EP0596185A1 - Détergents liquides stables inhibant le transfert de couleur - Google Patents

Détergents liquides stables inhibant le transfert de couleur Download PDF

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Publication number
EP0596185A1
EP0596185A1 EP92870182A EP92870182A EP0596185A1 EP 0596185 A1 EP0596185 A1 EP 0596185A1 EP 92870182 A EP92870182 A EP 92870182A EP 92870182 A EP92870182 A EP 92870182A EP 0596185 A1 EP0596185 A1 EP 0596185A1
Authority
EP
European Patent Office
Prior art keywords
dye transfer
polyamine
brightener
oxide
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP92870182A
Other languages
German (de)
English (en)
Inventor
Abdennaceur Fredj
Patrick Willy Maurits Goethals
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP92870182A priority Critical patent/EP0596185A1/fr
Priority to ES93870106T priority patent/ES2125967T3/es
Priority to DE1993622461 priority patent/DE69322461T2/de
Priority to EP19930870106 priority patent/EP0587550B1/fr
Priority to AU45456/93A priority patent/AU4545693A/en
Priority to CA002140283A priority patent/CA2140283A1/fr
Priority to US08/373,196 priority patent/US5458809A/en
Priority to PCT/US1993/006223 priority patent/WO1994002580A1/fr
Priority to PH46483A priority patent/PH30146A/en
Priority to CN 93116768 priority patent/CN1042647C/zh
Priority to MX9304298A priority patent/MX191084B/es
Priority to CN93116491A priority patent/CN1040656C/zh
Priority to US08/416,687 priority patent/US5571781A/en
Priority to PCT/US1993/009799 priority patent/WO1994009101A1/fr
Priority to EP93870200A priority patent/EP0593406A1/fr
Priority to AU53592/94A priority patent/AU5359294A/en
Priority to JP6510247A priority patent/JPH09509190A/ja
Priority to AU55904/94A priority patent/AU670851B2/en
Priority to PL93308760A priority patent/PL175677B1/pl
Priority to PCT/US1993/010542 priority patent/WO1994011473A1/fr
Priority to HU9501296A priority patent/HUT71963A/hu
Priority to KR1019950701775A priority patent/KR950704458A/ko
Priority to JP6512172A priority patent/JPH08503246A/ja
Priority to CA002148808A priority patent/CA2148808C/fr
Priority to CZ951165A priority patent/CZ116595A3/cs
Priority to CN93112697A priority patent/CN1041840C/zh
Priority to MX9306971A priority patent/MX9306971A/es
Priority to TW83100628A priority patent/TW233309B/zh
Publication of EP0596185A1 publication Critical patent/EP0596185A1/fr
Priority to US08/777,567 priority patent/US5783548A/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0004—Non aqueous liquid compositions comprising insoluble particles
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3792—Amine oxide containing polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest

Definitions

  • the present invention relates to stable liquid detergent compositions inhibiting dye transfer
  • Brighteners also known as fluorescent whitening agents, are commonly used in laundry detergents. Brighteners deposit onto fabrics where they absorb ultraviolet radiant energy and reemit it as blue light. This reduces or eliminates any yellowish cast to fabrics and gives them a bright appearance.
  • Copending EP Patent Application 92202168.8 describes dye transfer inhibiting compostions comprising polyamine N-oxides containing polymers.
  • a dye transfer inhibiting composition comprising a brightener which has improved stability upon storage.
  • the present invention relates to inhibiting dye transfer compositions comprising
  • compositions of the present invention comprise as essential elements
  • polyamine N-oxide polymers contain units having the following structure formula : wherein
  • the N-O group can be represented by the following general structures : wherein
  • the N-O group can be part of the polymerisable unit (P) or can be attached to the polymeric backbone or a combination of both.
  • Suitable polyamine N-oxides wherein the N-O group forms part of the polymerisable unit comprise polyamine N-oxides wherein R is selected from aliphatic, aromatic, alicyclic or heterocyclic groups.
  • polyamine N-oxides comprises the group of polyamine N-oxides wherein the nitrogen of the N-O group forms part of the R-group.
  • Preferred polyamine N-oxides are those wherein R is a heterocyclic group such as pyrridine, pyrrole, imidazole, pyrrolidine, piperidine and derivatives thereof.
  • Another class of said polyamine N-oxides comprises the group of polyamine N-oxides wherein the nitrogen of the N-O group is attached to the R-group.
  • polyamine N-oxides are the polyamine oxides whereto the N-O group is attached to the polymerisable unit.
  • Preferred class of these polyamine N-oxides are the polyamine N-oxides having the general formula (I) wherein R is an aromatic, heterocyclic or alicyclic groups wherein the nitrogen of the N-0 functional group is part of said R group.
  • polyamine N-oxides are the polyamine oxides having the general formula (I) wherein R are aromatic, heterocyclic or alicyclic groups wherein the nitrogen of the N-0 functional group is attached to said R groups.
  • polyamine oxides wherein R groups can be aromatic such as phenyl.
  • Any polymer backbone can be used as long as the amine oxide polymer formed is water-soluble and has dye transfer inhibiting properties.
  • suitable polymeric backbones are polyvinyls, polyalkylenes, polyesters, polyethers, polyamide, polyimides, polyacrylates and mixtures thereof.
  • the amine N-oxide polymers of the present invention typically have a ratio of amine to the amine N-oxide of 10 : 1 to 1: 1000000.
  • the amount of amine oxide groups present in the polyamine oxide polymer can be varied by appropriate copolymerisation or by appropriate degree of N-oxidation .
  • the ratio of amine to amine N-oxide is from 3:1 to 1:1000000.
  • the polymers of the present invention actually encompass random or block copolymers where one monomer type is an amine N-oxide and the other monomer type is an N-oxide or not.
  • the amine oxide unit of the polyamine N-oxides has a pKa ⁇ 10, preferably pKa ⁇ 7, more preferred PKa ⁇ 6.
  • the polyamine oxides can be obtained in almost any degree of polymerisation. The degree of polymerisation is not critical provided the material has the desired water-solubility and dye-suspending power.
  • the average molecular weight is within the range of 500 to 1000,000 ; more preferred 1000 to 500,000 ; most preferred 5000 to 100,000.
  • the polyamine N-oxides of the present invention are typically present from 0.01 to 10% , more preferably from 0.05 to 1 %, most preferred from 0.05 to 0.5 % by weight of the dye transfer inhibiting composition.
  • Preferred brighteners according to the present invention are hydrophobic brighteners which have the general formula: wherein R i , R 2 , R 3 and R 4 represent, selected independently, anilino, cyclohexylamino, piperazino, phenylenediamino, toluenediamino, morpholino, aminophenol, N-2-hydroxyethyl-N-methylamino, N-2-Bis- hydroxyethyl.
  • Suitable brightener species include any combination of the possible Ri-4. moieties.
  • preferred brightener species are the tetra-anilino, tetra-piperazino, tetra-cyclohexylamino and combinations thereof such as for example the di-anilinodipiperazino; and the dianilino-dicyclohexylamino species.
  • a preferred brightener system in the context of this invention contains at least 40% (by reference to the total amount of the detergent brightener) of the specific hydrophobic brightener referred to hereinbefore in combination with a conventional detergent brightener, e.g., a di-sulfonated dianilino, dimorpholino stilbene brightener.
  • Non-aromatic anionic surfactants suitable for the present invention are generally disclosed in US-A-3,929,678.
  • Classes of non-aromatic anionic surfactants include the classes are :
  • anionic surfactants are the sodium and potassium alkylsulfates, especially those obtained by sulfating the higher alcohols (C8-C18 carbon atoms) such as those produced by reducing the glycerides of tallow or coconut oil; in straight chain or branched configuration.
  • anionic surfactants suitable for the present invention are the alkyl polyethoxylate sulfates, particulary those in which the alkyl group contains from 10 to 22, preferably from 12 to 18 carbon atoms, and wherein the polyethoxylate chain contains from 1 to 15 ethoxylate moieties.
  • anionic surfactants suitable for the present invention include sodium alkyl glyceryl ether sulfonates, especially those ethers of higher alcohols derived from tallow and coconut oil; sodium coconut oil fatty acid monoglyceride sulfonates and sulfates; sodium or potassium salts of alkyl ethylene oxide ether sulfates containing 1 to 10 units of ethylene oxide per molecule and wherein the alkyl group contains from 10 to 20 carbon atoms.
  • anionic surfactants are particularly suitable herein, especially mixtures of sulphonate and sulphate surfactants in a weight ratio of from 5:1 to 1:2, preferably from 3:1 to 2:3, more preferably from 3:1 to 1:1.
  • Preferred sulphonates include alpha-sulphonated methyl fatty acid esters in which the fatty acid is derived from a C 12 -Cl8 fatty source preferably from a C 16 -C 18 fatty source. In each instance the cation is an alkali metal, preferably sodium.
  • Preferred sulphate surfactants are alkyl sulphates having from 12 to 18 carbon atoms in the alkyl radical, optionally in admixture with ethoxy sulphates having from 10 to 20, preferably 10 to 16 carbon atoms in the alkyl radical and an average degree of ethoxylation of 1 to 6.
  • alkyl sulphates herein are tallow alkyl sulphate, coconut alkyl sulphate, and C14 -15 alkyl sulphates.
  • the cation in each instance is again an alkali metal cation, preferably sodium.
  • a liquid detergent composition comprising the dye transfer inhibiting composition mixed with detergent ingredients.
  • a wide range of surfactants can be used in the detergent composition of the present invention.
  • One class of nonionic surfactants useful in the present invention are condensates of ethylene oxide with a hydrophobic moiety to provide a surfactant having an average hydrophilic-lipophilic balance (HLB) in the range from 8 to 17, preferably from 9.5 to 13.5, more preferably from 10 to 12.5.
  • HLB hydrophilic-lipophilic balance
  • the hydrophobic (lipophilic) moiety may be aliphatic or aromatic in nature and the length of the polyoxyethylene group which is condensed with any particular hydrophobic group can be readily adjusted to yield a water-soluble compound having the desired degree of balance between hydrophilic and hydrophobic elements.
  • Especially preferred nonionic surfactants of this type are the C 9 -C 15 primary alcohol ethoxylates containing 3-8 moles of ethylene oxide per mole of alcohol, particularly the C14-C15 primary alcohols containing 6-8 moles of ethylene oxide per mole of alcohol and the C 12 -C14 primary alcohols containing 3-5 moles of ethylene oxide per mole of alcohol.
  • Nonionic surfactants comprises alkyl polyglucoside compounds of general formula wherein Z is a moiety derived from glucose; R is a saturated hydrophobic alkyl group that contains from 12 to 18 carbon atoms; t is from 0 to 10 and n is 2 or 3; x is from 1.3 to 4, the compounds including less than 10% unreacted fatty alcohol and less than 50% short chain alkyl polyglucosides.
  • Z is a moiety derived from glucose
  • R is a saturated hydrophobic alkyl group that contains from 12 to 18 carbon atoms
  • t is from 0 to 10 and n is 2 or 3
  • x is from 1.3 to 4, the compounds including less than 10% unreacted fatty alcohol and less than 50% short chain alkyl polyglucosides.
  • Compounds of this type and their use in detergent are disclosed in EP-B 0 070 077, 0 075 996 and 0 094 118.
  • nonionic surfactants are poly hydroxy fatty acid amide surfactants of the formula wherein R 1 is H, or R 1 is C 1 - 4 hydrocarbyl, 2-hydroxy ethyl, 2-hydroxy propyl or a mixture thereof, R 2 is C s - 31 hydrocarbyl, and Z is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative thereof.
  • R 1 is methyl
  • R 2 is a straight C11 1 - 15 alkyl or alkenyl chain such as coconut alkyl or mixtures thereof
  • Z is derived from a reducing sugar such as glucose, fructose, maltose, lactose, in a reductive amination reaction.
  • compositions according to the present invention may further comprise a builder system.
  • a builder system Any conventional builder system is suitable for use herein including aluminosilicate materials, silicates, polycarboxylates and fatty acids, materials such as ethylenediamine tetraacetate, metal ion sequestrants such as aminopolyphosphonates, particularly ethylenediamine tetramethylene phosphonic acid and diethylene triamine pentamethylenephosphonic acid.
  • phosphate builders can also be used herein.
  • Suitable builders can be an inorganic ion exchange material, commonly an inorganic hydrated aluminosilicate material, more particularly a hydrated synthetic zeolite such as hydrated zeolite A, X, B or HS.
  • Another suitable inorganic builder material is layered silicate, e.g. SKS-6 (Hoechst).
  • SKS-6 is a crystalline layered silicate consisting of sodium silicate (Na 2 Si 2 0 s ).
  • Suitable polycarboxylates builders for use herein include citric acid, preferably in the form of a water-soluble salt, derivatives of succinic acid of the formula R-CH(COOH)CH2(COOH) wherein R is C10-20 alkyl or alkenyl, preferably C12-16, or wherein R can be substituted with hydroxyl, sulfo sulfoxyl or sulfone substituents.
  • lauryl succinate myristyl succinate, palmityl succinate2-dodecenylsuccinate, 2-tetradecenyl succinate.
  • Succinate builders are preferably used in the form of their water-soluble salts, including sodium, potassium, ammonium and alkanolammonium salts.
  • Other suitable polycarboxylates are oxodisuccinates and mixtures of tartrate monosuccinic and tartrate disuccinic acid such as described in US 4,663,071.
  • suitable fatty acid builders for use herein are saturated or unsaturated C10-18 fatty acids, as well as the corresponding soaps.
  • Preferred saturated species have from 12 to 16 carbon atoms in the alkyl chain.
  • the preferred unsaturated fatty acid is oleic acid.
  • Another preferred builder system for liquid compositions is based on dodecenyl succinic acid.
  • Other suitable water-soluble organic salts are the homo-or co-polymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms. Polymers of this type are disclosed in GB-A-1,596,756. Examples of such salts are polyacrylates of MW 2000-5000 and their copolymers with maleic anhydride, such copolymers having a molecular weight of from 20,000 to 70,000, especially about 40,000.
  • Detergency builder salts are normally included in amounts of from 10% to 80% by weight of the composition preferably from 20% to 70% and most usually from 30% to 60% by weight.
  • detergent compositions may be employed, such enzymes and stabilizers or activators therefore, soil-suspending agents soil-release agents, optical brighteners, abrasives, bactericides, tarnish inhibitors, coloring agents, and perfumes.
  • enzymes and stabilizers or activators therefore, soil-suspending agents soil-release agents, optical brighteners, abrasives, bactericides, tarnish inhibitors, coloring agents, and perfumes.
  • enzyme technologies which also provide a type of color care benefit. Examples are cellulase for color maintenance/ rejuvenation.
  • Other examples are the polymers disclosed in EP 92870017.8 filed January 31,1992 and enzyme oxidation scavengers disclosed in EP 92870018.6 filed January 31, 1992.
  • These components should preferably be chosen such that they are compatible with the bleach component of the composition.
  • liquid compositions according to the present invention can also be in "compact form", i.e. they may have a relatively higher density than conventional liquid detergents, i.e. from 550 to 950 g/I; in such case, the liquid detergent compositions according to the present invention will contain a lower amount of water, compared to conventional liquid detergents.
  • the stability of the brightener and polyamine N-oxide containing polymer incorporated in liquid detergent compositions were compared in the absence and presence of non-aromatic anionic surfactants. More in particular, the stability of polyamine N-oxide polymer/brightener was determined in the absence of ethoxylated surfactant and in the presence of ethoxylated surfactant.
  • the stability was determined by visual inspection of the samples after one month of storage at room temperature/at 35 ° C/50 ° C and at 4 ° C.
  • Liquid detergent compositions according to the present invention containing the brightener/polyamine N-oxide/non-aromatic anionic surfactant system have a translucent appearance.
  • the brightener starts to bind with the polyamine N-oxide containing polymer resulting in a complex, which in turn flocculates and changes the visual appearance of the bulk solution from translucent to transparent.
  • the brightener remains homogeneously dispersed in the liquid, resulting in a translucent liquid even after long periods of storage.
  • Liquid detergent compositions containing the brigh- tener/polyvinylpyrrolidone/non-aromatic anionic surfactant system have a transparent appearance both in the presence or abscense of non-aromatic anionic surfactant.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
EP92870182A 1992-07-15 1992-11-06 Détergents liquides stables inhibant le transfert de couleur Withdrawn EP0596185A1 (fr)

Priority Applications (29)

Application Number Priority Date Filing Date Title
EP92870182A EP0596185A1 (fr) 1992-11-06 1992-11-06 Détergents liquides stables inhibant le transfert de couleur
ES93870106T ES2125967T3 (es) 1992-07-15 1993-06-09 Composiciones que inhiben la transferencia de colorante con contenido en tensioactivo.
DE1993622461 DE69322461T2 (de) 1992-07-15 1993-06-09 Tenside enthaltende Zusammensetzungen zur Verhinderung der Farbstoffübertragung
EP19930870106 EP0587550B1 (fr) 1992-07-15 1993-06-09 Compositions pour éviter le transfert de colorant contenant des agents tensio-actifs
AU45456/93A AU4545693A (en) 1992-07-15 1993-06-30 Surfactant-containing dye transfer inhibiting compositions
CA002140283A CA2140283A1 (fr) 1992-07-15 1993-06-30 Compositions inhibitrices de transfert hydrotypique de colorants, contenant un agent tensio-actif
US08/373,196 US5458809A (en) 1992-07-15 1993-06-30 Surfactant-containing dye transfer inhibiting compositions
PCT/US1993/006223 WO1994002580A1 (fr) 1992-07-15 1993-06-30 Compositions inhibant le transfert de teintures, contenant un agent tensioactif
PH46483A PH30146A (en) 1992-11-06 1993-07-08 Surfactant containing dyf transfer inhibiting compositions
CN 93116768 CN1042647C (zh) 1992-07-15 1993-07-15 包含聚合物分散剂的染料转移抑制组合物
MX9304298A MX191084B (es) 1992-07-15 1993-07-15 Composiciones inhibidoras de trasnferencia de colorante que contienenagente tensioactivo.
CN93116491A CN1040656C (zh) 1992-07-15 1993-07-15 含有表面活性剂的染料转移抑制组合物
AU53592/94A AU5359294A (en) 1992-10-13 1993-10-13 Non-aqueous liquid detergent compositions
PCT/US1993/009799 WO1994009101A1 (fr) 1992-10-13 1993-10-13 Compositions detergentes liquides non aqueuses
EP93870200A EP0593406A1 (fr) 1992-10-13 1993-10-13 Compositions détergentes liquides non aqueuses
US08/416,687 US5571781A (en) 1992-10-13 1993-10-13 Non-aqueous liquid detergent compositions
JP6510247A JPH09509190A (ja) 1992-10-13 1993-10-13 非水性液体洗剤組成物
KR1019950701775A KR950704458A (ko) 1992-11-06 1993-11-03 이염을 억제하는 안정한 액체 세제 조성물(Stable liquid detergent compositions inhibiting dye transfer)
CZ951165A CZ116595A3 (en) 1992-11-06 1993-11-03 Dyestuff-transfer inhibiting stable liquid detergents
PCT/US1993/010542 WO1994011473A1 (fr) 1992-11-06 1993-11-03 Compositions detergentes liquides stables empechant le transfert des couleurs
HU9501296A HUT71963A (en) 1992-11-06 1993-11-03 Stable liquid detergent compositions inhibiting dye transfer
AU55904/94A AU670851B2 (en) 1992-11-06 1993-11-03 Stable liquid detergent compositions inhibiting dye transfer
JP6512172A JPH08503246A (ja) 1992-11-06 1993-11-03 染料移りを防止する安定な液体洗剤組成物
CA002148808A CA2148808C (fr) 1992-11-06 1993-11-03 Compositions liquides detergentes stables, empechant le transfert de colorant
PL93308760A PL175677B1 (pl) 1992-11-06 1993-11-03 Ciekła kompozycja inhibitująca przenoszenie barwnika
CN93112697A CN1041840C (zh) 1992-11-06 1993-11-06 稳定的液体染料转移抑制组合物及含它的洗涤剂组合物
MX9306971A MX9306971A (es) 1992-11-06 1993-11-08 Composiciones detergentes liquidas estables, que inhiben la transferenciade colorante.
TW83100628A TW233309B (en) 1992-07-15 1994-01-25 Surfactant-containing dye transfer inhibiting compositions
US08/777,567 US5783548A (en) 1992-11-06 1996-12-31 Stable liquid detergent compositions inhibiting dye transfer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP92870182A EP0596185A1 (fr) 1992-11-06 1992-11-06 Détergents liquides stables inhibant le transfert de couleur

Publications (1)

Publication Number Publication Date
EP0596185A1 true EP0596185A1 (fr) 1994-05-11

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP92870182A Withdrawn EP0596185A1 (fr) 1992-07-15 1992-11-06 Détergents liquides stables inhibant le transfert de couleur

Country Status (11)

Country Link
EP (1) EP0596185A1 (fr)
JP (1) JPH08503246A (fr)
KR (1) KR950704458A (fr)
CN (1) CN1041840C (fr)
AU (1) AU670851B2 (fr)
CA (1) CA2148808C (fr)
CZ (1) CZ116595A3 (fr)
HU (1) HUT71963A (fr)
MX (1) MX9306971A (fr)
PL (1) PL175677B1 (fr)
WO (1) WO1994011473A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005044965A1 (fr) * 2003-11-10 2005-05-19 Schwarzwälder Marketing Gmbh & Co. Utilisation d'une solution avec au moins un tensioactif non ionique
WO2009019136A1 (fr) * 2007-08-08 2009-02-12 Henkel Ag & Co. Kgaa Produit de lavage ou de nettoyage respectant les couleurs avec agent de blanchiment optique
WO2014146985A1 (fr) * 2013-03-22 2014-09-25 Henkel Ag & Co. Kgaa Détergent ou produit nettoyant protégeant les couleurs contenant un azurant optique
CN105907490A (zh) * 2016-05-17 2016-08-31 河南工程学院 一种酸性护色洗涤剂组合物
US9951298B2 (en) 2014-01-20 2018-04-24 The Procter & Gamble Company Fluorescent brightener premix

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5597795A (en) * 1992-10-27 1997-01-28 The Procter & Gamble Company Detergent compositions inhibiting dye transfer
CN1145093A (zh) * 1994-03-30 1997-03-12 普罗格特-甘布尔公司 具有改进的增白和染料转移抑制效果的洗衣用洗涤剂条
US5804543A (en) * 1994-10-11 1998-09-08 The Procter & Gamble Company Detergent compositions with optimized surfactant systems to provide dye transfer inhibition benefits
ES2163091T3 (es) 1996-01-25 2002-01-16 Unilever Nv Composicion detergente.
JP5396707B2 (ja) * 2007-11-07 2014-01-22 ライオンハイジーン株式会社 洗浄剤組成物
MX2015011690A (es) * 2013-03-05 2015-12-07 Procter & Gamble Composiciones de azucares mezclados.

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EP0135217A1 (fr) * 1983-07-22 1985-03-27 THE PROCTER & GAMBLE COMPANY Oxydes d'amines éthoxylés ayant des propriétés pour enlever des taches et d'antiredéposition, utilisables dans les compositions détergentes
EP0186386A2 (fr) * 1984-12-28 1986-07-02 The Procter & Gamble Company Composition de blanchiment liquide d'hypochlorite contenant des azurants optiques dissous dans de l'amine oxide
EP0314630A2 (fr) * 1987-10-30 1989-05-03 Sandoz Ag Compositions détergentes
EP0350449A2 (fr) * 1988-07-08 1990-01-10 Ciba-Geigy Ag Composition détergente liquide contenant des azurants optiques

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WO2005044965A1 (fr) * 2003-11-10 2005-05-19 Schwarzwälder Marketing Gmbh & Co. Utilisation d'une solution avec au moins un tensioactif non ionique
WO2009019136A1 (fr) * 2007-08-08 2009-02-12 Henkel Ag & Co. Kgaa Produit de lavage ou de nettoyage respectant les couleurs avec agent de blanchiment optique
WO2014146985A1 (fr) * 2013-03-22 2014-09-25 Henkel Ag & Co. Kgaa Détergent ou produit nettoyant protégeant les couleurs contenant un azurant optique
US10457894B2 (en) 2013-03-22 2019-10-29 Henkel Ag & Co. Kgaa Color-protecting detergent or cleaning agent having an optical brightener
US9951298B2 (en) 2014-01-20 2018-04-24 The Procter & Gamble Company Fluorescent brightener premix
CN105907490A (zh) * 2016-05-17 2016-08-31 河南工程学院 一种酸性护色洗涤剂组合物

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PL175677B1 (pl) 1999-01-29
KR950704458A (ko) 1995-11-20
CN1088610A (zh) 1994-06-29
WO1994011473A1 (fr) 1994-05-26
CA2148808A1 (fr) 1994-05-26
JPH08503246A (ja) 1996-04-09
PL308760A1 (en) 1995-08-21
AU670851B2 (en) 1996-08-01
AU5590494A (en) 1994-06-08
CN1041840C (zh) 1999-01-27
HU9501296D0 (en) 1995-06-28
HUT71963A (en) 1996-02-28
CA2148808C (fr) 1999-05-18
CZ116595A3 (en) 1995-12-13
MX9306971A (es) 1995-01-31

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