EP0476196B1 - Compositions combustibles hydrocarburées et additifs pour celles-ci - Google Patents

Compositions combustibles hydrocarburées et additifs pour celles-ci Download PDF

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Publication number
EP0476196B1
EP0476196B1 EP90310322A EP90310322A EP0476196B1 EP 0476196 B1 EP0476196 B1 EP 0476196B1 EP 90310322 A EP90310322 A EP 90310322A EP 90310322 A EP90310322 A EP 90310322A EP 0476196 B1 EP0476196 B1 EP 0476196B1
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EP
European Patent Office
Prior art keywords
fuel
composition according
soluble
component
optionally
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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EP90310322A
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German (de)
English (en)
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EP0476196A1 (fr
Inventor
Graeme Mcrobert Wallace
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Afton Chemical Ltd
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Afton Chemical Ltd
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Publication date
Application filed by Afton Chemical Ltd filed Critical Afton Chemical Ltd
Priority to ES90310322T priority Critical patent/ES2060058T3/es
Priority to EP90310322A priority patent/EP0476196B1/fr
Priority to DE90310322T priority patent/DE69004692T2/de
Priority to CA002051452A priority patent/CA2051452C/fr
Priority to JP3265442A priority patent/JPH04234489A/ja
Priority to AU84650/91A priority patent/AU635158B2/en
Publication of EP0476196A1 publication Critical patent/EP0476196A1/fr
Application granted granted Critical
Publication of EP0476196B1 publication Critical patent/EP0476196B1/fr
Priority to US09/107,577 priority patent/US5944858A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Definitions

  • This invention relates to liquid fuel compositions of enhanced performance properties, particularly as regards combustion characteristics.
  • Keszthelyi et al report in Period. Polytech., Chem. Eng. , Volume 21(1), pages 79-93 (1977) that in the combustion of light fuel oils in evaporating burners, 0.025% cyclopentadienyl manganese tricarbonyl was effective for soot reduction. And in Margantsevye Antidetonatory , edited by A. N. Nesmeyanov, Nauka, Moscow, 1971, at pages 192-199, Makhov et al report test work indicating that addition of cyclopentadienyl manganese tricarbonyl to diesel fuel reduces the level of smokiness of the exhaust gases.
  • Canadian Patent No. 1,188,891 describes an additive for fuel oils and diesel fuels and other liquid combustibles and motor fuels designed to improve combustion, reduce soot formation and enhance storage stability.
  • Such additive is composed of at least one oil-soluble or oil-dispersible organic compound of a transition metal or an alkaline earth metal; and at least one oxidation and polymerisation inhibitor for hydrocarbons stable at temperatures of at least 300°C.
  • the presence in such fuels of compounds of transition metals such as copper, manganese, cobalt, nickel and iron accelerate fuel deterioration in accelerated stability tests conducted at 149°C in the presence of air.
  • Such compounds as MMT, Ferrocene, copper naphthenate, iron naphthenate, and manganese naphthenate are indicated to cause such deterioration in the absence of a high temperature (e.g., 300°C) stabiliser such as heat-stable alkyl phenols, amines, aminophenols, dithiophosphates, dithiocarbamates and imidazoles and inorganic inhibitors in the form of oxides or hydroxides of aluminum, magnesium or silicon.
  • a high temperature (e.g. 300°C) stabiliser such as heat-stable alkyl phenols, amines, aminophenols, dithiophosphates, dithiocarbamates and imidazoles and inorganic inhibitors in the form of oxides or hydroxides of aluminum, magnesium or silicon.
  • a high temperature stabiliser such as heat-stable alkyl phenols, amines, aminophenols, dithiophosphates, dithiocarbamates and imidazoles and inorgan
  • G.B. Patent No. 1,413,323 describes a multi-component diesel fuel additive to avoid or reduce the formation of deposits on injector parts.
  • the additive comprises, inter alia, an ester of oleic or naphthenic acid having an acid number below 200; a naphthenic acid ester of cresol; an alkoxyalkyl ester of an aliphatic carboxylic acid; an organometallic tricarbonyl cyclopentadiene compound such as cyclopentadienyl manganese tricarbonyl; an amide derivative of a polyolefin obtained by the reaction of a polyolefin substituted succinic acid or anhydride with a polyamine; a copolymer of ethylene and a vinyl (or hydrocarbyl-substituted vinyl) ester of a carboxylic acid wherein the copolymer has a number average molecular weight of more than 3000; a re-odoriser composed of a mixture of natural and synthetic alcohols, ketones
  • compositions comprising the combination of a transition metal salt such as a manganese carboxylate, and an ashless hydrocarbonsoluble ashless dispersant.
  • a transition metal salt such as a manganese carboxylate
  • an ashless hydrocarbonsoluble ashless dispersant An optimum balance between beneficial and deleterious effects is said to be achieved in oils of lubricating viscosity and hydrocarbon fuels.
  • U.S.Pat.No. 3,883,320 discloses an additive for improving combustion of a jet fuel composition comprising a transition metal salt, an oil soluble compound of magnesium, calcium or barium and an oil soluble ammonium salt.
  • additive composition which is capable of reducing or inhibiting the amount of noxious emissions (e.g., carbon monoxide, unburned hydrocarbons, polyaromatic hydrocarbons, and/or particulates) formed when using the fuels in an engine or in a burner or like combustion apparatus.
  • noxious emissions e.g., carbon monoxide, unburned hydrocarbons, polyaromatic hydrocarbons, and/or particulates
  • the provision of additive compositions capable of decreasing fuel consumption is also a most desirable objective.
  • this invention provides an additive composition for hydrocarbonaceous fuels.
  • Such additive composition comprises:
  • this invention provides a fuel composition which comprises a major amount of a liquid hydrocarbonaceous fuel containing a minor combustion-improving amount of components a), b) and c) as just described.
  • the additive compositions and fuel compositions are essentially halogen-free, that is, they contain no more than 10 ppm of halogen, if any.
  • Preferred manganese carbonyl compounds -- component a) above -- are cyclopentadienyl manganese tricarbonyl compounds.
  • the preferred component b) salts are the sodium, potassium, calcium and magnesium salts of sulphonic acids, of alkylphenols,of sulphurised alkylphenols, and of carboxylic acids, especially aromatic carboxylic acids.
  • Preferred ashless dispersants for use as component c) are basic nitrogen-containing ashless dispersants, especially polyolefin-substituted succinimides of polyethylene polyamines such as polyethylene tetramines, polyethylene pentamines and polyethylene hexamines.
  • compositions for use in heating gas oils and similar burner fuels contain, in addition to components a), b) and c) above, one or more of the following:
  • compositions for use in road diesel fuels and similar middle distillate fuels contain, in addition to components a), b) and c) above, component d), namely, at least one fuel-soluble demulsifying agent.
  • fuel-soluble means that the compound or component under discussion has sufficient solubility at ordinary ambient temperature in the hydrocarbonaceous fuel in which it is to be used to provide a homogeneous solution containing the compound or component in at least the lowest concentration of the concentration ranges specified herein for such compound or component.
  • the manganese compounds -- component a) -- of the compositions of this invention are characterised by being fuel soluble and by having at least one carbonyl group bonded to a manganese atom.
  • the most desirable general type of manganese carbonyl compounds utilised in accordance with this invention comprise organomanganese polycarbonyl compounds.
  • organomanganese polycarbonyl compounds For best results, use should be made of a cyclopentadienyl manganese tricarbonyl compound of the type described in U. S. Pat. Nos. 2,818,417 and 3,127,351.
  • cyclopentadienyl manganese tricarbonyl methylcyclopentadienyl manganese tricarbonyl, ethylcyclopentadienyl manganese tricarbonyl, dimethylcyclopentadienyl manganese tricarbonyl, trimethylcyclopentadienyl manganese tricarbonyl, propylcyclopentadienyl manganese tricarbonyl, isopropylcyclopentadienyl manganese tricarbonyl, butylcyclopentadienyl manganese tricarbonyl, pentylcyclopentadienyl manganese tricarbonyl, hexylcyclopentadienyl manganese tricarbonyl, ethylmethylcyclopentadienyl manganese tricarbonyl, dimethyloctylcyclopentadienyl manganese tricarbonyl, dodecylcyclopenta
  • a preferred organomanganese compound is cyclopentadienyl manganese tricarbonyl. Particularly preferred for use in the practise of this invention is methylcyclopentadienyl manganese tricarbonyl.
  • organomanganese compounds which may be employed include the non-ionic diamine manganese tricarbonyl halide compounds such as bromo manganese dianiline tricarbonyl and bromo manganese dipyridine tricarbonyl, described in U. S. Pat. No. 2,902,489; the acyl manganese tricarbonyls such as methylacetyl cyclopentadienyl manganese tricarbonyl and benzoyl methyl cyclopentadienyl manganese tricarbonyl, described in U. S. Pat. No.
  • cyclopentadienyl manganese dicarbonyl compounds of the formula RMn(CO)2L where R is a substituted or unsubstituted cyclopentadienyl group having 5 to 18 carbon atoms, and L is a ligand, such as an olefin, an amine, a phosphine, SO2, tetrahydrofuran, or the like.
  • R is a substituted or unsubstituted cyclopentadienyl group having 5 to 18 carbon atoms
  • L is a ligand, such as an olefin, an amine, a phosphine, SO2, tetrahydrofuran, or the like.
  • Such compounds are referred to, for example in, Herberhold, M., Metal ⁇ -Complexes , Vol. II, Amsterdam, Elsevier, 1967 or Giordano, P. J. and Weighton, M.S., Inorg. Chem. ,
  • the metal-containing detergents are exemplified by oil-soluble neutral and basic salts of alkali or alkaline earth metals with one or more of the following acidic substances (or mixtures thereof): (1) sulphonic acids, (2) carboxylic acids, (3) salicylic acids, (4) alkylphenols, (5) sulphurised alkylphenols, (6) organic phosphorus acids characterised by at least one direct carbon-to-phosphorus linkage.
  • Such organic phosphorus acids include those prepared by the treatment of an olefin polymer (e.g., polyisobutene having a molecular weight of 1000) with a phosphorising agent such as phosphorus trichloride, phosphorus heptasulfide, phosphorus pentasulphide, phosphorus trichloride and sulphur, white phosphorus and a sulphur halide, or phosphorothioic chloride.
  • a phosphorising agent such as phosphorus trichloride, phosphorus heptasulfide, phosphorus pentasulphide, phosphorus trichloride and sulphur, white phosphorus and a sulphur halide, or phosphorothioic chloride.
  • phosphorising agent such as phosphorus trichloride, phosphorus heptasulfide, phosphorus pentasulphide, phosphorus trichloride
  • basic salt is used to designate metal salts wherein the metal is present in stoichiometrically larger amounts than the organic acid radical.
  • the commonly employed methods for preparing the basic salts involve heating a mineral oil solution of an acid with a stoichiometric excess of a metal neutralising agent such as the metal oxide, hydroxide, carbonate, bicarbonate, or sulphide at a temperature of about 50°C, and filtering the resulting mass.
  • a “promoter” in the neutralisation step to aid the incorporation of a large excess of metal likewise is known.
  • Examples of compounds useful as the promoter include phenolic substances such as phenol, naphthol, alkylphenol, thiophenol, sulphurised alkylphenol, and condensation products of formaldehyde with a phenolic substance; alcohols such as methanol, 2-propanol, octyl alcohol, cellosolve, carbitol, ethylene glycol, stearyl alcohol, and cyclohexyl alcohol; and amines such as aniline, phenylenediamine, phenothiazine, phenyl-beta-naphthylamine, and dodecylamine.
  • a particularly effective method for preparing the basic salts comprises mixing an acid with an excess of a basic alkaline earth metal neutralising agent and at least one alcohol promoter, and carbonating the mixture at an elevated temperature such as 60°-200°C.
  • suitable metal-containing detergents include, but are not limited to, such substances as lithium phenates, sodium phenates, potassium phenates, calcium phenates, magnesium phenates, sulphurised lithium phenates, sulphurised sodium phenates, sulphurised potassium phenates, sulphurised calcium phenates, and sulphurised magnesium phenates wherein each aromatic group has one or more aliphatic groups to impart hydrocarbon solubility; the basic salts of any of the foregoing phenols or sulphurised phenols (often referred to as "overbased" phenates or "overbased sulphurised phenates”); lithium sulphonates, sodium sulphonates, potassium sulphonates, calcium sulphonates, and magnesium sulphonates wherein each sulphonic acid moiety is attached to an aromatic nucleus which in turn usually contains one or more aliphatic substituents to impart hydrocarbon solubility; the basic salts of any of the foregoing
  • salts of two or more different alkali and/or alkaline earth metals can be used.
  • salts of mixtures of two or more different acids or two or more different types of acids e.g., one or more calcium phenates with one or more calcium sulphonates
  • rubidium, cesium and strontium salts are feasible, their expense renders them impractical for most uses.
  • barium salts are effective, the status of barium as a heavy metal under a toxicological cloud renders barium salts less preferred for present-day usage.
  • Ashless dispersants are described in numerous patent specifications, mainly as additives for use in lubricant compositions, but their use in hydrocarbon fuels has also been described. Ashless dispersants leave little or no metal-containing residue on combustion. They generally contain only carbon, hydrogen, oxygen and in most cases nitrogen, but sometimes contain in addition other non-metallic elements such as phosphorus, sulphur or boron.
  • the preferred ashless dispersant is an alkenyl succinimide of an amine having at least one primary amino group capable of forming an imide group.
  • alkenyl succinimides may be formed by conventional methods such as by heating an alkenyl succinic anhydride, acid, acid-ester, acid halide, or lower alkyl ester with an amine containing at least one primary amino group.
  • the alkenyl succinic anhydride may be made readily by heating a mixture of olefin and maleic anhydride to 180°-220°C.
  • the olefin is preferably a polymer or copolymer of a lower monoolefin such as ethylene, propylene and isobutene.
  • the more preferred source of alkenyl group is from polyisobutene having a molecular weight up to 10,000 or higher.
  • the alkenyl group is a polyisobutene group having a molecular weight of 500-5,000, and preferably 900-2,000, especially 900-1,200.
  • Amines which may be employed in forming the ashless dispersant include any that have at least one primary amino group which can react to form an imide group.
  • a few representative examples are: methylamine, 2-ethylhexylamine, n-dodecylamine, stearylamine, N,N-dimethylpropanediamine, N-(3-aminopropyl)morpholine, N-dodecylpropanediamine, N-aminopropyl-piperazine, ethanolamine and N-ethanol-ethylenediamine.
  • the preferred amines are the alkylene polyamines such as propylene diamine, dipropylene triamine, di-(1,2-butylene)triamine, and tetra-(1,2-propylene)pentamine.
  • the most preferred amines are the ethylene polyamines which can be depicted by the formula H2N(CH2CH2NH) n H wherein n is an integer from one to ten. These include: ethylene diamine, diethylene triamine, triethylene tetramine, tetraethylene pentamine and pentaethylene hexamine, including mixtures thereof in which case n is the average value of the mixture. These ethylene polyamines have a primary amine group at each end so can form mono-alkenylsuccinimides and bis-alkenylsuccinimides.
  • ethylene polyamine mixtures usually contain minor amounts of branched species and cyclic species such as N-aminoethyl piperazine, N,N'-bis(aminoethyl)piperazine and N,N'-bis(piperazinyl)ethane.
  • the preferred commercial mixtures have approximate overall compositions falling in the range corresponding to diethylene triamine to tetraethylene pentamine, mixtures generally corresponding in overall makeup to tetraethylene pentamine being most preferred.
  • especially preferred ashless dispersants for use in the present invention are the products of reaction of a polyethylene polyamine, e.g. triethylene tetramine or tetraethylene pentamine with a hydrocarbon substituted carboxylic acid or anhydride made by reaction of a polyolefin, preferably polyisobutene, having a number average molecular weight of 500 to 5,000, preferably 900 to 2,000 and especially 900 to 1,200, with an unsaturated polycarboxylic acid or anhydride, e.g., maleic anhydride, maleic acid and fumaric acid, including mixtures of two or more such substances.
  • a polyethylene polyamine e.g. triethylene tetramine or tetraethylene pentamine
  • a hydrocarbon substituted carboxylic acid or anhydride made by reaction of a polyolefin, preferably polyisobutene, having a number average molecular weight of 500 to 5,000, preferably 900 to 2,000 and especially 900 to
  • alkenyl succinic acid esters and diesters of alcohols containing 1-20 carbon atoms and 1-6 hydroxyl groups Representative examples are described in U.S. Pat. Nos. 3,331,776; 3,381,022; and 3,522,179.
  • the alkenyl succinic portion of these esters corresponds to the alkenyl succinic portion of the succinimides described above including the same preferred and most preferred subgenus, e.g., polyisobutenyl succinic acids wherein the polyisobutenyl group has a number average molecular weight of 500 to 5,000, preferably 900-2,000, especially 900 to 1,200.
  • Alcohols useful in preparing the esters include methanol, ethanol, isobutanol, octadecanol, eicosanol, ethylene glycol, diethylene glycol, tetraethylene glycol, diethylene glycol monoethylether, propylene glycol, tripropylene glycol, glycerol, sorbitol, 1,1,1-trimethylol ethane, 1,1,1-trimethylol propane, 1,1,1-trimethylol butane, pentaerythritol and dipentaerythritol.
  • the succinic esters are readily made by merely heating a mixture of alkenyl succinic acid, anhydrides or lower alkyl (e.g., C1-C4) ester with the alcohol while distilling out water or lower alkanol. In the case of acid-esters less alcohol is used. In fact, acid-esters made from alkenyl succinic anhydrides do not evolve water. In another method the alkenyl succinic acid or anhydrides can be merely reacted with an appropriate alkylene oxide such as ethylene oxide, propylene oxide, and the like, including mixtures thereof.
  • an appropriate alkylene oxide such as ethylene oxide, propylene oxide, and the like, including mixtures thereof.
  • the ashless dispersant is an alkenyl succinic ester-amide mixture.
  • alkenyl succinic ester-amide mixture may be made by heating the above-described alkenyl succinic acids, anhydrides or lower alkyl esters with an alcohol and an amine either sequentially or in a mixture.
  • the alcohols and amines described above are also useful in this embodiment.
  • amino alcohols can be used alone or with the alcohol and/or amine to form the ester-amide mixtures.
  • the amino alcohol can contain 1-20 carbon atoms, 1-6 hydroxy groups and 1-4 amine nitrogen atoms. Examples are ethanolamine, diethanolamine, N-ethanol-diethylene triamine, and trimethylol aminomethane.
  • ester-amide mixtures are described in U.S. Pat. Nos. 3,184,474; 3,576,743; 3,632,511; 3,804,763; 3,836,471; 3,862,981; 3,936,480; 3,948,800; 3,950,341; 3,957,854; 3,957,855; 3,991,098; 4,071,548; and 4,173,540.
  • Such ashless dispersants containing alkenyl succinic residues may, and as is well known, be post-reacted with boron compounds, phosphorus derivatives and/or carboxylic acid acylating agents, e.g. maleic anhydride.
  • Another useful class of ashless dispersants includes the Mannich condensates of hydrocarbyl-substituted phenols, formaldehyde or formaldehyde precursors (e.g. paraformaldehyde) and an amine having at least one primary amine group and containing 1-10 amine groups and 1-20 carbon atoms.
  • Mannich condensates useful in this invention are described in U.S. Pat. Nos.
  • Mannich condensates are those made by condensing a polyisobutenyl phenol wherein the polyisobutyl group has an average molecular weight of about 800-3,000 with formaldehyde or a formaldehyde precursor and an ethylene polyamine having the formula: H2N(CH2CH2NH) n H wherein n is an integer from one to ten or mixtures thereof especially those in which n has an average value of 3-5.
  • a further type of ashless dispersants which can be used comprises interpolymers of oil-solubilising monomers such as decyl methacrylate, vinyl decyl ether and high molecular weight olefins with monomers containing polar substituents, e.g., aminoalkyl acrylates or acrylamides and poly(oxyethylene)-substituted acrylates.
  • polar substituents e.g., aminoalkyl acrylates or acrylamides and poly(oxyethylene)-substituted acrylates.
  • Another class of ashless dispersants which can advantageously be used in the fuel compositions of this invention are the imidazoline dispersants which can be represented by the formula: wherein R1 represents a hydrocarbon group having 1 to 30 carbon atoms, e.g. an alkyl or alkenyl group having 7 to 22 carbon atoms, and R2 represents a hydrogen atoms or a hydrocarbon radical of 1 to 22 carbon atoms, or an aminoalkyl, acylaminoalkyl or hydroxyalkyl radical having 2 to 50 carbon atoms.
  • R1 represents a hydrocarbon group having 1 to 30 carbon atoms, e.g. an alkyl or alkenyl group having 7 to 22 carbon atoms
  • R2 represents a hydrogen atoms or a hydrocarbon radical of 1 to 22 carbon atoms, or an aminoalkyl, acylaminoalkyl or hydroxyalkyl radical having 2 to 50 carbon atoms.
  • Such long-chain alkyl (or long-chain alkenyl) imidazoline compounds may be made by reaction of a corresponding long-chain fatty acid (of formula R1-COOH), for example oleic acid, with an appropriate polyamine.
  • the imidazoline formed is then ordinarily called, for example, oleylimidazoline where the radical R1 represents the oleyl residue of oleic acid.
  • R1 represents the oleyl residue of oleic acid.
  • Other suitable alkyl substituents in the 2- position of these imidazolines include undecyl, heptadecyl, lauryl and erucyl.
  • Suitable N-substituents of the imidazolines i.e.
  • radicals R2 include hydrocarbyl groups, hydroxyalkyl groups, aminoalkyl groups, and acylaminoalkyl groups. Examples of the foregoing groups include methyl, butyl, decyl, cyclohexyl, phenyl, benzyl, tolyl, hydroxyethyl, aminoethyl, oleylaminoethyl and stearylaminoethyl.
  • Suitable ashless dispersants which may be incorporated in the fuel compositions of this invention include the products of condensation of a cyclic anhydride with a straight-chain N-alkylpolyamine of the formula: R-(NH-R'-) n -NH2 where n is an integer at least equal to 1, usually 3 to 5, R is a saturated or unsaturated linear hydrocarbon radical of 10 to 22 carbon atoms and R' is a divalent alkylene or alkylidene radical of 1 to 6 carbon atoms.
  • polyamines examples include N-oleyl-1,3-propanediamine, N-stearyl-1,3-propanediamine, N-oleyl-1,3-butanediamine, N-oleyl-2-methyl-1,3-propanediamine, N-oleyl-1,3-pentanediamine, N-oleyl-2-ethyl-1,3-propanediamine, N-stearyl-1,3-butanediamine, N-stearyl-2-methyl-1,3-propanediamine, N-stearyl-1,3-pentanediamine, N-stearyl-2-ethyl-1,3-propanediamine, N-oleyl-dipropylenetriamine and N-stearyl-dipropylenetriamine.
  • Such linear N-alkylpolyamines are condensed with, e.g., a succinic, maleic, phthalic or hexahydrophthalic acid anhydride which may be substituted by one or more radicals of up to 5 carbon atoms each.
  • Another class of ashless dispersant which can be incorporated in the compositions of the present invention are the products of reaction of an ethoxylated amine made by reaction of ammonia with ethylene oxide with a carboxylic acid of 8 to 30 carbon atoms.
  • the ethoxylated amine may be, for example, mono-, di- or tri-ethanolamine or a polyethoxylated derivative thereof, and the carboxylic acid may be, for example, a straight or branched chain fatty acid of 10 to 22 carbon atoms, a naphthenic acid, a resinic acid or an alkyl aryl carboxylic acid.
  • Still another type or ashless dispersants which can be used in the practise of this invention are the ⁇ -olefin-maleimide copolymers such as are described in U.S. Pat. No. 3,909,215.
  • Such copolymers are alternating copolymers of N-substituted maleimides and aliphatic ⁇ -olefins of from 8 to 30 carbon atoms.
  • the copolymers may have an average of 4 to 20 maleimide groups per molecule.
  • the substituents on the nitrogen of the maleimide may be the same or different and are organic radicals composed essentially of carbon, hydrogen and nitrogen having a total of 3 to 60 carbon atoms.
  • Chevron OFA 425B A commercially available material which is highly suitable for use in this invention is Chevron OFA 425B, and this material is believed to be or comprise an ⁇ -olefin maleimide copolymer of the type described in U.S. Pat. No. 3,909,215. Whatever its composition, it works quite well.
  • ashless dispersants which contain little, if any, halogen atoms such as chlorine atoms.
  • the additive composition contains no detectable amount of halogen.
  • Typical halogen (chlorine)-free ashless dispersants suitable for use in the compositions of this invention include, in addition to various types described hereinabove, those described in the following recently-published applications: WO 9003359 and EP 365288.
  • demulsifying agent improves the water tolerance level of the fuel compositions by minimizing or preventing excessive emulsion formation.
  • Exemplary demulsifiers which may be employed in the practise of this invention include poly(alkylphenol) formaldehyde condensates and the polyalkylenoxy modified reaction products thereof. These compounds are prepared by reacting an alkylphenol with formaldehyde and thereafter reacting the reaction product of the above with a C2 to C6 alkylene oxide such as ethylene oxide and propylene oxide.
  • the demulsifiers have a generalized structural formula wherein U is an alkylene of 2 to 6 carbons; y is an integer averaging between 4 and 10; x is an integer averaging between 4 and 10; and R5 is an alkyl having from 4 to 15 carbon atoms.
  • Preferred demulsifiers described by the above formula are polyethyleneoxy modified methylene bridged poly(alkylphenol) polymers having a polyethyleneoxy chain of 8 to 20 carbons and preferably from 10 to 16 carbons and at least about 75 number percent of the polyethyleneoxy chains being within the range specified.
  • the methylene bridged poly(alkylphenol) portion of the polymer has from 4 to 10 and preferably from 5 to 8 repeating methylene bridged alkylphenol units with 4 to 15 and preferably 6 to 12 carbons in the alkyl group.
  • the alkyl groups are a mixture of alkyls having between 4 and 12 carbon atoms.
  • Illustrative alkylphenols include p-isobutylphenol, p-diisobutylphenol, p-hexylphenol, p-heptylphenol, p-octylphenol, p-tripropylenephenol, and p-dipropylenephenol.
  • demulsifier component is an ammonia-neutralised sulphonated alkylphenol.
  • R1 is a hydrocarbyl group having from 4 to 15 carbon atoms, preferably from 6 to 12.
  • These compounds are prepared by sulphonating an alkylated phenol and thereafter neutralising the sulphonated product with ammonia.
  • demulsifier is an oxyalkylated glycol.
  • These compounds are prepared by reacting a polyhydroxy alcohol such as ethylene glycol, trimethylene glycol, etc., with ethylene or propylene oxide.
  • ethylene glycol trimethylene glycol, etc.
  • propylene oxide ethylene or propylene oxide.
  • Many of the compounds are commercially available from BASF-Wyandotte Chemical Company under the PLURONIC trademark. They are polyethers terminated by hydroxy groups and produced by the block copolymerisation of ethylene oxide and propylene oxide.
  • the ethylene oxide blocks act as the hydrophiles and the propylene oxide blocks as the hydrophobes. They are available in a wide range of molecular weights and with varying ratios of ethylene oxide to propylene oxide.
  • demulsifiers comprises a mixture of alkylaryl sulphonates, polyoxyalkylene glycols and oxyalkylated alkylphenolic resins.
  • Such products are supplied by Petrolite Corporation under the TOLAD trademark.
  • One such propriety product, identified as TOLAD 286K, is understood to be a mixture of these components dissolved in a solvent composed of alkyl benzenes. This product has been found efficacious for use in the compositions of this invention.
  • a related product, TOLAD 286, is also suitable. In this case the product apparently contains the same kind of active ingredients dissolved in a solvent composed of heavy aromatic naphtha and isopropanol.
  • other known demulsifiers can be used.
  • component e) a wide variety of suitable amines are available. This component contributes stability to the systems in which it is employed.
  • component e) is a monoamine although polyamines can be used, if desired.
  • suitable amines include the amines referred to in U.S. Pat. No. 3,909,215 such as tertiary alkyl primary amines including Primene 81R, and amines referred to in EP 188,042, namely alkyldimethylamines in which the alkyl group has 8 to 14 carbon atoms or mixtures thereof.
  • mixed alkyl-cycloalkyl amines such as N-cyclohexyl-N-butyl amine and N-methylcyclohexyl-N-octyl amine, as well as di- and tricycloalkyl amines such as N,N-dicyclohexyl amine, N,N-di-(ethylcyclohexyl)-amine and N,N,N-tricyclohexyl amine.
  • Preferred amines include N-cycloalkyl-N,N-dialkyl amines and N-cycloalkenyl-N,N-dialkylamines such as N-cyclohexyl-N,N-diethyl amine, N-cyclohexyl-N,N-dibutyl amine, N-cycloheptyl-N,N-dimethyl amine, N-cyclooctyl-N,N-dilauryl amine and N-cyclohexenyl-N,N-dipropyl amine. Particularly preferred is N-cyclohexyl-N,N-dimethyl amine. Mixtures of various amines, such as those referred to above, are also suitable for use in accordance with this invention.
  • metal deactivators fall into two broad categories.
  • One category comprises the passivators which are considered to react with the metal surface and thereby passivate the surface.
  • the other category comprises the chelators, i.e., substances which have the capability of reacting or complexing with dissolved metal and/or metal ions.
  • An example of the passivator type is the thiadiazoles such as HITEC 314 additive (Ethyl Petroleum Additives, Ltd.; Ethyl Petroleum Additives, Inc.).
  • Examples of the chelator type of metal deactivators include 8-hydroxyquinoline, ethylene diamine tetracarboxylic acid, ⁇ -diketones such as acetylacetone, ⁇ -ketoesters such as octyl acetoacetate,
  • the preferred metal deactivators which are generally regarded as chelators, are Schiff bases, such as N,N'-disalicylidene-1,2-ethanediamine, N,N'-disalicylidene-1,2-propanediamine, N,N'-disalicylidene-1,2-cyclohexanediamine, and N,N''-disalicylidene-N'-methyl-dipropylenetriamine.
  • Schiff bases such as N,N'-disalicylidene-1,2-ethanediamine, N,N'-disalicylidene-1,2-propanediamine, N,N'-disalicylidene-1,2-cyclohexanediamine,
  • a particular advantage associated with the use of the metal deactivators, especially of the Schiff base chelator type, is their ability to overcome instability caused in certain hydrocarbonaceous base fuels by the presence of typical manganese carbonyl compounds such as the cyclopentadienyl manganese tricarbonyls in combination with typical metal detergents.
  • the most preferred metal deactivators of this type are N,N'-disalicylidene-1,2-alkanediamines and N,N'-disalicylidene-1,2-cycloalkanediamines, especially N,N'-disalicylidene-1,2-propanediamine. Mixtures of metal deactivators can be used.
  • the advantages of this invention may be achieved in any liquid hydrocarbonaceous fuel derived from petroleum, coal, shale and/or tar sands.
  • the base fuels will be derived primarily, if not exclusively, from petroleum.
  • the invention is thus applicable to such fuels as kerosene, jet fuel, aviation fuel, diesel fuel, home heating oil, light cycle oil, heavy cycle oil, light gas oil, heavy gas oil, bunker fuels, residual fuel oils, ultra heavy fuel oils, and in general, any liquid (or flowable) hydrocarbonaceous product suitable for combustion either in an engine (e.g., diesel fuel and gas turbine fuels) or in a burner apparatus (e.g., gas oils, inland heavy fuel oil, residual fuel oils, visbreaker fuel oils and home heating oils,).
  • an engine e.g., diesel fuel and gas turbine fuels
  • a burner apparatus e.g., gas oils, inland heavy fuel oil, residual fuel oils, visbreaker fuel oils and home heating oils,).
  • suitable fuels may include liquid fuels derived from biomass, such as vegetable oils (e.g., rapeseed oil, jojoba oil and cottonseed oil,); or refuse-derived liquid fuels such as fuels derived from municipal and/or industrial wastes; or waste oils and/or liquid waste biomass and its derivatives; or mixtures of any of the foregoing substances.
  • vegetable oils e.g., rapeseed oil, jojoba oil and cottonseed oil,
  • refuse-derived liquid fuels such as fuels derived from municipal and/or industrial wastes; or waste oils and/or liquid waste biomass and its derivatives; or mixtures of any of the foregoing substances.
  • the additive compositions comprising components a), b), c) and at least one of components d), e) and f) -- preferably two of components d), e) and f) and most preferably all three of components d), e) and f) -- are especially useful in heating gas oils and like burner fuels and fuel oils for agricultural and industrial engines.
  • Typical specifications for such fuel oils can be found, for example, in BS 2869 : Part 2 : 1988 of the British Standards Institution.
  • the components of the additive compositions are employed in the fuels in minor amounts sufficient to improve the combustion characteristics and properties of the base hydrocarbonaceous fuel in which they are employed.
  • the amounts will thus vary in accordance with such factors as base fuel type and service conditions for which the finished fuel is intended.
  • concentrations (ppm) of the components (active ingredients) in the base fuels are illustrative:
  • the individual components a), b), and c), and also d), e), and/or f) (if used), can be separately blended into the fuel or can be blended therein in various subcombinations, if desired.
  • the particular sequence of such blending steps is not critical.
  • such components can be blended in the form of a solution in a diluent. It is preferable, however, to blend the components used in the form of an additive concentrate of this invention, as this simplifies the blending operations, reduces the likelihood of blending errors, and takes advantage of the compatibility and solubility characteristics afforded by the overall concentrate.
  • the additive concentrates of this invention will contain components a), b), and c), and optionally, but preferably, one or more of components d), e), and f) in amounts proportioned to yield fuel blends consistent with the concentrations tabulated above.
  • the additive concentrate will contain one or more diluents such as light mineral oils, to facilitate handling and blending of the concentrate.
  • concentrates containing up to 90% by weight of one or more diluents or solvents are frequently used.
  • the additive compositions and fuel compositions of this invention can also contain antioxidant, e.g., one or more phenolic antioxidants, aromatic amine antioxidants, sulphurised phenolic antioxidants, and organic phosphites.
  • antioxidant e.g., one or more phenolic antioxidants, aromatic amine antioxidants, sulphurised phenolic antioxidants, and organic phosphites.
  • Examples include 2,6-di-tert-butylphenol, liquid mixtures of tertiary butylated phenols, 2,6-di-tert-butyl-4-methylphenol, 4,4'-methylenebis(2,6-di-tert-butylphenol), 2,2'-methylenebis(4-methyl-6-tert-butylphenol), mixed methylene-bridged polyalkyl phenols, 4,4'-thiobis(2-methyl-6-tert-butylphenol), N,N'-di-sec-butyl-p-phenylenediamine, 4-isopropylaminodiphenyl amine, phenyl- ⁇ -naphthyl amine, and phenyl- ⁇ -naphthyl amine.
  • Corrosion inhibitors comprise another type of optional additive for use in this invention.
  • dimer and trimer acids such as are produced from tall oil fatty acids, oleic acid and linoleic acid, Products of this type are currently available from various commercial sources, such as, for example, the dimer and trimer acids sold under the HYSTRENE trademark by the Humco Chemical Division of Witco Chemical Corporation and under the EMPOL trademark by Emery Chemicals.
  • alkenyl succinic acid and alkenyl succinic anhydride corrosion inhibitors such as, for example, tetrapropenylsuccinic acid, tetrapropenylsuccinic anhydride, tetradecenylsuccinic acid, tetradecenylsuccinic anhydride, hexadecenylsuccinic acid and hexadecenylsuccinic anhydride.
  • half esters of alkenyl succinic acids having 8 to 24 carbon atoms in the alkenyl group with alcohols such as the polyglycols.
  • Preferred materials are the aminosuccinic acids or derivatives thereof represented by the formula: wherein each of R1, R2, R5, R6 and R7 is, independently, a hydrogen atom or a hydrocarbyl group containing 1 to 30 carbon atoms, and wherein each of R3 and R4 is, independently, a hydrogen atom, a hydrocarbyl group containing 1 to 30 carbon atoms, or an acyl group containing from 1 to 30 carbon atoms.
  • R1, R2, R3, R4, R5, R6 and R7 when in the form of a hydrocarbyl group, can be, for example, alkyl, cycloalkyl or aromatic containing groups.
  • R1 and R5 are the same or different straight-chain or branched-chain hydrocarbon radicals containing 1-20 carbon atoms.
  • R1 and R5 are saturated hydrocarbon radicals containing 3-6 carbon atoms.
  • R2, either R3 or R4, R6 and R7, when in the form of hydrocarbyl groups, are preferably the same or different straight-chain or branched-chain saturated hydrocarbon radicals.
  • a dialkyl ester of an aminosuccinic acid is used in which R1 and R5 are the same or different alkyl groups containing 3-6 carbon atoms, R2 is a hydrogen atom, and either R3 or R4 is an alkyl group containing 15-20 carbon atoms or an acyl group which is derived from a saturated or unsaturated carboxylic acid containing 2-10 carbon atoms.
  • R1 and R5 are isobutyl
  • R2 is a hydrogen atom
  • R3 is octadecyl and/or octadecenyl
  • R4 is 3-carboxy-1-oxo-2-propenyl.
  • R6 and R7 are most preferably hydrogen atoms.
  • the heavier fuels of this invention may contain cold flow improvers and pour-point depressants, e.g., olefin/vinyl acetate copolymers such as ethylene/vinyl acetate copolymers and polymethacrylates. Antifoam agents such as silicones, and dyes can also be used in the compositions of this invention.
  • the diesel fuels may contain cetane improvers such as peroxy compounds and organic nitrates (e.g., amyl nitrates, hexyl nitrates, heptyl nitrates, octyl nitrates, and other alkyl nitrates having 4 to 10 carbon atoms including mixtures thereof).
  • alkyl nitrates are cyclohexyl nitrate, methoxypropyl nitrate, mixed nitrate esters made by nitration of fusel oil, 2-ethylhexyl nitrate, n-octyl nitrate and n-decyl nitrate,
  • Typical peroxy compounds include acetyl peroxide, benzoyl peroxide, tert-butylperoxyacetate, and cumene hydroperoxide.
  • An additive composition is formed by blending together the following components in the amounts specified:
  • This composition is well adapted for use in heating gas oil, for example at treat rates of 250 to 37,000 ppm, typically 500 ppm.
  • An additive composition of this invention is formed using the following:
  • This composition is useful, for example at treat rates of 250 to 37,000 ppm, typically 500 ppm, in heating gas oils.
  • this additive concentrate When used, for example at a concentration in the range of 200 to 26,500 ppm, typically 400 ppm, this additive concentrate is especially adapted for improving combustion of road diesel fuels.
  • An additive concentrate is formed using the following components:
  • Examples 4 and 5 are repeated substituting in one case overbased potassium sulphonate and in another case overbased calcium phenate for the sulphonates of Examples 4 and 5.
  • Examples 1 through 3 The procedures of Examples 1 through 3 are repeated except that in one case the overbased calcium sulphonate is replaced by an equivalent amount of overbased magnesium sulphonate, in another case by an equivalent amount of overbased sodium sulphonate, and in a third case by an equivalent amount of overbased potassium sulphonate.
  • compositions of Examples 1 through 3 are formed with the exception that the methylcyclopentadienyl manganese tricarbonyl is replaced in one case by an equivalent amount of cyclopentadienyl manganese tricarbonyl, in another case by an equivalent amount of cyclopentadienyl manganese dicarboxyl triphenylphosphine, in a third case by an equivalent amount of indenyl manganese tricarbonyl, in a fourth case by an equivalent amount of dimanganese decacarbonyl, and in still another case by an equivalent amount of a mixture composed of 90% methylcyclopentadienyl manganese tricarbonyl and 10% cyclopentadienyl manganese tricarbonyl.
  • compositions of Examples 1 and 2 are blended at concentrations of 300, 500 and 1,000 ppm in a heating gas oil having a specific gravity at 15°C (DIN 51 757) of 0.845 g/mL, a kinematic viscosity at 20°C (DIN 51 562) of 5.3 mm2 per second, a pour point (DIN ISO 3016) of -9°C, a sulphur content (DIN 51 400) of 0.19%, and a distillation profile (DIN 51 751) of 27 volume % boiling to 250°C and 92 volume % boiling to 350°C.
  • Example 9 is repeated except that the same amounts of the respective components of the respective compositions of Examples 1 and 2 are blended individually or in sub-combinations into the gas oil.
  • Example 3 The composition of Example 3 is blended at concentrations of 300, 500, 1,000 and 1,500 ppm in a diesel fuel satisfying the requirements of DIN 51 601-DK (February 1986).
  • Example 11 is repeated except that the same amounts of the respective components of the composition of Example 3 are blended individually or in sub-combinations into the diesel fuel.
  • Examples 9 and 10 are repeated using as the fuels commercially-available heavy fuel oils and residual oils (e.g., industrial and refinery fuel oils) such as inland heavy fuel oils, and also hydrocarbonaceous marine fuels.
  • the additive treat levels in these fuels are 500, 800 and 1,500 ppm.
  • An additive composition is formed by blending together the following components in the amounts specified:
  • This composition is well adapted for use in heating gas oil, for example at treat rates of 250 to 37,000 ppm, typically 500 ppm.
  • Example 15 The procedure of Example 15 is repeated using the following proportions of the additive components:
  • Example 15 The procedure of Example 15 is repeated using the following proportions of the additive components:
  • Standard CFR engine tests (ASTM D613) were conducted using two different diesel fuels having cetane values of 52.7 (Fuel A) and 52.5 (Fuel B), respectively. Addition of 500 ppm of the composition of Example 1 to Fuel A caused no change in cetane rating. In Fuel B only a slight loss in cetane value (from 52.5 to 51.6) occurred by addition of 500 ppm of the composition of Example 1.
  • the same fuels were subjected to thermal stability tests wherein the sample is heated at 150°C for 90 minutes, filtered through a filter and the reflectance of the deposit on the filter measured.
  • the rating scale ranges from 0 (clean) to 20 (black). A rating of 7 or less is considered good.
  • Thermal oxidative stability tests according to ASTM D 2274 were also performed on these fuels. The performance in these tests is expressed in terms of milligrams of deposit per 100 milliliters of fuel. The results were as follows:
  • the tailpipe emissions produced by the same pair of fuel compositions were also determined during operation of the above Mercedes-Benz diesel engine. It was found that the emission of hydrocarbons was reduced from 0.627 grams per horsepower hour to 0.527 grams per horsepower hour by the presence in the fuel of the 400 ppm of the additive composition of Example 3. Likewise, the total particulates emitted by the clear fuel amounted to 0.3574 grams per horsepower hour whereas the total particulates emitted by the fuel containing 400 ppm of the additive composition of Example 3 amounted to only 0.3063 grams per horsepower hour. These reductions were achieved without significant change in NOx and carbon monoxide emission levels.
  • the fuels of this invention generally possess enhanced combustion properties (e.g., less smoke, lower soot acidity) and better thermal stability than the corresponding untreated fuels.
  • use of the fuels of this invention results in the formation of reduced amounts of sludge deposits on critical engine or burner parts or surfaces. Further, such fuels tend to emit smaller amounts of noxious emissions than the corresponding untreated base fuels.
  • this invention enables the provision of fuel compositions having enhanced demulsification properties and reduced corrosion tendencies with minimal interference with other desirable fuel properties.
  • the results of the foregoing tests also indicate that the additive compositions of this invention can result in decreased fuel consumption in diesel engines.
  • the data also indicate that all fuels do not necessarily respond to the same extent to treatment with the additive systems of this invention. Nonetheless, as a general proposition, the fuels of this invention do have significantly improved properties.
  • Also included among the embodiments of this invention are methods of improving the combustion characteristics of an at least predominantly hydrocarbonaceous liquid fuel during combustion in an engine, burner, or other combustion apparatus which comprises operating said engine, burner or other combustion apparatus on an at least predominantly hydrocarbonaceous liquid fuel containing a minor combustion-improving amount of:

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Lubricants (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Claims (23)

  1. Composition de combustible qui comprend une quantité dominante d'un combustible hydrocarboné liquide renfermant une petite quantité, améliorant la combustion,
    a) d'au moins un composé carbonylé de manganèse soluble dans le combustible ;
    b) d'au moins un détergent contenant un métal alcalin ou alcalino-terreux, soluble dans le combustible ;
    c) d'au moins un dispersant sans cendres, soluble dans le combustible ;
    d) facultativement, d'au moins un agent désémulsionnant soluble dans le combustible ;
    e) facultativement, d'au moins une amine aliphatique ou cycloaliphatique, soluble dans le combustible ; et
    f) facultativement, d'au moins un passivateur de métaux, soluble dans le combustible.
  2. Composition suivant la revendication 1, dans laquelle le constituant a) comprend au moins un composé du type cyclopentadiényl-manganèse-tricarbonyle.
  3. Composition suivant la revendication 1, dans laquelle le constituant a) comprend du méthylcyclopentadiényl-manganèse-tricarbonyle.
  4. Composition suivant l'une quelconque des revendications 1 à 3, dans laquelle le constituant b) comprend au moins un détergent surbasique contenant un métal alcalin ou alcalino-terreux.
  5. Composition suivant l'une quelconque des revendications 1 à 3, dans laquelle le constituant b) comprend au moins un détergent surbasique contenant un métal alcalino-terreux.
  6. Composition suivant l'une quelconque des revendications 1 à 3, dans laquelle le constituant b) comprend au moins un détergent surbasique contenant du calcium.
  7. Composition suivant la revendication 6, dans laquelle le constituant b) comprend au moins un détergent surbasique à base de sulfonate, phénate ou phénate sulfuré de calcium.
  8. Composition suivant l'une quelconque des revendications précédentes, dans laquelle le constituant c) comprend au moins un dispersant basique sans cendres contenant de l'azote.
  9. Composition suivant la revendication 8, dans laquelle le constituant c) comprend au moins un dispersant sans cendres du type succinimide.
  10. Composition suivant la revendication 9, dans laquelle le constituant c) comprend un succinimide à substituant polyoléfinique d'au moins une polyéthylènepolyamine ayant une composition moyenne totale comprise dans la plage de la triéthylènetétramine à la pentaéthylènehexamine, telle qu'un polyisobuténylsuccinimide d'un mélange de polyéthylènepolyamines acycliques et cycliques, mélange qui possède la composition approximative correspondant à la tétraéthylènepentamine.
  11. Composition suivant la revendication 10, dans laquelle le substituant polyisobutényle du succinimide possède une moyenne numérique du poids moléculaire de 900 à 2000.
  12. Composition suivant l'une quelconque des revendications précédentes, qui contient e) au moins une N-cycloalkyl-N,N-dialkylamine soluble dans le combustible, telle que la N-cyclohexyl-N,N-diméthylamine.
  13. Composition suivant l'une quelconque des revendications précédentes, qui contient f) au moins un passivateur de métaux du type chélateur, soluble dans le combustible, de préférence une N,N'-disalicylidène-1,2-alcanediamine ou N,N'-disalicylidène-1,2-cycloalcanediamine, telle que le N,N'-disalicylidène-1,2-propanediamine.
  14. Composition suivant l'une quelconque des revendications précédentes, dans laquelle les proportions (ppm) des constituants a), b) et c) dans le combustible de base sont respectivement égales à 1,5-10 000, 4-10 000 et 5-15 000.
  15. Composition suivant la revendication 14, dans laquelle le rapport (ppm) des constituants a), b) et c) dans le combustible de base est égal, respectivement, à 2,5-1500 : 5-6000 : 7-10 000.
  16. Composition suivant la revendication 15, dans laquelle le rapport (ppm) des constituants a), b) et c) est égal, respectivement, à 3-100 : 6-300 : 8-5000.
  17. Composition suivant la revendication 16, dans laquelle le rapport (ppm) des constituants a), b) et c) est égal, respectivement à 3-25 : 6-100 : 10-200.
  18. Composition suivant l'une quelconque des revendications précédentes, qui contient 0 à 10 ppm d'halogène incorporé et qui est de préférence dépourvue d'une quelconque quantité détectable d'halogène incorporé.
  19. Composition d'additif pour combustible, qui comprend les ingrédients a), b), c), facultativement d), facultativement e) et facultativement f) tels qu'ils sont définis dans l'une quelconque des revendications 1 à 17.
  20. Procédé pour améliorer les caractéristiques de combustion d'au moins un combustible liquide hydrocarboné prédominant, par exemple au cours de la combustion dans un moteur, un brûleur ou un autre appareil de combustion, qui compred le mélange à ce combustible d'une petite quantité, améliorant la combustion, des ingrédients a), b), c), facultativement d), facultativement e) et facultativement f), tels qu'ils sont définis dans l'une quelconque des revendications 1 à 17.
  21. Composition de combustible suivant l'une quelconque des revendications 1 à 17, dans laquelle le combustible est un combustible Diesel contenant un agent améliorant l'indice de cétane choisi entre des composés à fonction peroxy et des nitrates organiques.
  22. Composition de combustible suivant la revendication 21, dans laquelle l'agent améliorant l'indice de cétane est un nitrate d'alkyle ayant 4 à 10 atomes de carbone.
  23. Composition de combustible suivant la revendication 22, dans laquelle l'agent améliorant l'indice de cétane est le nitrate de 2-éthylhexyle.
EP90310322A 1990-09-20 1990-09-20 Compositions combustibles hydrocarburées et additifs pour celles-ci Expired - Lifetime EP0476196B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
ES90310322T ES2060058T3 (es) 1990-09-20 1990-09-20 Composiciones de combustible hidrocarbonado y aditivos para las mismas.
EP90310322A EP0476196B1 (fr) 1990-09-20 1990-09-20 Compositions combustibles hydrocarburées et additifs pour celles-ci
DE90310322T DE69004692T2 (de) 1990-09-20 1990-09-20 Kohlenwasserstoffzusammensetzungen und Zusätze dafür.
CA002051452A CA2051452C (fr) 1990-09-20 1991-09-16 Compositions de carburants hydrocarbones et additifs connexes
JP3265442A JPH04234489A (ja) 1990-09-20 1991-09-18 炭化水素性燃料およびその添加剤
AU84650/91A AU635158B2 (en) 1990-09-20 1991-09-20 Hydrocarbonaceous fuel compositions and additives therefor
US09/107,577 US5944858A (en) 1990-09-20 1998-02-17 Hydrocarbonaceous fuel compositions and additives therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP90310322A EP0476196B1 (fr) 1990-09-20 1990-09-20 Compositions combustibles hydrocarburées et additifs pour celles-ci

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EP0476196A1 EP0476196A1 (fr) 1992-03-25
EP0476196B1 true EP0476196B1 (fr) 1993-11-18

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Families Citing this family (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0557516B1 (fr) * 1991-09-13 1996-07-17 Chevron Chemical Company Compositions additives pour carburant contenant des succinimides de polyisobutenyle
GB9122158D0 (en) * 1991-10-18 1991-11-27 Exxon Chemical Patents Inc Fuel oil compositions
AU668151B2 (en) * 1992-05-06 1996-04-26 Afton Chemical Corporation Composition for control of induction system deposits
US5551957A (en) * 1992-05-06 1996-09-03 Ethyl Corporation Compostions for control of induction system deposits
AT397509B (de) * 1992-08-03 1994-04-25 Loba Feinchemie Aktiengesellsc Zusatzstoff für mineralöle und mineralölprodukte, speziell elektroisolieröle
AU661604B2 (en) * 1992-08-17 1995-07-27 General Electric Company Endothermic fuel additive to inhibit catalyst coking
GB2279965A (en) * 1993-07-12 1995-01-18 Ethyl Petroleum Additives Ltd Additive compositions for control of deposits, exhaust emissions and/or fuel consumption in internal combustion engines
GB9315205D0 (en) * 1993-07-22 1993-09-08 Exxon Chemical Patents Inc Additives and fuel compositions
GB9316021D0 (en) * 1993-08-03 1993-09-15 Exxon Chemical Patents Inc Additive for hydrocarbon oils
GB9321370D0 (en) * 1993-10-13 1993-12-08 Exxon Chemical Patents Inc Fuel additives
AU677114B2 (en) * 1993-12-23 1997-04-10 Afton Chemical Limited Evaporative burner fuels and additives therefor
GB2285057B (en) * 1993-12-23 1997-12-10 Ethyl Petroleum Additives Ltd Evaporative burner fuels and additives therefor
US5511517A (en) * 1994-02-10 1996-04-30 Ethyl Corporation Reducing exhaust emissions from otto-cycle engines
GB2289287A (en) * 1994-05-04 1995-11-15 Ethyl Petroleum Additives Ltd Fuel foam control additive
CA2194572A1 (fr) * 1994-05-31 1995-12-07 William C. Orr Procedes et compositions pour combustion en phase vapeur
US6070558A (en) * 1994-11-16 2000-06-06 The Lubrizol Corporation Process for reducing liner lacquering in a marine diesel engine and fuel therefor
GB9423259D0 (en) * 1994-11-16 1995-01-04 Bp Chemicals Additives Marine diesel fuels
GB9503104D0 (en) * 1995-02-17 1995-04-05 Bp Chemicals Additives Diesel fuels
JPH11504355A (ja) * 1995-04-24 1999-04-20 ジ アソシエーテッド オクテル カンパニー エルティーディー 改良された燃焼法
JPH11504974A (ja) * 1995-06-07 1999-05-11 オア，ウィリアム，シー． 蒸気相燃焼法および組成物ｉｉ
CA2205143C (fr) * 1996-05-14 2003-07-15 Ethyl Corporation Procede et produits permettant d'ameliorer l'efficacite de combustion de combustibles de chauffage hydrocarbones
GB9610563D0 (en) * 1996-05-20 1996-07-31 Bp Chemicals Additives Marine diesel process and fuel therefor
EP0829527A1 (fr) * 1996-09-12 1998-03-18 Exxon Research And Engineering Company Concentré additif pour des compositions de combustibles
US5925151A (en) * 1996-09-19 1999-07-20 Texaco Inc Detergent additive compositions for diesel fuels
DE19643832A1 (de) 1996-10-30 1998-05-07 Clariant Gmbh Schwere Öle mit verbesserten Eigenschaften und ein Additiv dafür
GB2322138A (en) * 1997-02-17 1998-08-19 Ethyl Petroleum Additives Ltd Foam reducing fuel additive
JP4620814B2 (ja) * 1997-04-23 2011-01-26 ザ ルブリゾル コーポレイション カルボン酸混合物を含有するディーゼル燃料
US6042626A (en) * 1997-08-01 2000-03-28 Ethyl Corporation Phosphorylated and/or boronated dispersants as thermal stability additives for distillate fuels
WO1999036489A1 (fr) * 1998-01-13 1999-07-22 Baker Hughes Incorporated Composition et procede permettant d'ameliorer le pouvoir lubrifiant des combustibles
CN1122702C (zh) 1998-12-29 2003-10-01 中国石油化工集团公司 一种烃类催化裂化硫转移助剂及其使用方法
GB9907058D0 (en) * 1999-03-26 1999-05-19 Infineum Uk Ltd Fuel oil compositions
US8211190B2 (en) 1999-03-26 2012-07-03 Infineum International Limited Fuel oil compositions
CA2308554A1 (fr) * 1999-06-22 2000-12-22 Scott D. Schwab Additifs phosphoryles pour augmenter la stabilite thermique de mazouts legers
US6361573B1 (en) * 1999-08-31 2002-03-26 Ethyl Corporation Fuel dispersants with enhanced lubricity
US6514297B1 (en) * 1999-11-24 2003-02-04 The Lubrizol Corporation Detergents for use in preventing formation of iron complexes in hydrocarbon fuels
GB0011908D0 (en) * 2000-05-16 2000-07-05 Infineum Int Ltd Process for operating diesel engines
IT1318868B1 (it) * 2000-08-03 2003-09-10 Cesare Pedrazzini Additivo per ridurre il particolato nelle emissioni derivanti dallacombustione di gasolio ed olio combustibile e composizione carburante
EP1344812A1 (fr) * 2002-03-13 2003-09-17 Infineum International Limited Compositions additives de sel métallique surbasique pour combustible diesel pour l'amélioration de pièges à particules
WO2003106595A2 (fr) * 2002-06-14 2003-12-24 The Lubrizol Corporation Composition de concentre d'additif de carburant aviation, composition de carburant et procedes correspondants
JP2004035882A (ja) * 2002-07-03 2004-02-05 Infineum Internatl Ltd 粒状物トラップ改良のための過塩基化金属塩ディーゼル燃料添加剤組成物
DE20212106U1 (de) * 2002-08-06 2003-03-06 Grafenhorst, Heinrich, 28215 Bremen Gasturbinenantrieb, insbesondere für Propeller-Flugzeuge
US7094274B2 (en) * 2003-04-17 2006-08-22 Afton Chemical Intangibles Llc Use of manganese compounds to improve the efficiency of and reduce back-corona discharge on electrostatic precipitators
EP1484387A1 (fr) * 2003-06-04 2004-12-08 Shell Internationale Researchmaatschappij B.V. Réduction de la corrosion dans les chauffe-eau
EP1484388A1 (fr) * 2003-06-04 2004-12-08 Shell Internationale Researchmaatschappij B.V. Réduction de la corrosion dans les chauffe-eau
US20040261313A1 (en) * 2003-06-25 2004-12-30 The Lubrizol Corporation, A Corporation Of The State Of Ohio Gel additives for fuel that reduce soot and/or emissions from engines
US20050005506A1 (en) * 2003-07-08 2005-01-13 Henly Timothy J. Distillate fuel compositions for improved combustion and engine cleanliness
US7402186B2 (en) 2004-02-09 2008-07-22 The Lubrizol Corporation Fuel composition containing a medium substantially free of sulphur and process thereof
ES2245872B2 (es) * 2004-03-22 2006-12-01 Repsol Ypf, S.A. Composicion de gasoleo o combustible destilado medio estabilizado.
DE102005032119A1 (de) * 2005-07-07 2007-01-18 Octel Deutschland Gmbh Russarm verbrennendes Heizöl
US20070094918A1 (en) * 2005-10-12 2007-05-03 Sawhney Kailash N Composition and method for enhancing the stability of jet fuels
CN101370916B (zh) * 2006-01-18 2012-11-07 巴斯夫欧洲公司 单羧酸和多环烃化合物的混合物在改善燃料添加剂浓缩物的储存稳定性中的用途
EP1847583A3 (fr) * 2006-04-21 2008-11-05 Infineum International Limited Biocarburant amélioré
GB0700534D0 (en) 2007-01-11 2007-02-21 Innospec Ltd Composition
EP2342311B1 (fr) * 2008-09-17 2016-03-09 ExxonMobil Research and Engineering Company Procédé destiné à améliorer la stabilité à l oxydation du biodiesel, telle que mesurée par le test rancimat
FR2977895B1 (fr) * 2011-07-12 2015-04-10 Total Raffinage Marketing Compositions d'additifs ameliorant la stabilite et les performances moteur des gazoles non routiers

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3490882A (en) * 1966-08-11 1970-01-20 Du Pont Stabilized distillate fuel oils and additive compositions therefor
US3994698A (en) * 1972-02-29 1976-11-30 Ethyl Corporation Gasoline additive concentrate composition
US3883320A (en) * 1972-12-07 1975-05-13 Standard Oil Co Reducing deposits and smoke from jet fuels with additives incorporating an ammonium salt
US4116644A (en) * 1975-03-24 1978-09-26 Jackisch Philip F Gasoline compositions
AT373274B (de) * 1981-10-12 1984-01-10 Lang Chem Tech Prod Zusatz mit verbrennungsfoerdernder und russhemmender wirkung zu heizoelen, dieselkraftstoffen und sonstigen fluessigen brenn- und treibstoffen, sowie fluessige brennund treibstoffe mit diesem zusatz
US4690687A (en) * 1985-08-16 1987-09-01 The Lubrizol Corporation Fuel products comprising a lead scavenger
US4781730A (en) * 1987-06-05 1988-11-01 The Lubrizol Corporation Fuel additive comprising a hydrocarbon soluble alkali or alkaline earth metal compound and a demulsifier
JP2644602B2 (ja) * 1988-01-27 1997-08-25 ザ ルブリゾル コーポレーション 燃料組成物

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DE69004692T2 (de) 1994-03-10
AU8465091A (en) 1992-03-26
CA2051452A1 (fr) 1992-03-21
JPH04234489A (ja) 1992-08-24
ES2060058T3 (es) 1994-11-16
EP0476196A1 (fr) 1992-03-25
AU635158B2 (en) 1993-03-11
DE69004692D1 (de) 1993-12-23
CA2051452C (fr) 2002-11-19

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