EP0586436A1 - Kationische, modifizierte schichtverbindungen - Google Patents

Kationische, modifizierte schichtverbindungen

Info

Publication number
EP0586436A1
EP0586436A1 EP92910385A EP92910385A EP0586436A1 EP 0586436 A1 EP0586436 A1 EP 0586436A1 EP 92910385 A EP92910385 A EP 92910385A EP 92910385 A EP92910385 A EP 92910385A EP 0586436 A1 EP0586436 A1 EP 0586436A1
Authority
EP
European Patent Office
Prior art keywords
carbon atoms
groups
cationic layer
layer compounds
additives
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP92910385A
Other languages
German (de)
English (en)
French (fr)
Inventor
Helmut Endres
Frido Löffelholz
Peter Wedl
Kurt Worschech
Angela Hansen
Günther GEISMAR
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0586436A1 publication Critical patent/EP0586436A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances

Definitions

  • the invention relates to special cationic layer compounds with a BET specific surface area of at least 50 m *** 7 g, which are modified with polyols, epoxidized esters, full and partial esters of polyols and / or phosphites, processes for producing the same and their use as co-stabilizers for halogen-containing plastics stabilized with calcium and / or zinc salts.
  • Halogen-containing plastics or molding compositions made from them are known to tend to degrade or decompose under heat conditions or when exposed to ultraviolet light.
  • heavy metal compounds based on lead, tin, barium and / or cadmium are conventionally used. From a work physiological point of view, however, there is a need to exchange these very effective stabilizers for less harmful substances.
  • the heavy metal compounds for example calcium and zinc soaps can be used as stabilizers, but they do not achieve the performance of the heavy metal compounds, so that co-stabilizers are required to increase their stabilizing effect.
  • German patent DE-C-30 19632 describes the use of hydrotalcites for inhibiting the thermal or ultraviolet degradation of halogen-containing thermoplastic resins.
  • German patent DE-C-30 19 632 proposes hydrotalcites with a large crystal grain and with a BET specific surface area of not more than 30 m 2 / g, which may be coated with an anionic surface-active agent such as sodium stearate can use.
  • European patent application EP-A-189899 also describes resin compositions which contain hydrotalcites with BET specific surface areas of less than 30 m 2 / g. From this European patent application it is known that the hydrotalcites can be modified with higher fatty acid esters, anionic surface-active agents and coupling agents of the silane or titanium types in order to improve the compatibility of the hydrotalcite with the plastic compositions. The modification of the hydrotalcites is said to be carried out in accordance with the cited European patent application EP-A-189 899 mechanical mixing of hydrotaleites with the modifiers in pure or dissolved form.
  • Cationic layer compounds which have such small specific surfaces are, however, only accessible with great effort, since the crystallization of the solid from the aqueous phase in the pressure reactor must take place at temperatures well above the normal boiling point of the water. This requires a high technical outlay and, due to the long crystallization times, an unsatisfactory space-time yield.
  • the use of hydrotalcites with small specific surfaces has the disadvantage that hydrogen chloride formed during the thermal decomposition of vinyl chloride resins can only be trapped on a very small surface.
  • EP-A-207 811 describes monodisperse, catalytic layer compounds modified with polyethylene glycol or glycerol, which are to be used as thickeners for water-based drilling fluids.
  • Modified cationic layer compounds produced in this way have, however, proven to be practically unusable as co-stabilizers in halogen-containing plastics.
  • the object of the present invention was to provide co-stabilizers for halogen-containing plastics, which
  • the present invention relates to cationic layer compounds of the general formula I
  • 0 ⁇ m ⁇ 10 apply, with a specific surface area according to BET of at least 50 m 2 / g, with one or more additives selected from the groups
  • esters of partially and completely epoxidized unsaturated carboxylic acids with 6 to 22 carbon atoms and
  • the unmodified cationic layer compounds of the general formula I are compounds known per se, the structure and preparation of which are described, for example, by WT Reichle in Chemtec (January 1986), pages 58-63.
  • M ( IJ ) preferably stands only for a divalent metal ion from the group mentioned and in particular for magnesium.
  • the general formula IM (** I) expediently stands for at least one trivalent metal ion selected from the group aluminum, bismuth, antimony, boron, gallium and indium, preferably only for a trivalent metal ion of this group mentioned and in particular for aluminum .
  • catalytic layer compounds of the general formula I in which A n "represents an acid anion with the charge n selected from the anion group carbonate, hydrogen carbonate, perchlorate, acetate, nitrate, tartrate, oxalate, hydroxide and iodide, preferably for carbonate
  • a n represents an acid anion with the charge n selected from the anion group carbonate, hydrogen carbonate, perchlorate, acetate, nitrate, tartrate, oxalate, hydroxide and iodide, preferably for carbonate
  • Cationic layer compounds of the general formula I in which M ( ⁇ * 0 for magnesium and M (m) for aluminum and A n ⁇ for carbonate, are particularly advantageous.
  • suitable cationic layer compounds are synthetic hydrocatalcites, which are also known as basic aluminum-magnesium carbonates are referred to and which can be produced according to the process described in German patent application DE-B-1592126 and the processes described in German patent application DE-A-20 61 114 or DE-A 29 05 256
  • hydrotalcite suspension of the formula [Mg6 ⁇ l2 (0H) i2] (C03) 3 • 4 H2O.
  • the production of the particularly preferred hydrotalcites is not restricted to this special process.
  • the reaction can also take place in the presence of other carbonate salts, although this is less preferred due to the introduction of foreign ions.
  • the suspension can also be obtained by other technically customary separation and drying processes, although spray drying is preferred.
  • the conditions of use of magnesium, aluminum and / or carbonate ions can also be varied.
  • Cationic layer connections which are produced by one of these processes, have a specific surface according to BET of at least 50 m 2 / g, preferably between 70 and 180 m 2 / g.
  • specific surface according to BET corresponds to the definition in Rö pp's Chemie Lexikon, Volume 1, 8th edition, 1979, page 423.
  • the cationic layered compounds are modified in situ with one or more additives from groups A) to D) during their production.
  • the additives A) to D) can either before or together with magnesium hydroxide and / or magnesium oxide to form an aqueous solution or suspension of aluminum hydroxide or before or together with aluminum hydroxide to form an aqueous solution or suspension of magnesium hydroxide and / or magnesium oxide are given.
  • the additives are expediently added to an aqueous suspension of aluminum hydroxide provided with stirring at room temperature (15 to 25 ° C.) before the reaction with magnesium hydroxide and / or magnesium oxide, preferably magnesium oxide, takes place. Subsequently, reaction temperatures of 50 to 100 ° C. are recommended to accelerate the reaction.
  • the carbonate ions are introduced in the form of their salts, preferably as magnesium hydroxycarbonate, at the latest together with the magnesium hydroxides and / or magnesium oxide.
  • the stoichiometric amounts of magnesium, aluminum and carbonate ions depend on the desired hydrotalcite and can be calculated from the general formula I.
  • the reaction slurry formed during the reaction is then dried by one of the known processes, preferably by spray drying.
  • the drying is expediently carried out at performed that does not exceed the boiling point of additives A) to D) by more than 10 ° C, in particular does not exceed.
  • additional dewatering by means of night drying which is advantageously carried out at temperatures between 110 ° C. to 280 ° C., for example in a drying cabinet, leads to improved cationic layered compounds according to the invention.
  • kano ⁇ layered compounds are obtained which are very homogeneously modified with the additives to be described.
  • liquid or low melting additives dispersing wei ⁇ direct additive selected from the groups A) to D) by inten ⁇ sive mixing at room temperature (15 to 25 obtained according to the preparation of I) cationic layer compounds ⁇ C) or a temperature below the decomposition temperatures of the cationic layer compounds and / or the additives, preferably below 300 ° C. (Ha).
  • the term low-melting additives is understood to mean additives which can be converted into the liquid state at the above-mentioned decomposition temperatures at normal pressure.
  • the cationic layer compounds obtained after preparation I) can then be selected with one or more additives selected from groups A) to D) in the presence of polar organic solvents or of water milled, preferably with a mill grinder and in particular with a ball mill, dried and optionally post-dried.
  • polar organic solvents is used at room temperature (15 to 25 ° C) understood liquid hydrocarbon compounds that carry at least one electronegative substituent than carbon. These include chlorinated hydrocarbons, alcohols, ketones, esters, ethers and / or glycol ethers.
  • Suitable polar organic solvents are methanol, ethanol, n-butanol, acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanol, isophorone, ethyl acetate, lactic acid ethyl ester, 2-methoxyethyl acetate, tetrahydrofuran, ethyl glycol monomethyl ether, diethylene glycol monoethyl ether.
  • Additives of group A) are polyols with at least two hydroxyl groups and a total of 3 to 30 carbon atoms.
  • examples of such polyols are diols with 3 to 30 carbon atoms, such as butanediols, hexanediols, dodecanediols, and polyols such as trimethylolpropane, pentaerythritol, glycerol and their technical oligomer mixtures with average degrees of condensation from 2 to 10.
  • polyols with 3 to 30 carbon atoms which carry all 3 carbon atoms at least one hydroxyl group or an ether oxygen, preferably glycerol and / or the technical oligoglycerol mixtures with average degrees of condensation of 2 to 10.
  • the additives in group B) are esters of partially or completely epoxidized unsaturated carboxylic acids having 6 to 22 carbon atoms.
  • Suitable esters are esters of mono-, di- and / or trihydric alcohols which are completely esterified with epoxidized unsaturated carboxylic acids having 6 to 22 carbon atoms, such as methyl, 2-ethylhexyl, ethylene glycol, butanediol, neopentyl glycol, , Glycerol and / or tri ethylol propane esters of epoxidized lauroleic acid, palmitoleic acid, oleic acid, ricinoleic acid, linoleic acid and / or linolenic acid.
  • esters of trihydric alcohols and completely epoxidized unsaturated car- bonic acids with 12 to 22 carbon atoms and in particular esters of glycerol with completely epoxidized unsaturated carboxylic acids with 12 to 22 carbon atoms.
  • the carboxylic acid component can be derived, for example, from palmitoleic acid, oleic acid, elaidic acid, petroselinic acid, ricinoleic acid, linolenic acid, gadoleic acid or erucic acid.
  • the unsaturated carboxylic acids are epoxidized by known methods.
  • the epoxidized carboxylic acid glycerides can also be technical mixtures such as those obtained by epoxidation of natural unsaturated fats and oils.
  • Epoxidized beet oil, epoxidized unsaturated soybean oil and / or epoxidized sunflower oil of new breed is preferably used.
  • the additives of group C) are full or partial esters which are obtained by the relevant methods of preparative organic chemistry, for example by acid-catalyzed reaction of polyols with carboxylic acids.
  • Suitable polyol components are those which have already been discussed in group A).
  • Preferred acid components are aliphatic, saturated and / or unsaturated carboxylic acids having 6 to 22 carbon atoms, such as caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, oleic acid, ricinoleic acid, linoleic acid, linolenic acid, behenic acid Erucic acid.
  • the carboxylic acid component can also be a technical mixture, as is the case with the pressure splitting of natural fats and oils.
  • Partial esters of glycerol and, in particular, of its technical igoglycerin acid with average degrees of condensation of 2 to 10 and saturated and / or unsaturated aliphatic carboxylic acids with 6 to 22 carbon atoms are preferred.
  • alkyl and aryl phosphites can be used, preferably those of the general formula II
  • R 1 , R 2 and R 3 independently of one another represent an alkyl radical having 1 to 18 carbon atoms or a phenyl radical.
  • Typical examples of additives of group D) are tributyl phosphite, triphenyl phosphite, dimethylphenyl phosphite and / or dimethyl stearyl phosphite. Diphenyldecylphosphite is preferred.
  • a total of one or more additives from groups A) to D) are used in the preparation according to I) in amounts of 0.5 to 15% by weight, based on cationic layer compounds.
  • the total amount of additive should be selected so that it is in the range from 1.0 to 15% by weight, based on cationic layered compounds .
  • the modified cationic layered compounds produced by process I) can additionally be produced in process Ha) with 3 to 100% by weight of the additives mentioned. based on cationic layer connection - are mixed.
  • Another object of the present invention is a process for the preparation of cationic layer compounds of the general formula I [M ( ⁇ ) ⁇ M (HI) (0H) y ] (An) z • mH 2 0 (I)
  • 0 ⁇ 10 apply, with a specific surface area according to BET of at least 50 m / g, with one or more additives selected from the groups
  • esters of partially and completely epoxidized unsaturated carboxylic acids with 6 to 22 carbon atoms and
  • Another object of the present invention is the use of cationic layered compounds of the type described as co-stabilizers for halogen-containing plastics stabilized with calcium and / or zinc salts of carboxylic acids having 6 to 22 carbon atoms.
  • the cationic layered compounds according to the invention are preferably used as co-stabilizers in halogen-containing plastics and in particular in PVC.
  • the modified cationic layer compounds are added in amounts of 0.01 to 5, preferably 0.1 to 3 parts by weight, based on 100 parts by weight of synthetic resins. As a rule, they are mechanically mixed with the plastics in the form of granules before the shaping, for example in the calendering and extrusion process, is carried out.
  • the commercially available zinc and / or calcium salts of carboxylic acids having 6 to 22 carbon atoms are usually mixed in as usual stabilizers at the same time as the modified cationic layer compounds.
  • other conventional additives such as the heat stabilizers described in European application EP-A-189899, can also be used.
  • the amounts of the stabilizers and co-stabilizers can vary as desired, with the proviso that the total stabilizer addition is within the quantitative limit of 0.5 to 5 parts by weight, based on 100 parts by weight of synthetic resins.
  • the minimum amount of modified cationic layer connection is accordingly at least 0.01% by weight.
  • the cationic layer compounds according to the invention By using the cationic layer compounds according to the invention with a modified surface, the action of zinc and / or calcium soaps in stabilizing the halogen containing plastics improved.
  • the modified cationic layer compounds can be incorporated in the halogen-containing plastics as co-stabilizers without impairing the rheology of the plastics.
  • Table 1 shows the additives or additive mixtures.
  • the amount of the additives means percent by weight based on the theoretical yield of cationic layer compound of the formula [Mg_j Al (0H) 12] (CO3) • 4 H2O.
  • the temperature specification relates to the temperature of the post-drying in ° C. Table 1; Cationic layer connection modified with
  • Alcamizer R 4" commercial PVC stabilizer based on hydrotalcite from Kyowa Chemical Ind. With a BET specific surface area of 8 m / g (cf. "Introduction of Alcamizer", Kyowa Chem. Ind. Co. Ltd Pages 2-36, Isuriganecho, Higashi-Ku, Osaka).
  • Spray-dried hydrotalcite produced analogously to Example 1, but without the addition of additives and without subsequent drying.
  • Spray-dried hydrotalcite produced analogously to Example 1, but without the addition of additives. After the spray drying, this hydrotalcite was dried in a laboratory drying cabinet at 200 ° C. for 2 hours.
  • polyvinyl chloride molding compounds containing stabilizer were processed on a laboratory rolling mill measuring 450 ⁇ 220 mm (from Berstorff) at a roll temperature of 170 ° C. and a roll speed of 12.5 rpm in parallel to test files.
  • the approx. 0.5 mm thick skins were cut into square test pieces with an edge length of 10 mm, which were then exposed to a temperature of 180 ° C. in a drying cabinet with six rotating trays (Heraeus FT 420 R).
  • the samples were removed at intervals of 15 minutes and their color change was assessed.
  • the discoloration was characterized by grades 1 (colorless) to 10 (black, stability drop).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paper (AREA)
EP92910385A 1991-05-24 1992-05-15 Kationische, modifizierte schichtverbindungen Withdrawn EP0586436A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4117035 1991-05-24
DE4117035A DE4117035A1 (de) 1991-05-24 1991-05-24 Kationische, modifizierte schichtverbindungen

Publications (1)

Publication Number Publication Date
EP0586436A1 true EP0586436A1 (de) 1994-03-16

Family

ID=6432364

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92910385A Withdrawn EP0586436A1 (de) 1991-05-24 1992-05-15 Kationische, modifizierte schichtverbindungen

Country Status (6)

Country Link
US (1) US5416141A (cs)
EP (1) EP0586436A1 (cs)
JP (1) JPH06507658A (cs)
DE (1) DE4117035A1 (cs)
TW (1) TW200510B (cs)
WO (1) WO1992020732A1 (cs)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4238567A1 (de) * 1992-11-16 1994-05-19 Henkel Kgaa Stabilisatormischungen für Polymerisate mit Granaten
DE19511016A1 (de) * 1995-03-25 1996-09-26 Henkel Kgaa Kationische Schichtverbindungen, deren Herstellung und deren Verwendung als PVC-Stabilisatoren
DE19617138A1 (de) * 1996-04-29 1997-11-06 Henkel Kgaa Kationische Schichtverbindungen, deren Herstellung und deren Verwendung als Stabilisatoren für halogenhaltige Kunststoffe
DE19753758A1 (de) 1997-12-04 1999-06-10 Henkel Kgaa Verfahren zur Herstellung kationischer Schichtverbindungen
JP4054144B2 (ja) * 1998-12-01 2008-02-27 協和化学工業株式会社 層間のアニオンとしてその一部または全部が珪素系、燐系及び硼素系多量体酸素酸イオンの少なくとも一種のアニオンとそれ以外のアニオンとを保持したハイドロタルサイト系化合物、その製法、農業用フィルム用赤外線吸収剤及び該赤外線吸収剤を含有する農業用フィルム
DE19836580A1 (de) * 1998-08-12 2000-02-17 Sued Chemie Ag Verbundmaterial mit Polymermatrix und anionisch interkalierten schichtförmigen Doppelhydroxiden
EP1196493A1 (en) * 1999-07-13 2002-04-17 Vantico AG Nanocomposites
US6784226B2 (en) 1999-07-28 2004-08-31 Chi Mei Corporation Process for producing a styrenic resin composition
US6413639B1 (en) 1999-10-01 2002-07-02 Toda Kogyo Corporation Mg-Al based hydrotalcite-type particles, chlorine-containing resin stabilizer and process for producing the particles
US7922984B2 (en) * 2000-02-18 2011-04-12 Selective Micro Technologies, Llc Apparatus and method for controlled delivery of a gas
DE10018210B4 (de) * 2000-04-12 2005-07-07 Sachtleben Chemie Gmbh Verfahren zur Herstellung von anorganischen Farbmitteln
WO2022093970A1 (en) 2020-10-27 2022-05-05 Selective Micro Technologies, Llc Gas generation apparatus and method utilizing hydrophobic membrane pouch reactor

Family Cites Families (12)

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Publication number Priority date Publication date Assignee Title
JPS5290192A (en) * 1976-01-23 1977-07-28 Kyowa Kagaku Kougiyou Kk Inorganic flame resisting agent
JPS5580447A (en) * 1978-12-14 1980-06-17 Kyowa Chem Ind Co Ltd Prevention of rust, deterioration or coloring of polyolefin and composition
GB2075989B (en) * 1980-05-13 1984-04-26 Kyowa Chem Ind Co Ltd Stabilized thermoplastic resin compositions
JPS5783538A (en) * 1980-11-12 1982-05-25 Kyowa Chem Ind Co Ltd Polyolefin composition and agent thereof
DE3306822C2 (de) * 1983-02-26 1985-01-03 Giulini Chemie Gmbh, 6700 Ludwigshafen Kristallines, basisches Aluminium-Magnesium-Carbonat
JPS61174270A (ja) * 1985-01-29 1986-08-05 Kyowa Chem Ind Co Ltd 耐発錆性ないし耐着色性賦与剤
JPH0639560B2 (ja) * 1986-08-14 1994-05-25 協和化学工業株式会社 ポリ塩化ビニル系樹脂の安定化組成物
FR2636956B1 (fr) * 1988-09-23 1992-03-27 Atochem Compositions stabilisantes pour polymeres halogenes, a base de beta-dicetone, d'hydrotalcite et de di-hydropyridine, et polymeres ainsi stabilises
JP2758031B2 (ja) * 1989-07-04 1998-05-25 協和化学工業株式会社 含ハロゲン樹脂用の安定剤組成物
EP0421933B1 (de) * 1989-10-06 1996-06-12 Ciba-Geigy Ag Stabilisierte chlorhaltige Polymerzusammensetzungen
US5143965A (en) * 1990-12-26 1992-09-01 The Dow Chemical Company Magnesium hydroxide having fine, plate-like crystalline structure and process therefor
FR2675149B1 (fr) * 1991-04-09 1994-06-24 Rhone Poulenc Chimie Compositions de polymere halogene stabilisees a l'aide d'un additif mineral.

Non-Patent Citations (1)

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Title
See references of WO9220732A1 *

Also Published As

Publication number Publication date
DE4117035A1 (de) 1992-11-26
TW200510B (cs) 1993-02-21
WO1992020732A1 (de) 1992-11-26
US5416141A (en) 1995-05-16
JPH06507658A (ja) 1994-09-01

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