EP0446238B1 - Flüssigkeitsgekühlter plasmabrenner mit übertragenem lichtbogen - Google Patents
Flüssigkeitsgekühlter plasmabrenner mit übertragenem lichtbogen Download PDFInfo
- Publication number
- EP0446238B1 EP0446238B1 EP89912979A EP89912979A EP0446238B1 EP 0446238 B1 EP0446238 B1 EP 0446238B1 EP 89912979 A EP89912979 A EP 89912979A EP 89912979 A EP89912979 A EP 89912979A EP 0446238 B1 EP0446238 B1 EP 0446238B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ignition
- plasma burner
- burner according
- main electrode
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000012530 fluid Substances 0.000 title claims 2
- 229920003023 plastic Polymers 0.000 claims description 9
- 239000004033 plastic Substances 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims 3
- 229910010293 ceramic material Inorganic materials 0.000 claims 2
- 239000012809 cooling fluid Substances 0.000 claims 2
- 239000004020 conductor Substances 0.000 claims 1
- 238000010276 construction Methods 0.000 claims 1
- 239000002826 coolant Substances 0.000 abstract description 14
- 241001088417 Ammodytes americanus Species 0.000 description 29
- 238000009413 insulation Methods 0.000 description 8
- 239000000919 ceramic Substances 0.000 description 4
- 239000000110 cooling liquid Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000005266 casting Methods 0.000 description 2
- 238000010292 electrical insulation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011265 semifinished product Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012811 non-conductive material Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/28—Cooling arrangements
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/341—Arrangements for providing coaxial protecting fluids
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/3421—Transferred arc or pilot arc mode
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/3478—Geometrical details
Definitions
- the invention relates to a liquid-cooled plasma torch with a transmitted arc, the cooling liquid, electricity and gas are led to the ignition and main electrodes via ignition and main electrode lances consisting of coaxial tubes.
- Plasma torches of this type are e.g. Known from DE-A 29 00 330 and consist essentially of the main components burner jacket with nozzle, main electrode lance with main electrode and ignition electrode lance with ignition electrode.
- both the ignition electrode lance and the main electrode lance are each liquid-cooled; each lance consists of tubes which are arranged coaxially to each other.
- the outer tube of the ignition electrode lance is closed on the end toward the ignition electrode and receives the ignition electrode.
- the inner tube of the ignition electrode lance leaves a gap to the end wall of the outer tube or the ignition electrode, through which the connection for the cooling liquid between the central bore of the inner tube and the annular channel between the inner tube and the outer tube will be produced.
- the current is conducted through the outer tube of the ignition electrode.
- the outer tube of the ignition electrode is guided via electrically insulating spacers or sleeves in the inner tube of the main electrode lance.
- the ignition plasma gas is conducted to the ignition electrode and the nozzle-shaped central bore of the main electrode which surrounds it between the outer tube and the ignition electrode lance and the inner tube of the main electrode lance.
- a main electrode lance consisting of three coaxially arranged tubes is used for cooling the main electrode. This creates a flow and return ring channel for the coolant diverted to the inner end wall of the main electrode.
- the main electrode can be supplied with current via the inner and / or outer tube of the main electrode lance.
- the electrical insulation between the outer tube of the main electrode lance and the inner tube of the burner jacket and the nozzle is carried out by means of spacers in the manner as described above with respect to the end electrode lance.
- the main plasma gas is also conducted into the area between the main electrode and the nozzle.
- the plasma burners known from the prior art are structurally very complex and have relatively high heat losses along their lateral surfaces.
- the present invention has for its object to develop the plasma torch described first such that its structure is simplified, previously occurring heat losses are reduced and a better efficiency can be achieved.
- a common cooling circuit for the ignition and main electrode lance which consist of three coaxially arranged tubes, the cooling liquid being guided in the interconnected ring channels between the outer tube and the middle tube on the one hand and between the middle tube and the inner tube on the other.
- this not only saves costs for pipes and seals, but also significantly simplifies the entire cooling water supply for the plasma torch.
- the diameter of the plasma torch shaft can be kept significantly smaller, which corresponds to a direct reduction in the external surface area of the burner, ie the heat losses of the jacket decrease and the efficiency of the burner is improved.
- a smaller torch diameter also allows more universality with regard to the use and installation options of plasma torches in vessels of different types and sizes, such as. B. in a melting furnace, a pan, a tundish or in a vacuum system.
- the main electrode and ignition electrode lance consist of a total of only three coaxially disordered tubes, the coolant being guided in the interconnected ring channels between the outer tube and the central tube on the one hand and between the central tube and the inner tube on the other hand, the fact that the The main electrode is the component that needs the greatest cooling.
- the main electrode current is conducted through the outer tube and the ignition electrode current through the inner tube.
- the ignition electrode lance is sealed off from the coolant channels and is electrically insulated from the main electrode lance or main electrode, the ignition gas can be conducted directly in the ignition electrode lance, which is simultaneously cooled from the outside.
- a correspondingly thin-walled insulation hose is selected, which, however, should preferably be highly elastic and resistant to high temperatures.
- One or more sleeves are used to center the ignition electrode lance.
- the center tube continues in the area of the main electrode through a substantially ring-shaped deflecting part, which at the end leaves open a connection between the coolant ring channels lying on both sides thereof.
- the center tube, the mentioned deflecting part and the sleeve for centering the ignition electrode lance are made of non-conductive material, preferably plastic.
- the ignition electrode and the gas nozzle into which the cylindrical interior of the ignition electrode lance merges, are electrically conductive.
- the nozzle effect of the gas nozzle is favored in that the corresponding pilot gas guide channels conically are guided outside, preferably in the form of several individual bores which are brought together again in the area of the main electrode or the outlet.
- the gas nozzle and the main electrode are connected to one another via an annular insulating sleeve, which sleeve can consist of a high-temperature-resistant plastic, a hydraulic fluid-tight ceramic or a composite material made of a plastic, a metal and a ceramic.
- the insulation hose is overlapped and sealed over the gas nozzle and part of the insulation sleeve to improve the liquid insulation.
- the O-ring seal provided between the outer surface of the gas nozzle and the inner surface of the insulating sleeve, which lies in a corresponding groove in the gas nozzle, optimizes the tightness.
- the main electrode itself is pot-shaped and electrically connected to the outer tube. An O-ring seal is used between these parts for tightness. Another O-ring seal is located in the overlap area of the insulating sleeve and the main electrode.
- the ignition electrode should be made of tungsten.
- the upper electrode of the ignition cone can be cast around with copper and the casting block in question forms the gas nozzle.
- the inner tube is flared in the lower part and adapted to the taper of the subsequent holes.
- the main components of the plasma torch are an ignition or auxiliary electrode 11, a main or nozzle electrode 12 and a nozzle 13, which are each electrically insulated from one another.
- the cylindrical inner or cavity 17 of the tube 16 merges into a conical widening 18 with the cone angle ⁇ in its lower region adjoining the gas nozzle 14.
- the gas nozzle 14 has a plurality of bores or through holes 19, for example ten evenly distributed on the circumference.
- the axes of the bores 19 are arranged on an (imaginary) conical surface (19 ') such that the bores 19 are closer together at their end facing the tube 16 (than at their end facing the ignition electrode 11) and with their end facing the tube 16 End overall within of the hollow cross section of the conical extension 18.
- the cone angle of the (imaginary) conical surface 19 ' is denoted by ⁇ in FIG. 2.
- the inner tube 16 is preferably made of copper, while the ignition electrode 11 is made of tungsten. It is advisable to prefabricate the ignition electrode 11 as a semifinished product as follows: The ignition electrode 11 is prepared into a rod with a cone 11 ′ with a cone angle and then cast with copper in the dimensions required for the gas nozzle 14 using the casting process.
- the semi-finished product thus produced is finished by manufacturing the bores 19 and connected to the tube 16.
- the outside of the gas nozzle 14 is surrounded by one end of an electrically insulating sleeve 20.
- the insulating sleeve 20 encloses a cylindrical flange 21 of the main electrode 12.
- the gas nozzle 14 and the main electrode 12 are kept at a distance with their flange 21 by an annular projection 22 on the inside of the sleeve 20.
- the insulating sleeve 20 therefore serves as a mechanical Link between the gas nozzle 14 and the main electrode 12 and causes an exact positioning of the ignition electrode 11 with respect to the main electrode 12.
- the insulating sleeve 20 is preferably made of a high-temperature-resistant plastic and / or hydraulic fluid-tight ceramic or a composite of plastic, metal and ceramic.
- the main electrode 12 has a central passage 23 which, over a partial length, in particular in the region of the cylindrical flange 21, forms an annular channel 24 with the outer surface of the ignition electrode 11.
- the inside diameter of the annular projection 22 is equal to the inside diameter of the adjoining flange 21 or the passage 23 of the main electrode 12.
- the bores 19 all lie within the area given by this diameter.
- the tube 16 is coated on its outside by an easily mountable and removable thin-walled, high-temperature-resistant and highly elastic insulation hose 25, which still surrounds the gas nozzle 14 and part of the insulating sleeve 20 in a ring.
- an electrically insulating coating can also be provided.
- the main electrode 12 is connected to an outer cylindrical part 26 in a current-conducting and pressure-fluid-tight manner with a tube 28.
- Another tube 27 is arranged between the tube 28 and the tube 16, which carries a deflection part 29 at its lower end.
- the tubes 16, 27, 28 are also referred to below as the inner tube 16, middle tube 27 and outer tube 28.
- the inner tube 16 with the gas nozzle 14 represents the ignition electrode lance and these form the main electrode lance together with the sleeve 20 and the central and outer tubes 27 and 28.
- sleeves 31 made of electrically insulating material and having axially parallel passages are used, which abut on the one hand on the insulation tube 25 and on the other hand on the inside of the center tube 27.
- the center tube 27 and the adjoining deflection part 29 as well as the centering sleeves 31 are preferably made of plastic, which in addition to the electrical insulation brings weight savings.
- the gas flow for the ignition electrode 11 takes place via the symbolically indicated ignition gas connection 32, the cavity 17, the bores 19 and the annular channel 24.
- the ignition electrode lance formed by the tube 16 is cooled on the inside by the cold ignition plasma gas.
- the ignition plasma gas emerges as a plasma jet from the central bore 23 of the main electrode 12.
- the flow of the gas for the main or power arc to be ignited between the main electrode 12 and another pole, for example a molten metal, takes place via the symbolically indicated plasma gas connection 33 and the Annular channel 34, which is formed by the outer surface of the outer tube 28 and the main electrode 12 on the one hand and the inner surface of the burner jacket and the nozzle 13 on the other.
- annular channel 35 and 36 for the flow of a liquid coolant. Both ring channels 35, 36 are connected to one another between the deflection part 29 and the end part of the main electrode 12. The ignition electrode lance formed by the inner tube 16 is also detected by the coolant flow.
- the ignition electrode 11 is electrically connected to a pole of a (not shown) current or voltage source via the gas nozzle 14, the inner tube 16 and the symbolically indicated current connection 37 located thereon.
- the main electrode 12 is connected to another pole of the current or voltage source via the outer tube 28 and the current connection 39 located there, which is also symbolically indicated.
- a liquid coolant is introduced into the ring channel 35 via the symbolically indicated coolant connection or inlet 41 and is returned under the deflection part 29 through the ring channel 36 to the symbolically indicated coolant outlet or outlet 43 .
- the outer tube 28 carrying the current to the main electrode 12 is cooled internally by the water supply.
- the outer tube 28 through the Main electrode 12 cooled by the main channel 34 flowing cold main plasma gas.
- the O-rings 45 ... 47 are held in ring grooves, of which the ring groove 48 in the gas nozzle 14 for the O-ring 45 and the ring groove 49 in the sleeve 20 for the O-ring 46 are shown by way of example in FIG. 2 .
- the inner tube 16 is also cooled by the plasma gas flowing through its cavity 17.
- the plasma torch described is preferably operated as a three-phase plasma torch. In addition, it can also be operated with direct and / or alternating current as described in EP-A-0 134 961.
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Geometry (AREA)
- Plasma Technology (AREA)
- Gas Burners (AREA)
- Gasification And Melting Of Waste (AREA)
- Discharge Heating (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3840485A DE3840485A1 (de) | 1988-12-01 | 1988-12-01 | Fluessigkeitsgekuehlter plasmabrenner mit uebertragenem lichtbogen |
DE3840485 | 1988-12-01 | ||
PCT/DE1989/000744 WO1990006666A1 (de) | 1988-12-01 | 1989-11-24 | Flüssigkeitsgekühlter plasmabrenner mit übertragenem lichtbogen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0446238A1 EP0446238A1 (de) | 1991-09-18 |
EP0446238B1 true EP0446238B1 (de) | 1994-08-17 |
Family
ID=6368234
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89912979A Expired - Lifetime EP0446238B1 (de) | 1988-12-01 | 1989-11-24 | Flüssigkeitsgekühlter plasmabrenner mit übertragenem lichtbogen |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0446238B1 (ko) |
JP (1) | JP2942354B2 (ko) |
KR (1) | KR900702756A (ko) |
AT (1) | ATE110221T1 (ko) |
CA (1) | CA2004226A1 (ko) |
DD (1) | DD292806A5 (ko) |
DE (2) | DE3840485A1 (ko) |
ES (1) | ES2017440A6 (ko) |
WO (1) | WO1990006666A1 (ko) |
ZA (1) | ZA899174B (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE202017000969U1 (de) | 2017-02-23 | 2017-04-03 | CEBra - Centrum für Energietechnologie Brandenburg GmbH | Hochspannungszündvorrichtung |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4022112C2 (de) * | 1990-07-11 | 1996-03-14 | Mannesmann Ag | Plasmabrenner für übertragenen Lichtbogen |
DE4034731A1 (de) * | 1990-10-30 | 1992-05-07 | Mannesmann Ag | Plasmabrenner zum schmelzen und warmhalten von in gefaessen zu behandelnden materialien |
NO174450C (no) * | 1991-12-12 | 1994-05-04 | Kvaerner Eng | Anordning ved plasmabrenner for kjemiske prosesser |
EP1371905B1 (en) | 2001-02-27 | 2010-12-01 | Yantai Longyuan Power Technology Co. Ltd. | Plasma igniter with assembled cathode |
KR100708320B1 (ko) * | 2004-04-22 | 2007-04-17 | 김기현 | 대기압 마이크로웨이브 플라즈마를 이용한 외장재 부품표면개질 장치 및 방법 |
JP4820317B2 (ja) * | 2006-04-06 | 2011-11-24 | 積水化学工業株式会社 | 放電処理装置 |
DE102009016932B4 (de) | 2009-04-08 | 2013-06-20 | Kjellberg Finsterwalde Plasma Und Maschinen Gmbh | Kühlrohre und Elektrodenaufnahme für einen Lichtbogenplasmabrenner sowie Anordnungen aus denselben und Lichtbogenplasmabrenner mit denselben |
JP4576476B1 (ja) * | 2009-12-28 | 2010-11-10 | 株式会社フェローテック | ストライカ式プラズマ発生装置及びプラズマ処理装置 |
JP6522968B2 (ja) | 2015-01-30 | 2019-05-29 | 株式会社小松製作所 | プラズマトーチ用絶縁ガイド、及び交換部品ユニット |
CN105491779B (zh) * | 2016-02-22 | 2017-09-29 | 衢州昀睿工业设计有限公司 | 一种电离协同的等离子体热解装置 |
CN112010377A (zh) * | 2020-08-07 | 2020-12-01 | 合肥中科远望环保科技有限公司 | 一种高浓度有机废液汽化处理装置 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NO119341B (ko) * | 1965-04-09 | 1970-05-04 | Inst Badan Jadrowych | |
US3569661A (en) * | 1969-06-09 | 1971-03-09 | Air Prod & Chem | Method and apparatus for establishing a cathode stabilized (collimated) plasma arc |
US4055741A (en) * | 1975-12-08 | 1977-10-25 | David Grigorievich Bykhovsky | Plasma arc torch |
DE2900330A1 (de) * | 1978-01-09 | 1979-07-12 | Inst Elektroswarki Patona | Verfahren zur plasmaerzeugung in einem plasma-lichtbogen-generator und vorrichtung zur durchfuehrung des verfahrens |
US4549065A (en) * | 1983-01-21 | 1985-10-22 | Technology Application Services Corporation | Plasma generator and method |
DE3435680A1 (de) * | 1984-09-28 | 1986-04-03 | Fried. Krupp Gmbh, 4300 Essen | Plasmabrenner |
DE3642375A1 (de) * | 1986-12-11 | 1988-06-23 | Castolin Sa | Verfahren zur aufbringung einer innenbeschichtung in rohre od. dgl. hohlraeume engen querschnittes sowie plasmaspritzbrenner dafuer |
-
1988
- 1988-12-01 DE DE3840485A patent/DE3840485A1/de not_active Withdrawn
-
1989
- 1989-11-24 KR KR1019900701563A patent/KR900702756A/ko not_active IP Right Cessation
- 1989-11-24 WO PCT/DE1989/000744 patent/WO1990006666A1/de active IP Right Grant
- 1989-11-24 EP EP89912979A patent/EP0446238B1/de not_active Expired - Lifetime
- 1989-11-24 JP JP2500128A patent/JP2942354B2/ja not_active Expired - Lifetime
- 1989-11-24 DE DE58908219T patent/DE58908219D1/de not_active Expired - Lifetime
- 1989-11-24 AT AT89912979T patent/ATE110221T1/de not_active IP Right Cessation
- 1989-11-29 DD DD89335004A patent/DD292806A5/de not_active IP Right Cessation
- 1989-11-29 ES ES8904071A patent/ES2017440A6/es not_active Expired - Fee Related
- 1989-11-30 ZA ZA899174A patent/ZA899174B/xx unknown
- 1989-11-30 CA CA002004226A patent/CA2004226A1/en not_active Abandoned
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE202017000969U1 (de) | 2017-02-23 | 2017-04-03 | CEBra - Centrum für Energietechnologie Brandenburg GmbH | Hochspannungszündvorrichtung |
Also Published As
Publication number | Publication date |
---|---|
DE58908219D1 (de) | 1994-09-22 |
EP0446238A1 (de) | 1991-09-18 |
KR900702756A (ko) | 1990-12-08 |
JPH04502531A (ja) | 1992-05-07 |
ZA899174B (en) | 1990-09-26 |
ES2017440A6 (es) | 1991-02-01 |
WO1990006666A1 (de) | 1990-06-14 |
DD292806A5 (de) | 1991-08-08 |
CA2004226A1 (en) | 1990-06-01 |
JP2942354B2 (ja) | 1999-08-30 |
DE3840485A1 (de) | 1990-06-07 |
ATE110221T1 (de) | 1994-09-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19910507 |
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