooctadecyl ester Chemical compound CCCCCCCCCCCCCCCCCCOS(O)(=O)=O HVWGGPRWKSHASF-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001348 alkyl chlorides Chemical class 0.000 description 1
- 125000005263 alkylenediamine group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- CSMFSDCPJHNZRY-UHFFFAOYSA-N decyl hydrogen sulfate Chemical compound CCCCCCCCCCOS(O)(=O)=O CSMFSDCPJHNZRY-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000001177 diphosphate Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical class [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000005021 gait Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 229910052598 goethite Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- LPTIRUACFKQDHZ-UHFFFAOYSA-N hexadecyl sulfate;hydron Chemical compound CCCCCCCCCCCCCCCCOS(O)(=O)=O LPTIRUACFKQDHZ-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 description 1
- ARZLUCYKIWYSHR-UHFFFAOYSA-N hydroxymethoxymethanol Chemical compound OCOCO ARZLUCYKIWYSHR-UHFFFAOYSA-N 0.000 description 1
- DLFKFFZPKVOYJI-UHFFFAOYSA-N icosyl hydrogen sulfate Chemical compound CCCCCCCCCCCCCCCCCCCCOS(O)(=O)=O DLFKFFZPKVOYJI-UHFFFAOYSA-N 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- UZZYXUGECOQHPU-UHFFFAOYSA-N octyl hydrogen sulfate Chemical compound CCCCCCCCOS(O)(=O)=O UZZYXUGECOQHPU-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical class C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- URLJMZWTXZTZRR-UHFFFAOYSA-N sodium myristyl sulfate Chemical compound CCCCCCCCCCCCCCOS(O)(=O)=O URLJMZWTXZTZRR-UHFFFAOYSA-N 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000005480 straight-chain fatty acid group Chemical group 0.000 description 1
- JDVPQXZIJDEHAN-UHFFFAOYSA-N succinamic acid Chemical class NC(=O)CCC(O)=O JDVPQXZIJDEHAN-UHFFFAOYSA-N 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000003784 tall oil Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/0043—Organic compounds modified so as to contain a polyether group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/01—Organic compounds containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/014—Organic compounds containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
Definitions
- the invention relates to a process for the production of iron ore concentrates by flotation of iron ores, in which mixtures of special ether amines with anionic and / or nonionic collectors are used as collectors.
- Iron ores are found in nature preferably in the form of oxides, among which magnetite, hematite, martite, limonite and goethite are the best known.
- the main contaminants are silicates, especially quartz, as well as phosphorus and sulfur compounds.
- the iron ore is first crushed and dry, but preferably ground wet and in water suspended.
- a collector is then added, often in conjunction with other reagents, which include foaming agents, regulators, pushers (deactivators) and / or Beieber (activators), to help separate the valuable minerals from the gangue minerals in the ore during the subsequent flotation.
- these reagents are usually allowed to act on the finely ground ore for a certain time (conditioning).
- the collector causes the surface of the impurities contained in the iron ore to become hydrophobic, so that these minerals adhere to the gas bubbles formed during the aeration.
- the mineral components are made hydrophobic selectively in such a way that the gait is floated out - and the concentrate remains as a residue (indirect flotation).
- Aminic compounds are preferably used as collectors in the flotative processing of iron ores. These have the task of adsorbing as selectively as possible on the surface of the contaminants in order to ensure a high depletion of these undesirable constituents in the flotation concentrate. In addition, the collectors should develop a stable, but not too stable, flotation foam.
- a process for removing silicate impurities from iron ores is known from US Pat. No. 4,168,227, in which alkylamines, alkylenediamines and etheramines are used as collectors.
- the Australian patent AU 86/53 766 proposes to carry out the flotative separation of silicates and phosphates from iron ores with the aid of collector mixtures containing ether amines and ether carboxamides.
- anionic surfactants as collectors or co-collectors in the flotation of non-sulfidic ores.
- examples include alkyl phosphates and alkyl ether phosphates [Erzmetall 30, 505 (1977)], ether carboxylic acids [DE 22 37 359 Al], sulfosuccinamides and succinamates [US 4,206,045; US 4,309,282 and US 4,139,481] and alkyl aspartic acids [EP 0 270 018 A1].
- the object of the invention was therefore to develop an improved flotation process for the production of iron ore concentrates which is free from the disadvantages described.
- the invention relates to a process for the production of iron ore concentrates by flotation, in which ground iron ore is mixed with water to form a suspension, air is introduced into the suspension in the presence of a reagent system and the resulting foam is separated off together with the solids floated therein, which is distinguished by this that as a collector mixtures containing a) at least one etheramine of the formula (I),
- R 1 O- [C n H 2n ] y -NH- [C m H 2m -NH] x H (I) in R 1 for a linear or branched aliphatic hydrocarbon radical with 6 to 22 carbon atoms and 0, 1, 2 or 3 double bonds, n and m independently of one another represent the numbers 1, 2 or 3, x represents 0 or the numbers 1, 2 or 3 and y represents 2 or 3, and b) uses at least one further anionic and / or nonionic collector.
- the collector mixtures to be used according to the invention can selectively remove phosphorus impurities from iron ores and do not negatively influence the cationic flotation of the silicates.
- the invention includes the finding that phosphorus and silicate flotation can be carried out both separately and in one step.
- the concentrates obtainable by the process according to the invention have phosphorus contents of less than 0.015% by weight, based on the concentrate.
- Etheramines of the formula (I) are known compounds which are obtainable by the relevant preparative organic chemistry processes. Their preparation is usually based on fatty alcohol sulfates which are reacted with alkanolamines or aminoalkylalkanolamines in the presence of alkali metal hydroxides at temperatures of about 180 ° C., alkali metal sulfate being formed as a by-product [DE 35 04 242 A1].
- Suitable starting materials for the ether amines to be used according to the invention are fatty alcohol sulfates based on saturated or unsaturated fatty alcohols and primary amines or diamines. Typical examples are reaction products of octyl sulphate, decyl sulphate, lauryl sulphate, myristyl sulphate, cetyl sulphate, stearyl sulphate, oleyl sulphate, elaidyl sulphate, petroselinyl sulphate, linolyl sulphate, linolenyl sulphanol, arachyl sulphate, eraducylyl sulphate, badenoleyl sulphate amine, gadoleyl sulphanol amine, gadoleyl sulphanol amine , Aminopropylethanolamine and aminopropylpropanolamine.
- sulfates based on technical fatty alcohol cuts can also be reacted with the amines mentioned.
- anionic collectors are anionic surfactants of the fatty acid type, alkyl sulfates, alkyl ether sulfates, alkyl sulfosuccinates, alkyl sulfosuccinamates, alkyl benzene sulfonates, alkane sulfonates, petroleum sulfonates, acyl lactylates, sarcosides, alkyl phosphates, alkyl ether phosphates, and alkyl carboxylic acid acids. All of these anionic surfactants are known compounds, the preparation of which - unless stated otherwise - for example in J. Falbe, U.
- Hasserodt ed.
- Catalysts ed.
- Surfactants and Mineral Oil Additives Thieme Verlag, Stuttgart, 1978 or J. Falbe (ed.) "Surfactants in Consumer Products", Springer Verlag, Berlin, 1986.
- Suitable fatty acids are in particular the straight-chain fatty acids of the formula (II) obtained from vegetable or animal fats and oils, for example by splitting and optionally fractionating and / or separating by the crosslinking process,
- R 2 -COOY (II) in which R 2 represents an aliphatic hydrocarbon radical having 12 to 18 carbon atoms and 0, 1, 2 or 3 double bonds and Y represents an alkali metal, alkaline earth metal or an ammonium radical.
- R 2 represents an aliphatic hydrocarbon radical having 12 to 18 carbon atoms and 0, 1, 2 or 3 double bonds and Y represents an alkali metal, alkaline earth metal or an ammonium radical.
- the sodium and potassium salts of oleic and tall oil fatty acids are of particular importance.
- Suitable alkyl sulfates are the water-soluble salts of sulfuric acid semi-esters of fatty alcohols of the formula (III)
- Suitable alkyl ether sulfates are the water-soluble salts of sulfuric acid semiesters of fatty alcohol polyglycol ethers of the formula (IV)
- R 4 represents a linear or branched alkyl radical having 8 to 22, preferably 12 to 18 carbon atoms
- R 5 represents hydrogen or a methyl group
- n represents 1 to 30, preferably 2 to 15 and Z has the meaning given above.
- Suitable alkylsulfosuccinates are sulfosuccinic acid monoesters of fatty alcohols of the formula (V)
- R 6 represents a linear or branched alkyl radical having 8 to 22, preferably 12 to 18 carbon atoms and Z has the meaning given above.
- Suitable alkylsulfosuccinamates are sulfosuccinic acid monoamides of fatty amines of the formula (VI), in which R 7 represents a linear or branched alkyl radical having 8 to 22, preferably 12 to 18 carbon atoms and Z has the meaning given above.
- Suitable alkylbenzene sulfonates are substances of the formula (VII)
- Suitable alkanesulfonates are substances of the formula (VIII)
- Suitable petroleum sulfonates are substances which are obtained by reacting lubricating oil fractions with sulfur trioxide or oleum and then neutralizing with sodium hydroxide solution. Products in which the hydrocarbon radicals predominantly have chain lengths of 8 to 22 carbon atoms are particularly suitable here.
- Suitable acyl lactylates are substances of the formula (IX)
- R 10 represents an aliphatic, cycloaliphatic or alicyclic, optionally substituted by hydroxyl group hydrocarbon radical having 7 to 23 carbon atoms and 0, 1, 2 or 3 double bonds and Z has the meaning given above.
- acyl lactylates in flotation is described in German patent application DE 32 38 060 A1.
- Suitable sarcosides are substances of the formula (X)
- R 11 represents an aliphatic hydrocarbon radical having 12 to 22 carbon atoms and 0, 1, 2 or 3 double bonds.
- Suitable alkyl phosphates and alkyl ether phosphates are substances of the formulas (XI) and (XII) and
- R 12 and R 13 independently of one another are an alkyl or alkenyl radical having 8 to 22 carbon atoms and p and q in the case of the alkyl phosphates are 0, in the case of the alkyl ether phosphates are numbers from 1 to 15 and Z has the meaning given above.
- the phosphates can be present as mono- or diphosphates. In this case, preference is given to using mixtures of mono- and dialkylphosphates of the type obtained in the industrial production of such compounds.
- Alkyl aspartic acids are to be understood as meaning compounds of the formula (XIII)
- R 14 represents an alkyl or alkenyl radical having 8 to 22 carbon atoms and Z has the meaning given above.
- nonionic collectors are to be understood as nonionic surfactants of the fatty alcohol polyglycol ether, alkylphenol polyglycol ether, fatty acid polyglycol ester, fatty acid amide polyglycol ether, fatty amine polyglycol ether, mixed ether, hydroxymethyl ether and alkyl glycoside types. All of these nonionic surfactants are known compounds, the preparation of which - unless stated otherwise - for example in J. Falbe, U. Hasserodt (ed.), "Catalysts, Surfactants and Mineral Oil Additives, Thieme Verlag, Stuttgart, 1978 or J.
- Suitable fatty alcohol polyglycol ethers are addition products of an average of n moles of ethylene and / or propylene oxide onto fatty alcohols, which follow the formula (XV)
- R 16 is a linear or branched alkyl radical having 8 to 22, preferably 12 to 18 carbon atoms
- R 5 is hydrogen or a methyl group
- n is a number from 1 to 30, preferably 2 to 15.
- Suitable alkylphenol polyglycol ethers are addition products of an average of n moles of ethylene and / or propylene glycol with alkylphenols, which follow the formula (XVI)
- R 17 represents an alkyl radical having 4 to 15, preferably 8 to 10 carbon atoms and R 5 and n have the meanings given above.
- Suitable fatty acid polyglycol esters are adducts of an average of n moles of ethylene and / or propylene oxide with fatty acids which follow the formula (XVII). in which R 18 represents an aliphatic carbon radical having 5 to 21 carbon atoms and 0, 1, 2 or 3 double bonds and R 5 and n have the meanings given above.
- Suitable fatty acid amide polyglycol ethers are addition products of an average of n moles of ethylene oxide and / or propylene oxide onto fatty acid amides which follow the formula (XVIII)
- R 19 represents an aliphatic hydrocarbon radical having 5 to 21 carbon atoms and 0, 1, 2 or 3 double bonds and R 5 and n have the meanings given above.
- Suitable fatty amine polyglycol ethers are addition products of an average of n moles of ethylene and / or propylene oxide with fatty amines, which follow the formula (XIX)
- Suitable mixed ethers are reaction products of fatty alcohol polyglycol ethers with alkyl chlorides of the formula (XX),
- R 21 represents an aliphatic carbon radical having 6 to 22 carbon atoms and 0, 1, 2 or 3 double bonds
- R 22 represents an alkyl radical having 1 to 4 carbon atoms or a benzyl radical and R ⁇ and n have the meanings given above.
- Suitable hydroxy mixed ethers are substances of the formula (XXI)
- R 23 represents an alkyl radical having 6 to 16 carbon atoms
- R 24 represents an alkyl radical having 1 to 4 carbon atoms or a benzyl radical
- R 5 and n have the meanings given above.
- the preparation of the hydroxymisethers is described in German patent application DE 37 23 323 A1.
- Suitable alkyl glycosides are substances of the formula (XXII)
- G is preferably a glucose unit and x is a number from 1.1 to 1.6.
- the preparation of the alkyl glycosides is described, for example, in German patent application DE 37 23 826 A1.
- the mixtures of the ether amines with the anionic and / or nonionic collectors can have a content of 5 to 95% by weight, preferably 10 to 60% by weight, of the ether amines. Particularly advantageous results are achieved with mixtures which, in addition to ether amines, contain fatty acids, alkyl aspartic acids and / or ether carboxylic acids or alkyl sulfosuccinamates, alkyl phosphates and / or alkyl ether phosphates.
- the collector mixture In order to achieve economically viable results in the flotation of iron ore, the collector mixture must be used in a certain minimum amount. However, a maximum amount must also not be exceeded, since otherwise the foam formation becomes too strong and the selectivity towards the contaminants to be flotated out decreases.
- the amounts in which the collector mixtures to be used according to the invention can be used are usually 20 to 2000, preferably 50 to 1000 g per ton of raw ore.
- the method according to the invention includes the use of reagents customary for flotation, such as foaming agents, regulators, activators, deactivators, etc.
- the flotation is carried out under the conditions of the methods of the prior art.
- hematite ore contained about 44% by weight of silicates (predominantly quartz) and 0.1 to 0.2% by weight of apatite.
- silicates predominantly quartz
- apatite 0.1 to 0.2% by weight
- the preparation comprised the following sub-steps:
- the amine collector and the anionic and / or nonionic collector were used in the Rougher flotation stage. 600 g of the previously roughly crushed ore were added with the addition of 13.4 mg sodium metasilicate, 40.2 mg sodium hydroxide and about 400 ml flotation water (hardness: 14.7 mg / l CaCl 2 ⁇ 2H 2 O and 4.9 mg / l MgSO 4 ⁇ 7H 2 O)) milled in a rod mill for 45 min. The ground ore had the following grain size distribution:
- the finely ground ore was then transferred to the desludging stage, diluted to about 8 l (solids content: 7% by weight), mixed with 3 ml of heat-treated corn starch (2.25% by weight) and the supernatant sludge was separated off after 2 minutes.
- the desludged flotation task (volume: approx. 1 1) was transferred to a 2-1 Denver agitator cell (type D1). Then 67 ml of sodium hydroxide and 12 ml of corn starch (2.25% by weight) were added, the cell was filled with flotation water and the slurry was conditioned with stirring for 2 minutes. The amine collector and the anionic and / or nonionic collector were then metered in. The Rougher flotation was then carried out at a stirring speed of 1200 rpm, at which a foam product and a concentrate were obtained in the cell. After metering the collector again, the flotation was carried out a second time and another foam product and the desired iron ore concentrate were obtained. Details of the flotation tests can be found in Tables 4, 5 and 6.
- Rougher 2 collector A, collector B (9/9 g / t) [9] e) Rougher 1: collector A, collector B, no conditioning
- a magnetite ore of the chemical composition given under II) was used, which had a grain size of 89% by weight less than 43 ⁇ m.
- the flotation was again carried out in a 2-1 Denver cell (type D1) with a turbidity density of approx. 220 g / l in water with a calcium ion content of 4 mg / l.
- the pH of the slurry was adjusted to 8.5 by adding sodium hydroxide; the stirring speed was 1200 rpm.
- air was introduced and floated at a flow rate of 130 to 150 l / h.
- the foam was removed over a period of 2 min in the general silicate flotation, with an additional phosphate flotation the flotation time was extended in accordance with the information in Table 7.
- the amine collector was dosed as a 0.25% by weight aqueous solution, and the anionic collector mixtures were added as 5% by weight aqueous solutions.
- a commercial foamer based on aldehydes, alcohols and esters with a dosage of 30 g / t was used in all flotation experiments and metered into the slurry undiluted.
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4133063 | 1991-10-04 | ||
DE4133063A DE4133063A1 (de) | 1991-10-04 | 1991-10-04 | Verfahren zur herstellung von eisenerzkonzentraten durch flotation |
PCT/EP1992/002224 WO1993006935A1 (de) | 1991-10-04 | 1992-09-25 | Verfahren zur herstellung von eisenerzkonzentraten durch flotation |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0609257A1 true EP0609257A1 (de) | 1994-08-10 |
EP0609257B1 EP0609257B1 (de) | 1996-06-12 |
Family
ID=6442114
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19920920650 Expired - Lifetime EP0609257B1 (de) | 1991-10-04 | 1992-09-25 | Verfahren zur herstellung von eisenerzkonzentraten durch flotation |
Country Status (6)
Country | Link |
---|---|
US (1) | US5540336A (de) |
EP (1) | EP0609257B1 (de) |
AU (1) | AU658226B2 (de) |
CA (1) | CA2120742A1 (de) |
DE (2) | DE4133063A1 (de) |
WO (1) | WO1993006935A1 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102259060A (zh) * | 2010-12-07 | 2011-11-30 | 鞍钢集团矿业公司 | 低品位铁矿物浮选捕收剂 |
US8784678B2 (en) | 2007-07-20 | 2014-07-22 | Clariant S.A. | Reverse iron ore flotation by collectors in aqueous nanoemulsion |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5540337A (en) * | 1994-04-04 | 1996-07-30 | Baker Hughes Incorporated | Alkyloxyalkaneamines useful as cationic froth flotation collectors |
US5724986A (en) * | 1995-11-06 | 1998-03-10 | Jones Medical Instrument Co. | Casing and spirometer for metered dose inhaler |
SE521949C2 (sv) * | 1997-11-27 | 2003-12-23 | Akzo Nobel Nv | Förfarande för skumflotation av silikatinnehållande järnmalm |
US7480848B2 (en) * | 2006-02-10 | 2009-01-20 | The Directv Group, Inc. | Methods and apparatus to select tornado error correction parameters |
DE102006010939A1 (de) | 2006-03-09 | 2007-09-13 | Clariant International Limited | Flotationsreagenz für Silikate |
DE102006019561A1 (de) | 2006-04-27 | 2007-10-31 | Clariant International Limited | Flotationsreagenz für silikathaltige Mineralien |
AU2007338062B2 (en) * | 2006-12-22 | 2012-01-12 | Akzo Nobel Chemicals International B.V. | Amine formulations for reverse froth flotation of silicates from iron ore |
BRPI0705593B1 (pt) * | 2007-11-22 | 2016-04-12 | Univ Minas Gerais | método de quantificação de aminas em resíduos de flotação de minério de ferro |
CN101234367B (zh) * | 2008-03-04 | 2011-04-06 | 昆明晶石矿冶有限公司 | 一种菱铁矿浮选捕收剂及其制备方法 |
DE102010004893A1 (de) | 2010-01-19 | 2011-07-21 | Clariant International Limited | Flotationsreagenz für magnetit- und/oder hämatithaltige Eisenerze |
AU2014286223B2 (en) | 2013-07-05 | 2017-12-21 | Akzo Nobel Chemicals International B.V. | The synthesis of new anionic surfactants and their use as collectors in froth flotation of non-sulphidic ores |
WO2016041916A1 (en) * | 2014-09-18 | 2016-03-24 | Akzo Nobel Chemicals International B.V. | Use of branched alcohols and alkoxylates thereof as secondary collectors |
WO2017127704A1 (en) * | 2016-01-21 | 2017-07-27 | Mlinar Matthew Albert | Cationic flotation of silica and apatite from oxidized iron ores at natural ph |
RU2747766C2 (ru) | 2016-07-08 | 2021-05-13 | Акцо Нобель Кемикалз Интернэшнл Б.В. | Способ обработки магнетитовой руды и композиция коллектора |
RU2741494C1 (ru) * | 2017-07-04 | 2021-01-26 | Норион Кемикалз Интернэшнл Б.В. | Способ обработки кремнистых несульфидных руд и соответствующая композиция собирателей |
RU2735681C1 (ru) * | 2017-07-04 | 2020-11-05 | Норион Кемикалз Интернэшнл Б.В. | Способ обработки карбонатных несульфидных руд и соответствующая композиция собирателей |
US20210252525A1 (en) * | 2018-06-19 | 2021-08-19 | Clariant International Ltd. | Use Of Polyols For Improving A Process For Reverse Froth Flotation Of Iron Ore |
WO2023180027A1 (en) | 2022-03-25 | 2023-09-28 | Clariant International Ltd | Novel cationic collectors for improving a process for froth flotation of silicates |
CN117585653B (zh) * | 2023-11-13 | 2024-08-09 | 湖北三峡实验室 | 一种多次沉淀法制备低成本电池级磷酸铁的方法 |
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US3363758A (en) * | 1966-12-08 | 1968-01-16 | Ashland Oil Inc | Use of primary aliphatic ether amine acid salts in froth flotation process |
AT317807B (de) * | 1971-07-30 | 1974-09-10 | Chem Y | Flotationsverfahren |
FR2367820A1 (fr) * | 1976-10-18 | 1978-05-12 | Ceca Sa | Procede de flottation de minerais oxydes |
BR7706938A (pt) * | 1976-10-18 | 1978-08-08 | Akzona Inc | Mistura de pre-emulsao,emulsao aquosa e processo de flotacao com espuma |
US4139481A (en) * | 1977-12-21 | 1979-02-13 | American Cyanamid Company | Combinations of alkylamidoalkyl monoesters of sulfosuccinic acid and fatty acids as collectors for non-sulfide ores |
US4206045A (en) * | 1978-12-07 | 1980-06-03 | American Cyanamid Company | Process for froth flotation of phosphate using combination collector |
US4309282A (en) * | 1980-04-14 | 1982-01-05 | American Cyanamid Company | Process of phosphate ore beneficiation in the presence of residual organic polymeric flocculants |
US4319987A (en) * | 1980-09-09 | 1982-03-16 | Exxon Research & Engineering Co. | Branched alkyl ether amines as iron ore flotation aids |
DE3238060A1 (de) * | 1982-10-14 | 1984-04-19 | Henkel KGaA, 4000 Düsseldorf | Flotationsmittel und verfahren zur flotation nichtsulfidischer minerale |
US4472270A (en) * | 1983-05-18 | 1984-09-18 | Mobil Oil Corporation | Beneficiation of ores |
DE3504242A1 (de) * | 1985-02-08 | 1986-08-14 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur herstellung von tertiaeren etheraminen |
US4732667A (en) * | 1985-02-20 | 1988-03-22 | Berol Kemi Ab | Process and composition for the froth flotation beneficiation of iron minerals from iron ores |
DE3536975A1 (de) * | 1985-10-17 | 1987-04-23 | Henkel Kgaa | Verwendung von nichtionischen tensiden als hilfsmittel fuer die flotation von nichtsulfidischen erzen |
DE3641579A1 (de) * | 1986-12-05 | 1988-06-16 | Henkel Kgaa | N-alkyl- und n-alkenylasparaginsaeuren als co-sammler fuer die flotation nichtsulfidischer erze |
DE3723323C2 (de) * | 1987-07-15 | 1998-03-12 | Henkel Kgaa | Hydroxy-Mischether, Verfahren zu deren Herstellung sowie deren Verwendung |
DE3723826A1 (de) * | 1987-07-18 | 1989-01-26 | Henkel Kgaa | Verfahren zur herstellung von alkylglykosiden |
-
1991
- 1991-10-04 DE DE4133063A patent/DE4133063A1/de not_active Withdrawn
-
1992
- 1992-09-25 AU AU26515/92A patent/AU658226B2/en not_active Ceased
- 1992-09-25 DE DE59206582T patent/DE59206582D1/de not_active Expired - Fee Related
- 1992-09-25 EP EP19920920650 patent/EP0609257B1/de not_active Expired - Lifetime
- 1992-09-25 US US08/211,522 patent/US5540336A/en not_active Expired - Fee Related
- 1992-09-25 CA CA 2120742 patent/CA2120742A1/en not_active Abandoned
- 1992-09-25 WO PCT/EP1992/002224 patent/WO1993006935A1/de active IP Right Grant
Non-Patent Citations (1)
Title |
---|
See references of WO9306935A1 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8784678B2 (en) | 2007-07-20 | 2014-07-22 | Clariant S.A. | Reverse iron ore flotation by collectors in aqueous nanoemulsion |
US9403174B2 (en) | 2007-07-20 | 2016-08-02 | Clariant S.A. | Reverse iron ore flotation by collectors in aqueous nanoemulsion |
CN102259060A (zh) * | 2010-12-07 | 2011-11-30 | 鞍钢集团矿业公司 | 低品位铁矿物浮选捕收剂 |
Also Published As
Publication number | Publication date |
---|---|
CA2120742A1 (en) | 1993-04-15 |
DE4133063A1 (de) | 1993-04-08 |
AU658226B2 (en) | 1995-04-06 |
DE59206582D1 (de) | 1996-07-18 |
US5540336A (en) | 1996-07-30 |
WO1993006935A1 (de) | 1993-04-15 |
EP0609257B1 (de) | 1996-06-12 |
AU2651592A (en) | 1993-05-03 |
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