EP0531996B1 - Vorsatzaggregat für Bildschirme oder dergleichen - Google Patents

Vorsatzaggregat für Bildschirme oder dergleichen Download PDF

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Publication number
EP0531996B1
EP0531996B1 EP92115501A EP92115501A EP0531996B1 EP 0531996 B1 EP0531996 B1 EP 0531996B1 EP 92115501 A EP92115501 A EP 92115501A EP 92115501 A EP92115501 A EP 92115501A EP 0531996 B1 EP0531996 B1 EP 0531996B1
Authority
EP
European Patent Office
Prior art keywords
layer
attachment
fact
accordance
glass pane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP92115501A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0531996A1 (de
Inventor
Axel Dr. Nöthe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Flabeg GmbH and Co KG
Original Assignee
Flachglas Wernberg GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Flachglas Wernberg GmbH filed Critical Flachglas Wernberg GmbH
Publication of EP0531996A1 publication Critical patent/EP0531996A1/de
Application granted granted Critical
Publication of EP0531996B1 publication Critical patent/EP0531996B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J29/00—Details of cathode-ray tubes or of electron-beam tubes of the types covered by group H01J31/00
    • H01J29/86—Vessels; Containers; Vacuum locks
    • H01J29/89—Optical or photographic arrangements structurally combined or co-operating with the vessel
    • H01J29/896—Anti-reflection means, e.g. eliminating glare due to ambient light
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J2229/00—Details of cathode ray tubes or electron beam tubes
    • H01J2229/89—Optical components associated with the vessel
    • H01J2229/8913—Anti-reflection, anti-glare, viewing angle and contrast improving treatments or devices
    • H01J2229/8916—Anti-reflection, anti-glare, viewing angle and contrast improving treatments or devices inside the vessel
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J2229/00—Details of cathode ray tubes or electron beam tubes
    • H01J2229/89—Optical components associated with the vessel
    • H01J2229/8913—Anti-reflection, anti-glare, viewing angle and contrast improving treatments or devices
    • H01J2229/8918—Anti-reflection, anti-glare, viewing angle and contrast improving treatments or devices by using interference effects
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y10T428/24967—Absolute thicknesses specified
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y10T428/24967—Absolute thicknesses specified
    • Y10T428/24975—No layer or component greater than 5 mils thick

Definitions

  • the invention relates to an attachment for screens or the like, such as cathode ray tubes of monitors, television sets or the like, with a glass pane which has a multilayer anti-reflection coating on its front facing away from the screen or the like and, if appropriate, a reflection-reducing, in particular on its rear facing the screen or the like has an absorbent coating (or the like).
  • screens or the like such as cathode ray tubes of monitors, television sets or the like
  • a glass pane which has a multilayer anti-reflection coating on its front facing away from the screen or the like and, if appropriate, a reflection-reducing, in particular on its rear facing the screen or the like has an absorbent coating (or the like).
  • the coating used for such attachment units should have a low surface resistance in order to be able to shield electromagnetic radiation. This usually requires an electrical sheet resistance of less than 100 ohms.
  • Double-layer systems for front-end units of the type mentioned at the outset, with which a good anti-reflective effect could be achieved over wide areas of the visible spectrum, are not known, rather the use of such simple layer systems is always associated with an intense color impression. Multi-layer systems are therefore used to reduce the color cast, but these require a much higher production expenditure.
  • the glass pane which there as well as in the invention can consist either of inorganic glass, in particular of tempered safety glass, or also of plastic, ie organic glass, has an absorption coating made of, for example, chrome on the back and an anti-reflection coating made of two or three layers with a different refractive index on the front, with the neutrality of the color impression and the manufacturing effort leave a wish.
  • an anti-reflection coating for glass panes in which a successive metal layer made of a material with a high degree of reflection but low absorption and a dielectric interference layer made of SiO2, for example, are applied to the glass panes, with copper, Silver, rhodium, aluminum or other similarly stable metals with the aforementioned properties are specified.
  • the use of such an antireflection coating in front-mounted units of the generic type leads, if metals other than copper are selected, to an undesirably intense color impression, while the use of copper is prohibited because of its lack of resistance for front-side coatings of front-mounted units of the type in question here.
  • GB-PS 826 754 electrically conductive coatings are described on glass panes, which can alternatively contain a gold, silver, nickel or iron layer as well as part of an outer anti-reflective layer, for example SiO2, with the exception of the use of gold intense color impression can be accepted in the field of application specified there and no indication is given to produce a neutral color impression by appropriate choice of material for the metal layer.
  • an outer anti-reflective layer for example SiO2
  • DE-PS 21 38 517 relates to a heat shield with a coating of gold and high-index dielectric material, the use of such a coating would not allow the desired reflection reduction in an attachment of the generic type.
  • the invention has for its object to provide a front unit of the generic type, the anti-reflective coating allows economical reduction of the light reflectance of the front of the glass pane from about 4% to less than 0.5%, is largely neutral in color and has a sheet resistance of less with economical production than 100 ohms.
  • the antireflection coating comprises a metal layer made of gold or a metal alloy with a gold content of more than 50% with a thickness of 4 to 10 nm and an essentially absorption-free layer on the side facing away from the glass pane, as an anti-reflective layer for has the visible spectral range interference layer made of dielectric material with a refractive index of n ⁇ 1.8.
  • the thickness of the metal layer is 5 to 7 nm.
  • the invention further proposes that the optical thickness of the interference layer is 60 to 140 nm.
  • the interference layer consists of at least one metal or semimetal oxide.
  • the interference layer consists of SiO2.
  • Another embodiment of the invention is characterized in that between the glass pane and the metal layer and / or an adhesive layer is arranged between the metal layer and the interference layer (in each case).
  • NiCr, silicon, indium oxide and / or indium tin oxide is used as the material for the adhesive layer (s).
  • the invention also proposes that at least some of the layers of the anti-reflective coating be produced by magnetron sputtering.
  • the invention is based on the surprising finding that the interaction of the metal and the interference layer according to the invention can achieve an antireflective color-neutral effect for a double-layer system. Hence, this effect is due to the unusual course of gold's complex refractive index, which is distinguished by the fact that its real part falls monotonously significantly in the visible spectrum.
  • DE-PS 21 38 517 describes the use of gold in conjunction with a high-refractive antireflection coating, while the object on which the invention is based can only be achieved by a combination of the gold layer and the low-refractive interference layer in the sense of the claimed antireflection coating is.
  • the glass pane 10 again consists of a float glass pane made of soda-lime-silicate glass with a thickness of 4 mm
  • a NiCr adhesive layer 16 with a thickness of 0.5 nm is successively applied to the glass pane 10
  • a gold layer 12 with a thickness of 6 nm is successively applied to the glass pane 10
  • attachment unit according to FIG. 2 was manufactured as follows:
  • the adhesive layer 16 as NiCr adhesive layer of 0.5 nm thickness by sputtering a NiCr (80/20) target in an argon atmosphere at a pressure of 1.5 ⁇ 10 ⁇ 1 Pa
  • the gold layer 12 of 6 nm thickness by sputtering a gold target in argon Atmosphere at a pressure of 1.5 ⁇ 10 ⁇ 1 Pa
  • the adhesive layer 18 as a SnO2-doped In2O3 adhesive layer in a thickness of 4 nm by reactive sputtering of the In90 / Sn10 target in an argon-oxygen atmosphere at a pressure of 3.5 ⁇ 10 ⁇ 1 Pa
  • the interference layer 14 as a SiO2 layer of 60 nm thickness by reactive sp
  • Fig. 4 shows that the real part of the complex refractive index of gold drops significantly monotonically over the visible spectral region, whereupon the surprising effect of the attachment unit according to the invention, in combination with the low-refractive interference layer used, may be essentially attributable.

Landscapes

  • Surface Treatment Of Glass (AREA)
  • Laminated Bodies (AREA)
  • External Artificial Organs (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)
  • Vessels, Lead-In Wires, Accessory Apparatuses For Cathode-Ray Tubes (AREA)
  • Brushes (AREA)
  • Battery Mounting, Suspending (AREA)
EP92115501A 1991-09-13 1992-09-10 Vorsatzaggregat für Bildschirme oder dergleichen Expired - Lifetime EP0531996B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4130930 1991-09-13
DE4130930A DE4130930A1 (de) 1991-09-13 1991-09-13 Vorsatzaggregat fuer bildschirme oder dergleichen

Publications (2)

Publication Number Publication Date
EP0531996A1 EP0531996A1 (de) 1993-03-17
EP0531996B1 true EP0531996B1 (de) 1995-10-04

Family

ID=6440815

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92115501A Expired - Lifetime EP0531996B1 (de) 1991-09-13 1992-09-10 Vorsatzaggregat für Bildschirme oder dergleichen

Country Status (6)

Country Link
US (1) US5288558A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP0531996B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AT (1) ATE128789T1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (2) DE4130930A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DK (1) DK0531996T3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ES (1) ES2079125T3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0533030B1 (en) * 1991-09-20 1995-06-21 Hitachi, Ltd. Method and apparatus for forming an anti-reflection film for a cathode-ray tube
DE69312017T2 (de) * 1992-11-06 1997-12-04 Toshiba Kawasaki Kk Antireflektionsschicht und Anzeigegerät mit dieser Schicht
JP2981528B2 (ja) * 1992-12-25 1999-11-22 三菱電機株式会社 陰極線管およびその製造方法
FR2708626B1 (fr) * 1993-08-02 1998-06-05 Director General Agency Ind Film ultramince transparent et conducteur et procédé pour sa fabrication.
USH1396H (en) * 1993-09-21 1995-01-03 The United States Of America As Represented By The Secretary Of The Army Oxide substrate with a strongly adherent gold film of 10 to 40 nm in thickness on the substrate
US5441914A (en) * 1994-05-02 1995-08-15 Motorola Inc. Method of forming conductive interconnect structure
US5728470A (en) * 1994-05-13 1998-03-17 Nec Corporation Multi-layer wiring substrate, and process for producing the same
KR0178734B1 (ko) * 1995-07-31 1999-05-01 김광호 배면 프로젝션 텔레비젼세트의 투사스크린
EP0883521B2 (de) 1996-03-02 2003-04-23 Volkswagen Aktiengesellschaft Multifunktionseinrichtung für ein kraftfahrzeug
JPH10223160A (ja) * 1997-02-12 1998-08-21 Hitachi Ltd カラー陰極線管
JP3039437B2 (ja) * 1997-04-15 2000-05-08 日本電気株式会社 カラープラズマディスプレイパネル
WO1998049707A1 (en) * 1997-04-28 1998-11-05 Koninklijke Philips Electronics N.V. Display device comprising an anti-static, anti-reflection filter and a method of manufacturing an anti-reflection filter on a cathode ray tube
EP1453371B1 (en) * 1997-06-24 2007-11-21 Bridgestone Corporation Electromagnetic wave shielding and light transmitting plate
JP2001270740A (ja) * 2000-01-19 2001-10-02 Nippon Sheet Glass Co Ltd ガラス物品及びディスプレイ用ガラス基板
US7097923B2 (en) 2002-04-30 2006-08-29 Hitachi Global Storage Technologies Method for forming thin film heads using a tri-layer anti-reflection coating for photolithographic applications and a structure thereof
US7365408B2 (en) * 2002-04-30 2008-04-29 International Business Machines Corporation Structure for photolithographic applications using a multi-layer anti-reflection coating
CN101205060B (zh) 2006-12-20 2011-05-04 清华大学 碳纳米管阵列的制备方法
CN101206980B (zh) * 2006-12-22 2010-04-14 清华大学 场发射阴极的制备方法
CN101206979B (zh) * 2006-12-22 2010-05-19 清华大学 场发射阴极的制备方法
EP2103965A4 (en) * 2006-12-27 2011-05-25 Asahi Glass Co Ltd ANTI-REFLEX PRODUCT AND DISPLAY ARRANGEMENT
US20100307553A1 (en) * 2008-08-26 2010-12-09 Defries Anthony Engineering light manipulation in structured films or coatings

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Publication number Priority date Publication date Assignee Title
US2366687A (en) * 1941-01-23 1945-01-02 Spencer Lens Co Means for decreasing light reflection from surfaces
GB826754A (en) * 1956-06-09 1960-01-20 George Edward Folkes Light transmissive electrically conducting article
US3532919A (en) * 1968-03-07 1970-10-06 Hughes Aircraft Co Cathode ray tube view screen structure
BE759235A (fr) * 1969-11-20 1971-05-21 Triplex Safety Glass Co Perfectionnements aux objets transparents conducteurs de l'electricite
FR2135033B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1971-05-03 1973-12-28 Saint Gobain Pont A Mousson
DE2138517C3 (de) * 1971-08-02 1978-10-05 Flachglas Ag Delog-Detag, 4650 Gelsenkirchen Wärmeschutz-Glasscheibe
US3935351A (en) * 1972-05-12 1976-01-27 Ppg Industries, Inc. Multiple glazed windows including selective reflecting metal/metal oxide coatings
US4235048A (en) * 1978-01-03 1980-11-25 Ppg Industries, Inc. Reversible window unit for alternately reflecting and absorbing solar energy
DE2924824C3 (de) * 1979-06-20 1986-07-10 Bfg Glassgroup, Paris Wärmereflexionsscheibe, insbesondere wärmereflektierende Fensterscheibe und deren Verwendung als Außenscheibe einer Mehrscheibenanordnung
DE3332995A1 (de) * 1983-07-14 1985-01-24 Nippon Sheet Glass Co. Ltd., Osaka Verfahren zum herstellen einer siliciumdioxidbeschichtung
DE3629996A1 (de) * 1986-09-03 1988-03-17 Flachglas Ag Vorsatzaggregat fuer die kathodenstrahlroehre von monitoren, fernsehapparaten und dergleichen
GB8621468D0 (en) * 1986-09-05 1986-10-15 Philips Nv Display device
US4882212A (en) * 1986-10-30 1989-11-21 Olin Corporation Electronic packaging of components incorporating a ceramic-glass-metal composite
DE3643088A1 (de) * 1986-12-17 1988-06-30 Flabeg Gmbh Fernseh-bildroehre mit verbundfrontscheibe
DE3941797A1 (de) * 1989-12-19 1991-06-20 Leybold Ag Belag, bestehend aus einem optisch wirkenden schichtsystem, fuer substrate, wobei das schichtsystem insbesondere eine hohe antireflexwirkung aufweist, und verfahren zur herstellung des belags

Also Published As

Publication number Publication date
DK0531996T3 (da) 1995-11-27
ES2079125T3 (es) 1996-01-01
EP0531996A1 (de) 1993-03-17
DE4130930A1 (de) 1993-03-25
ATE128789T1 (de) 1995-10-15
US5288558A (en) 1994-02-22
DE4130930C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1993-09-09
DE59203892D1 (de) 1995-11-09

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