EP0509878B1 - Composition aqueuse pour couchage de papier comportant un latex alcaligonflant sensiblement insoluble - Google Patents
Composition aqueuse pour couchage de papier comportant un latex alcaligonflant sensiblement insoluble Download PDFInfo
- Publication number
- EP0509878B1 EP0509878B1 EP92400961A EP92400961A EP0509878B1 EP 0509878 B1 EP0509878 B1 EP 0509878B1 EP 92400961 A EP92400961 A EP 92400961A EP 92400961 A EP92400961 A EP 92400961A EP 0509878 B1 EP0509878 B1 EP 0509878B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- latex
- composition according
- range
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004816 latex Substances 0.000 title claims abstract description 87
- 229920000126 latex Polymers 0.000 title claims abstract description 85
- 239000000203 mixture Substances 0.000 title claims description 51
- 239000011248 coating agent Substances 0.000 title claims description 15
- 238000000576 coating method Methods 0.000 title claims description 15
- 239000002245 particle Substances 0.000 claims abstract description 26
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 10
- 230000008961 swelling Effects 0.000 claims abstract description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- GLLRIXZGBQOFLM-UHFFFAOYSA-N Xanthorin Natural products C1=C(C)C=C2C(=O)C3=C(O)C(OC)=CC(O)=C3C(=O)C2=C1O GLLRIXZGBQOFLM-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000178 monomer Substances 0.000 claims description 25
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 23
- 239000000049 pigment Substances 0.000 claims description 21
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 13
- 239000000284 extract Substances 0.000 claims description 13
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 11
- 150000001732 carboxylic acid derivatives Chemical group 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 9
- 239000003431 cross linking reagent Substances 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 7
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 5
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 5
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 claims description 5
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 5
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 5
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 5
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 4
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 4
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 3
- 239000000539 dimer Substances 0.000 claims description 2
- 239000008199 coating composition Substances 0.000 abstract description 17
- 235000010216 calcium carbonate Nutrition 0.000 abstract description 3
- 239000001023 inorganic pigment Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 206010016807 Fluid retention Diseases 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 9
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 7
- -1 vinyl nitrile Chemical class 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000007853 buffer solution Substances 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- FCDZZFLRLVQGEH-UHFFFAOYSA-N ethane-1,2-diol;prop-2-enoic acid Chemical compound OCCO.OC(=O)C=C FCDZZFLRLVQGEH-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 238000001033 granulometry Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
- UKQBWWAPJNHIQR-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.CCC(CO)(CO)CO UKQBWWAPJNHIQR-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- VFXXTYGQYWRHJP-UHFFFAOYSA-N 4,4'-azobis(4-cyanopentanoic acid) Chemical compound OC(=O)CCC(C)(C#N)N=NC(C)(CCC(O)=O)C#N VFXXTYGQYWRHJP-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
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- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
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- 229910019142 PO4 Inorganic materials 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
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- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
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- 125000000129 anionic group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
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- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
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- 238000012512 characterization method Methods 0.000 description 1
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- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
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- 238000009792 diffusion process Methods 0.000 description 1
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- 238000012674 dispersion polymerization Methods 0.000 description 1
- 238000007606 doctor blade method Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- BHBPJIPGXGQMTE-UHFFFAOYSA-N ethane-1,2-diol;2-methylprop-2-enoic acid Chemical compound OCCO.CC(=C)C(O)=O.CC(=C)C(O)=O BHBPJIPGXGQMTE-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-L fumarate(2-) Chemical class [O-]C(=O)\C=C\C([O-])=O VZCYOOQTPOCHFL-OWOJBTEDSA-L 0.000 description 1
- 239000000416 hydrocolloid Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- VYGBQXDNOUHIBZ-UHFFFAOYSA-L sodium formaldehyde sulphoxylate Chemical compound [Na+].[Na+].O=C.[O-]S[O-] VYGBQXDNOUHIBZ-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
Definitions
- the present invention relates to an aqueous composition for coating of paper comprising a substantially alkaline swelling latex insoluble in water.
- composition for coating of paper By composition for coating of paper, one generally designates an aqueous coating composition essentially containing a filler (pigment), a binder and possibly various adjuvants.
- composition is applied to the paper in order to modify surface properties including whiteness, shine, printability, etc ...
- a hydrocolloid or a natural thickening agent such as carboxymethylcellulose, or synthetic such as polyvinyl alcohol and alkali-soluble latexes.
- alkaline-swelling latex is understood to mean, according to the invention, a latex swelling with alkalis (in particular, soda, potash, ammonia) contained or added to the aqueous emulsion. These latexes allow make coating compositions whose viscosities increase with the pH in the alkaline range.
- alkalis in particular, soda, potash, ammonia
- alkalinating latex improves the retention of water and the rheological properties of the coating composition.
- Such insoluble alkali-swelling latexes are for example described by FR-A 2,444,114 from a styrene / butadiene / acid copolymer acrylic whose viscosity of the coating bath is stabilized by addition of a polyalkylene glycol as well as in the US-A patent 3,793,244 where acrylic acid is replaced by itaconic acid.
- 1,3-butadiene is very hydrophobic which requires the use of significant amounts of acid monomers which are the because of the passage into polymer solution, which has the consequence greatly increase the viscosity of the bath and degrade the power binder.
- this patent teaches neither the size of the latex particles nor the fact that the pigment must necessarily contain at least 40% CaCO 3 .
- the present invention aims to provide a composition of coating for paper with better water retention and better machinability.
- composition of the above type the pigment of which comprises at least 40% of CaCO 3 , having acceptable gloss while having suitable water retention and a high dry extract.
- composition of the type above may be completely free of natural thickeners or synthetic.
- composition of the type above the binding part of which is a mixture of two insoluble latexes in water, one of which is alkaline, said mixture being stable at storage at neutral or slightly acidic pH.
- the ratio ⁇ A / ⁇ B measured at a pH between 2 and 4 is between 1.4 and 6, preferably between 1.8 and 3.0, even more preferably this ratio is close to 2.
- Latex A is a substantially insoluble film-forming latex and is not alkalinizing in alkaline solutions with a pH higher than 8, preferably greater than 9 and less than 13.
- Latex A can in fact be an organic polymer latex used usually for coating paper, since it is a film-forming latex, substantially insoluble and non-alkalinizing, the diameter ⁇ A of the polymer particles is between 60 and 300 nm.
- Latex A is preferably a copolymer based on styrene / 1,3-butadiene. More particularly suitable are copolymers based on 25 to 60% by weight of butadiene, 40 to 75% by weight of styrene and 0 to 6% of ethylenically unsaturated monomers comprising at least one carboxylic acid function and their monoesters with an alkanol in C 1 - C 8 .
- Examples of monomeric carboxylic acids which can be used are acrylic acid, methacrylic acid or its dimer, fumaric acid, crotonic acid, itaconic acid, maleic acid and also the monoesters of the above acids. with C 1 -C 8 alkanols, such as methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate, 2-ethyl hexyl acrylate, methyl methacrylate, ethyl methacrylate and n-butyl methacrylate.
- C 1 -C 8 alkanols such as methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate, 2-ethyl hexyl acrylate, methyl methacrylate, ethyl methacrylate and n-butyl methacrylate.
- Latex B is preferably a copolymer: acid monoester ethylenically unsaturated carboxylic acid / carboxylic acid ethylenic / vinyl aromatic unsaturation and / or vinyl nitrile.
- ethylenically unsaturated carboxylic acid monoester recommend using acrylates, methacrylates, fumarates and maleates of methyl, ethyl, isopropionic alcohols, propionic, isobutyl, n-butyl, tert-butyl and ethyl-2 hexyl.
- ethylenically unsaturated carboxylic acid use an acid or a mixture of acids mentioned above for the latex A, namely preferably acrylic acid, methacrylic acid, itaconic acid, fumaric acid and maleic acid.
- Latex B also comprises a third monomer chosen from a vinyl aromatic monomer such as styrene and methylstyrene and / or a vinyl nitrile such as acrylonitrile and methacrylonitrile.
- a vinyl aromatic monomer such as styrene and methylstyrene
- a vinyl nitrile such as acrylonitrile and methacrylonitrile.
- Latex B also contains a monomer comprising at least 2 ethylenic unsaturations and acting as a crosslinking agent incorporated during the polymerization of the monomers.
- This agent crosslinking is chosen from di (meth) acrylate ethylene glycol, tripolypropylene glycol diacrylate, trimethylolpropane tri (meth) acrylate, allyl (meth) acrylate, diallylmaleate, triallylcyanurate, divinylbenzene and methylene-bis acrylamide.
- Cross-linking agents are used, preferably at a rate of 0.1 to 5% preferably 0.2 to 1% by weight relative to the total weight of monomer, the preferred crosslinking agents being dimethacrylate ethylene glycol and divinylbenzene.
- a latex B which is more particularly suitable is a copolymer comprising 55 to 65% by weight of unsaturated carboxylic acid ester, preferably ethyl acrylate, 10 to 20% by weight of carboxylic acid unsaturated, preferably methacrylic acid, 20 to 32% by weight of styrene and 0.1 to 5% by weight of crosslinking agent.
- a particularly suitable monomer mixture comprises 58 to 60% by weight of ethyl acrylate, 14 to 16% by weight of methacrylic acid and 25 to 27% by weight of styrene and 0.2% to 1% by weight of crosslinking.
- the polymerization of latex B is carried out, in a manner known in oneself, in one or more stages.
- the monomers can be pre-emulsified with water in presence of an anionic or nonionic emulsifying agent, of which usually uses about 0.01 to 10%, calculated on the basis of weight of total monomers.
- a polymerization initiator of the type free radical generator such as ammonium persulfate or potassium, can be used alone or in combination with a accelerator, such as sodium metabisulfite or thiosulfate sodium, sodium formaldehyde sulphoxylate as well as ions metallic (iron, cobalt, copper ).
- free radical generators such as azo (2,2'-azobisisobutyronitrile, 4,4'-azobis (4-cyanopentanoic acid) ...) or peroxides such as hydrogen peroxide or tert-butyl hydroperoxide or cumene hydroperoxide in combination with a reducing agent.
- the initiator and the accelerator jointly constituting what is usually called catalyst, can be used at a rate of 0.1 at 2% each based on the weight of monomers to be copolymerized.
- the polymerization temperature can be between 30 ° C and 100 ° C, more favorably between 50 ° C and 90 ° C.
- crosslinking agents which are monomers having several, i.e. at least 2 ethylenic unsaturations, in an amount ranging from 0.1 to 5%, chosen from di (meth) acrylate ethylene glycol, tripopylene glycol diacrylate, tri (meth) acrylate trimethylolpropane, allyl (meth) acrylate, diallylmaleate, triallylcyanurate, divinylbenzene, methylene-bis acrylamide.
- latex B can be adjusted to a neutral pH or slightly acidic between 4 and 7 using one or more bases such as alkali hydroxides, ammonia or amines water-soluble organic substances such as 2-amino 2-methylpropanol, diethylaminoethanol or alternatively quaternary ammoniums such as tetrabutylammonium hydroxide.
- bases such as alkali hydroxides, ammonia or amines water-soluble organic substances such as 2-amino 2-methylpropanol, diethylaminoethanol or alternatively quaternary ammoniums such as tetrabutylammonium hydroxide.
- the composition aqueous coating has a concentration of dry extracts, i.e. solids (pigment plus latex particles A and B) comprised of preferably between 60 and 80% by weight, preferably between 65 and 75%.
- Latex A can have a dry extract of 40 and 60% in weight preferably between 50 and 55%.
- Latex B advantageously has a dry extract of between 30 and 50% and preferably between 40 and 45% by weight.
- pigment for 100 parts by weight of pigment, there are from 5 to 20 parts of dry extracts of latex A and 8, preferably between 7 and 15 parts.
- At least 40% by weight of the pigment consists of CaCO 3 , the remainder being chosen from the mineral pigments usually chosen for coating paper such as natural or calcined clay, kaolin, barium sulphate, oxide of titanium, talc, hydrated alumina, bentonite and calcium sulfoaluminate (satin white).
- all the pigment consists of ground CaCO 3 and / or precipitation optionally treated with a fatty acid ester such as calcium stearate.
- At least 50% by weight of the pigment has a particle size less than 2 ⁇ m, preferably less than 1 ⁇ m, the rest having a particle size between 2 and 10 ⁇ m.
- the fine-grained pigments can advantageously consist of precipitation CaCO 3 , kaolin, calcined clay or hydrated alumina, the coarser granulometry pigments generally consist of CaCO 3 and barium (natural barium sulphate crushed).
- the coating compositions according to the invention have, before the addition of alkali (preferably NH 4 OH or NaOH so as to reach a pH of between 8 and 13 preferably between 9 and 10), have an apparent viscosity of between 50 and 1000 mPa.s at 25 ° C.
- alkali preferably NH 4 OH or NaOH
- compositions after addition of alkali have a viscosity apparent generally between 4000 and 25000 mPas at 25 ° C preferably between 5,000 and 10,000 mPa.s. (Brookfield 10 rpm).
- the latex A emulsion is prepared, latex emulsion B and it is recommended to add it while homogenizing latex emulsion B in latex emulsion A, having previously adjust the pH of latex A between 4 and 7, preferably between 5.5 and 6.5.
- the mixture of latexes A and B is stable on storage at a pH preferably between 5 and 7 for at least several months.
- stable in storage is understood to mean mainly according to the invention that there is no significant change in the viscosity, the particle size of the emulsions and the pH of the mixture.
- the pigment dispersion based on CaCO 3 defined above.
- the pH is adjusted between 8 and 13 and preferably between 9 and 10 and the coating composition is ready for use.
- the coating compositions according to the invention can be used as is without the addition of conventional natural binders such as casein, starch, carboxymethylcellulose or synthetic thickeners such as polyvinyl alcohol and alkali-soluble latexes as for example described by US-A 4,397,984; they are more particularly recommended for coated papers and are used more particularly for printing in roto offset, in offset and lithography.
- conventional natural binders such as casein, starch, carboxymethylcellulose or synthetic thickeners such as polyvinyl alcohol and alkali-soluble latexes as for example described by US-A 4,397,984; they are more particularly recommended for coated papers and are used more particularly for printing in roto offset, in offset and lithography.
- compositions according to the invention can be used in the right way from 5 to 30 g, preferably 10 to 20 g of composition per m2 (1 side) of paper.
- Latex B is prepared in a stainless steel reactor fitted with a double jacket and "impeller” type stirring. The following ingredients are loaded into the cold reactor: Water 164 parts by weight, Alkylbenzene sulfonate 0.5 parts by weight.
- This emulsifier solution is brought to 82 ° C. and then successively: Ammonium persulfate 0.2 parts by weight, Water 1 part by weight. then a monomer mixture with a constant flow rate over a duration of 4 h 30 composed of: Ethyl acrylate 59 parts by weight, Styrene 24.5 parts by weight, Methacrylic acid 16 parts by weight, Ethylene glycol dimethacrylate 0.5 parts by weight.
- an aqueous solution is also added over a period of 4 h 45 min of a following mixture: Water 4 parts by weight, Alkylarylether ammonium sulfate: with 25 molecules of ethylene oxide 1 part by weight, Ammonium persulfate 0.2 parts by weight.
- the temperature of the reaction medium is kept constant at 82 ° C. throughout the duration of the polymerization.
- this latex is cooled to ambient temperature.
- the latex B obtained in Example 1 is neutralized with ammonia diluted (2%).
- buffer solutions whose pH is identical to that of latex.
- the buffer solutions are prepared according to the HANDBOOK OF CHEMISTRY AND PHYSICS Section D.
- Example 3 To produce the coating composition of Example 3, the ingredients below are mixed, the parts by weight of which are calculated on a dry basis. C 1 100 games, D 1 0.30 part, Latex A 8.50 parts, Latex 8 1.50 part, Dry extract 73.50 (%), pH 9.5, Viscosity (10 rpm): 4400 mPa.s, Viscosity (100 rpm): 1050 mPa.s, Water retention : 40 s, Blade pressure: 4. (relative unit)
- C 1 is dispersed in water in a high speed mixer in the presence of D 1 which serves as a dispersing agent for C 1 and the mixture of latex A and latex B is added having previously adjusted the pH of the latex A between 6 and 6.5.
- the solid content is adjusted to 73.50% by weight, then brings the pH of the mixture to 9-10 by adding an ammonia solution and measuring the viscosity and the water retention of the mixture.
- ink LORILLEUX® 3801 on a PRUFBAU® press under a printing force of 800N at a speed of 0.5 m / s.
- the optical density (OD) of the wet black inked area is measured and the optical density (OD) of the torn wet area.
- the tear-off note wet is given by the ratio of the DO of the wet part to the DO of the dry part.
- the OD of the inked non-wet area and the OD of the area are measured. wet.
- the ink refusal is then the ratio of the average of the density optics of the dry part on the average of the optical density of the wet part.
- a gain in gloss of the paper and ink is also obtained, in particular in the case of C 1 .
- the binding power of the coating composition is, in the case of Examples 3 and 5 at least equivalent if not greater (dry stripping) than that of the compositions of Comparative Examples 4 and 6 comprising CMC instead latex B.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
- Glass Compositions (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
Description
- 80 à 99 % en poids d'un latex insoluble et non alcaligonflant, et
- 1 à 20 % en poids d'un latex insoluble et alcaligonflant rendu insoluble par la présence de butadiène-1,3.
- un latex polymère vinylique A insoluble et non alcaligonflant ayant un diamètre moyen de particules A compris entre 60 et 300 nm.
- un latex polymère B alcaligonflant ayant un diamètre moyen de particules B compris entre 20 et 150 nm mesuré à un pH compris entre 2 et 4 et capable de gonfler au moins 1,5 fois en diamètre, en milieu alcalin, ledit latex comportant un agent de réticulation qui est un monomère comportant au moins deux insaturations éthyléniques, choisi parmi le diméthacrylate d'éthylène glycol, le diacrylate de tripropylèneglycol, le triméthacrylate de triméthylolpropane, le méthacrylate d'allyle, le diallylmaléate, le triallylcyanurate, le divinylbenzène, et/ou le méthylène-bis acrylamide,
- un pigment minéral C comprenant au moins 40 % en poids d'un pigment en CaCO3.
Eau | 164 parties en poids, |
Alkylbenzène sulfonate | 0,5 parties en poids . |
Persulfate d'ammonium | 0,2 parties en poids, |
Eau | 1 partie en poids. |
Acrylate d'éthyle | 59 parties en poids, |
Styrène | 24,5 parties en poids, |
Acide méthacrylique | 16 parties en poids, |
Diméthacrylate d'éthylèneglycol | 0,5 parties en poids. |
Eau | 4 parties en poids, |
Alkylaryléther sulfate d'ammonium : à 25 molécules d'oxyde d'éthylène | 1 partie en poids, |
Persulfate d'ammonium | 0,2 parties en poids. |
pH | GRANULOMETRIE (nm) |
2,3 | 68 |
4 | 69 |
5,6 | 77 |
6,4 | 82 |
7,2 | 93 |
8,2 | 112 |
8,5 | 132 |
9,2 | 170 |
10 | 175 |
- Latex AOn part d'un latex A ayant la composition suivante :
styrène 59,5 % en poids, butadiène-1,3 37,0 % en poids, acide acrylique 3,5 % en poids, Granulométrie moyenne 130 nm, pH 5,5 Viscosité (50 t/mn) 300 mPa.s. - Carbonate de calcium :
On utilise 2 carbonates de calcium différents C1 et C2 en
barbotine aqueuse à 70 % en poids de carbonate.
- C1 présente 90 % de particules ayant une granulométrie inférieure à 2 µm et 60 % de particules ayant une granulométrie inférieure à 1 µm.
- C2 présente 95 % de particules ayant une granulométrie inférieure à 2 µm et 78 % de particules ayant une granulométrie inférieure à 1 µm.
- Carboxyméthylcellulose : CMC est utilisée dans les exemples comparatifs 4 et 6 à la place du latex B.
- Dispex N40® : sel de sodium d'un polyacrylate de bas poids moléculaire.
C1 | 100 parties, |
D1 | 0,30 partie, |
Latex A | 8,50 parties, |
Latex 8 | 1,50 partie, |
Extrait sec | 73,50 (%), |
pH | 9,5, |
Viscosité (10 t/mn) : | 4400 mPa.s, |
Viscosité (100 t/mn) : | 1050 mPa.s, |
Rétention d'eau : | 40 s, |
Pression de lame : | 4.(unité relative) |
EXEMPLE | 3 | 4 | 5 | 6 |
C1 (partie) | 100 | 100 | 0 | 0 |
C2 (partie) | 0 | 0 | 100 | 100 |
Dispex N40® (partie) | 0,30 | 0,30 | 0,30 | 0,30 |
Latex A (partie) | 8,50 | 9,50 | 8,50 | 9,50 |
Latex B (partie) | 1,50 | 0 | 1,50 | 0 |
CMC (partie) | 0 | 0,50 | 0 | 0,50 |
Extrait sec % | 73,5 | 71,2 | 66 | 66 |
pH | 9,5 | 8,5 | 9,5 | 8,5 |
Viscosité (10 t/mn) | 4400 | 5200 | 7300 | 10500 |
Viscosité (100 t/mn) | 1050 | 1000 | 1400 | 1600 |
Rétention d'eau (s) | 40 | 20 | 25 | 12 |
Pression de lame (unité relative) | 4,0 | 4,0 | 2,0 | 3,0 |
Brillance du papier à 75°C en % | 60 | 58 | 66 | 63 |
Brillance de l'encre à 75°C en % | 74 | 69 | 60 | 60 |
Arrachage sec (cm/s) | ||||
encre 3805 | 70 | 50 | - | - |
encre 3808 | - | - | 130 | 130 |
Arrachage humide | ||||
encre 3801 | 9,5 | 9,5 | 8,5 | 8,5 |
Refus d'encre | 1,3 | 1,0 | 5 | 4 |
Claims (14)
- Composition aqueuse pour le couchage de papier à pH alcalin comportant :un latex polymère A insoluble et non alcali gonflant ayant un diamètre moyen de particules ΦA compris entre 60 et 300 nm,un latex polymère B alcali gonflant insoluble ayant un diamètre de particules ΦB compris entre 20 et 150 nm mesuré à pH compris entre 2 et 4, et capable de gonfler au moins 1,5 fois en diamètre en milieu alcalin, ledit latex comportant un agent de réticulation qui est un monomère comportant au moins deux insaturations éthyléniques, choisi parmi le diméthacrylate d'éthylène glycol, le diacrylate de tripropylèneglycol, le triméthacrylate de triméthylolpropane, le méthacrylate d'allyle, le diallylmaléate, le triallylcyanurate, le divinylbenzène, et/ou le méthylène-bis acrylamide,un pigment minéral C comprenant au moins 40 % en poids d'un pigment en CaCO3.
- Composition selon la revendication 1, caractérisée en ce que le latex B comporte 0,1 à 5 % en poids d'agent de réticulation.
- Composition selon l'une des revendications 1 et 2, caractérisée en ce que le latex B comporte 0,2 à 1 % en poids d'agent de réticulation.
- Composition selon la revendication 1, caractérisée en ce que le rapport ΦA/ΦB, mesuré à un pH compris entre 2 et 5, est compris entre 1,8 et 3,0.
- Composition selon la revendication 4, caractérisée en ce que le rapport ΦA/ΦB est voisin de 2.
- Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que le latex A est un copolymère styrène/butadiène-1,3.
- Composition selon la revendication 6, caractérisée en ce que le latex A est un copolymère à base de :25 à 60 % en poids de butadiène-1,3,40 à 75 % en poids de styrène,et 0 à 6 % en poids de monomères à insaturation éthylénique comportant au moins une fonction acide carboxylique et leurs monoesters avec un alcanol en C1-C8.
- Composition selon la revendication 7, caractérisée en ce que le latex A contient 0 à 6% d'un acide carboxylique choisi parmi l'acide acrylique, l'acide méthacrylique ou son dimère, l'acide itaconique, l'acide fumarique, et l'acide maléique.
- Composition selon rune quelconque des revendications précédentes, caractérisée en ce que le latex B est un copolymère à base de :55 à 65 % en poids de monoester d'acide carboxylique à insaturation éthylénique,10 à 20 % en poids d'acide carboxylique à insaturation éthylénique,20 à 32 % en poids de styrène,et 0,1 à 5 % en poids d'agent de réticulation qui est un monomère comportant au moins deux insaturations éthyléniques, choisi parmi le diméthacrylate d'éthylène glycol, le diacrylate de tripropylèneglycol, le triméthacrylate de triméthylolpropane, le méthacrylate d'allyle, le diallylmaléate, le triallylcyanurate, le divinylbenzène, et/ou le méthylène-bis acrylamide.
- Composition selon la revendication 9, caractérisée en ce que le latex B est un copolymère à base de :58 à 60 % en poids d'acrylate d'éthyle,14 à 16 % en poids d'acide méthacrylique,25 à 27 % en poids de styrène,et 0,2 à 1 % en poids de diméthacrylate de d'éthylène glycol ou de divinylbenzène.
- Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que l'on utilise 5 à 25 % en poids, de préférence 10 à 15 % de latex B par rapport au poids total des extraits secs des latex A et B.
- Composition selon la revendication 11, caractérisée en ce qu'elle présente un extrait sec compris entre 60 et 80 % en poids, de préférence entre 65 et 75 % en poids.
- Composition selon la revendication 12, caractérisée en ce que pour 100 parties en poids de pigment, il y a 5 à 20 parties en poids de particules de latex A et B, de préférence entre 7 et 15 parties.
- Composition selon l'une quelconque des revendications précédentes, caractérisée en ce qu'au moins 50 % en poids du pigment a une granulométrie inférieure à 2 µm, le reste ayant une granulométrie comprise entre 2 et 10 µm.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9104565A FR2675165B1 (fr) | 1991-04-15 | 1991-04-15 | Composition aqueuse pour couchage de papier comportant un latex alcaligonflant sensiblement insoluble. |
FR9104565 | 1991-04-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0509878A1 EP0509878A1 (fr) | 1992-10-21 |
EP0509878B1 true EP0509878B1 (fr) | 1998-07-01 |
Family
ID=9411825
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92400961A Expired - Lifetime EP0509878B1 (fr) | 1991-04-15 | 1992-04-07 | Composition aqueuse pour couchage de papier comportant un latex alcaligonflant sensiblement insoluble |
Country Status (7)
Country | Link |
---|---|
US (1) | US5563201A (fr) |
EP (1) | EP0509878B1 (fr) |
AT (1) | ATE167909T1 (fr) |
BR (1) | BR9201346A (fr) |
ES (1) | ES2121831T3 (fr) |
FI (1) | FI110386B (fr) |
FR (1) | FR2675165B1 (fr) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2700329B1 (fr) * | 1993-01-13 | 1995-03-24 | Rhone Poulenc Chimie | Compositions pour ciment comprenant un latex alcaligonflant et ciments obtenus à partir de ces compositions. |
JPH09503554A (ja) * | 1993-10-19 | 1997-04-08 | ビーエーエスエフ アクチェンゲゼルシャフト | 紙塗被組成物用のバインダー混合物 |
US5981668A (en) * | 1996-10-31 | 1999-11-09 | Sanyo Chemical Industries, Ltd. | Anti-bacterial water absorbing agent and anti-bacterial water absorbent material |
FR2785629B1 (fr) | 1998-11-10 | 2000-12-22 | Coatex Sa | Composition polymerique retenteur d'eau et activateur d'azurants optiques, sauces de couchage pour papier, et feuilles de papier couche ainsi obtenues |
DE10008276A1 (de) * | 2000-02-23 | 2001-08-30 | Basf Ag | Papierstreichmassen auf Basis von gering vernetzten Bindemitteln |
US6547929B2 (en) * | 2000-04-12 | 2003-04-15 | Rohm And Haas Company | Paper having improved print quality and method of making the same |
FI115150B (fi) * | 2000-11-24 | 2005-03-15 | Metso Paper Inc | Paperinpäällystysmenetelmä |
US6951250B2 (en) * | 2003-05-13 | 2005-10-04 | Halliburton Energy Services, Inc. | Sealant compositions and methods of using the same to isolate a subterranean zone from a disposal well |
US6884468B1 (en) | 2003-10-27 | 2005-04-26 | Basf Ag | Method of making a paper coating using a blend of a vinyl aromatic-acrylic polymer dispersion with a vinyl aromatic-diene polymer dispersion |
US7607483B2 (en) * | 2004-04-19 | 2009-10-27 | Halliburton Energy Services, Inc. | Sealant compositions comprising colloidally stabilized latex and methods of using the same |
US7488705B2 (en) * | 2004-12-08 | 2009-02-10 | Halliburton Energy Services, Inc. | Oilwell sealant compositions comprising alkali swellable latex |
US20070111901A1 (en) * | 2005-11-11 | 2007-05-17 | Reddy B R | Method of servicing a wellbore with a sealant composition comprising solid latex |
US20070111900A1 (en) * | 2005-11-11 | 2007-05-17 | Reddy B R | Sealant compositions comprising solid latex |
US8703659B2 (en) | 2005-01-24 | 2014-04-22 | Halliburton Energy Services, Inc. | Sealant composition comprising a gel system and a reduced amount of cement for a permeable zone downhole |
US7267174B2 (en) * | 2005-01-24 | 2007-09-11 | Halliburton Energy Services, Inc. | Methods of plugging a permeable zone downhole using a sealant composition comprising a crosslinkable material and a reduced amount of cement |
US20060167133A1 (en) * | 2005-01-24 | 2006-07-27 | Jan Gromsveld | Sealant composition comprising a crosslinkable material and a reduced amount of cement for a permeable zone downhole |
MX2007014898A (es) | 2005-05-27 | 2008-01-28 | Unilever Nv | Proceso de blanqueo. |
AU2006301605B2 (en) | 2005-10-12 | 2010-01-14 | Unilever Plc | Bleaching of substrates |
FR2894998A1 (fr) | 2005-12-16 | 2007-06-22 | Coatex Sas | Procede de fabrication de sauces de couchage a la retention d'eau et a la viscosite brookfield ameliorees mettant en oeuvre un polymere peigne avec au moins une fonction greffee oxyde de polyalkylene. |
US7576042B2 (en) * | 2006-02-28 | 2009-08-18 | Halliburton Energy Services, Inc. | Salt water stable latex cement slurries |
ZA200903684B (en) | 2007-01-16 | 2010-08-25 | Unilever Plc | Bleaching of substrates |
EP2075374A1 (fr) | 2007-12-17 | 2009-07-01 | Omya Development AG | Procédé de fabrication d'une sauce de couchage avec mise en oeuvre d'un epaississant acrylique à chaine hydrophobe ramifiée et sauce obtenue |
KR101735087B1 (ko) | 2010-03-03 | 2017-05-24 | 카텍셀 리미티드 | 표백 촉매 제조방법 |
EP2753627B1 (fr) | 2011-09-08 | 2018-05-09 | Catexel Technologies Limited | Catalyse |
US20140162910A1 (en) | 2012-12-10 | 2014-06-12 | Halliburton Energy Services, Inc. | Wellbore Servicing Compositions and Methods of Making and Using Same |
US10066146B2 (en) | 2013-06-21 | 2018-09-04 | Halliburton Energy Services, Inc. | Wellbore servicing compositions and methods of making and using same |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1262460A (en) * | 1968-04-16 | 1972-02-02 | Doverstrand Ltd | Coating compositions |
CA977221A (en) * | 1972-12-20 | 1975-11-04 | John R. Hitchmough | Production of coated paper |
DD117688A1 (fr) * | 1975-01-09 | 1976-01-20 | ||
CA1098633A (fr) * | 1978-12-14 | 1981-03-31 | Elsa S. Polatajko-Lobos | Compose de couchage |
US4751111A (en) * | 1986-05-02 | 1988-06-14 | The Dow Chemical Company | Method for producing low sheet gloss coated paper |
DE3720859A1 (de) * | 1987-06-24 | 1989-01-05 | Basf Ag | Lagerstabile waessrige polymerdispersionen |
US5093449A (en) * | 1988-07-18 | 1992-03-03 | Reichhold Chemicals, Inc. | Styrene-butadiene latex compositions |
-
1991
- 1991-04-15 FR FR9104565A patent/FR2675165B1/fr not_active Expired - Lifetime
-
1992
- 1992-04-07 ES ES92400961T patent/ES2121831T3/es not_active Expired - Lifetime
- 1992-04-07 EP EP92400961A patent/EP0509878B1/fr not_active Expired - Lifetime
- 1992-04-07 AT AT92400961T patent/ATE167909T1/de not_active IP Right Cessation
- 1992-04-13 BR BR929201346A patent/BR9201346A/pt not_active IP Right Cessation
- 1992-04-14 FI FI921674A patent/FI110386B/fi active
-
1994
- 1994-08-18 US US08/292,313 patent/US5563201A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US5563201A (en) | 1996-10-08 |
EP0509878A1 (fr) | 1992-10-21 |
FI921674A (fi) | 1992-10-16 |
FR2675165A1 (fr) | 1992-10-16 |
FR2675165B1 (fr) | 1993-08-06 |
BR9201346A (pt) | 1992-12-01 |
ES2121831T3 (es) | 1998-12-16 |
ATE167909T1 (de) | 1998-07-15 |
FI921674A0 (fi) | 1992-04-14 |
FI110386B (fi) | 2003-01-15 |
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