EP0524710B1 - Metallic cutlery - Google Patents
Metallic cutlery Download PDFInfo
- Publication number
- EP0524710B1 EP0524710B1 EP92250179A EP92250179A EP0524710B1 EP 0524710 B1 EP0524710 B1 EP 0524710B1 EP 92250179 A EP92250179 A EP 92250179A EP 92250179 A EP92250179 A EP 92250179A EP 0524710 B1 EP0524710 B1 EP 0524710B1
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- EP
- European Patent Office
- Prior art keywords
- bowl
- spoon
- cutlery
- eating utensil
- charaterized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G21/00—Table-ware
Definitions
- the invention relates to one-piece cutlery parts made of metal, in particular table cutlery, such as knives, forks, spoons.
- the high-quality cutlery parts made of steel or nickel silver which have become known and are available on the market, in particular made of rust-free chrome-nickel steel or nickel silver, have to be produced by complex manufacturing processes.
- the manufacturing processes for the production of cutlery made of nickel silver, which are silvered, and for cutlery made of chrome-nickel steel are roughly the same.
- Fork and spoon cutlery are cut out of sheet steel in one piece. These pre-cuts, called brandeln, have to be deburred and rolled. The burners for the production of spoon cutlery parts must be rolled down to a smaller material thickness in the area of the bowl to be formed later. Afterwards fork and spoon brandies have to be cut to size according to the model. Washing and glowing operations follow before the cutlery parts get their shape and decor through the embossing process.
- the embossing process creates an inevitable burr on the "high edge" of the cutlery. This burr has to be sanded down, only then can the grinding and polishing operations for leveling the surface and for producing the gloss on the surface take place. On The washing process then completes the steps for the manufacture of cutlery items made of chrome-nickel steel. With silver-plated cutlery, silvering follows.
- the knife booklet is welded together from two half-shells, which were previously formed from a sheet metal strip.
- the blade is fastened in the hollow knife handle part, preferably by welding or cementing. With this type of knife, the handle is made from a surface-finishable chrome-nickel steel.
- the blade is made of hardened, elastic, stainless steel.
- a one-piece knife is produced from a hardenable chrome-nickel steel by rolling and / or forging.
- JP-A-2057604 It is known from JP-A-2057604 to produce sintered bodies with excellent corrosion properties from stainless steel by injection molding metal powder mixtures kneaded with temporary organic binder and subsequently removing the binder from the green compact and sintering the green compact.
- the object of the invention is to provide cutlery parts for cutlery which are new, comparatively simple and economical to produce and which, in addition to the usual simple design, permit practically unlimited variety of shapes and design possibilities.
- the object of the invention is characterized in the characterizing part of the claim.
- the subclaims 2 to 11 have expedient refinements.
- cutlery parts according to the invention are comparatively less technically complex to manufacture, extremely variable in shape and - with unchanged good, partly improved usage properties - allow any new cutlery designs that are advantageous and expedient for increasingly internationalized eating habits. Cutlery parts according to the invention give every possibility for fashionable innovations and progressive designs.
- cutlery parts according to the invention use is made of powder metallurgical injection molding known for other purposes.
- This known working method involves the injection molding of metal powder mixtures pasted with temporary binders and the subsequent removal of the binder from the shaped body and sintering of the shaped body.
- MIM method metal injection molding
- cutlery parts according to the invention can also be produced with a complicated shape, for example a special decorative design of the cutlery handles or particularly “exotic” cutlery shapes.
- the starting materials for cutlery items according to the invention are commercially available.
- Metal powders of various compositions are available on the market in different particle sizes and shapes, in particular in spherical and spattery particle shapes with a relatively small particle size.
- such metal powders of up to 60 ⁇ m can be used well for cutlery items according to the invention.
- Metal powders down to 20 ⁇ m are especially recommended for the manufacture of cutlery items according to the invention.
- the special composition of the starting metal powder for the production of cutlery items according to the invention depends on the properties specifically desired for the finished cutlery items. In contrast to conventional sheet metal material, it is possible with metal powder mixtures as the starting material to achieve alloys not to be produced by melt metallurgy and thus to achieve material properties of the cutlery parts according to the invention which are adapted to the intended uses.
- the cutlery part properties for cutlery parts according to the invention can be influenced in a comparatively wide range by the composition of the metal powder mixtures used for the production.
- the metal composition is no longer restricted to alloy phases.
- Largely variable chemical compositions can be formed by powder metallurgy, and the shape, size and mixing ratio of differently shaped powder particles can influence the properties in the finished cutlery during its manufacture.
- One-piece cutlery parts according to the invention can have two or more different alloy compositions over their longitudinal extent.
- One-piece knife-cutlery parts according to the invention are particularly advantageous, the blade parts of which have a higher hardness than their shaft part.
- cutlery parts according to the invention can also have a partially desired porosity and have a decorative coating, at least partially, for example on the handle part.
- Cutlery parts according to the invention can have plastic functional and / or decorative elements that cannot be produced by sheet metal technology using industrial production methods at any desired location on the cutlery part surface. And they can be surface-treated in a manner known per se, for example provided with a detector by painting or enamelling.
- the surfaces of cutlery items according to the invention can advantageously be partially decorated according to the process described in DE-PS 12 98 384 by the applicant. You can silver in a manner known per se.
- Cutlery parts according to the invention require a small amount of material in their production because, in contrast to sheet metal production, there is practically no waste in the course of processing.
- the melting and homogenization process is controlled by the speed of the screw.
- the mixing length ie the screw length of the homogenizing extruder, calculated from the powder metal mass feed opening, was 12 D.
- the homogenized powder-binder melt then goes into the cooling extruder, which has a degassing device by means of which the solvent present in the melt has been removed.
- the binder was then heated from the demolded spoon body (green body), which consisted of 63 vol% powder metal and 37 vol% binder and was practically non-porous. For this, the green body was placed in a continuous furnace with a heating rate of 15 ° C / min.
- the binder-free spoon body was then sintered in a sintering furnace for 10 hours under a pressure of 0.01 mb at 1260 ° C. and then slowly cooled to room temperature.
- the spoon obtained in this way could be finished with conventional mechanical finishing and had an excellent appearance and very good usage properties.
- the contour edge 4 of the bowl 2 forms a curve which has cracks. This curve consists of a total of three individual curves that do not continuously adjoin each other.
- the bowl 2 has depressions 5 on its front side. As can be seen from FIG. 3, the dimensions of one depression 5a are larger than the other depression 5b. In addition, as can be clearly seen in FIG. 3, the thickness distribution of the bowl is discontinuous.
- the bowl near the contour edge 4 is thicker than in the recess part running towards the center of the bowl, and in the recess 5a, the material thickness at the contour edge 4 is weaker than in the center of the bowl.
- the bowl 2 also has an engraving 6 on its front side, which serves for decorative design, but at the same time also contributes to the identification of the different recesses 5 of the bowl 2.
- the different thickness of the spoon improves the usage properties of the spoon.
- the different recesses 5a and 5b which are delimited from one another, make it possible to separate dishes on this spoon, so that dishes received in the spoon can be wiped off separately from the lips, for example liquids and solids.
- a three-leaf opening 7 is provided in the spoon 1.
- This breakthrough is for decorative purposes. However, it can also be used to drain liquid from the bowl 2 in the particular handling position of the spoon.
- This breakthrough 7 is harmoniously followed on the one hand by the engraving 8 and on the other hand by the curved lines of the stem neck 9.
- the stem 3 offers an all-round view. It is designed on all sides with merging structured elements. From the stem neck 9, the stem 3 extends in a tapered profile 10 to the handle part 11.
- the profile 10, as illustrated in FIG. 4 has a shape in its cut surface which is irregularly formed by various curves and undercuts. Both the cross-section and the shape of the profile 10 change over the length of the profile.
- the spoon 15 shown in FIG. 5 is made in one piece from a bowl 16 and a handle 17 and, according to the material, from sintered metal made of stainless steel. It was manufactured using powder metallurgy.
- the bowl 16 is formed on one side with a straight edge 18. With such a spoon according to the invention, dishes, especially liquids, can advantageously be taken from a plate.
- the material distribution in the cross section of the bowl 16 is discontinuous. The thickness of the bowl is thinner on the straight edge 18 than on the opposite side. With this type of material distribution, the spoon is also suitable for being able to share food more easily.
- FIG. 6 shows a spoon cutlery part 19 made of stainless sintered steel and made of a bowl 20 and a stem 21 in a conical shape of a bowl with roundings on the bowl tip 22.
- this bowl 20 there are approximately straight side edges 23a and 23b on both sides, which bring about the same use effect as previously described in connection with the design according to FIG.
- FIGS. 7 to 10 Further novel creative bowl shapes which could not be produced industrially with conventional spoon cutlery parts are shown in FIGS. 7 to 10.
- the bowls 24, 26 and 29 shown in FIGS. 7, 8 and 9 have an advantageously thin bowl material, as a result of which very light cutlery parts are desirably created.
- the required stability in use is ensured according to the embodiments of FIGS. 7 and 8 by edge reinforcements 25 and 27, so that the cutlery parts according to the invention thus formed are stable in use despite the thin material thickness of the bowl due to the thickened and rounded rim of the bowl.
- the bowl 26 is designed to be pulled up laterally on one side.
- the rim 28 of the bowl does not run in one plane, which also has an advantageous effect on the properties of use.
- the light-weight cup 29 made of very thin material shown in FIG. 9 has an unreinforced, but angled cup edge 30 which ensures the required stability in use and is not unpleasant to handle and use.
- FIG. 10 shows a spoon shape of a cutlery part according to the invention made of sintered metal, which is made in one piece from the bowl 31 and the handle 33, the handle 33 already beginning at the lateral bowl edge 32 and / or the bowl 34 increasing in thickness and continuously in its part 34 facing the handle turns into a thickened stem neck.
- cutlery parts such as spoons, forks or knives in a conventional design, but consisting in one piece of sintered metal according to the invention.
- Cutlery parts according to the invention which are produced by powder metallurgy, can be finished by a polishing operation in such a way that they have the same surface quality as a previously common cutlery part, which was produced and polished from sheet metal material.
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Table Equipment (AREA)
- Powder Metallurgy (AREA)
- Baking, Grill, Roasting (AREA)
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Abstract
Description
Die Erfindung betrifft einteilige Besteckteile aus Metall, insbesondere Tafelbestecke, wie Messer, Gabel, Löffel.The invention relates to one-piece cutlery parts made of metal, in particular table cutlery, such as knives, forks, spoons.
Die bisher bekannt gewordenen und auf dem Markt befindlichen hochwertigen Besteckteile aus Stahl oder aus Neusilber, insbesondere aus rostfreiem Chrom-Nickel-Stahl oder Neusilber, müssen durch aufwendige Fertigungsverfahren hergestellt werden. Die Fertigungsverfahren zur Herstellung von Besteckteilen aus Neusilber, die eine Versilberung erhalten, und für Besteckteile aus Chrom-Nickel-Stahl sind in etwa gleich.The high-quality cutlery parts made of steel or nickel silver, which have become known and are available on the market, in particular made of rust-free chrome-nickel steel or nickel silver, have to be produced by complex manufacturing processes. The manufacturing processes for the production of cutlery made of nickel silver, which are silvered, and for cutlery made of chrome-nickel steel are roughly the same.
Gabel- und Löffel-Besteckteile werden aus Stahlblechen einstückig ausgeschnitten. Diese Vorschnitte, Brandeln genannt, müssen entgratet und richtgewalzt werden. Die Brandeln zur Herstellung von Löffel-Besteckteilen müssen im Bereich der später zu formenden Laffe auf eine geringere Materialdicke heruntergewalzt werden. Anschließend müssen Gabel- und Löffelbrandeln auf das dem Modell entsprechende Maß formbeschnitten werden. Wasch- und Glühoperationen schließen sich an, bevor dann durch den Prägearbeitsgang die Besteckteile ihre Form und ihr Dekor erhalten.Fork and spoon cutlery are cut out of sheet steel in one piece. These pre-cuts, called brandeln, have to be deburred and rolled. The burners for the production of spoon cutlery parts must be rolled down to a smaller material thickness in the area of the bowl to be formed later. Afterwards fork and spoon brandies have to be cut to size according to the model. Washing and glowing operations follow before the cutlery parts get their shape and decor through the embossing process.
Durch den Prägevorgang entsteht ein unvermeidlicher Grat an den "Hohen Kante" der Besteckteile. Dieser Grat muß abgeschliffen werden, erst dann können die Schleif- und Polierarbeitsgänge zum Einebnen der Oberfläche und zum Erzeugen des Glanzes auf der Oberfläche erfolgen. Ein Waschvorgang schließt dann die Arbeitsgänge für die Herstellung von Besteckteilen aus Chrom-Nickelstahl ab. Bei versilberten Tafelbestecken schließt sich die Versilberung an.The embossing process creates an inevitable burr on the "high edge" of the cutlery. This burr has to be sanded down, only then can the grinding and polishing operations for leveling the surface and for producing the gloss on the surface take place. On The washing process then completes the steps for the manufacture of cutlery items made of chrome-nickel steel. With silver-plated cutlery, silvering follows.
Allein diese Aufzählung zeigt schon, wie aufwendig die Herstellung ist. Die Probleme bei den einzelnen Arbeitsgängen verhindern bei der Besteckherstellung weitgehend eine Mechanisierung, weshalb hochwertige Bestecke in der Herstellung relativ teuer sind. Durch die vielen Arbeitsgänge ergibt sich auch eine lange Durchlaufzeit in der Fertigung.
Um bei Messerbesteckteilen diese in gleicher Weise dekorieren zu können, wie die dazugehörenden Löffel und Gabeln, müssen diese mehrteilig gefertigt werden. Das Messerheft wird aus zwei Halbschalen zusammengeschweißt, die vorher aus einem Blechstreifen umgeformt wurden. In dem hohlen Messerheft-Teil wird die Klinge befestigt, vorzugsweise durch Schweißen oder Einzementieren. Bei dieser Art Messer ist das Heft aus einem gut oberflächenbearbeitbaren Chrom-Nickel-Stahl hergestellt. Die Klinge besteht aber aus einem gehärteten, elastischen, rostfreien Stahl.This list alone shows how complex it is to manufacture. The problems in the individual work steps largely prevent mechanization in the manufacture of cutlery, which is why high-quality cutlery is relatively expensive to manufacture. The many work steps also result in a long lead time in production.
In order to be able to decorate cutlery parts in the same way as the associated spoons and forks, they must be made in several parts. The knife booklet is welded together from two half-shells, which were previously formed from a sheet metal strip. The blade is fastened in the hollow knife handle part, preferably by welding or cementing. With this type of knife, the handle is made from a surface-finishable chrome-nickel steel. The blade is made of hardened, elastic, stainless steel.
Um dieses aufwendige Herstellverfahren zu umgehen, ist die Herstellung von Monoblockmessern bekannt. Bei diesem Herstellverfahren wird aus einem härtbaren Chrom-Nickel-Stahl durch Walzen und/oder Schmieden ein einstückiges Messer hergestellt.In order to avoid this complex manufacturing process, the manufacture of monoblock knives is known. In this manufacturing process, a one-piece knife is produced from a hardenable chrome-nickel steel by rolling and / or forging.
Die unterschiedlichen Anforderungen, z.B. hinsichtlich mechanischer Festigkeit und Kratzfestigkeit für das Heft und andererseits die Schneidfähigkeit und Elastizität für das Klingenblatt, lassen sich bei der Verwendung einer einzigen Blechqualität aber nicht optimal erfüllen.The different requirements, for example with regard to mechanical strength and scratch resistance for the magazine and on the other hand the cutting ability and elasticity for the Blade blade, but can not be optimally fulfilled when using a single sheet quality.
Durch den Schmiede-Arbeitsgang lassen sich nicht die gleichen oder ähnlichen Dekore wie durch einen Präge-Arbeitsgang erreichen. Auch ist der Schmiedearbeitsgang sehr aufwendig, besonders weil die Oberfläche anschließend aufwendig poliert werden muß. Feine Dekore lassen sich hierbei nicht verwirklichen. Diese beim Schmieden eingebracht, würden beim Schleifarbeitsgang wieder abgeschliffen werden. Monoblockmesser können deshalb nur mit ganz einfachen Dekoren versehen werden. Die dazu passenden Löffel und Gabeln können, davon abgeleitet, auch nur einfache Dekore erhalten.The same or similar decors as with an embossing process cannot be achieved by the forging process. The forging process is also very complex, especially because the surface has to be polished afterwards. Fine decors cannot be achieved here. These introduced during forging would be ground down again during the grinding operation. Monoblock knives can therefore only be provided with very simple decors. The matching spoons and forks, derived from them, can only be given simple decors.
Bei der Herstellung von Messern, Gabeln und Löffeln ist man daher von dem Fertigungsverfahren her bei der Auswahl von Formen und Dekoren sehr eingeschränkt.In the manufacture of knives, forks and spoons, the manufacturing process is therefore very limited when it comes to the selection of shapes and decors.
Die üblichen Besteckteile zum Aufnehmen und Transportieren von Speisen vom Teller zum Mund haben sich in den letzten Hunderten von Jahren kaum geändert. Dies hängt damit zusammen, daß die Fertigungsverfahren es nicht zuließen, andere Formen kostengünstig herzustellen.The usual cutlery for picking up and transporting food from the plate to the mouth has hardly changed in the last hundreds of years. This is due to the fact that the manufacturing processes did not allow other shapes to be manufactured inexpensively.
Es besteht aber tatsächlich das Bedürfnis, Besteckteile so auszubilden, daß die Speisen leichter aus dem Teller aufgenommen und sicherer dem Mund zugeführt werden können. Außerdem besteht das Bedürfnis, die Laffe besser als bisher dem Mund anzupassen und die Stiele der Besteckteile so auszuformen, daß sie besser in der Hand liegen.
Darüber hinaus besteht der Wunsch, Bestecke mit reichhaltigen Dekoren und ausgeprägten Gestaltungsformen in industrieller Fertigung herstellen zu können.However, there is actually a need to design cutlery items in such a way that the dishes can be more easily taken from the plate and can be more safely fed to the mouth. There is also a need to adapt the bowl to the mouth better than before and to shape the handles of the cutlery so that they fit better in the hand.
In addition, there is a desire to be able to produce cutlery with rich decors and distinctive designs in industrial production.
Es ist aus JP-A-2057604 die Herstellung von Sinterkörpern mit ausgezeichneten Korrosionseigenschaften aus rostfreiem Stahl durch Spritzgießen von mit temporärem organischen Bindemittel verkneteten Metallpulvergemischen und nachfolgendes Entfernen des Bindemittels aus dem Grünling und Versintern des Grünlings bekannt.It is known from JP-A-2057604 to produce sintered bodies with excellent corrosion properties from stainless steel by injection molding metal powder mixtures kneaded with temporary organic binder and subsequently removing the binder from the green compact and sintering the green compact.
Die Anmelderin hat gefunden, daß es möglich ist, sich dieser bekannten pulvermetallurgischer Arbeitsweise zu bedienen, um einteiliges Tafelbesteck herzustellen, das über seine Längsausdehnung aus mindestens zwei unterschiedlichen Legierungszusammensetzungen besteht, deren eine eine höhere Härte hat.The applicant has found that it is possible to use this known powder-metallurgical method to produce one-piece cutlery which, over its longitudinal extent, consists of at least two different alloy compositions, one of which has a higher hardness.
Die Aufgabe der Erfindung besteht darin, nach für Bestecke neuer, vergleichsweise einfacher und wirtschaftlicher Fertigungsweise geschaffene Besteckteile zur Verfügung zu stellen, die neben der üblichen einfachen Gestaltung praktisch uneingeschränkte Formenvielfalt und gestalterische Möglichkeiten erlauben.The object of the invention is to provide cutlery parts for cutlery which are new, comparatively simple and economical to produce and which, in addition to the usual simple design, permit practically unlimited variety of shapes and design possibilities.
Der Gegenstand der Erfindung ist im Kennzeichen des Anspruchs charakterisiert. Die Unteransprüche 2 bis 11 weisen zweckmäßige Ausgestaltungen aus.The object of the invention is characterized in the characterizing part of the claim. The
Die erfindungsgemäßen Besteckteile sind vergleichsweise weniger technisch aufwendig in der Herstellung, extrem formvariabel und erlauben - bei unverändert guten, teils verbesserten Gebrauchseigenschaften - beliebige neue Besteck-Gestaltungen, wie sie für zunehmend internationalisierte Eßgewohnheiten vorteilhaft und zweckmäßig sind. Erfindungsgemäße Besteckteile geben jedwede Möglichkeit für modische Neuerungen und fortschrittliche Gestaltungen.The cutlery parts according to the invention are comparatively less technically complex to manufacture, extremely variable in shape and - with unchanged good, partly improved usage properties - allow any new cutlery designs that are advantageous and expedient for increasingly internationalized eating habits. Cutlery parts according to the invention give every possibility for fashionable innovations and progressive designs.
Für die Fertigung erfindungsgemäßer Besteckteile bedient man sich des für andere Zwecke bekannten pulvermetallurgischen Spritzgießens. Bei diesem bekannten Arbeitsverfahren handelt es sich um das Spritzgießen von mit temporären Bindemitteln angeteigten Metallpulvergemischen und das nachfolgende Entfernen des Bindemittels aus dem Formkörper und Sintern des Formkörpers. Mit dieser sogenannten MIM-Methode (metal injection moulding) lassen sich erfindungsgemäße Besteckteile auch mit komplizierter Formgebung, beispielsweise spezielle dekorative Gestaltung der Besteckgriffe oder besonders "exotische" Besteck-Formen herstellen.For the manufacture of cutlery parts according to the invention, use is made of powder metallurgical injection molding known for other purposes. This known working method involves the injection molding of metal powder mixtures pasted with temporary binders and the subsequent removal of the binder from the shaped body and sintering of the shaped body. With this so-called MIM method (metal injection molding), cutlery parts according to the invention can also be produced with a complicated shape, for example a special decorative design of the cutlery handles or particularly “exotic” cutlery shapes.
Die Ausgangsmaterialien für erfindungsgemäße Besteckteile sind im Handel erhältlich. Metallpulver verschiedener Zusammensetzung werden in unterschiedlichen Teilchengrößen und -formen, insbesondere in kugeliger und spratziger Teilchenform mit relativ kleiner Teilchengröße auf dem Markt angeboten. Insbesondere sind solche Metallpulver bis zu 60 µm für erfindungsgemäße Besteckteile gut brauchbar. Metallpulver bis zu 20 µm sind speziell für die Fertigung erfindungsgemäßer Besteckteile zu empfehlen. Die spezielle Zusammensetzung des Ausgangs-Metallpulvers für die Herstellung erfindungsgemäßer Besteckteile richtet sich nach den speziell gewünschten Eigenschaften für die fertigen Besteckteile. Anders als mit konventionellem Blechmaterial ist es mit Metallpulvergemischen als Ausgangsmaterial möglich, schmelzmetallurgisch nicht zu erzeugende Legierungen zu erzielen und damit für die vorgesehenen Verwendungszwecke angepaßte Werkstoffeigenschaften der erfindungsgemäßen Besteckteile zu erreichen.The starting materials for cutlery items according to the invention are commercially available. Metal powders of various compositions are available on the market in different particle sizes and shapes, in particular in spherical and spattery particle shapes with a relatively small particle size. In particular, such metal powders of up to 60 μm can be used well for cutlery items according to the invention. Metal powders down to 20 µm are especially recommended for the manufacture of cutlery items according to the invention. The special composition of the starting metal powder for the production of cutlery items according to the invention depends on the properties specifically desired for the finished cutlery items. In contrast to conventional sheet metal material, it is possible with metal powder mixtures as the starting material to achieve alloys not to be produced by melt metallurgy and thus to achieve material properties of the cutlery parts according to the invention which are adapted to the intended uses.
Die Besteckteil-Eigenschaften lassen sich für erfindungsgemäße Besteckteile durch Zusammensetzung der für die Fertigung eingesetzten Metallpulvergemische in vergleichsweise weiten Bereichen gezielt beeinflussen. Die Metallzusammensetzung ist nicht mehr auf Legierungsphasen beschränkt. Es lassen sich weitgehend variable chemische Zusammensetzungen pulvermetallurgisch bilden, und es läßt sich durch Gestalt und Größe und Mischungsverhältnis unterschiedlich geformter Pulverpartikel Einfluß auf die Eigenschaften im fertigen Besteckteil bei dessen Herstellung gewinnen.
Es können erfindungsgemäße einstückige Besteckteile über ihre Längsausdehnung zwei und mehr unterschiedliche Legierungszusammensetzungen aufweisen. Vorteilhaft sind insbesondere erfindungsgemäße einstückige Messer-Besteckteile, deren Klingenteil eine im Vergleich mit deren Schaftteil höhere Härte aufweisen.The cutlery part properties for cutlery parts according to the invention can be influenced in a comparatively wide range by the composition of the metal powder mixtures used for the production. The metal composition is no longer restricted to alloy phases. Largely variable chemical compositions can be formed by powder metallurgy, and the shape, size and mixing ratio of differently shaped powder particles can influence the properties in the finished cutlery during its manufacture.
One-piece cutlery parts according to the invention can have two or more different alloy compositions over their longitudinal extent. One-piece knife-cutlery parts according to the invention are particularly advantageous, the blade parts of which have a higher hardness than their shaft part.
Es können auch je nach Zusammensetzung der Metallpulver-Ausgangsgemische und je speziell gewählten Herstellungsbedingungen erfindungsgemäße Besteckteile eine teilweise gewünschte Porosität haben und dekorative Beschichtung, mindestens teilweise, z.B. am Griffteil, besitzen. Erfindungsgemäße Besteckteile können an jeder beliebigen Stelle der Besteckteil-Oberfläche blechtechnisch mit industriellen Fertigungsmethoden nicht herstellbare plastische Funktions- und/oder Dekorelemente aufweisen. Und sie können in an sich bekannter Weise oberflächenbehandelt, beispielsweise durch Lackieren oder Emaillieren mit Dektor versehen sein.
Man kann die Oberflächen erfindungsgemäßer Besteckteile vorteilhaft partiell gemäß dem in der DE-PS 12 98 384 der Anmelderin beschriebenen Verfahren dekorieren. Man kann in an sich bekannter Weise versilbern.Depending on the composition of the metal powder starting mixtures and the specially selected production conditions, cutlery parts according to the invention can also have a partially desired porosity and have a decorative coating, at least partially, for example on the handle part. Cutlery parts according to the invention can have plastic functional and / or decorative elements that cannot be produced by sheet metal technology using industrial production methods at any desired location on the cutlery part surface. And they can be surface-treated in a manner known per se, for example provided with a detector by painting or enamelling.
The surfaces of cutlery items according to the invention can advantageously be partially decorated according to the process described in
Erfindungsgemäße Besteckteile benötigen bei ihrer Fertigung einen geringen Materialeinsatz, weil im Gegensatz zur blechtechnischen Fertigung praktisch kein Abfall im Zuge der Bearbeitung anfällt.Cutlery parts according to the invention require a small amount of material in their production because, in contrast to sheet metal production, there is practically no waste in the course of processing.
Für die Herstellung eines Löffels wurde ein Metallpulvergemisch der folgenden Zusammensetzung und Korngrößenverteilung verwendet:
- 18 Teile Ferrochrom
- Korngröße 10 - 30 µm
6% Cr, 0,2% C, 0,05% Si, Rest Fe - 9 Teile Carbonyl-Nickel
- Korngröße 0,5 - 10 µm
- 73 Teile Carbonyl-Eisen
- Korngröße 0,5 - 10 µm.
- 18 parts of ferrochrome
- Grain size 10 - 30 µm
6% Cr, 0.2% C, 0.05% Si, balance Fe - 9 parts of carbonyl nickel
- Grain size 0.5 - 10 µm
- 73 parts of carbonyl iron
- Grain size 0.5 - 10 µm.
In einer Kugelmühle wurden 2,5 Vol.-% Polyethylenoxid als Dispersionshilfsmittel und 50 Vol.-% Xylol als Suspensionsmittel in das Pulver eingearbeitet. Es wurde eine gut angeteigte, zähflüssige Pulvermetallmasse erhalten. Als Bindemittel wurde Polyethylen in Granularform eingesetzt. Es wurde eine Tandem-Extruderanlage benutzt, wie sie zur Herstellung von Schaumbahnen bekannt ist und z.B. in der Fachzeitschrift "Plastverarbeitet" 32, 1981, Nr. 8, Seite 948, beschrieben ist. Der Homogenisierextruder der Tandemanlage war mit zwei im Abstand von 20 D (Schneckendurchmesser) angeordneten Einspeiseöffnungen ausgebildet. In die erste Einspeiseöffnung wurde kontinuierlich Bindemittelgranulat eingespeist, das in der Schnecke aufgeschmolzen wurde. In die zweite Einspeiseöffnung wurde kontinuierlich Pulvermetallsuspension eingespeist und in die Bindemittelschmelze eingemischt. Der Aufschmelz- und Homogenisiervorgang wird durch die Drehzahl der Schnecke gesteuert. Die Mischlänge, d.h. die Schneckenlänge des Homogenisierextruders, gerechnet ab Pulvermetallmasse-Einspeiseöffnung, betrug 12 D.
Danach gelange die homogenisierte Pulver-Bindemittel-Schmelze in den Kühlextruder, der eine Entgasungsvorrichtung aufwies, über die das in der Schmelze vorhandene Lösungsmittel entfernt wurde. Im Schneckenkopf wurde die von Lösungsmittel befreite Formmasse komprimiert und durch die Düse in eine Löffelform extrudiert. Aus dem entformten Löffelkörper (Grünling), der aus 63 Vol-% Pulvermetall und 37 Vol-% Bindemittel bestand und praktisch porenfrei war, wurde anschließend das Bindemittel ausgeheizt. Dazu wurde der Grünling in einem Durchlaufofen mit einer Aufheizrate von 15°C/Min. auf eine Temperatur von 350°C aufgeheizt und 5 Stunden auf dieser Temperatur gehalten. Die entstehenden Abbauprodukte (im wesentlichen Wasser, CO2 und geringe Mengen an Crackprodukten) wurden durch Diffusion kontinuierlich aus dem Ofenraum entfernt.
Danach wurde der bindemittelfreie Löffelkörper in einem Sinterofen 10 Stunden lang unter einem Druck von 0,01 mb bei 1260°C gesintert und anschließend auf Zimmertemperatur langsam abgekühlt.
Der so gewonnene Löffel konnte mit konventioneller mechanischer Nachbearbeitung fertiggestellt werden und hatte ein hervorragendes Aussehen und sehr gute Gebrauchseigenschaften.2.5% by volume of polyethylene oxide as dispersion aid and 50% by volume of xylene as suspending agent were incorporated into the powder in a ball mill. A well-pasted, viscous powder metal mass was obtained. Polyethylene in granular form was used as the binder. A tandem extruder system was used, as is known for the production of foam webs and is described, for example, in the trade magazine "Plastververarbeitung" 32, 1981, No. 8, page 948. The homogenizing extruder of the tandem system was designed with two feed openings arranged at a distance of 20 D (screw diameter). Binder granulate was continuously fed into the first feed opening and melted in the screw. Powder metal suspension was fed continuously into the second feed opening and mixed into the binder melt. The melting and homogenization process is controlled by the speed of the screw. The mixing length, ie the screw length of the homogenizing extruder, calculated from the powder metal mass feed opening, was 12 D.
The homogenized powder-binder melt then goes into the cooling extruder, which has a degassing device by means of which the solvent present in the melt has been removed. In the snail's head was solvent released molding compound is compressed and extruded through the nozzle into a spoon shape. The binder was then heated from the demolded spoon body (green body), which consisted of 63 vol% powder metal and 37 vol% binder and was practically non-porous. For this, the green body was placed in a continuous furnace with a heating rate of 15 ° C / min. heated to a temperature of 350 ° C and kept at this temperature for 5 hours. The resulting breakdown products (essentially water, CO 2 and small amounts of cracked products) were continuously removed from the furnace space by diffusion.
The binder-free spoon body was then sintered in a sintering furnace for 10 hours under a pressure of 0.01 mb at 1260 ° C. and then slowly cooled to room temperature.
The spoon obtained in this way could be finished with conventional mechanical finishing and had an excellent appearance and very good usage properties.
In der beigefügten Zeichnung sind erfindungsgemäße Besteckteile beispielsweise veranschaulicht. Es zeigen:
- Fig. 1
- eine Draufsicht auf eine Ausführungsform eines Löffel-Besteckteils,
- Fig. 2
- eine Seitenansicht des Löffel-Besteckteils der Fig. 1,
- Fig. 3
- einen Schnitt nach I-I der Fig. 1,
- Fig. 4
- einen Schnitt nach II-II der Fig. 1,
- Fig. 5
- eine Draufsicht auf eine andere Ausführungsform eines Löffel-Besteckteils,
- Fig. 6
- eine Draufsicht auf eine weitere Ausführungsform eines Löffel-Besteckteils,
- Fig. 7
- im Querschnitt eine Laffe-Gestaltung eines Löffel-Besteckteils,
- Fig. 8
- im Längsschnitt eine andere Laffe-Gestaltung eines Löffel-Besteckteils,
- Fig. 9
- im Querschnitt eine weitere Laffe-Gestaltung eines Löffel-Besteckteils, und
- Fig. 10
- im Längsschnitt eine Laffe-Stiel-Gestaltung an einem Löffel-Besteckteil.
- Fig. 1
- a plan view of an embodiment of a spoon cutlery part,
- Fig. 2
- 2 shows a side view of the spoon cutlery part of FIG. 1,
- Fig. 3
- 2 shows a section according to II of FIG. 1,
- Fig. 4
- 2 shows a section according to II-II of FIG. 1,
- Fig. 5
- a plan view of another embodiment of a spoon cutlery part,
- Fig. 6
- a plan view of a further embodiment of a spoon cutlery part,
- Fig. 7
- in cross-section a spoon cutlery part,
- Fig. 8
- in longitudinal section another bowl design of a piece of spoon cutlery,
- Fig. 9
- in cross-section another bowl design of a spoon cutlery part, and
- Fig. 10
- longitudinal section of a spoon-shaped handle on a piece of cutlery.
In den Figuren 1 bis 4 ist ein erfindungsgemäßer, aus Laffe 2 und Stiel 3 einstückig aus Sintermetall bestehender Löffel 1 aus rostfreiem Stahl illustriert. Der Löffel ist pulvermetallurgisch hergestellt. Die Laffe 2 ist - wie aus den Fig. 1 und 2 ersichtlich - unsymmetrisch zur Längs- und Querachse ausgebildet. Die Umrißkante 4 der Laffe 2 bildet eine Kurve, die Sprünge aufweist. Diese Kurve besteht aus insgesamt drei Einzalkurven, die nicht kontinuierlich aneinander grenzen. Die Laffe 2 weist auf ihrer Vorderseite Vertiefungen 5 auf.
Wie aus Fig. 3 ersichtlich, ist die eine Vertiefung 5a in ihren Abmessungen größer als die andere Vertiefung 5b. Außerdem ist, wie deutlich in Fig. 3 erkennbar, die Dickenverteilung der Laffe diskontinuierlich. Bei der Vertiefung 5b ist die Laffe in der Nähe der Umrißkante 4 dicker als in dem zur Laffenmitte laufenden Vertiefungsteil, und bei der Vertiefung 5a ist die Materialdicke an der Umrißkante 4 schwächer ausgebildet als in der Mitte der Laffe. Die Laffe 2 weist, wie Fig. 1 zeigt, weiterhin auf ihrer Vorderseite eine Gravur 6 auf, die zur dekorativen Gestaltung dient,aber gleichzeitig auch zur Kennzeichnung der unterschiedlichen Vertiefungen 5 der Laffe 2 beiträgt.
Die unterschiedliche Dicken-Gestaltung der Laffe verbessert die Gebrauchseigenschaften des Löffels. Durch die unterschiedlichen, gegeneinander abgegrenzten Vertiefungen 5a und 5b ist es möglich, Speisen auf diesem Löffel zu separieren, so daß im Löffel aufgenommene Speisen getrennt von den Lippen abgestreift werden können, z.B. etwa Flüssigkeiten und Feststoffe.1 to 4 illustrate an
As can be seen from FIG. 3, the dimensions of one
The different thickness of the spoon improves the usage properties of the spoon. The
Im Bereich des Übergangs von Laffe 2 zu Stiel 3 ist ein dreiflügliger Durchbruch 7 in dem Löffel 1 vorgesehen. Dieser Durchbruch dient dekorativen Zwecken. Er kann jedoch auch dazu benutzt werden, in der bestimmten Handhabungslage des Löffels Flüssigkeit von der Laffe 2 ablaufen zu lassen. Diesem Durchbruch 7 schließt sich harmonisch einerseits die Gravur 8 an, andererseits die geschwungenen Linien des Stielhalses 9. Der Stiel 3 bietet eine Rundumansicht. Er ist allseitig mit ineinander übergehenden strukturierten Elementen ausgebildet. Vom Stielhals 9 aus verläuft der Stiel 3 in einem sich verjüngenden Profil 10 bis zum Griffteil 11. Das Profil 10 weist, wie in Fig. 4 veranschaulicht, in seiner Schnittfläche eine Form auf, die unregelmäßig durch verschiedene Kurven und Hinterschnitte gebildet ist. Uber die Länge des Profils andert sich sowohl der Querschnitt als auch die Form des Profils 10. Etwa in der Mitte des Stieles 3 verdickt sich dieser in mehreren Sprüngen zum Griffteil 11. Das Griffteil 11 vergrößert sich in seinem Querschnitt diskontinuierlich bis zu dem Stielende 13. Das Profil 12 des Griffteils 11 ergibt sich bis zum Stielende 13 hin durch einen zur Stiellängsachse unter einem Winkel verlaufenden Schnitt abgeschrägt. Im Griffteil 11 sind, wie in Fig. 2 veranschaulicht, ovale Durchbrüche 14 vorgesehen.In the area of the transition from
Der in Fig. 5 dargestellte Löffel 15 besteht einstückig aus Laffe 16 und Stiel 17 und materialgemäß aus Sintermetall aus rostfreiem Stahl. Er wurde pulvermetallurgisch hergestellt. Die Laffe 16 ist einseitig mit einer geraden Kante 18 ausgebildet. Mit einem derartigen erfindungsgemäßen Löffel lassen sich Speisen, besonders Flüssigkeiten, vorteilhaft aus einem Teller aufnehmen. Die Materialverteilung im Querschnitt der Laffe 16 ist diskontinuierlich. Die Laffenstärke ist an der geraden Kante 18 dünner als an der ihr gegenüberliegenden Seite. Mit dieser Art der Materialverteilung ist der Löffel auch geeignet, Speisen leichter teilen zu können.The
In Fig. 6 ist ein erfindungsgemäß einstückig aus rostfreiem Sinterstahl bestehendes Löffel-Besteckteil 19 aus Laffe 20 und Stiel 21 in konisch verlaufender Laffenform mit Abrundungen an der Laffenspitze 22 dargestellt. Bei dieser Laffe 20 sind beidseits etwa gerade verlaufende Seitenkanten 23a und 23b vorhanden, die den gleichen Gebrauchseffekt bewirken, wie zuvor im Zusammenhang mit der Gestaltung gemäß Figur 5 beschrieben.FIG. 6 shows a
Weitere neuartige gestalterische Laffen-Formen, die bei herkömmlichen Löffel-Besteckteilen industriell nicht herstellbar waren, sind in den Figuren 7 bis 10 dargestellt.Further novel creative bowl shapes which could not be produced industrially with conventional spoon cutlery parts are shown in FIGS. 7 to 10.
Die in den Figuren 7, 8 und 9 gezeigten Laffen 24, 26 und 29 weisen ein vorteilhaft dünnes Laffenmaterial auf, wodurch wünschenswert sehr leichte Besteckteile geschaffen sind. Die erforderliche Gebrauchsstabilität wird gemäß den Ausführungsformen der Figuren 7 und 8 durch Randverstärkungen 25 und 27 sichergestellt, so daß die so ausgebildeten erfindungsgemäßen Besteckteile trotz der dünnen Materialstärke der Laffe infolge des verdickten und verrundeten Laffenrandes im Gebrauch stabil sind. Bei der Ausführungsform der Figur 8 ist die Laffe 26 an einer Seite seitlich hochgezogen ausgebildet. Der Laffenrand 28 verläuft nicht in einer Ebene, was sich ebenfalls vorteilhaft auf die Gebrauchseigenschaften auswirkt. Die in Figur 9 dargestellte leichtgewichtige Laffe 29 aus sehr dünnem Material hat einen unverstärkten, jedoch abgewinkelt geformten Laffenrand 30, der die erforderliche Gebrauchsstabilität sichert und bei der Handhabung und Benutzung nicht unangenehm ist.The
In Figur 10 ist eine einstückig aus Laffe 31 und Stiel 33 bestehende Löffel-Form eines erfindungsgemäßen Besteckteils aus Sintermetall gezeigt, wobei der Stiel 33 bereits am seitlichen Laffenrand 32 beginnt und/oder die Laffe in ihrem dem Stiel zugewandten Teil 34 an Dicke zunimmt und kontinuierlich in einen verdickten Stielhals übergeht. Durch diese Maßnahme wird die Biegefestigkeit des Besteckteils an der kritischen Stelle des Stielhalses heraufgesetzt, eine besonders gebrauchsstabile Ausführungsform.FIG. 10 shows a spoon shape of a cutlery part according to the invention made of sintered metal, which is made in one piece from the
Die in der Zeichnung für Löffel-Besteckteile illustrierten Gestaltungsmerkmale lassen sich selbstverständlich mit erfindunsgemäßen Gabel- und Messer-Besteckteilen vergleichbar verwirklichen.The design features illustrated in the drawing for spoon cutlery parts can of course be realized in a comparable manner to fork and knife cutlery parts according to the invention.
Ebenso ist es möglich und materialmäßig sowie herstellungsmäßig vorteilhaft, Besteckteile, wie Löffel, Gabel oder Messer in herkömmlicher Gestaltung, aber einstückig erfindungsgemäß aus Sintermetall bestehend vorzusehen.It is also possible and advantageous in terms of material and manufacture to provide cutlery parts, such as spoons, forks or knives in a conventional design, but consisting in one piece of sintered metal according to the invention.
Erfindungsgemäße Besteckteile, die pulvermetallurgisch hergestellt sind, können durch einen Polierarbeitsgang abschließend so bearbeitet sein, daß sie gleiche Oberflächenbeschaffenheit aufweisen wie ein bisher übliches Besteckteil, welches durch Umformen aus Blechmaterial hergestellt und poliert wurde.Cutlery parts according to the invention, which are produced by powder metallurgy, can be finished by a polishing operation in such a way that they have the same surface quality as a previously common cutlery part, which was produced and polished from sheet metal material.
Claims (11)
- Article of steel produced by injection-moulding of metallic powder mixtures, kneaded With a temporary organic bincer, and subsequent removal of the binder from the green part and sintering the green part, characterized in that said article means a one-piece eating utensil (1) consisting over its longitudinal extend of at least two differing alloy compositions with one of said alloy compositions exhibiting a higher hardness.
- Eating utensil (1) according to claim 1 wherein one of the alloy compositions is hardenable.
- Eating utensil (1) according to claim 1, charaterized in that the utensil surface, at any desired location, is provided with plastic fuctional elements (5a, 5b) and/or with decorative design elements (6, 7, 8).
- Eating utensil (1) according to any of claims 1 through 3, which is conventially surface-treated and/or decorated, at least partially.
- Eating utensil (1) according to claim 4, which is at least partially enameled.
- Spoon eating utensil (15) according to any of claims 1 through 5, characterized in that the bowl (16) is designed on one side with a straight edge (18).
- Spoon eating utensil (19) according to any of claims 1 through 5, charaterized in that said spoon has a conically extending bowl (20) with rounded portions on the bowl tip (22), and has on both sides partially linearly extending lateral edges (23a and 23b).
- Spoon eating utensil (1) according to any of claims 1 through 7, charaterized in that the bowl rim is designed with a reinforcement (25, 27).
- Spoon eating utensil (1) according to any of claims 1 through 8, charaterized in that the bowl rim (28) is fashioned, at least on one side of the bowl (26), to be drawn upward laterally curved.
- Spoon-(1) and fork eating utensil according to any of claims 1 through 9, charaterized in that the bowl (31) continuously increases in thickness passing over into a thickened handle neck (33).
- Spoon-(15) and fork eating utensil according to any of claims 1 through 10, charaterized in that the thickness of the bowl (16), as seen in cross section, is asymmetrical, decreasing from one side towards an opposite side of the bowl.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4124393A DE4124393A1 (en) | 1991-07-23 | 1991-07-23 | METAL CUTLERY PARTS |
DE4124393 | 1991-07-23 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0524710A2 EP0524710A2 (en) | 1993-01-27 |
EP0524710A3 EP0524710A3 (en) | 1994-03-02 |
EP0524710B1 true EP0524710B1 (en) | 1997-01-29 |
Family
ID=6436831
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92250179A Expired - Lifetime EP0524710B1 (en) | 1991-07-23 | 1992-07-09 | Metallic cutlery |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0524710B1 (en) |
JP (1) | JPH05230506A (en) |
AT (1) | ATE148318T1 (en) |
DE (3) | DE4124393A1 (en) |
DK (1) | DK0524710T3 (en) |
ES (1) | ES2099201T3 (en) |
GR (1) | GR3023273T3 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4302967C1 (en) * | 1993-02-03 | 1994-06-01 | Elektro Gas Armaturen | Enamelling of porous sintered ferrous metal part - esp. for surface protection of gas burner cover |
SE503422C2 (en) * | 1994-01-19 | 1996-06-10 | Soederfors Powder Ab | Process when making a composite product of stainless steel |
EP0701875B1 (en) | 1994-09-15 | 2000-06-07 | Basf Aktiengesellschaft | Process for preparing metallic articles by injection moulding |
US6309573B1 (en) * | 1999-05-19 | 2001-10-30 | Rutgers, The State University Of New Jersey | Low pressure injection molding of flat tableware from metal feedstocks |
GB0313017D0 (en) * | 2002-08-10 | 2003-07-09 | Emtelle Uk Ltd | Signal transmitting cable |
DE102009004675A1 (en) | 2009-01-12 | 2010-07-15 | Carl Mertens Besteckfabrik Gmbh | Method for manufacturing cutlery with pattern, involves cutting out, particularly die cutting of piece from sheet having predetermined sheet thickness |
JP2011030729A (en) * | 2009-07-31 | 2011-02-17 | Combi Corp | Spoon for ingesting liquid |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH148057A (en) * | 1930-02-27 | 1931-07-15 | Kramer Paul | Table set. |
FR764140A (en) * | 1933-11-22 | 1934-05-15 | Jakob Bischoff Aktien Ges | Utility spoon for all purposes |
CH216263A (en) * | 1940-08-08 | 1941-08-15 | Niklaus Waldesbuehl Paul | Spoon. |
FR1426656A (en) * | 1965-03-12 | 1966-01-28 | Neuzeughammer Ambosswerk Messe | Mouth spoon |
DD110782A1 (en) * | 1974-04-29 | 1975-01-12 | ||
US4425711A (en) * | 1979-06-29 | 1984-01-17 | Wood Geraldine E | Double-ended doubly-concaved baby spoon |
JPS6048472B2 (en) * | 1981-07-09 | 1985-10-28 | 東レ株式会社 | Zirconia sintered body |
DE3135034C2 (en) * | 1981-09-04 | 1984-02-23 | Degussa Ag, 6000 Frankfurt | Material for jewelry and articles of daily use and process for its manufacture |
JPS5883914A (en) * | 1981-11-16 | 1983-05-19 | 東レ株式会社 | Tablewear |
EP0520465B1 (en) * | 1991-06-27 | 1996-12-27 | Kyocera Corporation | Sintered alloy of golden color |
-
1991
- 1991-07-23 DE DE4124393A patent/DE4124393A1/en active Granted
- 1991-07-23 DE DE9116669U patent/DE9116669U1/de not_active Expired - Lifetime
-
1992
- 1992-06-29 JP JP4171161A patent/JPH05230506A/en active Pending
- 1992-07-09 DK DK92250179.6T patent/DK0524710T3/en active
- 1992-07-09 EP EP92250179A patent/EP0524710B1/en not_active Expired - Lifetime
- 1992-07-09 AT AT92250179T patent/ATE148318T1/en not_active IP Right Cessation
- 1992-07-09 DE DE59207977T patent/DE59207977D1/en not_active Expired - Fee Related
- 1992-07-09 ES ES92250179T patent/ES2099201T3/en not_active Expired - Lifetime
-
1997
- 1997-04-24 GR GR970400934T patent/GR3023273T3/en unknown
Also Published As
Publication number | Publication date |
---|---|
DE4124393C2 (en) | 1993-05-27 |
EP0524710A3 (en) | 1994-03-02 |
ES2099201T3 (en) | 1997-05-16 |
DE9116669U1 (en) | 1993-06-17 |
GR3023273T3 (en) | 1997-07-30 |
DE4124393A1 (en) | 1993-01-28 |
DK0524710T3 (en) | 1997-07-21 |
ATE148318T1 (en) | 1997-02-15 |
DE59207977D1 (en) | 1997-03-13 |
EP0524710A2 (en) | 1993-01-27 |
JPH05230506A (en) | 1993-09-07 |
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