EP0515669A1 - Plattenwärmetauscher. - Google Patents

Plattenwärmetauscher.

Info

Publication number
EP0515669A1
EP0515669A1 EP92903209A EP92903209A EP0515669A1 EP 0515669 A1 EP0515669 A1 EP 0515669A1 EP 92903209 A EP92903209 A EP 92903209A EP 92903209 A EP92903209 A EP 92903209A EP 0515669 A1 EP0515669 A1 EP 0515669A1
Authority
EP
European Patent Office
Prior art keywords
enclosure
fluid
exchanger according
collector circuit
external
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP92903209A
Other languages
English (en)
French (fr)
Other versions
EP0515669B1 (de
EP0515669B2 (de
Inventor
Claude Jullien
Yves Couillard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alfa Laval Packinox SAS
Original Assignee
Packinox SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9403501&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0515669(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Packinox SA filed Critical Packinox SA
Publication of EP0515669A1 publication Critical patent/EP0515669A1/de
Publication of EP0515669B1 publication Critical patent/EP0515669B1/de
Application granted granted Critical
Publication of EP0515669B2 publication Critical patent/EP0515669B2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D9/0006Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the plate-like or laminated conduits being enclosed within a pressure vessel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/007Auxiliary supports for elements
    • F28F9/0075Supports for plates or plate assemblies
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2265/00Safety or protection arrangements; Arrangements for preventing malfunction
    • F28F2265/26Safety or protection arrangements; Arrangements for preventing malfunction for allowing differential expansion between elements

Definitions

  • the present invention relates to the design of plate type heat exchangers. These are distinguished in general from tubular exchangers by the fact that the fluids in a heat exchange situation circulate longitudinally on either side of plates arranged contiguously parallel to each other.
  • heat exchangers of this type include a bundle of parallel planar plates which are made of thin sheets the more often made of stainless steel, provided with corrugations by which they are in contact with one another and by which they organize the circulation of fluids longitudinally from one end to the other of the exchanger (generally against the current each other), creating turbulence favorable to the heat exchanges which take place between the fluids through each plate.
  • the plates are welded together by means of tongues or frames forming spacers which maintain the spacing between two successive plates.
  • the stack of plates is framed by two relatively thick sheets, which transfer the weight of the beam onto a support.
  • the sheets of thick and mechanically resistant which surround the bundle of heat exchange plates are used to support the assembly in a chamber's Resistance to pressure fluids or ferrule, to which they are rigidly connected in the middle part of the exchanger, by lateral hooking plates.
  • the invention proposes a plate exchanger corresponding to a new way of assembling the bundle in its enclosure which better meets the different needs of the practice than previous plate exchangers, in particular in terms of manufacturing convenience, costs and operational safety.
  • a plate type exchanger comprising a bundle of heat exchange plates between fluids circulating between them which is disposed inside a pressure resistance enclosure, characterized in that it comprises means rigid suspension of said bundle to said enclosure at at least a first collector circuit comprising a first connection box at the upper end of the bundle and guiding a first of said fluids between this end and the outside of the enclosure.
  • the beam is now suspended according to the invention at the upper collector of the exchanger, which considerably limits the thickness of the sheets framing the beam, since they no longer have to take up suspension of the assembly. This also prevents the appearance of forces tending to spread these sheets in the lower part of the beam.
  • said first collector circuit comprises a conduit constituting the suspension means by the fact that it is in rigid connection with said connection box to suspend the latter from an upper cap closing the pregnant.
  • said suspension means comprise at least a first rigid connection plate of the first connection box with a ferrule limiting the enclosure around the beam.
  • connection box is made of thicker sheets than the plates constituting the bundle to use it for the suspension thereof.
  • the exchanger further comprises a second collector circuit comprising a second connection box at the upper end of said bundle e guiding a second of said fluids between this end outside of said enclosure.
  • connection boxes at the upper end of the bundle are produced in the form of substantially semi-cylindrical boxes mounted axially in one another.
  • the fluid collecting circuits as defined above are designed and dimensioned as a function of the properties of the fluids which they have to convey.
  • said collector circuits are intended to receive respectively for the internal collector a fluid to be extracted from the exchanger at a relatively low pressure, and said external collector to receive a fluid at relatively high pressure close to the pressure of this fluid filling the enclosure at its entry into 1 * exchanger.
  • they are advantageously intended to respectively receive fluids of neighboring temperatures as follows - from the efficiency characteristics of the device.
  • said first collector circuit constitutes an external collector circuit in which said second collector circuit constitutes an axially mounted circuit - - internal collector; and in that said first connection box for the first fluid contains axially said second connection box for the second fluid, the suspension of the beam being ensured by the conduit of the first external collector ensuring the guiding of the first fluid at the crossing of the cap upper closing the enclosure and being coaxial with an internal conduit d second collector ensuring the guiding of the second fluid the crossing of the upper cap.
  • the first fluid is the relatively high pressure fluid and the second fluid is the relatively low pressure fluid.
  • said first collector circuit constitutes an internal collector circuit mounted axially in said second collector circuit constituting an external collector circuit; and in that said second connection box for the second fluid contains axially said first connection box for the first fluid, the suspension of the beam being ensured by means of an external conduit ensuring the guidance of the second fluid at the crossing of the upper cap closing the enclosure and rigidly connected on the one hand to the upper cap and on the other hand to the conduit of the internal collector ensuring the guiding of the first fluid through the upper cap.
  • the first fluid is the relatively low pressure fluid and the second fluid is the relatively high pressure fluid.
  • Said second collector circuit constitutes an internal collector circuit mounted axially inside said first collector circuit constituting an external collector circuit for the first fluid;
  • said suspension means comprise at least two connecting plates having approximately the shape of a half-disc each linked rigidly by its rectilinear trench on a flat face which constitutes an end of the semi-cylinder formed by the first external connection box;
  • suspension means comprise at least two support plates having approximately the shape of a half-disc welded by their respective circular edges on the internal face of the shell limiting the enclosure of the bundle, said support plates being intended to receive the plates connecting linked to said first external connection box;
  • Said collector circuits each comprise a conduit ensuring the guiding of the fluid which they convey through a top cap closing the enclosure, each conduit being linked to a corresponding connection box by means of a metal bellows constituting an expansion compensator;
  • Each connecting plate comprises an oblong hole intended for the through passage of means for fixing to said support plate on which it rests and allowing the adjustment of the centering of the beam;
  • said fixing means preferably consisting of a nut / bolt assembly passing through said oblong hole and a circular hole formed in said support plate;
  • said collector circuits respectively comprise an external conduit and an internal conduit made up of coaxial cylindrical tubes and ensuring the guiding of the fluids through a upper cap closing the enclosure;
  • said external collector circuit includes a lateral connection outside the enclosure on said conduit external and said internal conduit is rigidly and sealingly connected to a cover closing said external conduit which it passes axially; said collector circuits are intended to respectively receive a first fluid to be extracted from the relatively high pressure exchanger, filling said enclosure at its entry into the exchanger, and a second fluid at relatively low pressure;
  • collector circuits are intended to receive respectively a first fluid at a relatively low temperature in the heat exchange, and a second fluid at a relatively high temperature;
  • the external and internal conduits each in at least two tubular sections welded end to end for the first form of realization or by means of an expansion bellows for the second preferred embodiment, an external section adjoining the enclosure being made of the same material as the latter and an internal section adjoining the bundle being made of the same material as the latter.
  • the internal section of the external conduit is preferably constituted, for at least part of its length, by two semi-cylindrical walls which are welded together on generators opposite to the manufacture of the exchanger, after the internal conduit is butted .
  • the pressure conditions prevailing on either side of the walls of each of the collecting circuits advantageously lead to the suspension of the beam being mechanically internal collector circuit whose walls are relatively thick, while the construction of the external collector circuit uses relatively thin walls having the role of sealing and not of mechanical suspension.
  • the fluid supply and extraction manifold circuits can be produced in any way in themselves conventional.
  • the exchanger according to the invention furthermore comprises means for centering the heat exchange bundle with respect to a cylindrical shell limiting the external enclosure, which are furthermore dimensioned so as to be able to support the bundle outside operating in horizontal longitudinal position.
  • the present invention has significant advantages in the manufacture of plate heat exchangers and in the safety of their operation.
  • FIGS. 1 to the attached drawings are illustrated by FIGS. 1 to the attached drawings, among which:
  • FIG. 1 schematically shows the exchanger seen in longitudinal section along the diametrical plane A-A of Figure 2 according to a first embodiment
  • FIG. 2 shows a schematic cross-section of the exchanger according to this first embodiment
  • FIG. 3 shows schematically another longitudinal section, along B-3 of Figure 2, where we have - made only show an upper part of the exchanger.
  • FIG. 4 shows a perspective view of a second preferred embodiment of the invention.
  • the exchanger of the invention essentially comprises a bundle 1 of rectangular plates 2 for heat exchange between two fluids which pass longitudinally through the bundle, and an external enclosure 3 " resistant to the pressure of the fluids, which encloses the bundle.
  • the exchanger is intended to operate in a vertical longitudinal position, the fluid inlets and outlets being located at the two longitudinally opposite ends of the exchanger, at the top and at the bottom of the external enclosure. However, it is intended that it can be easily transported in a horizontal position.
  • a first of these fluids is the charge; consisting of napthta, and hydrogen it represents the relatively cold fluid which must be preheated by the effluent in the exchanger.
  • the second is formed by the relatively hot effluent. It also happens that the charge of naphtha reaches the exchanger under a higher pressure than the effluent; this is why it penetrates, in the lower part of the exchanger, directly into the enclosure 3 5 which it fills, before crossing the beam.
  • the enclosure, or grille 3 is essentially limited by a cylindrical shell 10, enveloping the entire beam 1 over its entire length, and by two caps ser: i- spherical 4 and 5 which close the shell at the top and bottom of the exchanger. Given the individual dimensions of the plates 2 and their number, the parallelepipedic beam 1 is contained axially in the shell 3- The collecting, supply and extraction circuits guide the two fluids between the beam and the exterior of the enclosure cross the grille 3 as will be described later.
  • the figures also show a pipe 8 which comprises the lower cap 5 for introducing into the enclosure a recycling gas, and a manhole 9 closed by a plate 40, which serves to penetrate into the enclosure for mounting the elements. internal the exchanger and its maintenance.
  • the production of the actual heat exchange bundle is in accordance with that which has been described in French patent application n ° 88 13883, to which reference will be made in particular as regards the production of the plates 2, as well as that of the orifices for the inlet and outlet of fluids at the ends of the bundle.
  • the plates 2 appear by their edge in FIG. 2, on a scale which does not allow it to be seen how they rest on each other by undulations which simultaneously have the role of providing passages between plates guiding the fluids towards the beam inlet or outlet manifolds.
  • These plates are manufactured with their corrugations by explosion forming of thin sheets of stainless metal. They are stacked together to form the bundle, with the interposition of metal tabs welded on their edges as spacers closing the passages between plates on two opposite longitudinal faces 12 and 13 of the bundle 1.
  • the beam On its two other longitudinal faces, the beam is surrounded by two thick sheets 6 and 7, usually made of stainless steel, so as to constitute a frame for mechanically holding the stack of plates.
  • the thin sheets constituting the plates 2 have a thickness of the order of 1 mm.
  • the thick sheets 6 and 7 have a thickness of 35 mm while in the prior art a thickness of 10 mm was necessary because these plates had to take up all the mechanical forces and support the whole of the vertical beam in the ferrule of grille.
  • the exchanger described does not include any truly analogous support piece which is sufficiently resistant and welded both to the sheets 6 and 7 and to the shell 10 to connect them in a rigid structure resistant to the operating conditions.
  • spacers such as those shown in 18 and 19, constituted for example in the form of perforated or star grid, which serve to support the beam 1 in the shell of calender 10, either when it is in the vertical position and in operation, but only when it is in the horizontal position for transporting the complete exchanger. In operation, these spacers simply play the role of centering members, retaining the beam in the axis of the enclosure 3.
  • the bundle is carried suspended from the enclosure 3 at the head of the exchanger, by fluid collecting circuits.
  • the entire exchanger is supported by a base ncn represented on which the enclosure 3 rests by brackets 16 and 17, welded to it at the level of the circular weld connecting the lower cap 5 to the shell 10 in a sealed manner.
  • the load constituting the high pressure fluid enters the bottom of the exchanger directly into the enclosure 3 by a pipe 11. It fills this enclosure and it is taken up by the passages between plates at the bottom of the beam.
  • a first collector comprising a first connection box 21, of semi-cylindrical annular shape, connected to an external duct 22 which crosses the upper calender shell 4 axially in a leaktight manner and opens out outside the exchanger by a lateral connection 14 oriented at an angle, provided at the end with a flange suitable for its connection to pipes no longer part of the exchanger.
  • the conduit 22, the nozzle 14 and the box 21 together form what is considered here as constituting an external collector supply circuit of the exchanger for the charge of naphtha.
  • a second upper connection box analog 23 is welded to the beam at its upper end to ensure the supply of the effluent beam from an axial internal conduit 26 which guides the effluent through the upper cap 4 by forming an internal collecting circuit.
  • the conduit 35 of the effluent extraction collector circuit located in the lower part of the exchanger, is interrupted by a thermal expansion compensator, here constituted by a metal bellows 25.
  • a thermal expansion compensator here constituted by a metal bellows 25.
  • the embodiment is completely different in the upper part of the exchanger, as it appears in FIGS. 1 and 2.
  • the internal effluent collecting circuit comprising the second box this upper connection 23 and the internal conduit 26 is disposed axially at inside the external load supply collector circuit, at the level of the first upper connection box 21 and of the axial external duct 22.
  • a rigid assembly for hanging the beam 1 from the enclosure 3 by its end is thus formed upper, the effluent collector circuit, or internal circuit, being rigidly linked to the load collecting circuit, or external circuit, which is itself rigidly linked to the enclosure 3.
  • the rigid connections in question are produced in practice by welding, which ensures simultaneously sealing against fluids.
  • connection boxes and the sections of the external conduit 22 and the internal conduit 26 which are located inside the enclosure 3 ′′ under the upper cap 4, are advantageously made of stainless steel like the elements of the bundle itself.
  • the thickness of their walls can be relatively small, for example 25 mm for the internal collector and 4 to 6 mm for the external collector.
  • the conduits also comprise sections 27 and 28, called external sections, respectively welded end to end to the corresponding internal sections, which are inside the enclosure 3. It is at these sections 27 and 28 that the crossing takes place. of the cap 4, with sealed weld.
  • Their walls are thicker and they are made for example of chrome steel like the walls of the enclosure.
  • the section 28 of the internal manifold 29 passes through a lid closing the external collector beyond the stitching 14 and ends on the outside by a flange of one coupling 31-
  • the internal collector with its associated connection box which mechanically supports the beam to the cover 29 closing the external collector.
  • the walls of the section of the external collector inside the enclosure 3 in this case has a thickness substantially smaller than that of the walls of the internal collector.
  • the internal section of the conduit 22 is formed over a part of its length, between the transverse lines 3 and 33, by two semi-cylindrical connecting pieces which are welded on site to close the corresponding circuit.
  • the weld zone between two sections of different metallic materials, on the conduits of the internal and external collector circuits, can have its position calculated precisely in each particular application, according to the operating conditions envisaged. In all cases it will be noted that the temperature differences to which the walls of the circuits are subjected are smaller than in the assemblies of the prior art.
  • the elements of the collector circuits which have been designated above by the term of conduit are produced essentially in the form of cylindrical tubes, in particular at the level of the passage of the enclosure 3 > to which they are sealed.
  • FIG. 4 A preferred embodiment of the invention illustrated by FIG. 4 will be described below.
  • the suspension means illustrated in FIG. 4 comprise on the two flat faces 15 and 20 each constituting one end of the half-cylinder formed by the first external connection box 21, a connection plate 30 having approximately the shape of a half disc to adapt to the curvature of the ferrule 10.
  • connecting plates 30 are welded by their straight edge and the edge of stiffening brackets 34 on these flat faces 15 and 20.
  • These connecting plates are intended to rest on support plates 36 of similar shape, themselves welded by their respective circular section and the stiffening bracket section 37 on the internal face of the ferrule 10.
  • connection plates 30 to the support plates 36 is effected by means of one or more bolt / screen assemblies 41 " passing through the latter. Provision may be made, in order to facilitate the centering of the beam, to pass through the connection plates 30 by the fixing means is effected through an oblong hole 42 making it possible to adjust the position on the support plates 36.
  • the oblong holes 42 of the two connection plates 30 may be in directions perpendicular to one another. other to allow adjustment in both directions.
  • conduits 22 and 26 respectively guiding the first fluid from the external connection box 21 to the outside of the enclosure 3 and the second fluid from the outside of the enclosure 3 to the internal connection box 23, are no longer coaxial.
  • the sections 27 and 28 each end with a coupling flange 31.
  • the lower part of the exchanger is not modified compared to the first embodiment.
  • the exchanger is supported by a base on which the enclosure 3 rests by brackets not shown and the bundle is supported when the exchanger is in a horizontal position for transport by not shown spacers.
  • the beam support forces 1 are reported to the enclosure 3 via the connection boxes which are preferably welded by their edges constituting the longitudinal edges of the semi-cylinders on the edges plates 2 constituting the bundle 1.
  • each plate 2 can be individually linked to the longitudinal edges of the internal connection box 23 which are perpendicular to the plane in which the stack is made.
  • connection boxes 21 and 23 are rigidly linked together by their longitudinal ends by the fact that the flat faces are common to the two connection boxes 21 and 23, or if they are specific to each of them, they are welded to each other, the suspension forces are taken up by the two collectors in order to transfer them according to the embodiment, either on at least one conduit of a manifold, or on the connection plates.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Component Parts Of Construction Machinery (AREA)
EP92903209A 1990-12-21 1991-12-20 Plattenwärmetauscher Expired - Lifetime EP0515669B2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9016060 1990-12-21
FR9016060A FR2670877B1 (fr) 1990-12-21 1990-12-21 Echangeur a plaques dispose a l'interieur d'une enceinte de resistance en pression.
PCT/FR1991/001046 WO1992011500A1 (fr) 1990-12-21 1991-12-20 Echangeur a plaques

Publications (3)

Publication Number Publication Date
EP0515669A1 true EP0515669A1 (de) 1992-12-02
EP0515669B1 EP0515669B1 (de) 1994-10-12
EP0515669B2 EP0515669B2 (de) 1998-10-14

Family

ID=9403501

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92903209A Expired - Lifetime EP0515669B2 (de) 1990-12-21 1991-12-20 Plattenwärmetauscher

Country Status (7)

Country Link
US (1) US5333681A (de)
EP (1) EP0515669B2 (de)
JP (1) JPH05507348A (de)
AT (1) ATE112846T1 (de)
DE (1) DE69104607T3 (de)
FR (1) FR2670877B1 (de)
WO (1) WO1992011500A1 (de)

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US5360920A (en) * 1992-08-07 1994-11-01 The Procter & Gamble Company Hydrogenation in a plate heat exchanger
US6106789A (en) * 1993-12-30 2000-08-22 Phillips Petroleum Company Alkylation reactor with internal acid cooling zones
FR2731784B1 (fr) * 1995-03-17 1997-05-30 Packinox Sa Echangeur thermique a plaques
FR2732759B1 (fr) * 1995-04-04 1997-07-04 Packinox Sa Echangeur de chaleur a plaques pour fluide sous pression et utilisation
FR2751402B1 (fr) * 1996-07-19 1998-10-09 Packinox Sa Installation d'echange thermique entre au moins trois fluides
US6194609B1 (en) 1997-06-30 2001-02-27 Bp Amoco Corporation Crystallization in a plate heat exchanger
FR2772468B1 (fr) * 1997-12-17 2000-03-03 Packinox Sa Echangeur thermique a plaques
FR2830205B1 (fr) * 2001-09-28 2003-12-12 Inst Francais Du Petrole Enceinte reactionnelle comprenant une enveloppe contenant au moins un module relie par des moyens souples a l'enveloppe et contenant des moyens d'echange de chaleur
US6892797B2 (en) * 2001-12-21 2005-05-17 Honeywell International, Inc. Heat exchanger with biased and expandable core support structure
FR2869979B1 (fr) * 2004-05-06 2006-08-04 Packinox Sa Echangeur thermique a plaques
US6899169B1 (en) * 2004-07-02 2005-05-31 Richard D. Cox Plastic heat exchanger
JP2008286437A (ja) 2007-05-15 2008-11-27 Toshiba Corp 熱交換器
CN102645115B (zh) * 2012-05-14 2014-03-19 兰州兰石换热设备有限责任公司 板壳式换热器
JP2020523546A (ja) * 2017-06-11 2020-08-06 リヴニ,ツヴィ 分割されたマニホールド管を有するプレートおよびシェル熱交換システム
WO2019147168A2 (ru) * 2018-01-23 2019-08-01 Олег Викторович БАРЗИНСКИЙ Пластинчатый теплообменник для гидрогенизационных установок вторичной переработки нефти
RU2670996C1 (ru) * 2018-01-24 2018-10-29 Олег Викторович Барзинский Пластинчатый теплообменник для гидрогенизационных установок вторичной переработки нефти
RU2669989C1 (ru) * 2018-01-23 2018-10-17 Олег Викторович Барзинский Пластинчатый теплообменник для гидрогенизационных установок вторичной переработки нефти
CN111551066A (zh) * 2020-04-24 2020-08-18 上海石化机械制造有限公司 一种热交换器
FR3126034A1 (fr) * 2021-08-05 2023-02-10 Airbus (S.A.S.) Echangeur thermique limitant les risques de contamination entre deux fluides et aéronef comprenant au moins un tel échangeur thermique

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FR911373A (fr) * 1945-06-11 1946-07-05 Appareil pour l'échange de chaleur entre des liquides
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Also Published As

Publication number Publication date
DE69104607T3 (de) 1999-05-06
EP0515669B1 (de) 1994-10-12
EP0515669B2 (de) 1998-10-14
ATE112846T1 (de) 1994-10-15
DE69104607D1 (de) 1994-11-17
JPH05507348A (ja) 1993-10-21
FR2670877A1 (fr) 1992-06-26
US5333681A (en) 1994-08-02
WO1992011500A1 (fr) 1992-07-09
FR2670877B1 (fr) 1996-09-13
DE69104607T2 (de) 1995-02-16

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