EP0531996B1 - Vorsatzaggregat für Bildschirme oder dergleichen - Google Patents
Vorsatzaggregat für Bildschirme oder dergleichen Download PDFInfo
- Publication number
- EP0531996B1 EP0531996B1 EP92115501A EP92115501A EP0531996B1 EP 0531996 B1 EP0531996 B1 EP 0531996B1 EP 92115501 A EP92115501 A EP 92115501A EP 92115501 A EP92115501 A EP 92115501A EP 0531996 B1 EP0531996 B1 EP 0531996B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- attachment
- fact
- accordance
- glass pane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011521 glass Substances 0.000 claims abstract description 22
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052737 gold Inorganic materials 0.000 claims abstract description 22
- 239000010931 gold Substances 0.000 claims abstract description 22
- 238000000576 coating method Methods 0.000 claims abstract description 20
- 239000011248 coating agent Substances 0.000 claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 claims abstract description 18
- 239000002184 metal Substances 0.000 claims abstract description 18
- 230000003667 anti-reflective effect Effects 0.000 claims abstract description 8
- 239000006117 anti-reflective coating Substances 0.000 claims abstract description 7
- 239000003989 dielectric material Substances 0.000 claims abstract description 4
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract description 3
- 238000001228 spectrum Methods 0.000 claims abstract 2
- 239000010410 layer Substances 0.000 claims description 54
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 239000012790 adhesive layer Substances 0.000 claims description 14
- 229910052681 coesite Inorganic materials 0.000 claims description 7
- 229910052906 cristobalite Inorganic materials 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims description 7
- 229910052682 stishovite Inorganic materials 0.000 claims description 7
- 229910052905 tridymite Inorganic materials 0.000 claims description 7
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 claims description 6
- 229910001120 nichrome Inorganic materials 0.000 claims description 6
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910003437 indium oxide Inorganic materials 0.000 claims description 3
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 238000004544 sputter deposition Methods 0.000 claims description 3
- 230000002745 absorbent Effects 0.000 claims description 2
- 239000002250 absorbent Substances 0.000 claims description 2
- 230000003287 optical effect Effects 0.000 claims description 2
- 229910052752 metalloid Inorganic materials 0.000 claims 1
- 150000002738 metalloids Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 239000005329 float glass Substances 0.000 description 3
- 238000001755 magnetron sputter deposition Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- VVTSZOCINPYFDP-UHFFFAOYSA-N [O].[Ar] Chemical compound [O].[Ar] VVTSZOCINPYFDP-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000012300 argon atmosphere Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000005546 reactive sputtering Methods 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- 239000005368 silicate glass Substances 0.000 description 2
- 238000001429 visible spectrum Methods 0.000 description 2
- 229910001020 Au alloy Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000003353 gold alloy Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J29/00—Details of cathode-ray tubes or of electron-beam tubes of the types covered by group H01J31/00
- H01J29/86—Vessels; Containers; Vacuum locks
- H01J29/89—Optical or photographic arrangements structurally combined or co-operating with the vessel
- H01J29/896—Anti-reflection means, e.g. eliminating glare due to ambient light
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2229/00—Details of cathode ray tubes or electron beam tubes
- H01J2229/89—Optical components associated with the vessel
- H01J2229/8913—Anti-reflection, anti-glare, viewing angle and contrast improving treatments or devices
- H01J2229/8916—Anti-reflection, anti-glare, viewing angle and contrast improving treatments or devices inside the vessel
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2229/00—Details of cathode ray tubes or electron beam tubes
- H01J2229/89—Optical components associated with the vessel
- H01J2229/8913—Anti-reflection, anti-glare, viewing angle and contrast improving treatments or devices
- H01J2229/8918—Anti-reflection, anti-glare, viewing angle and contrast improving treatments or devices by using interference effects
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
- Y10T428/24975—No layer or component greater than 5 mils thick
Definitions
- the invention relates to an attachment for screens or the like, such as cathode ray tubes of monitors, television sets or the like, with a glass pane which has a multilayer anti-reflection coating on its front facing away from the screen or the like and, if appropriate, a reflection-reducing, in particular on its rear facing the screen or the like has an absorbent coating (or the like).
- screens or the like such as cathode ray tubes of monitors, television sets or the like
- a glass pane which has a multilayer anti-reflection coating on its front facing away from the screen or the like and, if appropriate, a reflection-reducing, in particular on its rear facing the screen or the like has an absorbent coating (or the like).
- the coating used for such attachment units should have a low surface resistance in order to be able to shield electromagnetic radiation. This usually requires an electrical sheet resistance of less than 100 ohms.
- Double-layer systems for front-end units of the type mentioned at the outset, with which a good anti-reflective effect could be achieved over wide areas of the visible spectrum, are not known, rather the use of such simple layer systems is always associated with an intense color impression. Multi-layer systems are therefore used to reduce the color cast, but these require a much higher production expenditure.
- the glass pane which there as well as in the invention can consist either of inorganic glass, in particular of tempered safety glass, or also of plastic, ie organic glass, has an absorption coating made of, for example, chrome on the back and an anti-reflection coating made of two or three layers with a different refractive index on the front, with the neutrality of the color impression and the manufacturing effort leave a wish.
- an anti-reflection coating for glass panes in which a successive metal layer made of a material with a high degree of reflection but low absorption and a dielectric interference layer made of SiO2, for example, are applied to the glass panes, with copper, Silver, rhodium, aluminum or other similarly stable metals with the aforementioned properties are specified.
- the use of such an antireflection coating in front-mounted units of the generic type leads, if metals other than copper are selected, to an undesirably intense color impression, while the use of copper is prohibited because of its lack of resistance for front-side coatings of front-mounted units of the type in question here.
- GB-PS 826 754 electrically conductive coatings are described on glass panes, which can alternatively contain a gold, silver, nickel or iron layer as well as part of an outer anti-reflective layer, for example SiO2, with the exception of the use of gold intense color impression can be accepted in the field of application specified there and no indication is given to produce a neutral color impression by appropriate choice of material for the metal layer.
- an outer anti-reflective layer for example SiO2
- DE-PS 21 38 517 relates to a heat shield with a coating of gold and high-index dielectric material, the use of such a coating would not allow the desired reflection reduction in an attachment of the generic type.
- the invention has for its object to provide a front unit of the generic type, the anti-reflective coating allows economical reduction of the light reflectance of the front of the glass pane from about 4% to less than 0.5%, is largely neutral in color and has a sheet resistance of less with economical production than 100 ohms.
- the antireflection coating comprises a metal layer made of gold or a metal alloy with a gold content of more than 50% with a thickness of 4 to 10 nm and an essentially absorption-free layer on the side facing away from the glass pane, as an anti-reflective layer for has the visible spectral range interference layer made of dielectric material with a refractive index of n ⁇ 1.8.
- the thickness of the metal layer is 5 to 7 nm.
- the invention further proposes that the optical thickness of the interference layer is 60 to 140 nm.
- the interference layer consists of at least one metal or semimetal oxide.
- the interference layer consists of SiO2.
- Another embodiment of the invention is characterized in that between the glass pane and the metal layer and / or an adhesive layer is arranged between the metal layer and the interference layer (in each case).
- NiCr, silicon, indium oxide and / or indium tin oxide is used as the material for the adhesive layer (s).
- the invention also proposes that at least some of the layers of the anti-reflective coating be produced by magnetron sputtering.
- the invention is based on the surprising finding that the interaction of the metal and the interference layer according to the invention can achieve an antireflective color-neutral effect for a double-layer system. Hence, this effect is due to the unusual course of gold's complex refractive index, which is distinguished by the fact that its real part falls monotonously significantly in the visible spectrum.
- DE-PS 21 38 517 describes the use of gold in conjunction with a high-refractive antireflection coating, while the object on which the invention is based can only be achieved by a combination of the gold layer and the low-refractive interference layer in the sense of the claimed antireflection coating is.
- the glass pane 10 again consists of a float glass pane made of soda-lime-silicate glass with a thickness of 4 mm
- a NiCr adhesive layer 16 with a thickness of 0.5 nm is successively applied to the glass pane 10
- a gold layer 12 with a thickness of 6 nm is successively applied to the glass pane 10
- attachment unit according to FIG. 2 was manufactured as follows:
- the adhesive layer 16 as NiCr adhesive layer of 0.5 nm thickness by sputtering a NiCr (80/20) target in an argon atmosphere at a pressure of 1.5 ⁇ 10 ⁇ 1 Pa
- the gold layer 12 of 6 nm thickness by sputtering a gold target in argon Atmosphere at a pressure of 1.5 ⁇ 10 ⁇ 1 Pa
- the adhesive layer 18 as a SnO2-doped In2O3 adhesive layer in a thickness of 4 nm by reactive sputtering of the In90 / Sn10 target in an argon-oxygen atmosphere at a pressure of 3.5 ⁇ 10 ⁇ 1 Pa
- the interference layer 14 as a SiO2 layer of 60 nm thickness by reactive sp
- Fig. 4 shows that the real part of the complex refractive index of gold drops significantly monotonically over the visible spectral region, whereupon the surprising effect of the attachment unit according to the invention, in combination with the low-refractive interference layer used, may be essentially attributable.
Landscapes
- Surface Treatment Of Glass (AREA)
- Laminated Bodies (AREA)
- Battery Mounting, Suspending (AREA)
- Brushes (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- External Artificial Organs (AREA)
- Vessels, Lead-In Wires, Accessory Apparatuses For Cathode-Ray Tubes (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4130930 | 1991-09-13 | ||
DE4130930A DE4130930A1 (de) | 1991-09-13 | 1991-09-13 | Vorsatzaggregat fuer bildschirme oder dergleichen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0531996A1 EP0531996A1 (de) | 1993-03-17 |
EP0531996B1 true EP0531996B1 (de) | 1995-10-04 |
Family
ID=6440815
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92115501A Expired - Lifetime EP0531996B1 (de) | 1991-09-13 | 1992-09-10 | Vorsatzaggregat für Bildschirme oder dergleichen |
Country Status (6)
Country | Link |
---|---|
US (1) | US5288558A (nl) |
EP (1) | EP0531996B1 (nl) |
AT (1) | ATE128789T1 (nl) |
DE (2) | DE4130930A1 (nl) |
DK (1) | DK0531996T3 (nl) |
ES (1) | ES2079125T3 (nl) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0626718B1 (en) * | 1991-09-20 | 2002-12-18 | Hitachi, Ltd. | Display comprising an anti-reflection film,cathode-ray tube and liquid crystal display |
US5444329A (en) * | 1992-11-06 | 1995-08-22 | Kabushiki Kaisha Toshiba | Antireflection film and display apparatus comprising the same |
JP2981528B2 (ja) * | 1992-12-25 | 1999-11-22 | 三菱電機株式会社 | 陰極線管およびその製造方法 |
FR2708626B1 (fr) * | 1993-08-02 | 1998-06-05 | Director General Agency Ind | Film ultramince transparent et conducteur et procédé pour sa fabrication. |
USH1396H (en) * | 1993-09-21 | 1995-01-03 | The United States Of America As Represented By The Secretary Of The Army | Oxide substrate with a strongly adherent gold film of 10 to 40 nm in thickness on the substrate |
US5441914A (en) * | 1994-05-02 | 1995-08-15 | Motorola Inc. | Method of forming conductive interconnect structure |
US5728470A (en) * | 1994-05-13 | 1998-03-17 | Nec Corporation | Multi-layer wiring substrate, and process for producing the same |
KR0178734B1 (ko) * | 1995-07-31 | 1999-05-01 | 김광호 | 배면 프로젝션 텔레비젼세트의 투사스크린 |
PT883521E (pt) | 1996-03-02 | 2000-04-28 | Volkswagen Ag | Dispositivo multifuncional para um veiculo automovel |
JPH10223160A (ja) * | 1997-02-12 | 1998-08-21 | Hitachi Ltd | カラー陰極線管 |
JP3039437B2 (ja) * | 1997-04-15 | 2000-05-08 | 日本電気株式会社 | カラープラズマディスプレイパネル |
JP2000515264A (ja) * | 1997-04-28 | 2000-11-14 | コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ | 静電防止、反射防止フィルタを具える表示装置及び陰極線管上に反射防止フィルタを製造する方法 |
EP1028611B1 (en) * | 1997-06-24 | 2004-06-09 | Bridgestone Corporation | Electromagnetic wave shielding and light transmitting plate |
JP2001270740A (ja) * | 2000-01-19 | 2001-10-02 | Nippon Sheet Glass Co Ltd | ガラス物品及びディスプレイ用ガラス基板 |
US7097923B2 (en) | 2002-04-30 | 2006-08-29 | Hitachi Global Storage Technologies | Method for forming thin film heads using a tri-layer anti-reflection coating for photolithographic applications and a structure thereof |
US7365408B2 (en) | 2002-04-30 | 2008-04-29 | International Business Machines Corporation | Structure for photolithographic applications using a multi-layer anti-reflection coating |
CN101205060B (zh) | 2006-12-20 | 2011-05-04 | 清华大学 | 碳纳米管阵列的制备方法 |
CN101206979B (zh) * | 2006-12-22 | 2010-05-19 | 清华大学 | 场发射阴极的制备方法 |
CN101206980B (zh) * | 2006-12-22 | 2010-04-14 | 清华大学 | 场发射阴极的制备方法 |
WO2008081837A1 (ja) * | 2006-12-27 | 2008-07-10 | Asahi Glass Company, Limited | 反射防止体およびディスプレイ装置 |
US20100307553A1 (en) * | 2008-08-26 | 2010-12-09 | Defries Anthony | Engineering light manipulation in structured films or coatings |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2366687A (en) * | 1941-01-23 | 1945-01-02 | Spencer Lens Co | Means for decreasing light reflection from surfaces |
GB826754A (en) * | 1956-06-09 | 1960-01-20 | George Edward Folkes | Light transmissive electrically conducting article |
US3532919A (en) * | 1968-03-07 | 1970-10-06 | Hughes Aircraft Co | Cathode ray tube view screen structure |
BE759235A (fr) * | 1969-11-20 | 1971-05-21 | Triplex Safety Glass Co | Perfectionnements aux objets transparents conducteurs de l'electricite |
FR2135033B1 (nl) * | 1971-05-03 | 1973-12-28 | Saint Gobain Pont A Mousson | |
DE2138517C3 (de) * | 1971-08-02 | 1978-10-05 | Flachglas Ag Delog-Detag, 4650 Gelsenkirchen | Wärmeschutz-Glasscheibe |
US3935351A (en) * | 1972-05-12 | 1976-01-27 | Ppg Industries, Inc. | Multiple glazed windows including selective reflecting metal/metal oxide coatings |
US4235048A (en) * | 1978-01-03 | 1980-11-25 | Ppg Industries, Inc. | Reversible window unit for alternately reflecting and absorbing solar energy |
DE2924824C3 (de) * | 1979-06-20 | 1986-07-10 | Bfg Glassgroup, Paris | Wärmereflexionsscheibe, insbesondere wärmereflektierende Fensterscheibe und deren Verwendung als Außenscheibe einer Mehrscheibenanordnung |
DE3332995A1 (de) * | 1983-07-14 | 1985-01-24 | Nippon Sheet Glass Co. Ltd., Osaka | Verfahren zum herstellen einer siliciumdioxidbeschichtung |
DE3629996A1 (de) * | 1986-09-03 | 1988-03-17 | Flachglas Ag | Vorsatzaggregat fuer die kathodenstrahlroehre von monitoren, fernsehapparaten und dergleichen |
GB8621468D0 (en) * | 1986-09-05 | 1986-10-15 | Philips Nv | Display device |
US4882212A (en) * | 1986-10-30 | 1989-11-21 | Olin Corporation | Electronic packaging of components incorporating a ceramic-glass-metal composite |
DE3643088A1 (de) * | 1986-12-17 | 1988-06-30 | Flabeg Gmbh | Fernseh-bildroehre mit verbundfrontscheibe |
DE3941797A1 (de) * | 1989-12-19 | 1991-06-20 | Leybold Ag | Belag, bestehend aus einem optisch wirkenden schichtsystem, fuer substrate, wobei das schichtsystem insbesondere eine hohe antireflexwirkung aufweist, und verfahren zur herstellung des belags |
-
1991
- 1991-09-13 DE DE4130930A patent/DE4130930A1/de active Granted
-
1992
- 1992-09-10 DK DK92115501.6T patent/DK0531996T3/da active
- 1992-09-10 DE DE59203892T patent/DE59203892D1/de not_active Expired - Fee Related
- 1992-09-10 EP EP92115501A patent/EP0531996B1/de not_active Expired - Lifetime
- 1992-09-10 ES ES92115501T patent/ES2079125T3/es not_active Expired - Lifetime
- 1992-09-10 AT AT92115501T patent/ATE128789T1/de not_active IP Right Cessation
- 1992-09-11 US US07/944,109 patent/US5288558A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US5288558A (en) | 1994-02-22 |
ES2079125T3 (es) | 1996-01-01 |
DE4130930C2 (nl) | 1993-09-09 |
DE59203892D1 (de) | 1995-11-09 |
ATE128789T1 (de) | 1995-10-15 |
EP0531996A1 (de) | 1993-03-17 |
DK0531996T3 (da) | 1995-11-27 |
DE4130930A1 (de) | 1993-03-25 |
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