EP0505578A1 - Flammhemmende faser - Google Patents
Flammhemmende faser Download PDFInfo
- Publication number
- EP0505578A1 EP0505578A1 EP91919279A EP91919279A EP0505578A1 EP 0505578 A1 EP0505578 A1 EP 0505578A1 EP 91919279 A EP91919279 A EP 91919279A EP 91919279 A EP91919279 A EP 91919279A EP 0505578 A1 EP0505578 A1 EP 0505578A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fiber
- flame
- weight
- parts
- retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/48—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of halogenated hydrocarbons
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/50—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyalcohols, polyacetals or polyketals
Definitions
- the present invention relates to a flame-retardant fiber and a process for producing the same, said flame-retardant fiber exhibiting not only good flame retardance even in the form of composite fiber combined with a combustible fiber but also good colorfastness to heat.
- flame-retardant fibers which are produced by the post-treatment of combustible natural or synthetic fiber with a flame retardant or by the incorporation of a raw material of synthetic fiber with a flame retardant at the time of spinning.
- An example of flame retardant synthetic fibers is one which is produced by wet spinning from a spinning solution containing polyvinyl chloride (as a halogen-containing polymer), polyvinyl alcohol, and stannic acid (as a flame retardant), followed by acetalization. It finds use as furnishing fabrics, bedclothes, and industrial materials because of its good flame retardance and its extremely low toxic combustion gas.
- one Japanese Patent Application relating to a flame-retardant fiber was Laid-open under No. 6611/1990. It is composed of 100 parts by weight of a major constituent (which is composed of a halogen-containing polymer and polyvinyl alcohol in a weight ratio of from 80:20 to 20:80), 0.3-10 parts by weight of stannic acid, and 1-5 parts by weight of antimony pentoxide.
- a major constituent which is composed of a halogen-containing polymer and polyvinyl alcohol in a weight ratio of from 80:20 to 20:80
- stannic acid 0.3-10 parts by weight of stannic acid
- antimony pentoxide 1-5 parts by weight of antimony pentoxide.
- the products are such bed sheets and bathrobes as are made of moisture-absorbing composite fiber composed of a cellulosic fiber and a flame-retardant fiber proposed in JP Laid-open No.6611/1990.
- the composite fiber contains more flame-retardant fiber than cellulosic fiber for improved flame retardance.
- the problem is that the resulting composite fiber is poor in moisture absorption and unsuitable for the above-mentioned passage property because the flame-retardant fiber is essentially thermoplastic.
- the ratio of the flame-retardant fibers is decreased for passage property a flame retardance as the composite fiber becomes unsatisfactory.
- the present inventors carried out a series of researches on the formulation of a flame-retardant fiber to be combined with a cellulosic fiber for the production of a composite fiber which meets the above-mentioned flame retardance and passage property. It was experimentally found that a flame-retardant fiber that facilitates passage property should contain a cellulosic fiber in an amount more than 65%, preferably more than 70%. It was also found that in the composite fiber contains a flame-retardant fiber in an amount less than 35%, preferably less than 30%, it improves in flame retardance in proportion to the amount of flame retardant it contains but becomes poor in colorfastness to heat. To address this problem, the present inventors investigated the combination of a flame retardant and a heat stabilizer.
- the present invention relates to a flame-retardant fiber having good colorfastness to heat and a process for the production thereof, said flame-retardant fiber comprising 100 parts by weight of a principal constituent composed of a halogen-containing polymeric substance and polyvinyl alcohol in a weight ratio of from 80:20 to 20:80, 5-35 parts by weight of antimony pentoxide, and 0.13-5.0 parts by weight of octyl tin-type heat stabilizer in which the compositional ratio of mercaptans to laurates is from 5/5 to 3/7.
- the halogen-containing polymeric substance used in the present invention includes homopolymers of halogen-containing polymerizable monomers such as vinyl chloride, vinylidene chloride, and chloroprene, and copolymers of two or more of these monomers and optional other polymerizable monomers, or mixtures of the homopolymers and copolymers. They may be in the form of fine particles in suspension or emulsion. Further, the polyvinyl alcohol should preferably be one which contains vinyl acetate in an amount less than 2%.
- the ratio of the halogen-containing polymeric substance and polyvinyl alcohol is important for adequate spinning. With a ratio greater than 80:20, it is difficult to perform smooth spinning and the resulting fiber is poor in strength and elongation required for practical use. Conversely, with a ratio lower than 20:80, it is difficult to achieve the desired flame retardance despite the incorporation with additional antimony compounds such as antimony trioxide and antimony pentoxide.
- the antimony compound to be added to the flame-retardant fiber should preferably be antimony pentoxide in the form of colloid having a particle diameter smaller than 100 ⁇ m.
- the amount of the antimony compound should be 5-35 parts by weight for 100 parts by weight of the principal constituent (as solids). An amount less than 5 parts by weight is not enough for the antimony compound to impart sufficient flame retardance to the composite fiber containing a combustible fiber such as cellulosic fiber.
- the antimony compound improves the flame retardance only at the expense of spinnability and colorfastness to heat. Incorporation as much as 45 parts by weight is of no practical use because the resulting fiber solution is capable of spinning but gives rise to a fiber which is poor in strength.
- heat stabilizers which are based on metal soaps such as barium/zinc and calcium/zinc, organic phosphite esters, epoxy resins, butyl tins, or octyl tins.
- the first one is not so effective and needs such a large amount to produce the desired effect that it adversely affects the stability of the spinning solution and its spinning.
- the second one also is not effective for the spinning solution in the present invention.
- the third one has a problem associated with dispersion stability of heat stability composition.
- the forth one is undesireble because of its toxicity.
- the heat stabilizer based on octyl tin is desirable.
- the octyl tins heat stabilizer includes those of laurates, malates, mercaptomalates and mercaptans.
- Those of malates and mercaptomalates are undesirable because they become ineffective due to hydrolysis that takes place during spinning repeated washing.
- That of mercaptans if used alone in large quantities, improves the colorfastness to heat but gives off smoke and odor when exposed to high temperatures during spinning, which poses a problem associated with environmental hygiene.
- That of laurates contributes only to colorfastness to heat mainly on account of its function to capture hydrochloric acid; therefore, it is slightly inferior in colorfastness to heat to that of mercaptans when it is used alone. It is possible to overcome these disadvantages by using those of laurates and mercaptans in combination.
- the ratio of combination should preferably be from 5/5 to 3/7 (mercaptans/laurates).
- the octyl tins heat stabilizer should be added in the form of heat stabilizer composition containing a phthalate plasticizer and a surface active agent.
- a phthalate plasticizer examples include dialkyl phthalate such as dioctyl phthalate and dibutyl phthalate.
- the surface active agent is not specifically limited so long as it stably disperses the octyl tin heat stabilizer and phthalate plasticizer and keeps the spinning solution stable. Its preferred examples include aromatic nonionic surface active agents such as polyoxyethylene nonylphenyl ether, polyoxyethylene octylphenyl ether, polyoxyethylene dodecylphenyl ether, and polyoxyethylene alkylaryl ether.
- the above-mentioned heat stabilizer, phthalate plasticizer, and surface active agent should preferably be handled in the form of composition so that the antimony compound is stably dispersed.
- a composition should be composed of 65-75 parts by weight of octyl tin heat stabilizer, 20-30 parts by weight of phthalate plasticizer, and 5-15 parts by weight of surface active agent, with the total amount being 100 parts by weight.
- the amount of the surface active agent should be more than 5 parts by weight from the standpoint of dispersion stability.
- the amount of the oxtyl tins heat stabilizer is preferably less than 75 parts by weight from the standpoint of the stability and spinnability of the spinning solution.
- the phthalate plasticizers in an amount less than 20 parts by weight is not enough to provide sufficient slip between fibers and metal rolls during spinning, which prevents smooth spinning.
- the phthalate plasticizer in an amount more than 30 parts by weight lowers the colorfastness to heat on account of the relative decrease of the octyl tins heat stabilizer.
- the above-mentioned heat stabilizer composition should be used in an amount of 0.2-5 parts by weight (depending on the amount of the antimony compound) for 100 parts by weight of the principal constituent of the flame-retardant fiber of the present invention which is composed of a halogen-containing polymeric substance and polyvinyl alcohol in a weight ratio of from 80:20 to 20:80.
- the beat stabilizer composition in an amount less than 0.2 part by weight is not enough to protect the flame retardant fiber from discoloration that takes place during spinning and also during drying and ironing that follow washing for business use.
- the heat stabilizer composition in an amount more than 5 parts by weight unstabilizes the spinning solution, making spinning difficult.
- the flame-retardant fiber of the present invention to have further improved flame retardance, it is desirable to add 0.3-10 parts by weight of stannic acid for 100 parts by weight of the principal constituent (as solids).
- the stannic acid is composed of SnO2 and H2O in a molar ratio of 0.5-0.7. With an amount less than 0.3 part by weight, the stannic acid does not improve the flame retardance sufficiently. With an amount in excess of 10 parts by weight, the stannic acid improves the flame retardance of the flame-retardant fiber in proportion to its amount but does not improve so much the flame retardance of the composite fiber (composed of the flame-retardant fiber and combustible fiber). It rather deteriorates the spinnability of the fiber solution.
- the above-mentioned emulsion of halogen-containing polymeric substance and aqueous solution of polyvinyl alcohol are mixed in a ratio of from 80:20 to 20:80 in terms of solids to give an aqueous solution containing 15-30% solids.
- this aqueous solution is incorporated with stannic acid, antimony pentoxide, heat stabilizer, plasticizer, and surface active agent in prescribed amounts.
- the resulting spinning solution undergoes wet spinning, which is followed by optional post treatments for individual uses.
- the flame-retardant fiber of the present invention which has good colorfastness to heat.
- the stannic acid, antimony compound, heat stabilizer, plasticizer, and surface active agent may be added one by one sequentially or in a group of two or more members. They are preferably formed into a composition of liquid dispersion before incorporation into the spinning solution. After wet spinning, the fibers undergo wet-heat treatment, water washing, drying, hot drawing, and heat setting. The fibers are acetalized in a bath containing an aldehyde compound and subjected to washing, finishing, crimping, cutting, and drying. These post treatments may be partly omitted or supplemented by other treatments.
- the above-mentioned aldehyde compound includes formalin, acetaldehyde, furfural, glyoxal, and benzaldehyde.
- the flame-retardant fiber of the present invention is superior in both flame retardance and colorfastness to heat. It may be combined with any combustible fiber such as cellulosic fiber, polyester fiber, acrylic fiber, vinylon fiber, nylon fiber, and polypropylene fiber to give a composite flame-retardant fiber. It is effective particularly for cellulosic fiber, especially cotton fiber.
- any combustible fiber such as cellulosic fiber, polyester fiber, acrylic fiber, vinylon fiber, nylon fiber, and polypropylene fiber. It is effective particularly for cellulosic fiber, especially cotton fiber.
- the flame-retardant fiber of the present invention may be incorporated with other additives and adjuvants than mentioned above according to need, such as pigment, antistatic agent, light resistance improver, dyeability improver, and delusterizing agent which are commonly used in the production and processing of fibers.
- a 4:6 mixture (by weight) was prepared from two kinds of octyl tin heat stabilizers. The first one is "Gleck T-130FM” (a mercaptan-based heat stabilizer made by Dainippon Ink and Chemicals, Inc.) and the second one is “Breck T-7048” (a laurate-based heat stabilizer made by Dainippon Ink and Chemicals, Inc.).
- a liquid mixture containing 22 wt% solids was prepared by mixing polyvinyl chloride emulsion (composed mainly of vinyl chloride) and polyvinyl alcohol aqueous solution in a ratio of 50:50 by weight as solids.
- Amount of colloidal antimony pentoxide Amount of heat stabilizer composition
- Example 1 8.5 parts 2 parts
- Each of the spinning solutions kept at 80°C, was spun out through a spinneret into a saturated aqueous solution at 40°C of sodium sulfate for wet spinning.
- the emergent fibers underwent wet heat treatment in a saturated aqueous solution of sodium sulfate at 95°C, washing with cold water, drying, drawing, and heat-setting. It turned out that the spinning solution was stable and capable of spinning in the satisfactory manner.
- the thus obtained filaments were acetalized by immersion in a bath at 70°C for 60 minutes, containing 15 parts by weight of sulfuric acid, 15 parts by weight of sodium sulfate, 5.5 parts by weight of formaldehyde, and 64.5 parts by weight of water.
- the acetalized filaments were squeezed, thoroughly washed with warm water (at 40°C), washed with an aqueous solution containing 30 g/L of sodium carbonate at 50°C for neutralization, and washed again with water at room temperature.
- the fibers were finally treated with a finishing agent, dried, crimped,and cut into 2-denier staples of flame-retardant fiber.
- a sample of blended yarn having a cotton count of 20 was prepared by blending 30 parts by weight of the flame-retardant fiber in staple form obtained in Examples 1 to 3 and Comparative Examples 1 and 2 mentioned above and 70 parts by weight of cotton fiber.
- the blended yarn was made into a fabric of plain weave having a basis weight of 140 g/m2. This fabric underwent washing repeatedly under the conditions employed by laundries. The washed fabric was dried and ironed by passing over a hot metal plate at 175°C at a speed of 40 m/min. This passage property posed no problems at all.
- Each sample of the fabric was tested for flame retardance and whiteness before and after repeated washing (100 times). The results are shown in Table 1. It is noted that the fabric composed of the flame-retardant fiber of the present invention and cotton fiber is superior in whiteness and colorfastness to heat to the comparative sample which is not incorporated with the heat stabilizer.
- a sample of blended yarn having a cotton count of 20 was prepared by blending 60 parts by weight of the flame-retardant fiber obtained in Examples 1 to 3 or the fiber obtained in Comparative Example 1 and 40 parts by weight of cotton fiber.
- the blended yarn was made into a circular knitted fabric having a basis weight of 165-170 g/m2. This fabric underwent scoring at 45°C for 30 minutes in a bath containing 2 g/L of "Scorerol 700" (an ether-type nonionic scoring-washing agent made by Kao Atlas Co., Ltd.) After drying at 75°C, the sample fabric was tested for LOI (limited oxygen index). The results are shown in Table 2. It is noted that the flame-retardant fiber of the present invention retains its good flame retardance even when combined with combustible fiber such as cotton.
- Samples of blended yarn having a cotton count of 20 were prepared by blending the flame retardant fiber obtained in Example 1 or the fiber obtained in Comparative Example 1 and combustible fiber selected from cotton fiber, polyester fiber, acrylic fiber, vinylon fiber, nylon fiber, and polypropylene fiber, according to the blending ratio shown in Tables 3 and 4.
- the blended yarn was made into a circular knitted fabric having a basis weight of 165-170 g/m2. This fabric underwent scoring at 45°C for 30 minutes in a bath containing 2 g/L of "Scorerol 700" (an ether-type nonionic scoring-washing agent made by Kao Atlas Co., Ltd.). After drying at 75°C, the sample fabric was tested for LOI (limited oxygen index). The results are shown in Tables 3 and 4. It is noted that the flame-retardant fiber of the present invention effectively prevents the LOI value from lowering even when it is blended with any one of the combustible fibers used.
- the present invention provides a flame-retardant fiber, which is suitable for use of business washing, containing an antimony compound as a flame retardant and a heat stabilizer of specific formulation, thereby the products having superior properties in such as flame-retardance, colorfastness to heat, passage property of post treatment of business washing are obtained.
- a flame-retardant fiber which is suitable for use of business washing, containing an antimony compound as a flame retardant and a heat stabilizer of specific formulation, thereby the products having superior properties in such as flame-retardance, colorfastness to heat, passage property of post treatment of business washing are obtained.
- an antimony compound as a flame retardant and a heat stabilizer of specific formulation
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2272137A JP2887208B2 (ja) | 1990-10-12 | 1990-10-12 | 耐熱着色性に優れた難燃性繊維 |
JP272137/90 | 1990-10-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0505578A1 true EP0505578A1 (de) | 1992-09-30 |
EP0505578A4 EP0505578A4 (en) | 1993-09-22 |
Family
ID=17509607
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19910919279 Ceased EP0505578A4 (en) | 1990-10-12 | 1991-10-11 | Flame-retardant fiber |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0505578A4 (de) |
JP (1) | JP2887208B2 (de) |
AU (1) | AU8660991A (de) |
CA (1) | CA2071525A1 (de) |
WO (1) | WO1992007125A1 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2851581A1 (fr) * | 2003-02-21 | 2004-08-27 | Rhodianyl | Fils, fibres, filaments et articles textiles ignifuges |
WO2012167203A2 (en) * | 2011-06-01 | 2012-12-06 | The Moore Company | Flame-resistant elastomeric composition and use thereof |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998040545A1 (fr) * | 1997-03-11 | 1998-09-17 | Kaneka Corporation | Fibres de chlorure de vinyl et procede d'elaboration |
US6066396A (en) * | 1997-10-07 | 2000-05-23 | Kuraray Co., Ltd. | Flame-retardant polyvinyl alcohol base fiber |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60166336A (ja) * | 1984-02-09 | 1985-08-29 | Adeka Argus Chem Co Ltd | ハロゲン含有樹脂用液状安定剤 |
EP0183014A2 (de) * | 1984-10-05 | 1986-06-04 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Flammverzögerndes Fasergemisch |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS536617A (en) * | 1976-07-07 | 1978-01-21 | Kohjin Co Ltd | Composite fibers |
FR2524475A1 (fr) * | 1982-04-01 | 1983-10-07 | Rhovyl | Solutions a base de polychlorure de vinyle, leur procede d'obtantion et fils et fibres ainsi obtenus |
JPS59211613A (ja) * | 1983-05-10 | 1984-11-30 | Kanegafuchi Chem Ind Co Ltd | 難燃繊維及びその製造方法 |
JPS61215773A (ja) * | 1985-03-19 | 1986-09-25 | 株式会社 興人 | 塩化ビニル系繊維の白色度向上方法 |
JPH026611A (ja) * | 1988-06-27 | 1990-01-10 | Kohjin Co Ltd | 難燃性繊維及びその組成物 |
-
1990
- 1990-10-12 JP JP2272137A patent/JP2887208B2/ja not_active Expired - Fee Related
-
1991
- 1991-10-11 EP EP19910919279 patent/EP0505578A4/en not_active Ceased
- 1991-10-11 WO PCT/JP1991/001390 patent/WO1992007125A1/ja not_active Application Discontinuation
- 1991-10-11 AU AU86609/91A patent/AU8660991A/en not_active Abandoned
- 1991-10-11 CA CA 2071525 patent/CA2071525A1/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60166336A (ja) * | 1984-02-09 | 1985-08-29 | Adeka Argus Chem Co Ltd | ハロゲン含有樹脂用液状安定剤 |
EP0183014A2 (de) * | 1984-10-05 | 1986-06-04 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Flammverzögerndes Fasergemisch |
Non-Patent Citations (2)
Title |
---|
DATABASE WPI Week 8541, Derwent Publications Ltd., London, GB; AN 85-252594 & JP-A-60 166 336 (ADEKA ARGUS CHEM) 29 August 1985 * |
See also references of WO9207125A1 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2851581A1 (fr) * | 2003-02-21 | 2004-08-27 | Rhodianyl | Fils, fibres, filaments et articles textiles ignifuges |
WO2004079080A1 (fr) * | 2003-02-21 | 2004-09-16 | Rhodianyl | Fils, fibres, filaments et articles textiles ignifuges |
WO2012167203A2 (en) * | 2011-06-01 | 2012-12-06 | The Moore Company | Flame-resistant elastomeric composition and use thereof |
WO2012167203A3 (en) * | 2011-06-01 | 2013-02-21 | The Moore Company | Flame-resistant elastomeric composition and use thereof |
Also Published As
Publication number | Publication date |
---|---|
WO1992007125A1 (fr) | 1992-04-30 |
EP0505578A4 (en) | 1993-09-22 |
AU8660991A (en) | 1992-05-20 |
JP2887208B2 (ja) | 1999-04-26 |
JPH04153310A (ja) | 1992-05-26 |
CA2071525A1 (en) | 1992-04-13 |
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