EP0462059B1 - Adjuvants textiles aqueux, peu moussants et exempts de silicones, leur préparation et leur application - Google Patents

Adjuvants textiles aqueux, peu moussants et exempts de silicones, leur préparation et leur application Download PDF

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Publication number
EP0462059B1
EP0462059B1 EP19910810421 EP91810421A EP0462059B1 EP 0462059 B1 EP0462059 B1 EP 0462059B1 EP 19910810421 EP19910810421 EP 19910810421 EP 91810421 A EP91810421 A EP 91810421A EP 0462059 B1 EP0462059 B1 EP 0462059B1
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Prior art keywords
component
textile auxiliary
auxiliary composition
acid
weight
Prior art date
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EP19910810421
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German (de)
English (en)
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EP0462059A3 (en
EP0462059A2 (fr
Inventor
Christian Guth
Albert Stehlin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Geigy AG
Ciba Spezialitaetenchemie Holding AG
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3788—Graft polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937—Stabilising agents
    • C11D3/394—Organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D06L1/14—De-sizing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/8305—Miscellaneous [e.g., treated surfaces, etc.]

Definitions

  • the present invention relates to low-foaming, silicone-free, aqueous textile auxiliaries, their production and multiple uses, e.g. as wetting agents, detergents, dispersants or as stabilizers in peroxide bleaching liquors.
  • EP-A-0,360,736 discloses a wetting and washing agent which comprises (a) a mixture of monomeric and oligomeric phosphoric acid esters, (b) a copolymer of monomeric carboxylic or sulfonic acids and polyalkylene oxide adducts, (c) a nonionic surfactant and (e) a Contains antifoam as an optional component. It is used in textile pretreatment.
  • EP-A-0,299,691 discloses a stable composition which contains (a) an emulsion stabilizer which is prepared by the polymerization of an unsaturated carboxylic acid such as acrylic acid in the presence of a water-soluble nonionic surfactant and (b) a free nonionic surfactant, and as suitable hydrotrope diisonaphthalene monosulfonate.
  • the composition is used in textile treatment to remove hydrocarbonaceous dirt.
  • the low-foaming, silicone-free, aqueous textile auxiliaries according to the invention are characterized in that they contain components (a), (b) and optionally (c) listed in claim 1.
  • the substituent R in formula (1) advantageously represents the hydrocarbon radical of an unsaturated or saturated aliphatic monoalcohol with 8 to 22 carbon atoms.
  • the hydrocarbon radical can be straight-chain or branched.
  • R is preferably an alkyl or alkenyl radical having 9 to 14 carbon atoms.
  • Lower alkyl means hydrocarbon radicals which have 1 to 5, in particular 1 to 4, carbon atoms. Examples of such groups are methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, tert-butyl, amyl, isoamyl or tert-amyl.
  • aliphatic saturated monoalcohols natural alcohols, such as, for example, lauryl alcohol, myristyl alcohol, cetyl alcohol or stearyl alcohol, and synthetic alcohols, such as, for example, 2-ethylhexanol, 1,1,3,3-tetramethylbutanol, octan-2-ol, isononyl alcohol, trimethylhexanol, trimethylnonyl alcohol
  • Decanol, C 9 -C 11 oxo alcohol, tridecyl alcohol, isotridecanol or linear primary alcohols (alfoles) with 8 to 18 carbon atoms can be used. Some representatives of these alfoles are Alfol (8-10), Alfol (9-11), Alfol (10-14), Alfol (12-13) or Alfol (16-18).
  • Alfol is a registered trademark).
  • Unsaturated aliphatic monoalcohols are, for example, dodecenyl alcohol, hexadecenyl alcohol or oleyl alcohol.
  • the alcohol residues can be present individually or in the form of mixtures of two or more components, e.g. Mixtures of alkyl and / or alkenyl groups derived from soy fatty acids, palm kernel fatty acids or tallow oils.
  • Alkylene-O p chains are preferably of the ethylene glycol, ethylene propylene glycol or ethylene isopropylene glycol type; p is preferably 4 to 20.
  • the nonionic surfactants of the formulas (1) and (4) are prepared in a manner known per se, for example by reacting the corresponding alkylene oxide addition products with thionyl chloride and then reacting the chlorine compound formed with a short-chain, cycloaliphatic, fatty, lower alkylphenyl or Styryl alcohol.
  • Acid water-solubilizing groups from which component (a) is obtained are e.g. Carbonyl and / or sulfonic acid groups.
  • Ethylenically unsaturated polymerizable carboxylic or sulfonic acids are suitable. Both monocarboxylic acids and dicarboxylic acids and their anhydrides as well as sulfonic acids, each of which has an ethylenically unsaturated aliphatic radical and preferably at most 7 carbon atoms, can be used.
  • the monocarboxylic acids are e.g. acrylic acid, methacrylic acid, ⁇ -haloacrylic acid, 2-hydroxyethylacrylic acid, ⁇ -cyanoacrylic acid, crotonic acid and vinyl acetic acid.
  • Ethylenically unsaturated dicarboxylic acids are preferably fumaric acid, maleic acid or itaconic acid, furthermore mesaconic acid, citraconic acid, glutaconic acid and methylmalonic acid.
  • Maleic anhydride is particularly mentioned as the anhydride of these acids.
  • Suitable sulfonic acids are vinylsulfonic acid or 2-acrylamido-2-methylpropanesulfonic acid.
  • Monocarboxylic acids having 2 to 5 carbon atoms in particular methacrylic acid and especially acrylic acid, are preferred.
  • Practically important compounds corresponding to component (a) are those which have been obtained from 5 to 50% by weight of a nonionic surfactant of the formula (4) and 95 to 50% by weight of acrylic acid or methacrylic acid.
  • the compounds of component (a) of the composition according to the invention are prepared by methods known per se, expediently such that the corresponding nonionic surfactant is first mixed with at least 20% by weight, based on the end product, of an ethylenically unsaturated compound which has acidic, water-solubilizing groups, such as, for example, matching carboxylic acids, their anhydrides or sulfonic acids, and then carrying out the reaction in the presence of catalysts, expediently at a temperature of 60 to 100.degree.
  • Free radical-forming organic initiators are preferably used as catalysts.
  • Suitable initiators for carrying out the reaction are e.g. symmetrical aliphatic azo compounds such as azo-bis-isobutyronitrile, azo-bis-2-methylvaleronitrile, 1,1'-azo-bis-1-cyclo-hexanitrile and 2,2'-azo-bis-isobutyric acid alkyl ester; symmetrical diacyl peroxides, e.g.
  • Suitable peroxides are: tert-butyl hydroperoxide, di-tert-butyl peroxide, cumene hydroperoxide, di-cumene peroxide and tert-butyl perpivalate.
  • Another suitable compound is potassium persulfate, which is preferably used in the present invention.
  • the catalysts are generally used in amounts of 0.1 to 10% by weight, preferably 0.5 to 2% by weight, based on the starting products.
  • the reaction is advantageously carried out in an inert atmosphere, for example in the presence of nitrogen.
  • Optional component (c) is 2-ethylkenyl sulfate.
  • the textile auxiliary mixtures according to the invention can be prepared by simply stirring components (a), (b) and optionally (c).
  • the preparation is preferably carried out by mixing components (a), (b) and optionally (c) with stirring and adding deionized water until a homogeneous solution is obtained.
  • the new mixtures are low-foaming, APEO and silicone-free textile auxiliaries. Due to their liquid commercial form, they are easy to handle, which is why they are particularly suitable for modern dosing systems. You are universal can be used and can therefore be considered for various applications.
  • they can be used as wetting agents, textile detergents, dispersants or as stabilizers in peroxide bleaching liquors.
  • Possible fiber materials are: cellulose, especially untreated natural cellulose such as hemp, linen, jute, cellulose, viscose, acetate treyon, native cellulose fiber and especially raw cotton, wool, polyamide, polyacrylonitrile or polyester fiber materials as well as fiber blends, e.g. those made of polyacrylonitrile / cotton or polyester / cotton.
  • the fiber material to be treated can be in various processing stages, e.g. the cellulose-containing material as loose material, yarn, woven or knitted fabric. As a rule, these are always textile fiber materials which are produced from pure textile cellulose fibers or from mixtures of textile cellulose fibers with textile synthetic fibers.
  • the fiber material can be treated continuously or batchwise in an aqueous liquor.
  • the aqueous treatment liquors can be applied to the fiber materials in a known manner, advantageously by impregnation on the padder, the liquor absorption being about 70 to 120% by weight.
  • the padding process is used in particular in the pad-steam process and pad-batch process.
  • the impregnation can be carried out at 10 to 60 ° C, but preferably at room temperature.
  • the cellulose material is optionally subjected to a heat treatment, e.g. Subject at temperatures from 80 to 140 ° C.
  • the heat treatment is preferably carried out by steaming at 95 to 140 ° C., preferably 100 to 106 ° C. Depending on the type of heat development and the temperature range, the heat treatment can take 30 seconds to 60 minutes.
  • the impregnated goods are rolled up without drying and then optionally packed with a plastic film and stored at room temperature for 1 to 24 hours.
  • the treatment of the fiber materials can also be carried out in long liquors with a liquor ratio of e.g. 1: 3 to 1: 100, preferably 1: 4 to 1:25 and at 10 to 100, preferably 60 to 98 ° C for about 1/4 to 3 hours under normal conditions, i.e. under atmospheric pressure in conventional equipment, e.g. a jigger, jet or reel runner.
  • a liquor ratio of e.g. 1: 3 to 1: 100, preferably 1: 4 to 1:25 and at 10 to 100, preferably 60 to 98 ° C for about 1/4 to 3 hours under normal conditions, i.e. under atmospheric pressure in conventional equipment, e.g. a jigger, jet or reel runner.
  • the treatment up to 150 ° C, preferably 105 to 140 ° C under pressure in so-called high-temperature equipment (HT equipment) can be carried out.
  • HT equipment high-temperature equipment
  • the fiber materials are then, if required by the process, with hot Water from about 90 to 98 ° C and then thoroughly rinsed with warm and finally with cold water, neutralized if necessary and then preferably dried at elevated temperatures.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Claims (10)

  1. Adjuvants textiles aqueux, peu moussants et exempts de silicones, caractérisés en ce qu'ils contiennent
    (a) un produit résultant de la réaction d'un agent tensioactif non ionogène de formule
    Figure imgb0005
     dans laquelle
    R2 est un groupe alkyle en C9-14,
    R4 est un atome d'hydrogène, un groupe alkyle en C1-4 ou (alkyle en C1-5)-phényle,
    un des résidus Y5 et Y6 représente un atome d'hydrogène et l'autre un groupe éthyle,
    n3 représente un nombre entier compris entre 4 et 8 et
    m3 est un nombre entier compris entre 1 et 3,
    avec un composé présentant un groupe acide hydrosolubilisant,
    (b) un agent tensioactif non ionogène de formule
    Figure imgb0006
     dans laquelle
    R représente un résidu aliphatique comportant au moins 8 atomes de carbone,
    R1 représente un atome d'hydrogène, un résidu alkyle en C1-8 et un résidu cycloaliphatique comportant au moins 5 atomes de carbone, un résidu (alkyle en C1-5)-phényle ou styryle,
    le terme "alkylène" représente un résidu alkylène comportant de 2 à 4 atomes de carbone et
    p représente un nombre compris entre 2 et 60, et, éventuellement,
    (c) du 2-éthylhexylsulfate jouant le rôle d'agent solubilisant.
  2. Adjuvants textiles conformes à la revendication 1, caractérisés en ce que le groupe acide hydrosolubilisant du composant (a) provient d'un acide sulfonique ou acide carboxylique polymérisable comportant une insaturation éthylénique, ou d'un anhydride correspondant.
  3. Adjuvants textiles conformes à la revendication 2, caractérisés en ce que dans le composant (a), les acides carboxyliques à insaturation éthylénique sont des acides monocarboxyliques comportant de 2 à 5 atomes de carbone et sont, de préférence, l'acide méthacrylique ou l'acide acrylique.
  4. Adjuvants textiles conformes à la revendication 3 caractérisés en ce que l'acide monocarboxylique dans le composant (a) est l'acide acrylique.
  5. Adjuvants textiles conformes à la revendication 1, caractérisés en ce que, le composant (a) est obtenu à partir de 5 à 50 % en poids d'un agent tensioactif non ionogène conforme à la formule (4) et de 95 à 50 % en poids d'acide acrylique ou méthacrylique.
  6. Adjuvants textiles conformes à la revendication 1, caractérisés en ce qu'ils contiennent, rapporté au poids de l'adjuvant,
    de 2 à 22 % en poids de composant (a),
    de 10 à 95 % en poids de composant (b),
    de 0 à 15 % en poids de composant (c) et
    une quantité suffisante d'eau pour obtenir 100 %.
  7. Utilisation de l'adjuvant textile conforme à l'une de revendications 1 à 6 en tant qu'agent mouillant, agent lavant de textiles, agent de dispersion ou stabilisateur dans des bains de traitement aux peroxydes.
  8. Procédé de mouillage et/ou de lavage de matériaux fibreux, caractérisé en ce que l'on traite ces matériaux dans des milieux aqueux en présence d'un mélange d'adjuvants textiles contenant
    (a) un produit résultant de la réaction d'un agent tensioactif non ionogène de formule (4) avec un composé présentant un groupe acide hydrosolubilisant,
    (b) un agent tensioactif non ionogène de formule (1) et, éventuellement,
    (c) du 2-éthylhexylsulfate jouant le rôle d'agent solubilisant, les adjuvants textiles de la présente invention étant ajoutés au bains traitants à raison de 0,1 à 30 g par litre.
  9. Procédé conforme à la revendication 8, caractérisé en ce que l'on traite le matériau fibreux en continu ou en discontinu.
  10. Matériau fibreux traité conformément à une des revendications 8 et 9.
EP19910810421 1990-06-11 1991-06-04 Adjuvants textiles aqueux, peu moussants et exempts de silicones, leur préparation et leur application Expired - Lifetime EP0462059B1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CH194590 1990-06-11
CH1945/90 1990-06-11
CH709/91 1991-03-08
CH70991 1991-03-08

Publications (3)

Publication Number Publication Date
EP0462059A2 EP0462059A2 (fr) 1991-12-18
EP0462059A3 EP0462059A3 (en) 1992-03-11
EP0462059B1 true EP0462059B1 (fr) 1997-07-02

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Country Link
US (1) US5456847A (fr)
EP (1) EP0462059B1 (fr)
JP (1) JP2872447B2 (fr)
KR (1) KR100221114B1 (fr)
DE (1) DE59108759D1 (fr)
ES (1) ES2106068T3 (fr)

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EP0638635A1 (fr) * 1993-08-12 1995-02-15 Ciba-Geigy Ag Adjuvants textiles aqueux
DE4327327A1 (de) * 1993-08-13 1995-02-16 Henkel Kgaa Detergensgemische
ES2163606T3 (es) * 1995-05-19 2002-02-01 Ciba Sc Holding Ag Materia prima detergente multifuncional.
DE19719855A1 (de) * 1997-05-12 1998-11-19 Henkel Kgaa Netzmittel für die textile Vorbehandlung
DE59912401D1 (de) 1999-10-16 2005-09-15 Ciba Sc Pfersee Gmbh Zusammensetzung für die Vorbehandlung von Fasermaterialien
EP1149945A1 (fr) * 2000-04-29 2001-10-31 Ciba Spezialitätenchemie Pfersee GmbH Composition pour le prétraitement de matériaux fibreux
DE10118236A1 (de) * 2001-04-11 2002-10-17 Ciba Sc Pfersee Gmbh Zusammensetzung für die Vorbehandlung von Fasermaterialien
AU2016335680B2 (en) 2015-10-07 2020-03-05 Elementis Specialties, Inc. Wetting and anti-foaming agent

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US5456847A (en) 1995-10-10
JP2872447B2 (ja) 1999-03-17
KR920001026A (ko) 1992-01-29
ES2106068T3 (es) 1997-11-01
EP0462059A3 (en) 1992-03-11
KR100221114B1 (ko) 1999-09-15
JPH0544161A (ja) 1993-02-23
DE59108759D1 (de) 1997-08-07
EP0462059A2 (fr) 1991-12-18

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