EP0598973A1 - Multi-purpose liquid cleaning composition - Google Patents

Multi-purpose liquid cleaning composition Download PDF

Info

Publication number
EP0598973A1
EP0598973A1 EP92870191A EP92870191A EP0598973A1 EP 0598973 A1 EP0598973 A1 EP 0598973A1 EP 92870191 A EP92870191 A EP 92870191A EP 92870191 A EP92870191 A EP 92870191A EP 0598973 A1 EP0598973 A1 EP 0598973A1
Authority
EP
European Patent Office
Prior art keywords
nonionic surfactant
hlb
hydrophilic
composition
compositions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP92870191A
Other languages
German (de)
English (en)
French (fr)
Inventor
Stefano Scialla
Sergio Cardola
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP92870191A priority Critical patent/EP0598973A1/en
Priority to AT93870181T priority patent/ATE172234T1/de
Priority to DK93870181T priority patent/DK0600847T3/da
Priority to EP93870181A priority patent/EP0600847B2/en
Priority to ES93870181T priority patent/ES2124778T5/es
Priority to DE69321562T priority patent/DE69321562T3/de
Priority to TR01058/93A priority patent/TR28413A/xx
Priority to EP94901627A priority patent/EP0670876A1/en
Priority to JP6513290A priority patent/JPH08505413A/ja
Priority to AU56149/94A priority patent/AU681365B2/en
Priority to RU95113462/04A priority patent/RU95113462A/ru
Priority to AU65156/94A priority patent/AU670374B2/en
Priority to PCT/US1993/011293 priority patent/WO1994012599A1/en
Priority to NZ258466A priority patent/NZ258466A/en
Priority to PCT/US1993/011294 priority patent/WO1994012600A1/en
Priority to US08/432,154 priority patent/US5559091A/en
Priority to CA 2148810 priority patent/CA2148810C/en
Priority to US08/432,153 priority patent/US5536438A/en
Priority to JP6513291A priority patent/JPH08503731A/ja
Priority to CA002149227A priority patent/CA2149227C/en
Priority to NZ278814A priority patent/NZ278814A/en
Priority to BR9307515-4A priority patent/BR9307515A/pt
Priority to KR1019950702134A priority patent/KR950704462A/ko
Priority to EG73993A priority patent/EG20373A/xx
Priority to MA23345A priority patent/MA23039A1/fr
Publication of EP0598973A1 publication Critical patent/EP0598973A1/en
Priority to NO952057A priority patent/NO952057D0/no
Priority to FI952539A priority patent/FI952539A0/fi
Priority to NO952058A priority patent/NO952058L/no
Priority to FI952540A priority patent/FI952540A/fi
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • the present invention relates to the field of detergent or cleaning compositions.
  • the compositions of the present invention are multi-purpose cleaning compositions which are suitable for use as hard-surface cleaners as well as in laundry applications.
  • cleaning compositions have been described in the art. Typically, cleaning compositions can be divided into hard surface cleaning compositions and laundry cleaning compositions. Cleaning compositions of these two types are traditionally very different in formulation and are sold as different 8roducts with different marketing concepts. These differences impose on the consumer to have to purchase and use at least two different products. Furthermore, compositions of the two types above, especially hard surface cleaners, can be divided into subtypes. Indeed, many different kinds of hard-surface cleaners are available, for instance bathroom cleaners, kitchen cleaners or floor cleaners.
  • kitchen soils comprise mainly edible oils
  • bathroom soils comprise mainly sebum and soap scum, also limescale
  • floor soils comprise mainly particulate soils and laundry may have many different soils and stains.
  • compositions according to the present invention should also be able to perform in a variety of conditions, i.e. in hard and soft water. They should also provide satisfactory shine performance and surface safety when used as hard surface cleaners.
  • the present invention is an aqueous cleaning composition having a pH of from 0.5 to 6, said composition comprising from 2% to 40% by weight of the total composition of a nonionic surfactant system, whereby said nonionic surfactant system comprises:
  • compositions herein further comprise hydrogen peroxide.
  • compositions according to the present invention are aqueous liquid cleaning compositions.
  • Said aqueous compositions have a pH as is of from 0.5 to 6, preferably 1 to 5, most preferably from 2 to 4.5.
  • the pH of the compositions can be adjusted by using organic or inorganic acids, or alkalinizing agents.
  • compositions according to the present invention further comprise a specific nonionic surfactant system comprising at least four nonionic surfactants.
  • Said nonionic surfactant system is efficient in cleaning a variety of different soils, and significant cooperation has been observed between the four different types of surfactants.
  • the nonionic surfactant system herein comprises a mixture of at least four different nonionic surfactants, each of which lies in a specified HLB (hydrophilic-lipophilic balance) range.
  • HLB hydrophilic-lipophilic balance
  • nonionic surfactant system according to the present invention comprises:
  • Suitable highly hydrophobic surfactants for use herein are Dobanol ® 23-3, Lutensol ® AO3, Dobanol ® 91-2.5 and Dobanol ® 23-2.
  • compositions according to the present invention said nonionic surfactants belonging to the four classes described hereinabove act in synergy, particularly on kitchen dirt soils and bathtub soils. It is thus possible to use low total levels of said nonionic surfactant system.
  • the compositions according to the present invention comprise from 40% down to 2% by weight of the total composition of said nonionic surfactant system, preferably from 15% to 3%.
  • nonionic surfactant system wherein the weight ratio of highly hydrophilic surfactant to hydrophilic surfactant is at most 1:1.5, and wherein the combined amount of said highly hydrophilic and hydrophilic surfactant in the total composition is at least 2% by weight, preferably at least 2.5%.
  • nonionic surfactant system wherein the weight ratio of highly hydrophobic to hydrophobic surfactant is from 1.5:1 to 2.5:1, preferably 2:1, and wherein the combined amount of said hydrophobic and highly hydrophobic nonionic surfactant in the total composition is at least 1.5% by weight.
  • compositions according to the present invention may further comprise additional nonionic surfactants, i.e. there can be more than one surfactant in each class hereinabove.
  • additional nonionic surfactants i.e. there can be more than one surfactant in each class hereinabove.
  • the compositions according to the present invention do not require the use of an anionic surfactant system. Accordingly, the compositions according to the present invention are preferably free of anionic surfactants.
  • compositions herein presents a good suds profile and therefore does not require the use of a suds suppressing ingredient. It has been found that, for an optimum suds profile, it is preferable to use a nonionic surfactant system according to the present invention wherein the weight ratio of the sum of the highly hydrophilic and hydrophilic surfactants to the highly hydrophobic surfactant is of 1.5:1 or more.
  • compositions herein preferably comprise from 2% to 15% by weight of the total composition of hydrogen peroxide or a source thereof.
  • hydrogen peroxide provides strong cleaning benefits which are particularly noticeable in laundry applications.
  • the nonionic surfactant system for use in the compositions according to the present invention is remarkably compatible with hydrogen peroxide in that good hydrogen peroxide storage stability was observed, even in the absence of hydrogen peroxide stabilizers.
  • ingredients which are typically sensitive to hydrogen peroxide such as dyes or brighteners, appear to be stable upon storage in the compositions according to the present invention without having to add stabilizers for that purpose.
  • compositions according to the present invention may further comprise a variety of optional ingredients such as builders, solvents, brighteners, perfumes and dyes.
  • compositions according to the present invention can be used as a household cleaner in the bathroom or in the kitchen, and can also be used as a laundry detergent or as a laundry detergent booster. When used as hard surface cleaners, the compositions according to the present invention are easy to rinse and provide good shine characteristics on the cleaned surfaces.
  • compositions were made by mixing the listed ingredients in the listed proportions (weight % unless otherwise specified).
  • the compositions in the examples were tested and proved satisfactory on cleaning laundry, kitchen dirt soils as well as bathtub soils. Furthermore, the stability of hydrogen peroxide, brightener and dye was monitored and proved satisfactory at 50°c for two weeks.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
EP92870191A 1992-11-26 1992-11-26 Multi-purpose liquid cleaning composition Withdrawn EP0598973A1 (en)

Priority Applications (29)

Application Number Priority Date Filing Date Title
EP92870191A EP0598973A1 (en) 1992-11-26 1992-11-26 Multi-purpose liquid cleaning composition
AT93870181T ATE172234T1 (de) 1992-11-26 1993-08-31 Reinigungsmittelzusammensetzungen mit einer kombination aus stark hydrophilen und stark hydrophoben nichtionischen tensiden
DK93870181T DK0600847T3 (da) 1992-11-26 1993-08-31 Rensesammensætning med kombineret stærkt hydrofile og stærkt hydrofobe, nonioniske, overfladeaktive midler
EP93870181A EP0600847B2 (en) 1992-11-26 1993-08-31 Cleaning compositions with combined highly hydrophilic and highly hydrophobic nonionic surfactants
ES93870181T ES2124778T5 (es) 1992-11-26 1993-08-31 Composiciones de limpieza con tensioactivos no ionicos combinados muy hidrofilos y muy hidrofobos.
DE69321562T DE69321562T3 (de) 1992-11-26 1993-08-31 Reinigungsmittelzusammensetzungen mit einer Kombination aus stark hydrophilen und stark hydrophoben nichtionischen Tensiden
TR01058/93A TR28413A (tr) 1992-11-26 1993-11-16 Birlikte yüksek ölcüde hidrofilik ve yüksek ölcüde hidrofobik noniyonik sürfaktanlara sahip olan temizleme bilesimleri.
US08/432,154 US5559091A (en) 1992-11-26 1993-11-19 Alkaline cleaning compositions with combined highly hydrophilic and highly hydrophobic nonionic surfactants
JP6513291A JPH08503731A (ja) 1992-11-26 1993-11-19 多目的液状クリーニング組成物
AU56149/94A AU681365B2 (en) 1992-11-26 1993-11-19 Cleaning compositions with combined highly hydrophilic and highly hydrophobic nonionic surfactants
RU95113462/04A RU95113462A (ru) 1992-11-26 1993-11-19 Водная чистящая композиция
AU65156/94A AU670374B2 (en) 1992-11-26 1993-11-19 Multi-purpose liquid cleaning composition
PCT/US1993/011293 WO1994012599A1 (en) 1992-11-26 1993-11-19 Cleaning compositions with combined highly hydrophilic and highly hydrophobic nonionic surfactants
NZ258466A NZ258466A (en) 1992-11-26 1993-11-19 Cleaning compositions comprising a non-ionic surfactant system containing a mixture of highly hydrophilic and highly hydrophobic non-ionic surfactants and at least one alkanolamine
PCT/US1993/011294 WO1994012600A1 (en) 1992-11-26 1993-11-19 Multi-purpose liquid cleaning composition
EP94901627A EP0670876A1 (en) 1992-11-26 1993-11-19 Multi-purpose liquid cleaning composition
CA 2148810 CA2148810C (en) 1992-11-26 1993-11-19 Multi-purpose liquid cleaning composition
US08/432,153 US5536438A (en) 1992-11-26 1993-11-19 Multi-purpose liquid cleaning composition comprising nonionic surfactants of different HLB values
JP6513290A JPH08505413A (ja) 1992-11-26 1993-11-19 高親水性および高疎水性のノニオン性界面活性剤を組み合わせたクリーニング組成物
CA002149227A CA2149227C (en) 1992-11-26 1993-11-19 Cleaning compositions with combined highly hydrophilic and highly hydrophobic nonionic surfactants
NZ278814A NZ278814A (en) 1992-11-26 1993-11-19 Liquid cleaning composition; comprises a non-ionic surfactant system with at least four non-ionic surfactants belonging to four hlb classes
BR9307515-4A BR9307515A (pt) 1992-11-26 1993-11-19 Composições de limpeza com tensoativos não iÈnicos altamente hidrofìlicos e altamente hidrofóbicos combinados
KR1019950702134A KR950704462A (ko) 1992-11-26 1993-11-19 고 친수성 및 고 소수성 비이온계 계면활성제의 혼합물을 함유하는 세정 조성물(cleaning compositions with combined highly hydrophilic and highly hydrophobic nonionic surfactants)
EG73993A EG20373A (en) 1992-11-26 1993-11-24 Cleaning compositions with combined highly hydrophilic and highly hydrophobic monionic surfactants
MA23345A MA23039A1 (fr) 1992-11-26 1993-11-25 Composition de nettoyage avec des tensio-actifs non ioniques hautement hydrophiles et hautement hydrophobes combines.
NO952057A NO952057D0 (no) 1992-11-26 1995-05-24 Fleranvendelig flytende rengjöringsmiddelblanding
FI952539A FI952539A0 (fi) 1992-11-26 1995-05-24 Monikäyttöinen nestemäinen puhdistuskoostumus
NO952058A NO952058L (no) 1992-11-26 1995-05-24 Renseblandinger med kombinerte höyhydrofile og höyhydrofobe ikke-ioniske overflateaktive midler
FI952540A FI952540A (fi) 1992-11-26 1995-05-24 Puhdistuskoostumukset, joissa on hyvin hydrofiilisiä ja hyvin hydrofobisia ei-ionisia pinta-aktiivisia aineita

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP92870191A EP0598973A1 (en) 1992-11-26 1992-11-26 Multi-purpose liquid cleaning composition

Publications (1)

Publication Number Publication Date
EP0598973A1 true EP0598973A1 (en) 1994-06-01

Family

ID=8212287

Family Applications (2)

Application Number Title Priority Date Filing Date
EP92870191A Withdrawn EP0598973A1 (en) 1992-11-26 1992-11-26 Multi-purpose liquid cleaning composition
EP94901627A Withdrawn EP0670876A1 (en) 1992-11-26 1993-11-19 Multi-purpose liquid cleaning composition

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP94901627A Withdrawn EP0670876A1 (en) 1992-11-26 1993-11-19 Multi-purpose liquid cleaning composition

Country Status (9)

Country Link
EP (2) EP0598973A1 (fi)
JP (1) JPH08503731A (fi)
AU (1) AU670374B2 (fi)
CA (1) CA2148810C (fi)
FI (1) FI952539A0 (fi)
NO (1) NO952057D0 (fi)
NZ (1) NZ278814A (fi)
RU (1) RU95113462A (fi)
WO (1) WO1994012600A1 (fi)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0666308A2 (en) * 1994-02-03 1995-08-09 The Procter & Gamble Company Multi-purpose liquid cleaning compositions
EP0686691A1 (en) * 1994-06-10 1995-12-13 The Procter & Gamble Company Aqueous emulsions with brighteners
US5501816A (en) * 1994-07-12 1996-03-26 Basf Corporation Aqueous based solvent free degreaser composition
WO1997001622A1 (de) * 1995-06-26 1997-01-16 Henkel-Ecolab Gmbh & Co. Ohg Wässriges reinigungsmittel
US5634979A (en) * 1994-12-22 1997-06-03 Henkel Corporation Composition and method for degreasing metal surfaces
US5767055A (en) * 1996-02-23 1998-06-16 The Clorox Company Apparatus for surface cleaning
DE19750455C1 (de) * 1997-11-14 1999-04-29 Henkel Kgaa Verwendung von peroxidhaltigen Zubereitungen
US5902354A (en) * 1994-04-12 1999-05-11 The Procter & Gamble Company Bleaching compositions
GB2359818A (en) * 2000-03-01 2001-09-05 Reckitt & Colmann Prod Ltd Hard surface cleaning composition
EP1149945A1 (de) * 2000-04-29 2001-10-31 Ciba Spezialitätenchemie Pfersee GmbH Zusammensetzung für die Vorbehandlung von Fasermaterialien
DE102005034752A1 (de) * 2005-07-21 2007-01-25 Henkel Kgaa Reinigungs- und Pflegemittel mit verbesserter Emulgierfähigkeit
WO2011088089A1 (en) 2010-01-12 2011-07-21 The Procter & Gamble Company Intermediates and surfactants useful in household cleaning and personal care compositions, and methods of making the same
WO2012112828A1 (en) 2011-02-17 2012-08-23 The Procter & Gamble Company Bio-based linear alkylphenyl sulfonates
WO2012138423A1 (en) 2011-02-17 2012-10-11 The Procter & Gamble Company Compositions comprising mixtures of c10-c13 alkylphenyl sulfonates
WO2014095793A1 (en) * 2012-12-19 2014-06-26 Akzo Nobel Chemicals International B.V. The use of an ethoxylated alcohol as a hydrotrope for an alkylene oxide adduct of an alcohol
DE102016117674A1 (de) 2016-09-20 2018-03-22 Bundesdruckerei Gmbh Verfahren zur Herstellung eines Sicherheits- oder Wertprodukts mit einem diffraktiven Sicherheitselement
EP3969553B1 (en) 2019-05-16 2023-04-19 Unilever Global Ip Limited Laundry composition

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PT687726E (pt) * 1994-06-17 2000-09-29 Procter & Gamble Composicoes de branqueamento
US5968888A (en) * 1998-11-13 1999-10-19 Colgate Palmolive Company Liquid crystal compositions containing a 2 alkyl alkanol and abrasive
US6620774B1 (en) 1999-01-26 2003-09-16 The Procter & Gamble Company Bleaching composition comprising substantially linear nonionic surfactants
JP5567255B2 (ja) * 2008-06-04 2014-08-06 花王株式会社 衣料用液体漂白剤組成物
JP5463026B2 (ja) * 2008-12-11 2014-04-09 花王株式会社 抗菌剤組成物
EP2963100B1 (en) * 2014-07-04 2018-09-19 Kolb Distribution Ltd. Liquid rinse aid compositions

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FR2062732A5 (fi) * 1970-03-31 1971-06-25 Roehm & Haas Gmbh
GB2011944A (en) * 1978-01-09 1979-07-18 Unilever Ltd Liquid nonionic detergent composition
EP0265041A2 (en) * 1986-10-21 1988-04-27 The Clorox Company Thickening system for cleaning products incorporating fluorescent whitening agents
WO1989011525A1 (en) * 1988-05-27 1989-11-30 Henkel Kommanditgesellschaft Auf Aktien Anti-froth alkyl polyglycol ethers for detergents (i)
EP0379256A2 (en) * 1989-01-17 1990-07-25 Colgate-Palmolive Company Acidic disinfectant all-purpose liquid cleaning composition
WO1991003540A1 (de) * 1989-08-30 1991-03-21 Henkel Kommanditgesellschaft Auf Aktien Antischaummittel für die maschinelle geschirr- und flaschenreinigung
EP0475002A1 (de) * 1990-09-05 1992-03-18 Hüls Aktiengesellschaft Viskose säurehaltige Reinigungsmittel
EP0497337A2 (de) * 1991-02-01 1992-08-05 Hoechst Aktiengesellschaft Wässrige Suspensionen von Peroxicarbonsäuren

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JPH078991B2 (ja) * 1989-07-18 1995-02-01 花王株式会社 中性液体洗浄剤組成物
ES2113421T3 (es) * 1992-11-16 1998-05-01 Procter & Gamble Composiciones de limpieza y blanqueo.
ES2124778T5 (es) * 1992-11-26 2002-05-01 Procter & Gamble Composiciones de limpieza con tensioactivos no ionicos combinados muy hidrofilos y muy hidrofobos.

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2062732A5 (fi) * 1970-03-31 1971-06-25 Roehm & Haas Gmbh
GB2011944A (en) * 1978-01-09 1979-07-18 Unilever Ltd Liquid nonionic detergent composition
EP0265041A2 (en) * 1986-10-21 1988-04-27 The Clorox Company Thickening system for cleaning products incorporating fluorescent whitening agents
WO1989011525A1 (en) * 1988-05-27 1989-11-30 Henkel Kommanditgesellschaft Auf Aktien Anti-froth alkyl polyglycol ethers for detergents (i)
EP0379256A2 (en) * 1989-01-17 1990-07-25 Colgate-Palmolive Company Acidic disinfectant all-purpose liquid cleaning composition
WO1991003540A1 (de) * 1989-08-30 1991-03-21 Henkel Kommanditgesellschaft Auf Aktien Antischaummittel für die maschinelle geschirr- und flaschenreinigung
EP0475002A1 (de) * 1990-09-05 1992-03-18 Hüls Aktiengesellschaft Viskose säurehaltige Reinigungsmittel
EP0497337A2 (de) * 1991-02-01 1992-08-05 Hoechst Aktiengesellschaft Wässrige Suspensionen von Peroxicarbonsäuren

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995021233A1 (en) * 1994-02-03 1995-08-10 The Procter & Gamble Company Aqueous cleaning compositions containing a 2-alkyl alkanol, h2o2, an anionic and a low hlb nonionic
EP0666308A3 (en) * 1994-02-03 1996-06-05 Procter & Gamble Liquid cleaning compositions for all uses.
EP0666308A2 (en) * 1994-02-03 1995-08-09 The Procter & Gamble Company Multi-purpose liquid cleaning compositions
US5902354A (en) * 1994-04-12 1999-05-11 The Procter & Gamble Company Bleaching compositions
EP0686691A1 (en) * 1994-06-10 1995-12-13 The Procter & Gamble Company Aqueous emulsions with brighteners
WO1995034621A1 (en) * 1994-06-10 1995-12-21 The Procter & Gamble Company Aqueous emulsions containing a hydrophobic brightener, a hydrophilic surfactant and a hydrophobic surfactant
US5501816A (en) * 1994-07-12 1996-03-26 Basf Corporation Aqueous based solvent free degreaser composition
US5634979A (en) * 1994-12-22 1997-06-03 Henkel Corporation Composition and method for degreasing metal surfaces
WO1997001622A1 (de) * 1995-06-26 1997-01-16 Henkel-Ecolab Gmbh & Co. Ohg Wässriges reinigungsmittel
US5767055A (en) * 1996-02-23 1998-06-16 The Clorox Company Apparatus for surface cleaning
DE19750455C1 (de) * 1997-11-14 1999-04-29 Henkel Kgaa Verwendung von peroxidhaltigen Zubereitungen
GB2359818A (en) * 2000-03-01 2001-09-05 Reckitt & Colmann Prod Ltd Hard surface cleaning composition
GB2359818B (en) * 2000-03-01 2004-04-21 Reckitt & Colmann Prod Ltd Container containing hard surface cleaning composition, and cleaning method
EP1149945A1 (de) * 2000-04-29 2001-10-31 Ciba Spezialitätenchemie Pfersee GmbH Zusammensetzung für die Vorbehandlung von Fasermaterialien
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FI952539A (fi) 1995-05-24
CA2148810C (en) 1999-01-19
RU95113462A (ru) 1997-03-20
AU6515694A (en) 1994-06-22
FI952539A0 (fi) 1995-05-24
WO1994012600A1 (en) 1994-06-09
JPH08503731A (ja) 1996-04-23
EP0670876A1 (en) 1995-09-13
NO952057L (no) 1995-05-24
EP0670876A4 (en) 1995-06-02
CA2148810A1 (en) 1994-06-09
NO952057D0 (no) 1995-05-24
NZ278814A (en) 1998-05-27
AU670374B2 (en) 1996-07-11

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