EP0423703A2 - Geschlichtete Aramidfasern, die während der Bewirkungen anschmutzen - Google Patents
Geschlichtete Aramidfasern, die während der Bewirkungen anschmutzen Download PDFInfo
- Publication number
- EP0423703A2 EP0423703A2 EP90119787A EP90119787A EP0423703A2 EP 0423703 A2 EP0423703 A2 EP 0423703A2 EP 90119787 A EP90119787 A EP 90119787A EP 90119787 A EP90119787 A EP 90119787A EP 0423703 A2 EP0423703 A2 EP 0423703A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- aramid
- fiber
- finish
- fibers
- para
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
- D06M13/295—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof containing polyglycol moieties; containing neopentyl moieties
Definitions
- This invention relates to finishes for aramid fibers which not only increase surface lubricity and improve the static electricity characteristics of the fibers, but also do not rub off of the fibers as a result of normal handling forces.
- Finishes have been put onto fibers almost since fibers have been made. Finishes are used to change the handling or performance characteristics of a fiber in specific ways; and finishes are often very specific in the results which are achieved on fibers of particular materials.
- potassium salts of alkyl phosphate acid esters have long been used as a finish material for decreasing electrostatic charge buildup and improving the handleability of polyester and nylon fibers. Indeed, such aliphatic phosphate salts have been used with some success as antistatic finishes for aramid fibers but they have left troublesome deposits on fiber guides and other elements of the fiber handling machinery during processing of the fibers.
- Fatty acid esters such as coconut oil, castor oil, and polyethylene glycol mono/di fatty acid esters, have been commonly used as finish ingredients to improve the lubricity of aramid fibers but these ingredients don't help in reducing static charges.
- the present invention provides an aramid fiber product having a filament denier of 0.75 to 3 or, perhaps, 5 and a uniform coating on the fibers of potassium salts of ethoxylated alkyl phosphate acid esters in the amount of from 0.2 to 1.0 %, based on the weight of the aramid fiber.
- This invention also provides a process for making a fiber product comprising the steps of establishing an aqueous finish bath having 1 to 50% of potassium salts of ethoxylated alkyl phosphate acid esters based on the total weight of the bath, contacting the aqueous finish bath with aramid fiber having a denier of 0.75 to as much as 5, and drying the aramid fiber to leave a uniform coating of 0.2 to 1.0% potassium salts of ethoxylated alkyl phosphate acid esters on the fiber.
- the fibers of this invention are aramid fibers and can be made from any aramid polymeric material.
- the aramid which is preferred is para-aramid and the preferred para-aramid is poly(p-phenylene terephthalamide).
- poly(p-phenylene terephthalamide) PPD-T
- PPD-T poly(p-phenylene terephthalamide)
- other aromatic diamines and other aromatic diacid chlorides can, also, be used in amounts up to as much as about 10 mole percent of the p-phenylene diamine or the terephthaloyl chloride, or perhaps slightly higher, provided only that the other diamines and diacid chlorides have no reactive groups which interfere with the polymerization reaction.
- the fibers can be staple or continuous filaments of any denier.
- Aramid fibers can, also, be made from meta-aramid and the preferred meta-aramid is poly(m-phenylene isophthalamide). Meta-aramids and meta-aramid fibers are disclosed in United States Patent No. 3,287,324. Para-aramids and para-aramid fibers are disclosed in United States Patents Nos. 3,869,429.
- Aramid fibers are generally wet spun from spinning dope solutions of the aramid polymer and, after being extruded from a spinneret, the dope solution is coagulated in an aqueous coagulating bath either after passing through a non-coagulating gap or not.
- the coagulating step is followed by washing in various ways and drying, either under tension or not.
- the finish of this invention is applied to the aramid fiber during the course of the fiber manufacture and is usually applied after the washing step.
- the finish is water soluble and can, therefore, be applied by conducting the fiber through an aqueous solution of the finish and then drying the fiber. It is possible to contact the aqueous finish bath with the aramid fiber while the fiber is still in the "never-dried" form. That is, before application of the finish, the fiber can still retain at least about 20 weight percent water from the spinning process. Applying the finish to never-dried fibers causes more of the finish to be imbibed into the fiber structure.
- finish which is somewhat bound to the fiber is more effective than finish which has been merely coated onto the outer surface of the fiber. It is, however, preferred and more practical to add the finish to dried fibers.
- Discrete staple fibers are manufactured into continuous spun yarn by means of the classic ring spinning method which can be summarized as sequentially comprising the steps of
- fibers are conducted through and around various guide devices for yarn placement and alignment.
- This further processing also, causes buildup of deposits from the fibers on the guide devices.
- This deposit buildup appears to be an especial problem with aramid fibers because the buildup of deposits is thought to be a function of the tension forces applied to the fibers and the resulting friction between the fibers and the guides.
- the present invention includes a finish which yields improved finish solution stability and improved fiber static properties and which does not result in deposit buildup on guide surfaces during manufacture of staple yarn or during additional handling before and after manufacture of the spun yarn.
- the finish of this invention comprises a potassium salt of ethoxylated aliphatic phosphate acid esters, characterized as mono- or dialkyl phosphate acid esters.
- the aliphatic portion of the finish molecule is alkyl from 8 to 18 carbons with two or three ethylene oxide groups linked thereto.
- the finish compound of the present invention can be made by reacting aliphatic alcohol having 8-18 carbon atoms and 2 or 3 ethylene oxide groups with phosphorus pentoxide and then neutralizing the product with potassium hydroxide.
- the ethylene oxide groups increase water solubility of the finish and decrease the incidence of deposits.
- the finishes of this invention are soluble in water to the extent of as much as 50% or, perhaps, more, based on weight of the water, and, in any event, finish material present in excess of the solubility limit is easily emulsified or dispersed.
- the finish of this invention is applied, most usually, by dipping the fibers into a finish bath made up as an aqueous solution of the finish compound.
- the concentration of finish in the finish bath should be such that, when all other aspects of the finish bath contact and finish bath drying are considered, the fiber product will have about 0.2 to 1.0% finish based on the weight of the starting aramid fiber.
- the finish bath should include from about 1 to 50% finish compound.
- the finish of this invention is especially effective because it is water soluble and can, therefore, be applied from an aqueous solution. Application from a solution, permits application of an even coating of finish without rich or lean areas.
- the water solubility is not, however, the only quality which is necessary for obtaining a finish good for use with aramid fibers. It has been determined that several finishes with water solubility, when applied to aramid fibers, yield an aramid fiber product which has an even coating of finish and good static properties; but that those finishes, on aramid fibers, consistently leave a buildup of deposits when run across yarn contact surfaces.
- Examples of such water soluble finishes which leave excessive deposits on contact surfaces include: potassium salts of alkyl phosphate acid esters wherein the alkyl is 4-12 carbon atoms; potassium salts of ethoxylated alkyl amine sulfates such as tallow amine diethyl sulfate wherein the tallow includes from 2 to 20 ethylene oxide residues; diethyl amine salt of alkyl phosphate esters wherein the alkyl is a blend of 8, 10, and 12 carbon atoms; and potassium salt of alkyl phosphonate ethyl acid ester wherein the alkyl is 8 carbon atoms.
- finish used in the present invention incorporates elements of the materials listed above and, thereby, becomes a finish of excellent performance despite the poor performance of other materials having somewhat similar composition.
- the present invention is based on the fact that aramid fibers having a finish material of particular potassium salts of ethoxylated aliphatic phosphate esters exhibit a combination of qualities which appear to be unique to that combination of fiber and finish.
- Finish on yarn is determined by dissolving the finish from a sample of yarn using methanol, evaporating the methanol to dryness, weighing the residue, weighing the clean yarn sample, and calculating the percent of finish based on the clean yarn.
- Finish Uniformity is determined by microscopic inspection of the fibers in question. Separate splotches on lumps of finish denote “poor” finish uniformity. “Medium” finish uniformity indicates that the finish can be detected microscopically as a substantially continuous but nonuniform coating. “Good” finish uniformity indicates that the finish can be detected microscopically as a continuous uniform coating. A finish of "Excellent” uniformity cannot be detected microscopically.
- Finish Deposits are determined as the amount of finish material accumulated on a test fiber guide or yarn guide after passage of a known amount of fiber under specified conditions.
- the yarn in question is run at 100 yards per minute for about two minutes through two 14-rung tensional ladder guides under 1.5 grams per denier tension at a wrap angle of 180 degrees.
- the finish deposits accumulated on the guide are removed and weighed and the total weight of yarn run through the guide is calculated. Finish deposits are reported as milligrams of deposits per kilogram of yarn run through the guide.
- fibers of this invention were prepared and were tested against fibers utilizing finishes outside the teaching of this invention.
- Continuous yarns of dry PPD-T homopolymer fiber having filaments with a filament denier of 1.5 were conducted through a finish bath having a finish concentration of about 15 weight percent; the finish-soaked yarn was conducted through a crimper to crimp the yarn and to remove excess finish solution; additional finish was then added to the crimped yarn when required to achieve the desired finish on yarn; the yarn was cut into staple having a length of about 1 1/2 to 2 inches; and the staple was baled. Spun yarns were, subsequently, produced from the staple using the ring spinning method.
- the staple was tested for finish content, finish uniformity, and finish deposits.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
- Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US42201389A | 1989-10-16 | 1989-10-16 | |
US422013 | 1989-10-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0423703A2 true EP0423703A2 (de) | 1991-04-24 |
EP0423703A3 EP0423703A3 (en) | 1991-08-28 |
Family
ID=23673030
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19900119787 Withdrawn EP0423703A3 (en) | 1989-10-16 | 1990-10-16 | Finished aramid fibers, exhibiting no deposit during processing |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0423703A3 (de) |
JP (1) | JPH03185180A (de) |
KR (1) | KR910008184A (de) |
CN (1) | CN1051770A (de) |
AU (1) | AU629993B2 (de) |
BR (1) | BR9005205A (de) |
CA (1) | CA2027661A1 (de) |
IE (1) | IE903679A1 (de) |
NO (1) | NO904449L (de) |
PT (1) | PT95604A (de) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4402193C1 (de) * | 1994-01-26 | 1995-06-01 | Hoechst Ag | Präparationshaltige Aramidfasern und deren Verwendung |
DE4410708C1 (de) * | 1994-03-28 | 1995-07-13 | Hoechst Ag | Präparationshaltige Aramidfasern und deren Verwendung |
EP1435407A1 (de) * | 2003-01-02 | 2004-07-07 | Teijin Twaron B.V. | Mit einer leitfähigen Ausrüstung versehenes Aramidgarn |
US7799239B2 (en) * | 2004-11-01 | 2010-09-21 | Teijin Techno Products Limited | Phosphate ester treated para-type aromatic polyamide short fibers |
US7976943B2 (en) | 2007-10-09 | 2011-07-12 | E. I. Du Pont De Nemours And Company | High linear density, high modulus, high tenacity yarns and methods for making the yarns |
WO2013096395A1 (en) | 2011-12-20 | 2013-06-27 | E. I. Du Pont De Nemours And Company | High linear density, high modulus, high tenacity yarns and methods for making the yarns |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101310136B1 (ko) * | 2008-04-30 | 2013-09-23 | 코오롱인더스트리 주식회사 | 아라미드 멀티필라멘트 및 그의 제조방법 |
JP6068621B2 (ja) * | 2012-05-09 | 2017-01-25 | テイジン・アラミド・ビー.ブイ. | 連続アラミド糸条を含む布強化材 |
EP2971325B1 (de) * | 2013-03-15 | 2017-05-10 | Teijin Aramid B.V. | Verfahren zur hochgeschwindigkeitsverlitzung von aramidgarnen |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3926816A (en) * | 1970-05-22 | 1975-12-16 | Goulston Co George A | Textile fiber lubricants |
EP0010764A2 (de) * | 1978-11-06 | 1980-05-14 | Phillips Petroleum Company | Polypropylengarnerzeugnis mit verbesserter Stabilität sowie Verfahren zur Herstellung eines Textilmaterials |
US4256589A (en) * | 1978-02-16 | 1981-03-17 | Eastman Kodak Company | Fiber treating compositions comprising (a) blend of random copoly(oxyethylene-oxypropylene)butanols (b) alkali metal sulfur compound and (c) alkali metal organic phosphate compound |
US4452709A (en) * | 1981-10-09 | 1984-06-05 | Lester Laboratories, Inc. | Antistatic composition |
US4624793A (en) * | 1984-06-20 | 1986-11-25 | National Distillers And Chemical Corporation | Fiber finishes |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS531342B2 (de) * | 1972-05-08 | 1978-01-18 | ||
US4126564A (en) * | 1977-12-12 | 1978-11-21 | Allied Chemical Corporation | Spin finish for polyamide carpet yarn |
US4191656A (en) * | 1978-10-05 | 1980-03-04 | Allied Chemical Corporation | Non-yellowing biocide for control of bacteria in spin finish emulsions used on nylon yarn |
JPS58156079A (ja) * | 1982-03-09 | 1983-09-16 | 帝人株式会社 | 芳香族ポリアミド系合成繊維の処理方法 |
-
1990
- 1990-10-15 CA CA002027661A patent/CA2027661A1/en not_active Abandoned
- 1990-10-15 IE IE367990A patent/IE903679A1/en unknown
- 1990-10-15 NO NO90904449A patent/NO904449L/no unknown
- 1990-10-16 PT PT95604A patent/PT95604A/pt not_active Application Discontinuation
- 1990-10-16 EP EP19900119787 patent/EP0423703A3/en not_active Withdrawn
- 1990-10-16 AU AU64656/90A patent/AU629993B2/en not_active Withdrawn - After Issue
- 1990-10-16 BR BR909005205A patent/BR9005205A/pt unknown
- 1990-10-16 JP JP2275473A patent/JPH03185180A/ja active Pending
- 1990-10-16 KR KR1019900016422A patent/KR910008184A/ko not_active Application Discontinuation
- 1990-10-16 CN CN90109362A patent/CN1051770A/zh active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3926816A (en) * | 1970-05-22 | 1975-12-16 | Goulston Co George A | Textile fiber lubricants |
US4256589A (en) * | 1978-02-16 | 1981-03-17 | Eastman Kodak Company | Fiber treating compositions comprising (a) blend of random copoly(oxyethylene-oxypropylene)butanols (b) alkali metal sulfur compound and (c) alkali metal organic phosphate compound |
EP0010764A2 (de) * | 1978-11-06 | 1980-05-14 | Phillips Petroleum Company | Polypropylengarnerzeugnis mit verbesserter Stabilität sowie Verfahren zur Herstellung eines Textilmaterials |
US4452709A (en) * | 1981-10-09 | 1984-06-05 | Lester Laboratories, Inc. | Antistatic composition |
US4624793A (en) * | 1984-06-20 | 1986-11-25 | National Distillers And Chemical Corporation | Fiber finishes |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4402193C1 (de) * | 1994-01-26 | 1995-06-01 | Hoechst Ag | Präparationshaltige Aramidfasern und deren Verwendung |
EP0665323A2 (de) * | 1994-01-26 | 1995-08-02 | Hoechst Aktiengesellschaft | Präparationshaltige Aramidfasern und deren Verwendung |
EP0665323A3 (de) * | 1994-01-26 | 1997-08-20 | Hoechst Ag | Präparationshaltige Aramidfasern und deren Verwendung. |
DE4410708C1 (de) * | 1994-03-28 | 1995-07-13 | Hoechst Ag | Präparationshaltige Aramidfasern und deren Verwendung |
EP1435407A1 (de) * | 2003-01-02 | 2004-07-07 | Teijin Twaron B.V. | Mit einer leitfähigen Ausrüstung versehenes Aramidgarn |
WO2004061196A1 (en) * | 2003-01-02 | 2004-07-22 | Teijin Twaron B.V. | Aramid filament yarn provided with a conductive finish |
US7438975B2 (en) | 2003-01-02 | 2008-10-21 | Teijin Aramid B.V. | Aramid filament yarn provided with a conductive finish |
US7799239B2 (en) * | 2004-11-01 | 2010-09-21 | Teijin Techno Products Limited | Phosphate ester treated para-type aromatic polyamide short fibers |
US7976943B2 (en) | 2007-10-09 | 2011-07-12 | E. I. Du Pont De Nemours And Company | High linear density, high modulus, high tenacity yarns and methods for making the yarns |
WO2013096395A1 (en) | 2011-12-20 | 2013-06-27 | E. I. Du Pont De Nemours And Company | High linear density, high modulus, high tenacity yarns and methods for making the yarns |
Also Published As
Publication number | Publication date |
---|---|
EP0423703A3 (en) | 1991-08-28 |
KR910008184A (ko) | 1991-05-30 |
BR9005205A (pt) | 1991-09-17 |
AU6465690A (en) | 1991-04-18 |
AU629993B2 (en) | 1992-10-15 |
CN1051770A (zh) | 1991-05-29 |
JPH03185180A (ja) | 1991-08-13 |
NO904449L (no) | 1991-04-17 |
IE903679A1 (en) | 1991-04-24 |
PT95604A (pt) | 1991-09-30 |
NO904449D0 (no) | 1990-10-15 |
CA2027661A1 (en) | 1991-04-17 |
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Legal Events
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18W | Application withdrawn |
Withdrawal date: 19921202 |