EP0596185A1 - Stable liquid detergent compositions inhibiting dye transfer - Google Patents
Stable liquid detergent compositions inhibiting dye transfer Download PDFInfo
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- EP0596185A1 EP0596185A1 EP92870182A EP92870182A EP0596185A1 EP 0596185 A1 EP0596185 A1 EP 0596185A1 EP 92870182 A EP92870182 A EP 92870182A EP 92870182 A EP92870182 A EP 92870182A EP 0596185 A1 EP0596185 A1 EP 0596185A1
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- EP
- European Patent Office
- Prior art keywords
- dye transfer
- polyamine
- brightener
- oxide
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0004—Non aqueous liquid compositions comprising insoluble particles
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3792—Amine oxide containing polymers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
Definitions
- the present invention relates to stable liquid detergent compositions inhibiting dye transfer
- Brighteners also known as fluorescent whitening agents, are commonly used in laundry detergents. Brighteners deposit onto fabrics where they absorb ultraviolet radiant energy and reemit it as blue light. This reduces or eliminates any yellowish cast to fabrics and gives them a bright appearance.
- Copending EP Patent Application 92202168.8 describes dye transfer inhibiting compostions comprising polyamine N-oxides containing polymers.
- a dye transfer inhibiting composition comprising a brightener which has improved stability upon storage.
- the present invention relates to inhibiting dye transfer compositions comprising
- compositions of the present invention comprise as essential elements
- polyamine N-oxide polymers contain units having the following structure formula : wherein
- the N-O group can be represented by the following general structures : wherein
- the N-O group can be part of the polymerisable unit (P) or can be attached to the polymeric backbone or a combination of both.
- Suitable polyamine N-oxides wherein the N-O group forms part of the polymerisable unit comprise polyamine N-oxides wherein R is selected from aliphatic, aromatic, alicyclic or heterocyclic groups.
- polyamine N-oxides comprises the group of polyamine N-oxides wherein the nitrogen of the N-O group forms part of the R-group.
- Preferred polyamine N-oxides are those wherein R is a heterocyclic group such as pyrridine, pyrrole, imidazole, pyrrolidine, piperidine and derivatives thereof.
- Another class of said polyamine N-oxides comprises the group of polyamine N-oxides wherein the nitrogen of the N-O group is attached to the R-group.
- polyamine N-oxides are the polyamine oxides whereto the N-O group is attached to the polymerisable unit.
- Preferred class of these polyamine N-oxides are the polyamine N-oxides having the general formula (I) wherein R is an aromatic, heterocyclic or alicyclic groups wherein the nitrogen of the N-0 functional group is part of said R group.
- polyamine N-oxides are the polyamine oxides having the general formula (I) wherein R are aromatic, heterocyclic or alicyclic groups wherein the nitrogen of the N-0 functional group is attached to said R groups.
- polyamine oxides wherein R groups can be aromatic such as phenyl.
- Any polymer backbone can be used as long as the amine oxide polymer formed is water-soluble and has dye transfer inhibiting properties.
- suitable polymeric backbones are polyvinyls, polyalkylenes, polyesters, polyethers, polyamide, polyimides, polyacrylates and mixtures thereof.
- the amine N-oxide polymers of the present invention typically have a ratio of amine to the amine N-oxide of 10 : 1 to 1: 1000000.
- the amount of amine oxide groups present in the polyamine oxide polymer can be varied by appropriate copolymerisation or by appropriate degree of N-oxidation .
- the ratio of amine to amine N-oxide is from 3:1 to 1:1000000.
- the polymers of the present invention actually encompass random or block copolymers where one monomer type is an amine N-oxide and the other monomer type is an N-oxide or not.
- the amine oxide unit of the polyamine N-oxides has a pKa ⁇ 10, preferably pKa ⁇ 7, more preferred PKa ⁇ 6.
- the polyamine oxides can be obtained in almost any degree of polymerisation. The degree of polymerisation is not critical provided the material has the desired water-solubility and dye-suspending power.
- the average molecular weight is within the range of 500 to 1000,000 ; more preferred 1000 to 500,000 ; most preferred 5000 to 100,000.
- the polyamine N-oxides of the present invention are typically present from 0.01 to 10% , more preferably from 0.05 to 1 %, most preferred from 0.05 to 0.5 % by weight of the dye transfer inhibiting composition.
- Preferred brighteners according to the present invention are hydrophobic brighteners which have the general formula: wherein R i , R 2 , R 3 and R 4 represent, selected independently, anilino, cyclohexylamino, piperazino, phenylenediamino, toluenediamino, morpholino, aminophenol, N-2-hydroxyethyl-N-methylamino, N-2-Bis- hydroxyethyl.
- Suitable brightener species include any combination of the possible Ri-4. moieties.
- preferred brightener species are the tetra-anilino, tetra-piperazino, tetra-cyclohexylamino and combinations thereof such as for example the di-anilinodipiperazino; and the dianilino-dicyclohexylamino species.
- a preferred brightener system in the context of this invention contains at least 40% (by reference to the total amount of the detergent brightener) of the specific hydrophobic brightener referred to hereinbefore in combination with a conventional detergent brightener, e.g., a di-sulfonated dianilino, dimorpholino stilbene brightener.
- Non-aromatic anionic surfactants suitable for the present invention are generally disclosed in US-A-3,929,678.
- Classes of non-aromatic anionic surfactants include the classes are :
- anionic surfactants are the sodium and potassium alkylsulfates, especially those obtained by sulfating the higher alcohols (C8-C18 carbon atoms) such as those produced by reducing the glycerides of tallow or coconut oil; in straight chain or branched configuration.
- anionic surfactants suitable for the present invention are the alkyl polyethoxylate sulfates, particulary those in which the alkyl group contains from 10 to 22, preferably from 12 to 18 carbon atoms, and wherein the polyethoxylate chain contains from 1 to 15 ethoxylate moieties.
- anionic surfactants suitable for the present invention include sodium alkyl glyceryl ether sulfonates, especially those ethers of higher alcohols derived from tallow and coconut oil; sodium coconut oil fatty acid monoglyceride sulfonates and sulfates; sodium or potassium salts of alkyl ethylene oxide ether sulfates containing 1 to 10 units of ethylene oxide per molecule and wherein the alkyl group contains from 10 to 20 carbon atoms.
- anionic surfactants are particularly suitable herein, especially mixtures of sulphonate and sulphate surfactants in a weight ratio of from 5:1 to 1:2, preferably from 3:1 to 2:3, more preferably from 3:1 to 1:1.
- Preferred sulphonates include alpha-sulphonated methyl fatty acid esters in which the fatty acid is derived from a C 12 -Cl8 fatty source preferably from a C 16 -C 18 fatty source. In each instance the cation is an alkali metal, preferably sodium.
- Preferred sulphate surfactants are alkyl sulphates having from 12 to 18 carbon atoms in the alkyl radical, optionally in admixture with ethoxy sulphates having from 10 to 20, preferably 10 to 16 carbon atoms in the alkyl radical and an average degree of ethoxylation of 1 to 6.
- alkyl sulphates herein are tallow alkyl sulphate, coconut alkyl sulphate, and C14 -15 alkyl sulphates.
- the cation in each instance is again an alkali metal cation, preferably sodium.
- a liquid detergent composition comprising the dye transfer inhibiting composition mixed with detergent ingredients.
- a wide range of surfactants can be used in the detergent composition of the present invention.
- One class of nonionic surfactants useful in the present invention are condensates of ethylene oxide with a hydrophobic moiety to provide a surfactant having an average hydrophilic-lipophilic balance (HLB) in the range from 8 to 17, preferably from 9.5 to 13.5, more preferably from 10 to 12.5.
- HLB hydrophilic-lipophilic balance
- the hydrophobic (lipophilic) moiety may be aliphatic or aromatic in nature and the length of the polyoxyethylene group which is condensed with any particular hydrophobic group can be readily adjusted to yield a water-soluble compound having the desired degree of balance between hydrophilic and hydrophobic elements.
- Especially preferred nonionic surfactants of this type are the C 9 -C 15 primary alcohol ethoxylates containing 3-8 moles of ethylene oxide per mole of alcohol, particularly the C14-C15 primary alcohols containing 6-8 moles of ethylene oxide per mole of alcohol and the C 12 -C14 primary alcohols containing 3-5 moles of ethylene oxide per mole of alcohol.
- Nonionic surfactants comprises alkyl polyglucoside compounds of general formula wherein Z is a moiety derived from glucose; R is a saturated hydrophobic alkyl group that contains from 12 to 18 carbon atoms; t is from 0 to 10 and n is 2 or 3; x is from 1.3 to 4, the compounds including less than 10% unreacted fatty alcohol and less than 50% short chain alkyl polyglucosides.
- Z is a moiety derived from glucose
- R is a saturated hydrophobic alkyl group that contains from 12 to 18 carbon atoms
- t is from 0 to 10 and n is 2 or 3
- x is from 1.3 to 4, the compounds including less than 10% unreacted fatty alcohol and less than 50% short chain alkyl polyglucosides.
- Compounds of this type and their use in detergent are disclosed in EP-B 0 070 077, 0 075 996 and 0 094 118.
- nonionic surfactants are poly hydroxy fatty acid amide surfactants of the formula wherein R 1 is H, or R 1 is C 1 - 4 hydrocarbyl, 2-hydroxy ethyl, 2-hydroxy propyl or a mixture thereof, R 2 is C s - 31 hydrocarbyl, and Z is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative thereof.
- R 1 is methyl
- R 2 is a straight C11 1 - 15 alkyl or alkenyl chain such as coconut alkyl or mixtures thereof
- Z is derived from a reducing sugar such as glucose, fructose, maltose, lactose, in a reductive amination reaction.
- compositions according to the present invention may further comprise a builder system.
- a builder system Any conventional builder system is suitable for use herein including aluminosilicate materials, silicates, polycarboxylates and fatty acids, materials such as ethylenediamine tetraacetate, metal ion sequestrants such as aminopolyphosphonates, particularly ethylenediamine tetramethylene phosphonic acid and diethylene triamine pentamethylenephosphonic acid.
- phosphate builders can also be used herein.
- Suitable builders can be an inorganic ion exchange material, commonly an inorganic hydrated aluminosilicate material, more particularly a hydrated synthetic zeolite such as hydrated zeolite A, X, B or HS.
- Another suitable inorganic builder material is layered silicate, e.g. SKS-6 (Hoechst).
- SKS-6 is a crystalline layered silicate consisting of sodium silicate (Na 2 Si 2 0 s ).
- Suitable polycarboxylates builders for use herein include citric acid, preferably in the form of a water-soluble salt, derivatives of succinic acid of the formula R-CH(COOH)CH2(COOH) wherein R is C10-20 alkyl or alkenyl, preferably C12-16, or wherein R can be substituted with hydroxyl, sulfo sulfoxyl or sulfone substituents.
- lauryl succinate myristyl succinate, palmityl succinate2-dodecenylsuccinate, 2-tetradecenyl succinate.
- Succinate builders are preferably used in the form of their water-soluble salts, including sodium, potassium, ammonium and alkanolammonium salts.
- Other suitable polycarboxylates are oxodisuccinates and mixtures of tartrate monosuccinic and tartrate disuccinic acid such as described in US 4,663,071.
- suitable fatty acid builders for use herein are saturated or unsaturated C10-18 fatty acids, as well as the corresponding soaps.
- Preferred saturated species have from 12 to 16 carbon atoms in the alkyl chain.
- the preferred unsaturated fatty acid is oleic acid.
- Another preferred builder system for liquid compositions is based on dodecenyl succinic acid.
- Other suitable water-soluble organic salts are the homo-or co-polymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms. Polymers of this type are disclosed in GB-A-1,596,756. Examples of such salts are polyacrylates of MW 2000-5000 and their copolymers with maleic anhydride, such copolymers having a molecular weight of from 20,000 to 70,000, especially about 40,000.
- Detergency builder salts are normally included in amounts of from 10% to 80% by weight of the composition preferably from 20% to 70% and most usually from 30% to 60% by weight.
- detergent compositions may be employed, such enzymes and stabilizers or activators therefore, soil-suspending agents soil-release agents, optical brighteners, abrasives, bactericides, tarnish inhibitors, coloring agents, and perfumes.
- enzymes and stabilizers or activators therefore, soil-suspending agents soil-release agents, optical brighteners, abrasives, bactericides, tarnish inhibitors, coloring agents, and perfumes.
- enzyme technologies which also provide a type of color care benefit. Examples are cellulase for color maintenance/ rejuvenation.
- Other examples are the polymers disclosed in EP 92870017.8 filed January 31,1992 and enzyme oxidation scavengers disclosed in EP 92870018.6 filed January 31, 1992.
- These components should preferably be chosen such that they are compatible with the bleach component of the composition.
- liquid compositions according to the present invention can also be in "compact form", i.e. they may have a relatively higher density than conventional liquid detergents, i.e. from 550 to 950 g/I; in such case, the liquid detergent compositions according to the present invention will contain a lower amount of water, compared to conventional liquid detergents.
- the stability of the brightener and polyamine N-oxide containing polymer incorporated in liquid detergent compositions were compared in the absence and presence of non-aromatic anionic surfactants. More in particular, the stability of polyamine N-oxide polymer/brightener was determined in the absence of ethoxylated surfactant and in the presence of ethoxylated surfactant.
- the stability was determined by visual inspection of the samples after one month of storage at room temperature/at 35 ° C/50 ° C and at 4 ° C.
- Liquid detergent compositions according to the present invention containing the brightener/polyamine N-oxide/non-aromatic anionic surfactant system have a translucent appearance.
- the brightener starts to bind with the polyamine N-oxide containing polymer resulting in a complex, which in turn flocculates and changes the visual appearance of the bulk solution from translucent to transparent.
- the brightener remains homogeneously dispersed in the liquid, resulting in a translucent liquid even after long periods of storage.
- Liquid detergent compositions containing the brigh- tener/polyvinylpyrrolidone/non-aromatic anionic surfactant system have a transparent appearance both in the presence or abscense of non-aromatic anionic surfactant.
Abstract
The present invention relates to inhibiting dye transfer compositions comprising
- (a) from 0.01 % to 5% of a polyamine N-oxide polymer
- (b) from 0.01 % to 1% of a brightener
- (c) from 5% to 30% of a non-aromatic anionic surfactant
Description
- The present invention relates to stable liquid detergent compositions inhibiting dye transfer
- Optical brighteners, also known as fluorescent whitening agents, are commonly used in laundry detergents. Brighteners deposit onto fabrics where they absorb ultraviolet radiant energy and reemit it as blue light. This reduces or eliminates any yellowish cast to fabrics and gives them a bright appearance. However, it has been found to be difficult to create and maintain the brightener dispersed in liquid detergent compositions containing polymers which exhibit dye transfer inhibiting properties. These polymers are used to complex or absorb the fugitive dyes washed out of dyed fabrics before they have the opportunity to become attached to other articles in the wash.
- Such polymers that have been used within detergent compositions to inhibit dye transfer are disclosed in EP-A-O 102 923, DE-A-2 814 329, FR-A-2 144 721 and EP-265 257.
- Copending EP Patent Application 92202168.8 describes dye transfer inhibiting compostions comprising polyamine N-oxides containing polymers.
- Surprisingly, it has now been found that improved storage stability of liquid detergent compositions comprising polyamine N-oxide containing polymers and brightener can be achieved by adding non-aromatic anionic surfactants.
- According to the present invention, a dye transfer inhibiting composition comprising a brightener is provided which has improved stability upon storage.
- The present invention relates to inhibiting dye transfer compositions comprising
- (a) from 0.01 % to 5% of a polyamine N-oxide containing polymer
- (b) from 0.01 % to 1% of a brightener
- (c) from 5% to 30% of a non-aromatic anionic surfactant
- The compositions of the present invention comprise as essential elements
- (a) from 0.01 % to 5% of a polyamine N-oxide polymer
- (b) from 0.01 % to 1% of a brightener
- (c) from 5% to 30% of a non-aromatic anionic surfactant
-
- P is a polymerisable unit, whereto the N-O group can be attached to or wherein the N-O group forms part of the polymerisable unit or a combination of both.
- A is
- x is or 0 or 1;
- R are aliphatic, ethoxylated aliphatics, aromatic, heterocyclic or alicyclic groups or any combination thereof whereto the nitrogen of the N-O group can be attached or wherein the nitrogen of the N-O group is part of these groups.
-
- R1, R2, R3 are aliphatic groups, aromatic, heterocyclic or alicyclic groups or combinations thereof, x or/and y or/and z is 0 or 1 and wherein the nitrogen of the N-O group can be attached or wherein the nitrogen of the N-O group forms part of these groups.
- The N-O group can be part of the polymerisable unit (P) or can be attached to the polymeric backbone or a combination of both.
- Suitable polyamine N-oxides wherein the N-O group forms part of the polymerisable unit comprise polyamine N-oxides wherein R is selected from aliphatic, aromatic, alicyclic or heterocyclic groups.
- One class of said polyamine N-oxides comprises the group of polyamine N-oxides wherein the nitrogen of the N-O group forms part of the R-group. Preferred polyamine N-oxides are those wherein R is a heterocyclic group such as pyrridine, pyrrole, imidazole, pyrrolidine, piperidine and derivatives thereof. Another class of said polyamine N-oxides comprises the group of polyamine N-oxides wherein the nitrogen of the N-O group is attached to the R-group.
- Other suitable polyamine N-oxides are the polyamine oxides whereto the N-O group is attached to the polymerisable unit.
- Preferred class of these polyamine N-oxides are the polyamine N-oxides having the general formula (I) wherein R is an aromatic, heterocyclic or alicyclic groups wherein the nitrogen of the N-0 functional group is part of said R group.
- Examples of these classes are polyamine oxides wherein R is a heterocyclic compound such as pyrridine, pyrrole, imidazole and derivatives thereof.
- Another preferred class of polyamine N-oxides are the polyamine oxides having the general formula (I) wherein R are aromatic, heterocyclic or alicyclic groups wherein the nitrogen of the N-0 functional group is attached to said R groups.
- Examples of these classes are polyamine oxides wherein R groups can be aromatic such as phenyl.
- Any polymer backbone can be used as long as the amine oxide polymer formed is water-soluble and has dye transfer inhibiting properties. Examples of suitable polymeric backbones are polyvinyls, polyalkylenes, polyesters, polyethers, polyamide, polyimides, polyacrylates and mixtures thereof.
- The amine N-oxide polymers of the present invention typically have a ratio of amine to the amine N-oxide of 10 : 1 to 1: 1000000. However the amount of amine oxide groups present in the polyamine oxide polymer can be varied by appropriate copolymerisation or by appropriate degree of N-oxidation . Preferably, the ratio of amine to amine N-oxide is from 3:1 to 1:1000000. The polymers of the present invention actually encompass random or block copolymers where one monomer type is an amine N-oxide and the other monomer type is an N-oxide or not.
- The amine oxide unit of the polyamine N-oxides has a pKa < 10, preferably pKa < 7, more preferred PKa < 6. The polyamine oxides can be obtained in almost any degree of polymerisation. The degree of polymerisation is not critical provided the material has the desired water-solubility and dye-suspending power.
- Typically, the average molecular weight is within the range of 500 to 1000,000 ; more preferred 1000 to 500,000 ; most preferred 5000 to 100,000.
- The polyamine N-oxides of the present invention are typically present from 0.01 to 10% , more preferably from 0.05 to 1 %, most preferred from 0.05 to 0.5 % by weight of the dye transfer inhibiting composition.
- Preferred brighteners according to the present invention are hydrophobic brighteners which have the general formula:
wherein Ri, R2, R3 and R4 represent, selected independently, anilino, cyclohexylamino, piperazino, phenylenediamino, toluenediamino, morpholino, aminophenol, N-2-hydroxyethyl-N-methylamino, N-2-Bis- hydroxyethyl. - Suitable brightener species include any combination of the possible Ri-4. moieties. Examples of preferred brightener species are the tetra-anilino, tetra-piperazino, tetra-cyclohexylamino and combinations thereof such as for example the di-anilinodipiperazino; and the dianilino-dicyclohexylamino species.
- Highly preferred for reasons of minimizing brightener staining are the tetraanilino derivatives, having the following formula : 4,4' -bis (4-anilino-6-anilino-s-triazin-2-yl)amino)-2,2'- stilbe ne disulfonic acid sodium salt (A). A preferred brightener system in the context of this invention contains at least 40% (by reference to the total amount of the detergent brightener) of the specific hydrophobic brightener referred to hereinbefore in combination with a conventional detergent brightener, e.g., a di-sulfonated dianilino, dimorpholino stilbene brightener.
- Conventional detergent brighteners for use in combination with the hydrophobic species described hereinabove embrace common detergent brighteners inclusives of:
- 4,4(2H-naphtho(1,2-d)triazol-2-yl)-2-stilbenesulfonic acid, sodium salt; (i)
- 4,41-bis((4-anilino-6(N-2-hydroxyethyl-N-methylamino)-s-triazin-2-yl)amino)-2,21-stilbenedisulfonic acid disodium salt; (ii)
- 4,41-bis((4-anilino-6-morpholino-s-triazine-2-yl)amino)-2,21-stilbenedisulfonic acid, sodium salt; (iii)
- 2,2-(4,41-biphenylene divinylene)-dibenzenesulfonic acid, disodium salt; (ivi)
- 4,41-bis(4-phenyl-2H-1,2,3-triazol-2-yl) disodium salt (vi)
- 4,41-bis(4-anilino-6-morpholino-1 ,3,5-triazin-2-yl)amino)-2-stilbene sulfonate sodium salt. (vii)
- Non-aromatic anionic surfactants suitable for the present invention are generally disclosed in US-A-3,929,678.
- Classes of non-aromatic anionic surfactants include the classes are :
- 1. Ordinary alkali metal soaps such as the sodium, potassium, ammonium and alkylolammonium salts of higher fatty acids containing from 8 to 24 carbon atoms, preferably from 10 to 20 carbon atoms.
- 2. Water-soluble salts, preferably the alkali metal, ammonium and alkylolammonium salts, of organic sulfuric reaction products having in their molecular structure an alkyl group containing from 10 to 20 carbon atoms and a sulfonic acid or sulfuric acid ester group.
- Examples of this group of anionic surfactants are the sodium and potassium alkylsulfates, especially those obtained by sulfating the higher alcohols (C8-C18 carbon atoms) such as those produced by reducing the glycerides of tallow or coconut oil; in straight chain or branched configuration.
- Other anionic surfactants suitable for the present invention are the alkyl polyethoxylate sulfates, particulary those in which the alkyl group contains from 10 to 22, preferably from 12 to 18 carbon atoms, and wherein the polyethoxylate chain contains from 1 to 15 ethoxylate moieties.
- Other anionic surfactants suitable for the present invention include sodium alkyl glyceryl ether sulfonates, especially those ethers of higher alcohols derived from tallow and coconut oil; sodium coconut oil fatty acid monoglyceride sulfonates and sulfates; sodium or potassium salts of alkyl ethylene oxide ether sulfates containing 1 to 10 units of ethylene oxide per molecule and wherein the alkyl group contains from 10 to 20 carbon atoms.
- Mixtures of anionic surfactants are particularly suitable herein, especially mixtures of sulphonate and sulphate surfactants in a weight ratio of from 5:1 to 1:2, preferably from 3:1 to 2:3, more preferably from 3:1 to 1:1. Preferred sulphonates include alpha-sulphonated methyl fatty acid esters in which the fatty acid is derived from a C12-Cl8 fatty source preferably from a C16-C18 fatty source. In each instance the cation is an alkali metal, preferably sodium. Preferred sulphate surfactants are alkyl sulphates having from 12 to 18 carbon atoms in the alkyl radical, optionally in admixture with ethoxy sulphates having from 10 to 20, preferably 10 to 16 carbon atoms in the alkyl radical and an average degree of ethoxylation of 1 to 6. Examples of preferred alkyl sulphates herein are tallow alkyl sulphate, coconut alkyl sulphate, and C14 -15 alkyl sulphates. The cation in each instance is again an alkali metal cation, preferably sodium.
- In another embodiment of the present invention, a liquid detergent composition is provided comprising the dye transfer inhibiting composition mixed with detergent ingredients. A wide range of surfactants can be used in the detergent composition of the present invention.
- A typical listing of anionic, nonionic, ampholytic and switterionic classes, and species of these surfactants, is given in US Patent 3,664,961 issued to Norris on May 23, 1972.
- One class of nonionic surfactants useful in the present invention are condensates of ethylene oxide with a hydrophobic moiety to provide a surfactant having an average hydrophilic-lipophilic balance (HLB) in the range from 8 to 17, preferably from 9.5 to 13.5, more preferably from 10 to 12.5. The hydrophobic (lipophilic) moiety may be aliphatic or aromatic in nature and the length of the polyoxyethylene group which is condensed with any particular hydrophobic group can be readily adjusted to yield a water-soluble compound having the desired degree of balance between hydrophilic and hydrophobic elements.
- Especially preferred nonionic surfactants of this type are the C9-C15 primary alcohol ethoxylates containing 3-8 moles of ethylene oxide per mole of alcohol, particularly the C14-C15 primary alcohols containing 6-8 moles of ethylene oxide per mole of alcohol and the C12-C14 primary alcohols containing 3-5 moles of ethylene oxide per mole of alcohol.
- Another class of nonionic surfactants comprises alkyl polyglucoside compounds of general formula
wherein Z is a moiety derived from glucose; R is a saturated hydrophobic alkyl group that contains from 12 to 18 carbon atoms; t is from 0 to 10 and n is 2 or 3; x is from 1.3 to 4, the compounds including less than 10% unreacted fatty alcohol and less than 50% short chain alkyl polyglucosides. Compounds of this type and their use in detergent are disclosed in EP-B 0 070 077, 0 075 996 and 0 094 118. - Also suitable as nonionic surfactants are poly hydroxy fatty acid amide surfactants of the formula
wherein R1 is H, or R1 is C1 -4 hydrocarbyl, 2-hydroxy ethyl, 2-hydroxy propyl or a mixture thereof, R2 is Cs-31 hydrocarbyl, and Z is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative thereof. Preferably, R1 is methyl, R2 is a straight C11 1 -15 alkyl or alkenyl chain such as coconut alkyl or mixtures thereof, and Z is derived from a reducing sugar such as glucose, fructose, maltose, lactose, in a reductive amination reaction. - The compositions according to the present invention may further comprise a builder system. Any conventional builder system is suitable for use herein including aluminosilicate materials, silicates, polycarboxylates and fatty acids, materials such as ethylenediamine tetraacetate, metal ion sequestrants such as aminopolyphosphonates, particularly ethylenediamine tetramethylene phosphonic acid and diethylene triamine pentamethylenephosphonic acid. Though less preferred for obvious environmental reasons, phosphate builders can also be used herein.
- Suitable builders can be an inorganic ion exchange material, commonly an inorganic hydrated aluminosilicate material, more particularly a hydrated synthetic zeolite such as hydrated zeolite A, X, B or HS. Another suitable inorganic builder material is layered silicate, e.g. SKS-6 (Hoechst). SKS-6 is a crystalline layered silicate consisting of sodium silicate (Na2Si20s). Suitable polycarboxylates builders for use herein include citric acid, preferably in the form of a water-soluble salt, derivatives of succinic acid of the formula R-CH(COOH)CH2(COOH) wherein R is C10-20 alkyl or alkenyl, preferably C12-16, or wherein R can be substituted with hydroxyl, sulfo sulfoxyl or sulfone substituents.
- Specific examples include lauryl succinate , myristyl succinate, palmityl succinate2-dodecenylsuccinate, 2-tetradecenyl succinate. Succinate builders are preferably used in the form of their water-soluble salts, including sodium, potassium, ammonium and alkanolammonium salts. Other suitable polycarboxylates are oxodisuccinates and mixtures of tartrate monosuccinic and tartrate disuccinic acid such as described in US 4,663,071.
- Especially for the liquid execution herein, suitable fatty acid builders for use herein are saturated or unsaturated C10-18 fatty acids, as well as the corresponding soaps. Preferred saturated species have from 12 to 16 carbon atoms in the alkyl chain. The preferred unsaturated fatty acid is oleic acid. Another preferred builder system for liquid compositions is based on dodecenyl succinic acid. Other suitable water-soluble organic salts are the homo-or co-polymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms. Polymers of this type are disclosed in GB-A-1,596,756. Examples of such salts are polyacrylates of MW 2000-5000 and their copolymers with maleic anhydride, such copolymers having a molecular weight of from 20,000 to 70,000, especially about 40,000.
- Detergency builder salts are normally included in amounts of from 10% to 80% by weight of the composition preferably from 20% to 70% and most usually from 30% to 60% by weight.
- Other components used in detergent compositions may be employed, such enzymes and stabilizers or activators therefore, soil-suspending agents soil-release agents, optical brighteners, abrasives, bactericides, tarnish inhibitors, coloring agents, and perfumes. Especially preferred are combinations with enzyme technologies which also provide a type of color care benefit. Examples are cellulase for color maintenance/ rejuvenation. Other examples are the polymers disclosed in EP 92870017.8 filed January 31,1992 and enzyme oxidation scavengers disclosed in EP 92870018.6 filed January 31, 1992.
- Also particulary suitable are amine base catlyst stabilizers disclosed in EP 92870019.4 filed January 31, 1992.
- These components, particularly the enzymes, optical brighteners, coloring agents, and perfumes, should preferably be chosen such that they are compatible with the bleach component of the composition.
- The liquid compositions according to the present invention can also be in "compact form", i.e. they may have a relatively higher density than conventional liquid detergents, i.e. from 550 to 950 g/I; in such case, the liquid detergent compositions according to the present invention will contain a lower amount of water, compared to conventional liquid detergents.
- The following examples are meant to exemplify compositions of the present inventions, but are not necessarily meant to limit the scope of the invention.
- To assess the stabilizing effect of the non-aromatic anionic surfactants , the stability of the brightener and polyamine N-oxide containing polymer incorporated in liquid detergent compositions were compared in the absence and presence of non-aromatic anionic surfactants. More in particular, the stability of polyamine N-oxide polymer/brightener was determined in the absence of ethoxylated surfactant and in the presence of ethoxylated surfactant.
- Similar measurements were made for samples wherein the polyamine N-oxide was replaced by another dye transfer inhibiting polymer known in the art e.g polyvinylpyrrolidone.
- The stability was determined by visual inspection of the samples after one month of storage at room temperature/at 35 ° C/50 ° C and at 4 ° C.
-
- Liquid detergent compositions according to the present invention, containing the brightener/polyamine N-oxide/non-aromatic anionic surfactant system have a translucent appearance.
- In the abscence of non-aromatic anionic surfactants, the brightener starts to bind with the polyamine N-oxide containing polymer resulting in a complex, which in turn flocculates and changes the visual appearance of the bulk solution from translucent to transparent. In the presence of non-aromatic anionic surfactant the brightener remains homogeneously dispersed in the liquid, resulting in a translucent liquid even after long periods of storage. Liquid detergent compositions containing the brigh- tener/polyvinylpyrrolidone/non-aromatic anionic surfactant system have a transparent appearance both in the presence or abscense of non-aromatic anionic surfactant.
Claims (6)
1. A liquid dye transfer inhibiting composition comprising
(a) from 0.01 % to 5% of a polyamine N-oxide containing polymer
(b) from 0.01 % to 1% of a brightener
(c) from 5% to 30% of a non-aromatic anionic surfactant
2. A dye transfer inhibiting composition according to claim 1 wherein the brightener is a hydrophobic brightener.
3. A dye transfer inhibiting composition according to claim 1-2 wherein the non-aromatic anionic surfactant is an ethoxylated surfactant.
4. A dye transfer inhibiting composition according to claim 1-3 wherein the polyamine N-oxide is polyvinylpyridine N-oxide.
5. A dye transfer inhibiting composition according to claims 1-4 which is a detergent additive, in the form of a liquid.
6. A detergent composition which comprises a dye transfer inhibiting composition according to claims 1-5 further comprising surfactants, builders, enzymes and other conventional detergent ingredients.
Priority Applications (29)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP92870182A EP0596185A1 (en) | 1992-11-06 | 1992-11-06 | Stable liquid detergent compositions inhibiting dye transfer |
DE1993622461 DE69322461T2 (en) | 1992-07-15 | 1993-06-09 | Compositions containing surfactants to prevent dye transfer |
EP19930870106 EP0587550B1 (en) | 1992-07-15 | 1993-06-09 | Surfactant containing dye transfer inhibiting compositions |
ES93870106T ES2125967T3 (en) | 1992-07-15 | 1993-06-09 | COMPOSITIONS INHIBITING THE TRANSFER OF DYE WITH SURFACE CONTENT. |
US08/373,196 US5458809A (en) | 1992-07-15 | 1993-06-30 | Surfactant-containing dye transfer inhibiting compositions |
AU45456/93A AU4545693A (en) | 1992-07-15 | 1993-06-30 | Surfactant-containing dye transfer inhibiting compositions |
CA002140283A CA2140283A1 (en) | 1992-07-15 | 1993-06-30 | Surfactant-containing dye transfer inhibiting compositions |
PCT/US1993/006223 WO1994002580A1 (en) | 1992-07-15 | 1993-06-30 | Surfactant-containing dye transfer inhibiting compositions |
PH46483A PH30146A (en) | 1992-11-06 | 1993-07-08 | Surfactant containing dyf transfer inhibiting compositions |
CN93116491A CN1040656C (en) | 1992-07-15 | 1993-07-15 | Surfactant-containing dye transfer inhibiting compositions |
CN 93116768 CN1042647C (en) | 1992-07-15 | 1993-07-15 | Dye transfer inhibiting compositions comprising polymeric dispersing agents |
MX9304298A MX191084B (en) | 1992-07-15 | 1993-07-15 | DYE TRANSFER INHIBITOR COMPOSITIONS CONTAINING SURGICAL CONTAINER. |
PCT/US1993/009799 WO1994009101A1 (en) | 1992-10-13 | 1993-10-13 | Non-aqueous liquid detergent compositions |
AU53592/94A AU5359294A (en) | 1992-10-13 | 1993-10-13 | Non-aqueous liquid detergent compositions |
EP93870200A EP0593406A1 (en) | 1992-10-13 | 1993-10-13 | Non-aqueous liquid detergent compositions |
JP6510247A JPH09509190A (en) | 1992-10-13 | 1993-10-13 | Non-aqueous liquid detergent composition |
US08/416,687 US5571781A (en) | 1992-10-13 | 1993-10-13 | Non-aqueous liquid detergent compositions |
CZ951165A CZ116595A3 (en) | 1992-11-06 | 1993-11-03 | Dyestuff-transfer inhibiting stable liquid detergents |
PL93308760A PL175677B1 (en) | 1992-11-06 | 1993-11-03 | Stable detergents inhibiting dye transfer |
JP6512172A JPH08503246A (en) | 1992-11-06 | 1993-11-03 | Stable liquid detergent composition that prevents dye transfer |
HU9501296A HUT71963A (en) | 1992-11-06 | 1993-11-03 | Stable liquid detergent compositions inhibiting dye transfer |
CA002148808A CA2148808C (en) | 1992-11-06 | 1993-11-03 | Stable liquid detergent compositions inhibiting dye transfer |
AU55904/94A AU670851B2 (en) | 1992-11-06 | 1993-11-03 | Stable liquid detergent compositions inhibiting dye transfer |
PCT/US1993/010542 WO1994011473A1 (en) | 1992-11-06 | 1993-11-03 | Stable liquid detergent compositions inhibiting dye transfer |
KR1019950701775A KR950704458A (en) | 1992-11-06 | 1993-11-03 | Stable liquid detergent compositions inhibiting dye transfer |
CN93112697A CN1041840C (en) | 1992-11-06 | 1993-11-06 | Stable liquid detergent compositions inhibiting dye transfer |
MX9306971A MX9306971A (en) | 1992-11-06 | 1993-11-08 | STABLE LIQUID DETERGENT COMPOSITIONS, INHIBITING THE COLORING TRANSFER. |
TW83100628A TW233309B (en) | 1992-07-15 | 1994-01-25 | Surfactant-containing dye transfer inhibiting compositions |
US08/777,567 US5783548A (en) | 1992-11-06 | 1996-12-31 | Stable liquid detergent compositions inhibiting dye transfer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP92870182A EP0596185A1 (en) | 1992-11-06 | 1992-11-06 | Stable liquid detergent compositions inhibiting dye transfer |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0596185A1 true EP0596185A1 (en) | 1994-05-11 |
Family
ID=8212282
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92870182A Withdrawn EP0596185A1 (en) | 1992-07-15 | 1992-11-06 | Stable liquid detergent compositions inhibiting dye transfer |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP0596185A1 (en) |
JP (1) | JPH08503246A (en) |
KR (1) | KR950704458A (en) |
CN (1) | CN1041840C (en) |
AU (1) | AU670851B2 (en) |
CA (1) | CA2148808C (en) |
CZ (1) | CZ116595A3 (en) |
HU (1) | HUT71963A (en) |
MX (1) | MX9306971A (en) |
PL (1) | PL175677B1 (en) |
WO (1) | WO1994011473A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005044965A1 (en) * | 2003-11-10 | 2005-05-19 | Schwarzwälder Marketing Gmbh & Co. | Use of a solution comprising at least one nonionic surfactant |
WO2009019136A1 (en) * | 2007-08-08 | 2009-02-12 | Henkel Ag & Co. Kgaa | Color-safe detergent or cleaning agent having optical brightener |
WO2014146985A1 (en) * | 2013-03-22 | 2014-09-25 | Henkel Ag & Co. Kgaa | Color-protecting detergent or cleaning agent having an optical brightener |
CN105907490A (en) * | 2016-05-17 | 2016-08-31 | 河南工程学院 | Acidic colour-protecting detergent composition |
US9951298B2 (en) | 2014-01-20 | 2018-04-24 | The Procter & Gamble Company | Fluorescent brightener premix |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5597795A (en) * | 1992-10-27 | 1997-01-28 | The Procter & Gamble Company | Detergent compositions inhibiting dye transfer |
WO1995027038A1 (en) * | 1994-03-30 | 1995-10-12 | The Procter & Gamble Company | Laundry detergent bars with improved whitening and dye transfer inhibition |
US5804543A (en) * | 1994-10-11 | 1998-09-08 | The Procter & Gamble Company | Detergent compositions with optimized surfactant systems to provide dye transfer inhibition benefits |
ES2163091T3 (en) | 1996-01-25 | 2002-01-16 | Unilever Nv | DETERGENT COMPOSITION. |
JP5396707B2 (en) * | 2007-11-07 | 2014-01-22 | ライオンハイジーン株式会社 | Cleaning composition |
MX2015011690A (en) * | 2013-03-05 | 2015-12-07 | Procter & Gamble | Mixed sugar compositions. |
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-
1992
- 1992-11-06 EP EP92870182A patent/EP0596185A1/en not_active Withdrawn
-
1993
- 1993-11-03 PL PL93308760A patent/PL175677B1/en unknown
- 1993-11-03 CZ CZ951165A patent/CZ116595A3/en unknown
- 1993-11-03 JP JP6512172A patent/JPH08503246A/en active Pending
- 1993-11-03 CA CA002148808A patent/CA2148808C/en not_active Expired - Fee Related
- 1993-11-03 AU AU55904/94A patent/AU670851B2/en not_active Ceased
- 1993-11-03 HU HU9501296A patent/HUT71963A/en unknown
- 1993-11-03 WO PCT/US1993/010542 patent/WO1994011473A1/en not_active Application Discontinuation
- 1993-11-03 KR KR1019950701775A patent/KR950704458A/en not_active Application Discontinuation
- 1993-11-06 CN CN93112697A patent/CN1041840C/en not_active Expired - Fee Related
- 1993-11-08 MX MX9306971A patent/MX9306971A/en not_active IP Right Cessation
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WO2005044965A1 (en) * | 2003-11-10 | 2005-05-19 | Schwarzwälder Marketing Gmbh & Co. | Use of a solution comprising at least one nonionic surfactant |
WO2009019136A1 (en) * | 2007-08-08 | 2009-02-12 | Henkel Ag & Co. Kgaa | Color-safe detergent or cleaning agent having optical brightener |
WO2014146985A1 (en) * | 2013-03-22 | 2014-09-25 | Henkel Ag & Co. Kgaa | Color-protecting detergent or cleaning agent having an optical brightener |
US10457894B2 (en) | 2013-03-22 | 2019-10-29 | Henkel Ag & Co. Kgaa | Color-protecting detergent or cleaning agent having an optical brightener |
US9951298B2 (en) | 2014-01-20 | 2018-04-24 | The Procter & Gamble Company | Fluorescent brightener premix |
CN105907490A (en) * | 2016-05-17 | 2016-08-31 | 河南工程学院 | Acidic colour-protecting detergent composition |
Also Published As
Publication number | Publication date |
---|---|
CA2148808C (en) | 1999-05-18 |
CA2148808A1 (en) | 1994-05-26 |
AU5590494A (en) | 1994-06-08 |
HUT71963A (en) | 1996-02-28 |
WO1994011473A1 (en) | 1994-05-26 |
PL308760A1 (en) | 1995-08-21 |
PL175677B1 (en) | 1999-01-29 |
CN1041840C (en) | 1999-01-27 |
MX9306971A (en) | 1995-01-31 |
AU670851B2 (en) | 1996-08-01 |
CN1088610A (en) | 1994-06-29 |
CZ116595A3 (en) | 1995-12-13 |
HU9501296D0 (en) | 1995-06-28 |
KR950704458A (en) | 1995-11-20 |
JPH08503246A (en) | 1996-04-09 |
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