EP0455660A1 - System und verfahren für die regelung der temperatur des heizdampfes bei zirkulierenden wirbelbetten. - Google Patents
System und verfahren für die regelung der temperatur des heizdampfes bei zirkulierenden wirbelbetten.Info
- Publication number
- EP0455660A1 EP0455660A1 EP19900901818 EP90901818A EP0455660A1 EP 0455660 A1 EP0455660 A1 EP 0455660A1 EP 19900901818 EP19900901818 EP 19900901818 EP 90901818 A EP90901818 A EP 90901818A EP 0455660 A1 EP0455660 A1 EP 0455660A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- reheater
- stage
- steam
- temperature
- cold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 14
- 238000002485 combustion reaction Methods 0.000 claims abstract description 30
- 239000007789 gas Substances 0.000 description 25
- 239000003546 flue gas Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 12
- 238000013459 approach Methods 0.000 description 11
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 10
- 239000007787 solid Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000011144 upstream manufacturing Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 206010022000 influenza Diseases 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D5/00—Devices using endothermic chemical reactions, e.g. using frigorific mixtures
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K7/00—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating
- F01K7/16—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating the engines being only of turbine type
- F01K7/22—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating the engines being only of turbine type the turbines having inter-stage steam heating
Definitions
- the present invention relates to a power plant including a two-stage steam turbine and a steam generator plant having a fluidized bed combustion system that includes a fluidized bed combustor, at least one separator, and a gas flue comprising a reheater and superheater.
- the present invention relates also to a method of controlling reheater temperatures in a steam generator having a fluidized bed combustion system that includes a fluidized bed combustor, at least one hot separator, and a reheater in a gas flue.
- reheater temperature control is the use of a system for gas bypass over the reheater.
- Two separate flue gas passes are provided in the convection pass of the boiler (one for superheater and one for reheater), with means such as dampers downstream of each to vary the amount of flue gas flow over each section.
- the outlet steam temperature of the reheater can be controlled by varying the amount of flue gas flow between the convection pass sections.
- the main disadvantage of this system is that the dampers are located in a higher temperature (260-371°C) dust laden flue gas path making them susceptible to erosion and mechanical failure. Also, the steam temperature control range is limited with this type of system.
- reheater outlet steam temperature control is by the use of external heat exchangers.
- an externally mounted fluidized bed heat exchanger i.e. external heater exchanger (EHE)
- EHE external heater exchanger
- the quantity of heat transfer to the reheater and the reheater outlet steam temperature is controlled.
- EHE external heater exchanger
- the main disadvantages of this system are that the solids flow control valve is a high maintenance item and the reheat tube surface within the EHE is subject to erosion. This effects the availability of the unit.
- a further approach to the control of the reheater outlet steam temperature is by the use of spray desuperheater.
- This approach utilizes spraying water for desuperheating and thereby controlling reheater outlet steam temperature. This is a simple approach, but not generally accepted because it degrades the cycle efficiency.
- a still further approach is by the use of gas recirculation.
- gas recirculation By this approach, large quantities of flue gases are recirculated to achieve the rated reheater outlet steam temperature.
- This approach requires the use of a gas recirculation fan for handling a hot dust laden gas and requires additional power consumption, which makes this approach disadvantageous.
- the present invention is directed to an improved method and system for reheat steam temperature control.
- a steam generator having a fluidized bed combustion system that includes a fluidized bed combustor, at least one separator, and a reheater in a flue gas pass and is characterized by - a first stage of reheater and a second or final stage of reheater sequentially disposed in a common gas flue, - means for dividing cold steam from a turbine into selec ⁇ tive first and second portions and directing said first portion through the first stage of reheater, and - means for recombining the first and second portions and directing same through the second stage of reheater.
- the steam generator includes means" for control ⁇ ling the temperature of the second or final stage of the reheater and comprises means for by-passing a selected portion of cold steam around said first stage reheater directly to said second or final stage reheater.
- a method according to the present invention is characterized by - dividing the reheater into a first and second or final stage reheater and sequentially disposing the first and second stages of the reheater in a common gas flue, - dividing cold steam returning to the reheater into selective first and second portions and directing the first portion through the first stage of reheater and
- Fig. 1 is a schematic diagram illustrating a typical circulating fluidized bed boiler system embodying the present invention
- Fig. 2 is a schematic diagram illustrating another embodi- ment of the present invention.
- Fig. 3 is a schematic diagram illustrating an arrangement of two typical boilers connected to a single turbine.
- the boiler system designated generally by the numeral 10
- the boiler system comprises a fluid bed combustor 12 having a combustion chamber 14 into which combustible material, non-combustible material, possibly additives or recirculated material, primary air and secondary air are fed.
- the bed is maintained in fluidized state by having the correct inventory of bed material and flow of air.
- the combustion chamber is provided with a bottom 16 having a grid-like construction through which fluidizing air is introduced.
- the combustion chamber walls are preferably constructed with membrane type tube walls, with or without a refractory covering.
- First and second stages of superheaters 18 and 20 are located within the combustion chamber.
- the combustion chamber materials are carried from the combustion chamber by way of flues 22 to a hot separator 24 wherein the solids are separated from the flue gases for return by way of particle recycling system 26, 28 and 30 to the bottom of the combustion chamber for recirculation. These may be passed through fluidized bed coolers or the like prior to return to the combustion chamber.
- Flue gases from the hot separator pass along by way of flue 32 to a convection pass 34.
- a single stage superheater 38 is placed or located in the convection pass with re- heaters 40 and 42 located downstream of the superheater 38 and upstream of an economizer surface 44.
- the reheater is illustrated as two stages with 42 being a first stage and 40 being a second or final stage.
- the reheater may have more than two stages, with the final stage just down stream from superheater 38 such as 40 is located. These are arranged as counter flow heat exchangers with the gas flow direction down and the reheat steam flow direction up.
- the placement of the superheater 38 within this pass helps keep the temperature of the gas flow to reheater 40 below the critical temperature. This arrangement together with the bypass feature as will be explained enables a unique and effective control of the temperatures within the reheater sections.
- the generating system as illustrated in Fig. 1 is supplying steam to a two-stage turbine.
- steam from superheater 38 flows via an outlet header 46 and supply line 48 by way of valve 50 to the inlet side of the high pressure turbine (HPT) 52.
- HPT high pressure turbine
- Cold steam leaving the turbine 52 returns by way of return line 53 to the reheaters 42 and 40.
- a bypass line 54 joins the return line 53 at 55 and bypasses a portion of the cold steam with the remaining portion of the steam going by way of differential control valve 56 to the inlet header 58 of the first stage reheater 42.
- the steam passing through the reheater 42 exists by way of a header 60 and rejoins or combines with the bypass portion of the cold steam at 62.
- a flow control valve 64 is provided in the bypass line 54 for control of the flow between the inlet manifold of the first stage reheater 42 and the bypass line.
- the recombined steam at 62 flows into inlet header 66 of the second or final stage reheater 40 where it is further heated and flows by way of outlet header 68, supply line 70 and valve 72 to the second stage or lower stage of the turbine (IPT) 74.
- IPT second stage or lower stage of the turbine
- the location of the first stage reheater 42 along the flue gas path is so chosen that bypassing the required portion of the cold reheat steam directly to the second stage reheater 40 cannot increase the steam temperature leaving the first stage reheater to more than the allowed metal temperature for the reheater tube material.
- a limit will be set to protect the first stage reheater materials from exceeding their allowable metal temperature.
- the value of 566°C is a typical limit and may vary depending upon the actual design conditions.
- the purpose of the system is such that the maximum tube outside surface temperature will not exceed the allowable metal temperature limit for the material selected.
- control valves 56 and 64 are so chosen that controlability is achieved throughout the steam temperature control range and permits all reheater surfaces to be placed in the convection pass of the boiler, eliminating the need for in furnace reheater surfaces. This also makes feasible a simplified start-up scheme when more than one boiler for example is connected to a common turbine system. In this arrangement, the set of valves provide a means for reheat steam flow balancing under various operating conditions.
- the combustion takes place in a fluidized bed of inert material.
- the fluidized bed material leaving the combustor is returned by means of a hot collector (such as a hot cyclone) through suitable sealing device.
- air and fuel are delivered to the combustion chamber 14 wherein the bed material is maintained in a fluidized state by having the correct flow of air and bed material.
- the fluidizing air is introduced through a grid-like grating or construction at 16 in the bottom of the chamber.
- the flue gas and combustion products, along with the carry over solids first convey heat to the superheaters 18 and 20 and are conveyed by way of flue 22 into the hot separator 24 wherein the solids are separated and returned to the combustion chamber through the recycling arrangement 26, 28 and 30.
- the hot flue gases are then conveyed from the hot separa ⁇ tors) by way of flue 32 to the convection pass section 34 wherein the final stage superheater 38 and the reheater stages 40 and 42 are located.
- Three superheater stages are disposed in the described system, these being 18 and 20 and 38, with 38 being in the flue gas convection pass.
- Desuperheaters may be positioned between the superheater stages for steam temperature control if necessary.
- the two stages 40 and 42 of the reheater are positioned in the convection pass 34 and in conjunction with the control valves and interconnecting piping so that precise control of the reheater outlet steam temperature is possible.
- the piping system is such that cold steam reentering this system at pipe 53 is selectively divided into two streams at the juncture 55 thereof with the bypass line 54.
- One stream passes to the first stage reheater and is distributed through inlet header 58.
- the other steam goes to the second stage reheater by way of valve 64 and inlet header 66.
- the selective division of the stream will be in proportion to the temperature control necessary, which is accomplished by the valves 56 and 64.
- the hot steam leaving the first stage reheater from the outlet header 60 is mixed with the cold steam via the bypass line 54 after or down stream of the flow control valve 64 and the blended stream enters the second stage reheater by way of the inlet header 66.
- the flow through the first stage reheater is controlled by proper manipulati- on of the two control valves 56 and 64, which in turn control the steam temperature leaving the second stage reheater 40.
- Hot steam from the second or final stage reheater is directed back to the turbine by way of the hot reheat steam line 70.
- a differential pressure responsive control unit 80 controls the setting of valve 56 for controlling the pressure differential available for the control valve 64.
- the control unit 80 is responsive to the pressure differential between the cold steam return line 53 and the outlet pressure at juncture 62 of the outlet of reheater 42 and the bypass line 54. This is indicated by phantom line 84 in Fig. 1.
- the control unit 80 is set to control the valve 56 as a function of load on the boiler.
- the valve 64 in the bypass line 54 is controlled by tempera ⁇ ture responsive control unit 82 which responds to the temperature of the outlet steam from the second or final stage reheater 40. This is indicated by phantom line 86 in Fig. 1.
- the temperature of reheater 40 is maintained within the limit of about 538°C, plus or minus 10 °C.
- the valve 64 is opened to bypass additional cold steam directly to reheater 40.
- the valve 64 is closed to reduce the flow of bypass cold steam to the second stage 40.
- Fig. 2 a system identical to Fig. 1, but with super ⁇ heater 38 located between the reheaters 40 and 42, is disclosed.
- a single staged superheater 38 is placed in the convection pass, with second stage reheater 40 located upstreams and first stage reheater 42 downstream of the superheater.
- An economizer 44 is located downstream of the superheater 38. This is in contrast to what was shown in Fig. 1.
- the placement of the second stage reheater 40 upstream of the superheater 38 allows it to pick up more heat at lower loads. This gives it the potential to extend its steam temperature control range, while having little if any effect on the superheater control range. This potential extension of the reheat steam temperature control range will enhance the coupling of two units to one turbine easier as to temperature matching capabilities.
- a system identical to Fig. 1, but with a duplicate boiler is disclosed.
- the components of the first boiler arrangement are identified by the same reference numerals as in Fig. 1, with the second boiler arrangement being identified with the same numbers primed. Therefore, in this arrangement, a boiler turbine system is disclosed wherein two boilers are supp ⁇ lying steam to a single turbine.
- One essential feature required for this type of system is that means be provided for controlling the amount of reheat steam flow to each boiler, so that the steam temperature at reheat outlet is within limits at all possible operating conditions.
- duplicate controls and piping are provided for the two boilers.
- the control valves 56 and 64 for the reheat steam temperatu ⁇ re control can be used for flow balancing and maintaining the reheater outlet temperature within limits under both normal and abnormal operating conditions.
- pressure reducing valves 80 and 82, along with desuperheaters 76 and 78, provide for flexibility during cold start-up, hot start-up and also when starting the second unit while the first one is on line.
- This simple sys- tern eliminates the need for a sophisticated steam blending system. It provides a simple and effective system and method for reheat outlet steam temperature control under varying load conditions.
- combustion is initiated in the combustion chamber 14 with the introduction of fuel and combustion air.
- the hot gases of combustion move upward in the combustion chamber transferring heat to the water in the combustion chamber walls and to superheaters 18 and 20.
- the hot gas, combustion products, and solids pass from the combustion chamber along flue 22 into the hot separator 24 where the solids are separated for return to the combus- tion chamber.
- the hot flue gas passes along flue 32 into the convection pass 34 where the heat is transferred in sequence to the superheater 38, the second or final stage reheater 40, and the first stage reheater 42.
- the flow of hot gas through the system begins before the flow of cold steam.
- the boiler is fired and fuel burns for a period of time providing hot gas before steam is generated and starts the turbine.
- Cold reheat steam does not start flowing until after the turbine starts.
- the temperature drops so that it is less at each successive stage. It should be noted that the gas temperature leaving the combustion chamber outlet at full load will be in the range of 843 to 927°C. The greater the temperature diffe ⁇ rential between the gas and the water, the greater the heat transfer will be, and the cooler the gas will be as it passes from the respective heater.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Control Of Steam Boilers And Waste-Gas Boilers (AREA)
- Fluidized-Bed Combustion And Resonant Combustion (AREA)
- Control Of Turbines (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT90901818T ATE93038T1 (de) | 1989-01-24 | 1990-01-23 | System und verfahren fuer die regelung der temperatur des heizdampfes bei zirkulierenden wirbelbetten. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US30162189A | 1989-01-24 | 1989-01-24 | |
US301621 | 1989-01-24 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0455660A1 true EP0455660A1 (de) | 1991-11-13 |
EP0455660B1 EP0455660B1 (de) | 1993-08-11 |
Family
ID=23164149
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90901818A Expired - Lifetime EP0455660B1 (de) | 1989-01-24 | 1990-01-23 | System und verfahren für die regelung der temperatur des heizdampfes bei zirkulierenden wirbelbetten |
Country Status (15)
Country | Link |
---|---|
EP (1) | EP0455660B1 (de) |
JP (1) | JP2532750B2 (de) |
KR (1) | KR0147059B1 (de) |
CN (1) | CN1020951C (de) |
AU (1) | AU639437B2 (de) |
CA (1) | CA2045571C (de) |
CZ (1) | CZ284932B6 (de) |
DD (1) | DD291803A5 (de) |
DE (1) | DE69002758T2 (de) |
ES (1) | ES2045903T3 (de) |
LT (1) | LT3379B (de) |
LV (1) | LV11061B (de) |
PL (1) | PL166038B1 (de) |
UA (1) | UA24009C2 (de) |
WO (1) | WO1990008917A1 (de) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10039317A1 (de) * | 2000-08-11 | 2002-04-11 | Alstom Power Boiler Gmbh | Dampferzeugeranlage |
FI120658B (fi) * | 2005-05-04 | 2010-01-15 | Metso Power Oy | Välitulistushöyryn lämmönsäätömenetelmä, lämmönsäätöjärjestelmä sekä voimalaitos |
CN101893232B (zh) * | 2010-06-24 | 2012-02-01 | 东南大学 | 火电机组再热汽温改进受限广义预测控制方法 |
WO2014048089A1 (zh) * | 2012-09-26 | 2014-04-03 | 上海伏波环保设备有限公司 | 自然循环间接式烟气再热器 |
KR102051101B1 (ko) * | 2013-07-19 | 2019-12-02 | 한국전력공사 | 유동층 보일러의 가변 열교환 장치 |
JP6317652B2 (ja) | 2014-09-12 | 2018-04-25 | 株式会社東芝 | プラント制御装置及びコンバインドサイクル発電プラント |
CN105889899B (zh) * | 2014-12-16 | 2018-06-15 | 华北电力大学(保定) | 一种适用于scr低负荷下投运的过热汽温调节系统及方法 |
CN104501425A (zh) * | 2014-12-19 | 2015-04-08 | 中国科学院电工研究所 | 带过热器启动保护的太阳能热发电控制循环吸热器 |
CN106545833B (zh) * | 2016-10-28 | 2018-07-17 | 杭州红山热电有限公司 | 锅炉汽水系统 |
HUE056813T2 (hu) * | 2017-07-27 | 2022-03-28 | Sumitomo SHI FW Energia Oy | Fluidágyas kazántelep és eljárás égésgáz elõmelegítésére fluidágyas kazántelepben |
KR102093302B1 (ko) | 2018-07-19 | 2020-04-23 | 한국생산기술연구원 | 복수의 라이저부를 구비한 유동사 하강형 순환유동층 보일러 및 이의 운전방법 |
EP3848562A4 (de) * | 2018-10-10 | 2022-09-28 | Beijing Cynertec Co., Ltd. | Verfahren zur verbesserung des wirkungsgrades des rankine-zyklus |
CN113753237B (zh) * | 2021-09-21 | 2023-04-07 | 中国航空工业集团公司西安飞机设计研究所 | 一种制冷组件温度控制解耦方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54151743A (en) * | 1978-05-22 | 1979-11-29 | Babcock Hitachi Kk | Steam temperature controller |
DE3125849A1 (de) | 1981-07-01 | 1983-01-20 | Deutsche Babcock Anlagen Ag, 4200 Oberhausen | Dampferzeuger mit zirkulierender atmosphaerischer oder druckaufgeladener wirbelschichtfeuerung sowie verfahren zu seiner regelung |
JPS58164093A (ja) * | 1982-03-25 | 1983-09-28 | Toshiba Corp | 不揮発性メモリ− |
JPS59219603A (ja) * | 1983-05-27 | 1984-12-11 | 三菱重工業株式会社 | 工場用再熱ボイラ |
DE3625373A1 (de) | 1986-07-26 | 1988-02-04 | Steinmueller Gmbh L & C | Dampferzeuger mit zirkulierender atmosphaerischer oder druckaufgeladener wirbelschichtfeuerung, sowie verfahren zu seiner regelung |
DE3625992A1 (de) * | 1986-07-31 | 1988-02-04 | Steinmueller Gmbh L & C | Verfahren zum verbrennen von kohlenstoffhaltigen materialien in einer zirkulierenden wirbelschicht und wirbelschichtfeuerungsanlage zur durchfuehrung des verfahrens |
DE3642396A1 (de) * | 1986-12-11 | 1988-06-16 | Siemens Ag | Dampferzeugeranlage mit einer zirkulierenden wirbelschicht |
-
1990
- 1990-01-23 AU AU49419/90A patent/AU639437B2/en not_active Ceased
- 1990-01-23 WO PCT/FI1990/000026 patent/WO1990008917A1/en active IP Right Grant
- 1990-01-23 DD DD90337276A patent/DD291803A5/de not_active IP Right Cessation
- 1990-01-23 DE DE90901818T patent/DE69002758T2/de not_active Expired - Lifetime
- 1990-01-23 ES ES90901818T patent/ES2045903T3/es not_active Expired - Lifetime
- 1990-01-23 CA CA002045571A patent/CA2045571C/en not_active Expired - Fee Related
- 1990-01-23 CN CN90100421A patent/CN1020951C/zh not_active Expired - Lifetime
- 1990-01-23 UA UA93002096A patent/UA24009C2/uk unknown
- 1990-01-23 JP JP2502023A patent/JP2532750B2/ja not_active Expired - Lifetime
- 1990-01-23 EP EP90901818A patent/EP0455660B1/de not_active Expired - Lifetime
- 1990-01-23 KR KR1019900702150A patent/KR0147059B1/ko not_active IP Right Cessation
- 1990-01-24 CZ CS90330A patent/CZ284932B6/cs not_active IP Right Cessation
- 1990-01-24 PL PL90283427A patent/PL166038B1/pl unknown
-
1993
- 1993-06-28 LV LVP-93-662A patent/LV11061B/en unknown
- 1993-08-10 LT LTIP842A patent/LT3379B/lt not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of WO9008917A1 * |
Also Published As
Publication number | Publication date |
---|---|
CN1045168A (zh) | 1990-09-05 |
JPH04503095A (ja) | 1992-06-04 |
KR910700434A (ko) | 1991-03-15 |
CA2045571A1 (en) | 1990-07-25 |
WO1990008917A1 (en) | 1990-08-09 |
CS33090A3 (en) | 1992-03-18 |
PL166038B1 (pl) | 1995-03-31 |
ES2045903T3 (es) | 1994-01-16 |
CN1020951C (zh) | 1993-05-26 |
DE69002758T2 (de) | 1993-12-16 |
JP2532750B2 (ja) | 1996-09-11 |
AU639437B2 (en) | 1993-07-29 |
CZ284932B6 (cs) | 1999-04-14 |
DD291803A5 (de) | 1991-07-11 |
LTIP842A (en) | 1995-02-27 |
EP0455660B1 (de) | 1993-08-11 |
UA24009C2 (uk) | 1998-08-31 |
CA2045571C (en) | 1995-09-12 |
LV11061A (lv) | 1996-02-20 |
LV11061B (en) | 1996-06-20 |
KR0147059B1 (ko) | 1998-08-17 |
DE69002758D1 (de) | 1993-09-16 |
LT3379B (en) | 1995-08-25 |
AU4941990A (en) | 1990-08-24 |
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