EP0437698A1 - Procédé pour faire fonctionner une installation de gazéification de combustibles solides - Google Patents
Procédé pour faire fonctionner une installation de gazéification de combustibles solides Download PDFInfo
- Publication number
- EP0437698A1 EP0437698A1 EP90121843A EP90121843A EP0437698A1 EP 0437698 A1 EP0437698 A1 EP 0437698A1 EP 90121843 A EP90121843 A EP 90121843A EP 90121843 A EP90121843 A EP 90121843A EP 0437698 A1 EP0437698 A1 EP 0437698A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- oxygen
- dust
- gasification
- primary
- channel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/50—Fuel charging devices
- C10J3/506—Fuel charging devices for entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1223—Heating the gasifier by burners
Definitions
- EP-A1-0 370 201 which does not belong to the prior art, relates to a method for operating a system for the gasification of fine-grained to dust-like solid fuels, with Gasification reactor equipped with gasification burners, Device for the separation of dust from the raw gas, Dust collection container and device for the return of dust in the gasification reactor, wherein the gasification burners burn into the gasification reactor with a fuel / reactant jet that is rotationally symmetrical at the gasification burner outlet and a primary reaction zone of high temperature is formed by the fuel / reactant jets in the gasification reactor.
- the method of operation according to EP-A1-0 370 201 is based on the task of guiding the process in such a way that the fly dust separated dry from the raw gas is fully integrated in the slag without any special treatment and without interfering with the gasification process, the at the same time residual carbon contained in the dust is to be burned completely.
- the dust with its raw gas content and its residual carbon are introduced into the axis of at least one fuel / reactant jet by a conveying gas stream, are introduced by the fuel / reactant jet into the primary reaction zone and are melted down therein.
- gasification burners can be used which have a feed channel for primary oxygen which is coaxial with the burner axis, a surrounding ring channel for the fuel feed and a ring channel surrounding this for the feed of secondary oxygen.
- the fly dust should be fed through a special feed channel (lance) which is arranged in the axis of the feed channel for the primary oxygen.
- the invention is therefore based on the object of optimizing the method variant described above with regard to its operating conditions.
- the invention proposes that a mass ratio of primary oxygen to secondary oxygen of 1: 1 to 1: 4, preferably 1: 1 to 1: 3, be used.
- the primary oxygen primarily ensures that the fuel metered in the ring channel with high flow rate density but low speed is sufficiently accelerated and swirled. Due to this swirling of the fuel flow, the fuel particles receive the required amount of oxygen for reaction, which takes place directly at the burner mouth as combustion to CO2.
- the fly dust which is also dosed in the center of the gasification burner with a high flow rate density and low speed, therefore reaches a high temperature zone at the burner mouth, which favors the reaction of the residual carbon contained in the fly dust.
- the secondary oxygen is said to loosen up and accelerate the fuel flow from the outside.
- the raw synthesis gas already generated is recirculated from the reaction space of the gasification reactor to the burner mouth by the secondary oxygen emerging from the gasification burner at high speed and by the other material flows.
- the mass ratio of primary oxygen to secondary oxygen according to the invention, the supply of secondary oxygen to the raw synthesis gas is limited.
- the raw synthesis gas which consists of 90% CO + H2
- a further combustion reaction to CO2 + H2O can therefore only take place to a very limited extent.
- the mass ratio of primary oxygen to secondary oxygen is observed, the CO2 content in the synthesis gas generated by the gasification can be kept in the range between 1 and 3% for most fuels.
- water vapor which serves as a temperature moderator in the reaction zone
- the mass ratio of oxygen (total) to water vapor in the range from 1: 0.1 to 1: 0.6 should lie.
- the water vapor should preferably be added to the secondary oxygen.
- CO2 can also be used as a temperature moderator instead of water vapor if this does not result in the desired composition of the partial oxidation crude gas generated is adversely affected.
- impure oxygen with e.g. 15% ⁇ N2 +.
- Ar or strongly preheated air can be used as an oxygen carrier, the numerical values given above of course always referring to pure oxygen.
- the supply of the flying dust is not via a lance arranged in the axis of the supply duct for the primary oxygen, but via an appropriately arranged ring channel.
- the flow of primary oxygen is distributed over two channels, namely a first channel in the center of the gasification burner and an annular channel which surrounds the feed channel for the flying dust from the outside.
- the distribution of the primary oxygen over the first and second channels takes place due to the pressure losses in a ratio of approximately 1: 2. This ensures that the dust can react better with the primary oxygen.
- the flow density of the fly dust must be reduced by adding a carrier gas.
- a carrier gas For example, N2 and / or CO2 or part of the synthesis gas generated can be used for this.
- the particle size of the flying dust particles must not exceed 1 mm. Oversized grain must therefore before the introduction of the Airborne dust in the gasification burner can be removed by suitable measures.
- the head of a gasification burner suitable for carrying out this process variant is shown in the figure as an axial section.
- the burner jacket 1 is provided with a circumferential cooling channel 2 and an annular channel 3 for the introduction of protective gas.
- the ring channel 4 serves to supply the secondary oxygen and the ring channel 5 serves to supply the fuel.
- the outlet openings of the ring channels 3 to 5 are inclined towards the burner axis.
- the dust is supplied here through the ring channel 6, which is arranged in the area of the central supply of the primary oxygen, so that it is introduced through the central supply channel 7 and the ring channel 8.
- the swirl bodies 9 can be arranged in the feed channel 7 and in the ring channel 8, by means of which the swirling of the primary oxygen with the flying dust and the fuel is improved. This effect is also supported by the fact that the outlet openings of the ring channels 3 to 5 are inclined towards the burner axis. The supply of protective gas via the ring channel 3 reduces the oxygen concentration on the cooled burner mouth 10.
- the central supply of primary oxygen via the supply channel 7 also has the advantage that the light guide 11 of a flame detector installed outside the gasification burner can be arranged in the center of the gasification burner.
- the gasification burner described above can also be used as a pilot burner if by the Ring channel 6, a gaseous ignition medium, such as natural gas or propane, is introduced instead of flying dust.
- a gaseous ignition medium such as natural gas or propane
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Gasification And Melting Of Waste (AREA)
- Processing Of Solid Wastes (AREA)
- Air Supply (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3941816A DE3941816A1 (de) | 1988-11-05 | 1989-12-19 | Verfahren zum betrieb einer anlage fuer die vergasung fester brennstoffe |
DE3941816 | 1989-12-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0437698A1 true EP0437698A1 (fr) | 1991-07-24 |
EP0437698B1 EP0437698B1 (fr) | 1993-02-03 |
Family
ID=6395735
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90121843A Expired - Lifetime EP0437698B1 (fr) | 1989-12-19 | 1990-11-15 | Procédé pour faire fonctionner une installation de gazéification de combustibles solides |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0437698B1 (fr) |
CN (1) | CN1025868C (fr) |
DE (1) | DE59000845D1 (fr) |
DK (1) | DK0437698T3 (fr) |
ES (1) | ES2038862T3 (fr) |
PL (1) | PL164928B3 (fr) |
ZA (1) | ZA909213B (fr) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0767235A2 (fr) * | 1995-10-03 | 1997-04-09 | Mitsubishi Jukogyo Kabushiki Kaisha | Brûleur et méthode d'alimentation de combustible |
AT402440B (de) * | 1995-06-01 | 1997-05-26 | Voest Alpine Ind Anlagen | Brenner |
WO2006113229A1 (fr) | 2005-04-18 | 2006-10-26 | General Electric Company | Injecteur d'alimentation amélioré pour la gazéification et méthode connexe |
WO2009019272A1 (fr) * | 2007-08-06 | 2009-02-12 | Shell Internationale Research Maatschappij B.V. | Brûleur |
DE102008063505A1 (de) | 2008-12-17 | 2010-07-01 | Uhde Gmbh | Verfahren zur Vergleichmäßigung der Förderung von Brennstoffen in einen Vergaser zur Erzeugung von Synthesegas |
US9032623B2 (en) | 2007-08-06 | 2015-05-19 | Shell Oil Company | Method of manufacturing a burner front face |
EP2238223B1 (fr) | 2008-01-28 | 2015-08-26 | Shell Internationale Research Maatschappij B.V. | Procédé pour le démarrage d'un réacteur de gazéification du charbon |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8434700B2 (en) | 2008-04-30 | 2013-05-07 | General Electric Company | Methods and systems for mixing reactor feed |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE968970C (de) * | 1952-12-11 | 1958-04-17 | Basf Ag | Verfahren zur Vergasung staubfoermiger bis koerniger Brennstoffe |
US4443230A (en) * | 1983-05-31 | 1984-04-17 | Texaco Inc. | Partial oxidation process for slurries of solid fuel |
US4480559A (en) * | 1983-01-07 | 1984-11-06 | Combustion Engineering, Inc. | Coal and char burner |
EP0129921A2 (fr) * | 1983-06-24 | 1985-01-02 | Shell Internationale Researchmaatschappij B.V. | Procédé et brûleur pour la gazéification de combustible solide |
EP0367966A1 (fr) * | 1988-11-05 | 1990-05-16 | Krupp Koppers GmbH | Brûleur pour la gazéification des combustibles solides à grains fins ou pulvérulents |
-
1990
- 1990-11-15 DK DK90121843.8T patent/DK0437698T3/da active
- 1990-11-15 EP EP90121843A patent/EP0437698B1/fr not_active Expired - Lifetime
- 1990-11-15 ES ES199090121843T patent/ES2038862T3/es not_active Expired - Lifetime
- 1990-11-15 DE DE9090121843T patent/DE59000845D1/de not_active Expired - Fee Related
- 1990-11-16 ZA ZA909213A patent/ZA909213B/xx unknown
- 1990-12-10 CN CN90109926A patent/CN1025868C/zh not_active Expired - Fee Related
- 1990-12-18 PL PL90288309A patent/PL164928B3/pl unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE968970C (de) * | 1952-12-11 | 1958-04-17 | Basf Ag | Verfahren zur Vergasung staubfoermiger bis koerniger Brennstoffe |
US4480559A (en) * | 1983-01-07 | 1984-11-06 | Combustion Engineering, Inc. | Coal and char burner |
US4443230A (en) * | 1983-05-31 | 1984-04-17 | Texaco Inc. | Partial oxidation process for slurries of solid fuel |
EP0129921A2 (fr) * | 1983-06-24 | 1985-01-02 | Shell Internationale Researchmaatschappij B.V. | Procédé et brûleur pour la gazéification de combustible solide |
EP0367966A1 (fr) * | 1988-11-05 | 1990-05-16 | Krupp Koppers GmbH | Brûleur pour la gazéification des combustibles solides à grains fins ou pulvérulents |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT402440B (de) * | 1995-06-01 | 1997-05-26 | Voest Alpine Ind Anlagen | Brenner |
EP0767235A2 (fr) * | 1995-10-03 | 1997-04-09 | Mitsubishi Jukogyo Kabushiki Kaisha | Brûleur et méthode d'alimentation de combustible |
EP0767235A3 (fr) * | 1995-10-03 | 1997-05-07 | Mitsubishi Jukogyo Kabushiki Kaisha | Brûleur et méthode d'alimentation de combustible |
US5997595A (en) * | 1995-10-03 | 1999-12-07 | Mitsubishi Jukogyo Kabushiki Kaisha | Burner and a fuel etc. supply method |
WO2006113229A1 (fr) | 2005-04-18 | 2006-10-26 | General Electric Company | Injecteur d'alimentation amélioré pour la gazéification et méthode connexe |
JP2008537092A (ja) * | 2005-04-18 | 2008-09-11 | ゼネラル・エレクトリック・カンパニイ | ガス化用の改善された供給インジェクタ及び関連する方法。 |
WO2009019272A1 (fr) * | 2007-08-06 | 2009-02-12 | Shell Internationale Research Maatschappij B.V. | Brûleur |
AU2008285638B2 (en) * | 2007-08-06 | 2011-02-10 | Air Products And Chemicals, Inc. | Burner |
US9032623B2 (en) | 2007-08-06 | 2015-05-19 | Shell Oil Company | Method of manufacturing a burner front face |
US9546784B2 (en) | 2007-08-06 | 2017-01-17 | Shell Oil Company | Burner |
EP2238223B1 (fr) | 2008-01-28 | 2015-08-26 | Shell Internationale Research Maatschappij B.V. | Procédé pour le démarrage d'un réacteur de gazéification du charbon |
DE102008063505A1 (de) | 2008-12-17 | 2010-07-01 | Uhde Gmbh | Verfahren zur Vergleichmäßigung der Förderung von Brennstoffen in einen Vergaser zur Erzeugung von Synthesegas |
WO2010075911A1 (fr) | 2008-12-17 | 2010-07-08 | Uhde Gmbh | Procédé et dispositif d'homogénéisation du transport de combustibles arrivant dans un gazéificateur utilisé pour la production de gaz de synthèse |
Also Published As
Publication number | Publication date |
---|---|
ZA909213B (en) | 1991-09-25 |
DE59000845D1 (de) | 1993-03-18 |
ES2038862T3 (es) | 1993-08-01 |
CN1052889A (zh) | 1991-07-10 |
PL288309A3 (en) | 1991-12-02 |
EP0437698B1 (fr) | 1993-02-03 |
CN1025868C (zh) | 1994-09-07 |
DK0437698T3 (da) | 1993-06-01 |
PL164928B3 (pl) | 1994-10-31 |
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