EP0443468B1 - Machine frigorifique à sorption - Google Patents
Machine frigorifique à sorption Download PDFInfo
- Publication number
- EP0443468B1 EP0443468B1 EP91102215A EP91102215A EP0443468B1 EP 0443468 B1 EP0443468 B1 EP 0443468B1 EP 91102215 A EP91102215 A EP 91102215A EP 91102215 A EP91102215 A EP 91102215A EP 0443468 B1 EP0443468 B1 EP 0443468B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- refrigerator according
- ultrasonic transducer
- sorption
- generator
- sorption refrigerator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000001179 sorption measurement Methods 0.000 title claims abstract description 27
- 238000005057 refrigeration Methods 0.000 title abstract description 4
- 238000010521 absorption reaction Methods 0.000 claims abstract description 7
- 239000003507 refrigerant Substances 0.000 claims description 15
- 238000002604 ultrasonography Methods 0.000 claims description 9
- 239000012530 fluid Substances 0.000 claims description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims 1
- 238000011144 upstream manufacturing Methods 0.000 claims 1
- 230000002745 absorbent Effects 0.000 description 11
- 239000002250 absorbent Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000002918 waste heat Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B33/00—Boilers; Analysers; Rectifiers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F31/00—Mixers with shaking, oscillating, or vibrating mechanisms
- B01F31/80—Mixing by means of high-frequency vibrations above one kHz, e.g. ultrasonic vibrations
- B01F31/86—Mixing by means of high-frequency vibrations above one kHz, e.g. ultrasonic vibrations with vibration of the receptacle or part of it
Definitions
- the invention relates to a sorption refrigerator according to the preamble of claim 1 and a method according to the preamble of claim 12.
- Sorption chillers are only used to a lesser extent because the efficiency is lower than that of chillers that work with a compressor.
- an additional auxiliary gas can be used in a so-called absorption refrigerator, which, however, complicates the structure of the refrigerator.
- the expeller is designed to be pressure-resistant in a manner known per se and has a somewhat elongated, essentially tubular, basic structure. It is particularly favorable to use an insert body which is designed in the manner of a Venturi nozzle, the feed line of the rich absorbent solution opening into the insert body.
- the insert body expediently extends essentially coaxially in front of the active surface of the piezo element used for ultrasound generation.
- the insert body has surfaces that reflect the ultrasound, so that there is a bundling and at the same time transmission of the sound into the space downstream of the feed line.
- the expeller is provided with an internal return line which branches off above the insert body, passes through a flow restrictor and opens in the region of the piezo element.
- the fluid is able to pass through a gap between the outer circumference of the piezo element and the insert body, so that there is a flow path which supports the escape of the refrigerant.
- an adsorption element can be used, the selection of which depends on the two-substance mixture used.
- the flow resistance for refrigerant vapor can hereby be kept comparatively low, so that there is only a small pressure drop.
- a mixture of water and alcohol was used as the two-substance mixture.
- the use of a piezo element for the radiation of an ultrasonic power of 20 W resulted in a surprisingly high degree of efficiency, based on the cooling power generated.
- a power transistor was mounted directly below the piezo element in a heat-conducting connection with it, so that the heat loss from the power amplifier could also be used.
- a zeolite was used as the adsorption element.
- a sorption refrigerator shown schematically in FIG. 1 10 has a condenser 12, into which refrigerant enters in vapor form and is cooled and condensed via a cooling coil 14, which is connected, for example, to the ambient air.
- the liquid refrigerant then passes through a control or throttle valve 16 and is fed to an evaporator 18, which has a further heat exchanger, not shown, via which the useful cold that is produced due to the evaporation is released.
- the refrigerant passes from the outlet of the evaporator 18 in a relaxed state to an expeller 26 according to the invention, the structure of which is explained in more detail with reference to FIG. 2.
- the refrigerant then emerges from the expeller 26 essentially in the gas phase at a relatively high pressure and then reaches the condenser 12 again.
- the expeller 26 has a feed line 30 for the absorbent solution and a discharge line 32 for the essentially gaseous refrigerant.
- the feed line 30 opens into an insert body 36, which has the shape of a Venturi nozzle, essentially at its narrowest point.
- the Venturi nozzle 36 has an essentially vertical axis which passes through an ultrasound transducer 38 arranged below it.
- the ultrasonic transducer 38 has a piezo element 40 with an active surface 42 facing upwards. The sound waves emitted by the active surface 42 are reflected on the essentially conically tapering inner surface 44 of the insert body 36 and are bundled approximately in an area 46 where the feed line 30 also opens.
- a space 48 above the insert body 36 is closed at the top by an adsorption element 50, which is permeable to refrigerants and at the same time has a low flow resistance for them.
- the derivative 34 is on the side connected.
- the discharge line 34 leads to an internal return line 52 of the expeller, which runs through a flow limiter 54 and returns absorption medium solution into a ring region around the ultrasound transducer 38.
- a gap 56 is provided between the ultrasound transducer 38 and the insert body 36, through which the absorbent solution originating from the internal return line 52 of the expeller 26 can again enter the area 46 and is subjected to the ultrasound there.
- alcohol is used as the refrigerant and water as the absorbent.
- a zeolite is suitable for this purpose as an adsorption element, it being understood that any other suitable two-substance mixture can be used.
- the two-substance mixture used here has the additional advantage of being non-toxic and also harmless in the further.
- the flow is accelerated at the narrow point of the insert body 36 designed as a Venturi nozzle, so that there is also an acceleration for the rich absorbent solution on the feed line 30.
- the space 48 also serves to equalize the flow.
Landscapes
- Engineering & Computer Science (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Sorption Type Refrigeration Machines (AREA)
- Transducers For Ultrasonic Waves (AREA)
- Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Separation By Low-Temperature Treatments (AREA)
Claims (12)
- Machine frigorifique à sorption avec un éjecteur (26), qui présente une conduite d'alimentation (30) pour un fluide d'absorption riche et une conduite d'évacuation (34) pour un réfrigérant sensiblement gazeux, caractérisée en ce qu'un convertisseur à ultra-sons (38) est disposé dans l'éjecteur (26) pour émettre des ondes ultra-sonores dans une zone (46) de l'éjecteur (26) et la conduite d'alimentation (30) débouche dans cette zone (46).
- Machine frigorifique à sorption selon la revendication 1, caractérisée en ce que le convertisseur à ultra-sons (38) présente un élément piézo-électrique (40), dont la surface active (42) est orientée vers la zone (46).
- Machine frigorifique à sorption selon l'une ou l'ensemble des revendications précédentes, caractérisée en ce que la conduite d'alimentation (30) débouche dans la zone d'un amplificateur sonore (36) du convertisseur à ultra-sons (38), en particulier dans la zone d'une corne acoustique.
- Machine frigorifique à sorption selon l'une ou l'ensemble des revendications précédentes, caractérisée en ce qu'un amplificateur sonore (36) précédent le convertisseur à ultra-sons (38) est conformé comme un tube de Venturi, la conduite d'alimentation (30) débouchant sensiblement dans la zone du point rétréci.
- Machine frigorifique à sorption selon l'une ou l'ensemble des revendications précédentes, caractérisée en ce que l'éjecteur (26) présente une conduite de retour (52) interne qui, par rapport aux ondes sonores émises par le convertisseur à ultra-sons (38), commence derrière la conduite d'alimentation (30) et se termine devant la conduite d'alimentation (30), en particulier dans une fente (56).
- Machine frigorifique à sorption selon la revendication 5, caractérisée en ce que la conduite de retour interne (52) présente un limiteur d'écoulement (54).
- Machine frigorifique à sorption selon l'une ou l'ensemble des revendications précédentes, caractérisée en ce que l'éjecteur (26) présente en aval de la conduite d'alimentation (30) un élément d'adsorption (50), en particulier une zéolithe.
- Machine frigorifique à sorption selon l'une ou l'ensemble des revendications précédentes, caractérisée en ce que devant une surface active (42) du convertisseur à ultra-sons (38), il est prévu un corps d'insert (36), qui présente des surfaces (44) réfléchissant les ondes acoustiques et ultra-sonores et qui est en particulier conçu comme un tube de Venturi.
- Machine frigorifique à sorption selon l'une ou l'ensemble des revendications précédentes, caractérisée en ce que le convertisseur à ultra-sons (38) se trouve dans une liaison de conduction thermique avec un amplificateur de puissance électrique.
- Machine frigorifique à sorption selon l'une ou l'ensemble des revendications précédentes, caractérisée en ce qu'un espace (48) destiné à uniformiser l'écoulement est prévu entre la zone (46) et un élément d'adsorption (50).
- Utilisation d'un convertisseur à ultra-sons pour l'éjection dans une machine frigorifique à sorption.
- Procédé pour la production de froid utilisant une machine frigorifique à sorption, en particulier une machine frigorifique à absorption, où un fluide d'absorption riche avec au moins deux composants peut être fractionné dans un éjecteur en deux fluides, dont l'un est sensiblement gazeux et est acheminé à un condenseur, caractérisé en ce que l'on fait agir des ultra-sons sur le fluide d'absorption riche dans l'éjecteur.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4005192 | 1990-02-19 | ||
| DE4005192A DE4005192A1 (de) | 1990-02-19 | 1990-02-19 | Sorptionskaeltemaschine |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0443468A2 EP0443468A2 (fr) | 1991-08-28 |
| EP0443468A3 EP0443468A3 (en) | 1991-12-18 |
| EP0443468B1 true EP0443468B1 (fr) | 1994-06-22 |
Family
ID=6400500
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP91102215A Expired - Lifetime EP0443468B1 (fr) | 1990-02-19 | 1991-02-16 | Machine frigorifique à sorption |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0443468B1 (fr) |
| AT (1) | ATE107759T1 (fr) |
| DE (2) | DE4005192A1 (fr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102013212531A1 (de) | 2013-06-27 | 2014-12-31 | Dürr Systems GmbH | Anlage und Verfahren für das Aufbereiten von Gasen |
| DE102013212537A1 (de) * | 2013-06-27 | 2014-12-31 | Dürr Systems GmbH | Anlage und Verfahren für das Aufbereiten von Gasen |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB379391A (en) * | 1930-05-31 | 1932-09-01 | Electrolux Ltd | Improvements in or relating to the operation of absorption refrigerating apparatus |
| US2537497A (en) * | 1946-12-07 | 1951-01-09 | Stator Company | Fluid feed device |
| DE1062260B (de) * | 1958-02-12 | 1959-07-30 | Hans Stierlin | Absorptions-Kuehlaggregat mit druckausgleichendem Gas |
| US3586462A (en) * | 1969-05-01 | 1971-06-22 | Carrier Corp | Absorption refrigeration machine pump |
| DE2922971A1 (de) * | 1979-06-06 | 1980-12-11 | Allg Kuehlmoebelbau Gmbh | Verkaufstheke |
| DE3313399A1 (de) * | 1983-04-13 | 1984-10-18 | Karl 8904 Friedberg Leuprecht | Kuehltheke |
-
1990
- 1990-02-19 DE DE4005192A patent/DE4005192A1/de not_active Withdrawn
-
1991
- 1991-02-16 DE DE59101964T patent/DE59101964D1/de not_active Expired - Fee Related
- 1991-02-16 AT AT91102215T patent/ATE107759T1/de not_active IP Right Cessation
- 1991-02-16 EP EP91102215A patent/EP0443468B1/fr not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE4005192A1 (de) | 1991-08-22 |
| ATE107759T1 (de) | 1994-07-15 |
| EP0443468A2 (fr) | 1991-08-28 |
| EP0443468A3 (en) | 1991-12-18 |
| DE59101964D1 (de) | 1994-07-28 |
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