EP0404539B1 - Retroreflektierende Filme mit Schutzdeckschicht - Google Patents

Retroreflektierende Filme mit Schutzdeckschicht Download PDF

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Publication number
EP0404539B1
EP0404539B1 EP90306724A EP90306724A EP0404539B1 EP 0404539 B1 EP0404539 B1 EP 0404539B1 EP 90306724 A EP90306724 A EP 90306724A EP 90306724 A EP90306724 A EP 90306724A EP 0404539 B1 EP0404539 B1 EP 0404539B1
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EP
European Patent Office
Prior art keywords
layer
laminate
microspheres
retroreflective
cover sheet
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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EP90306724A
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English (en)
French (fr)
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EP0404539A2 (de
EP0404539A3 (de
Inventor
Lynn E. C/O Minnesota Mining And Faykish
Wallace K. C/O Minnesota Mining And Bingham
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3M Co
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Minnesota Mining and Manufacturing Co
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Publication of EP0404539A3 publication Critical patent/EP0404539A3/de
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    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix

Definitions

  • the invention relates to retroreflective security films designed to be laminated to the surfaces of documents such as driver licenses and identification cards to provide means for authenticating the documents and means for enabling detection of alterations of the information contained therein.
  • the retroreflective security films disclosed in U.S. Patent No. 3,801,183 provide many features making them well-suited for use as security overlays which can be laminated over a document or portions thereof.
  • Such films are commonly used on such documents as identification cards, driver licenses, or documents of title, providing means for authenticating the documents as well as means for readily detecting tampering or attempted tampering therewith.
  • Such security films are typically made with reflective layers which are substantially transparent in diffuse light conditions, thereby permitting the information on the document surface to be easily read.
  • the entire surface of the film has some level of retroreflection that is readily observable with a retroreflective viewing device such as disclosed in U.S. Patent Nos.
  • any penetration of the film is disruptive to retroreflection by the film and is thus readily apparent under retroreflective viewing conditions, thereby providing means for enabling detection of tampering.
  • Legends or patterns of enhanced retroreflection can be provided as desired in the form of logos, special messages, or other images to provide means for authentication.
  • U.S. Patent No. 4,099,838 discloses a retroreflective sheet material which carries retroreflective legends provided by a dielectric mirror wherein the mirror is patterned so that the reflectivity from the mirror carries a pattern of contrasting colors.
  • the patent discloses that security films of the type disclosed in U.S. Patent No. 3,801,183 may be made with such patterned reflectivity.
  • Previously known security films have been provided both in “exposed lens” (i.e., with the front surfaces of the microspheres protruding from the front surfaces of the film) and “embedded-lens” (i.e., with the front surfaces of the microspheres being embedded within the film) embodiments.
  • security films may exhibit certain disadvantages, including limited resistance to abrasion, tendency to deform or for retroreflectivity to be disturbed when subjected to moderate pressures, limited durability under certain conditions of use such as are encountered by employee identification cards and driver licenses, and particularly in the case of exposed-lens constructions, tendency to accumulate dirt between microspheres and tendency for microspheres to dislodge when the sheeting is exposed to high humidity.
  • the present invention provides embedded-lens retroreflective security laminates which may be applied to documents, e.g., over visual information on the surfaces thereof, to provide means for authenticating the documents, means for deterring attempts to tamper with the documents and information thereon, and means for providing readily detectable indication of such tampering.
  • Security laminates of the invention can provide many advantages over previously available security films, including higher resistance to abrasion, higher resistance to deformation under moderate pressures such as are typically encountered by ordinary handling and use, higher resistance to accumulation of dirt, and higher retention of microspheres when the laminate is flexed. Accordingly, security laminates of the invention can provide exceptional durability under varied conditions of use to which documents such as employee identification cards and driver licenses are typically subjected.
  • Laminates of the invention can be made in flexible or rigid form as desired.
  • security laminates of the invention are legend-containing, substantially transparent laminates which are retroreflective over at least a portion of their surface area, having retroreflective legend areas and retroreflective background areas, which areas are substantially transparent and substantially indistinguishable under ordinary diffuse light viewing conditions.
  • substantially transparent it is meant that under diffuse light conditions the laminate appears to be essentially transparent and free of a legend or that, if detectable by the unaided eye, the legend is too faint to substantially obscure the visual information on the document over which the laminate has been applied.
  • One of the areas i.e., either the background area or the legend area, has a greater retroreflective efficiency than the other whereby the legend areas are readily discernible from the background areas under retroreflective light viewing conditions.
  • the security laminates of the invention as defined in Claim 1 comprise:
  • the present invention also provides novel methods of making such security laminates.
  • the security laminates of the invention are particularly useful when applied to documents such as identification cards, passports, driver licenses, credit cards, stock certificates, deeds, automobile titles, etc.
  • the laminates can be used to provide means for identifying or authenticating the document including the visual information displayed thereon and means for deterring or rendering more difficult tampering with the document or counterfeiting of same.
  • Other advantages of the laminates of the invention include the difficulty of removing the laminate from the document without destroying the structural integrity of the laminate thereby providing readily detectable indication of tampering, and the difficulty of duplicating or reproducing the laminate and legend contained therein without relatively sophisticated and expensive equipment and know-how.
  • each circle represents a full circumference as though the microspheres were of uniform diameters and arranged in uniform rows.
  • legends will normally be much wider than only a few microspheres as is schematically illustrated.
  • Figure 1 illustrates a portion of one embodiment of security laminate 10 of the invention.
  • laminate 10 comprises base sheet 12 and cover sheet 14.
  • Base sheet 12 comprises microspheres 16 which are embedded in binder 18 with lacquer 19 in an imagewise pattern and reflector 20 disposed behind the rear surfaces thereof.
  • binder 18 provides a spacing layer immediately behind the rear surface of microspheres 16.
  • laminate 10 further comprises attachment adhesive 22 on the back side thereof. Attachment adhesive 22 is typically covered by optional release liner 24.
  • the microspheres used herein are preferably substantially spherical in shape in order to provide the most uniform and efficient retroreflection. Furthermore, the microspheres are typically preferably substantially transparent so as to minimize the amount of light absorbed by the microspheres and thereby optimize the amount of light which is retroreflected by laminates of the invention. Furthermore, the microspheres are typically preferably substantially colorless; although, in some instances, the microspheres may be colored to produce special effects if desired. Microspheres used herein may be made from glass or synthetic resin having the optical properties and physical characteristics taught herein. Glass microspheres are typically preferred because they typically cost less than microspheres made of synthetic resins.
  • Microspheres used in security laminates of the present invention will typically have an average diameter of between about 40 and about 200 microns. Microspheres which are smaller than this range may tend to provide lower levels of retroreflection because of diffraction effects, whereas microspheres larger than this range may tend to impart undesirably high thickness to resultant laminates or make laminates incorporating the same more susceptible to cracking when flexed.
  • the refractive index of microspheres used in laminates of the present invention is typically between about 2.00 and about 2.60. It will be understood, however, that microspheres having refractive indices outside this range may be used in accordance with the present invention.
  • the optimum index of refraction for microspheres in a laminate of the invention will depend in part upon the overall construction of the security laminate, i.e., whether the binder provides a spacing layer behind microspheres, the thickness of such spacing layer, etc.
  • base sheet 12 which comprises microspheres 16 embedded in binder 18 with lacquer 19 and reflector 20 therebehind.
  • the first step is typically to apply a mixture or slurry of selected microspheres 16 in binder material or composition 18 to carrier 26.
  • Carrier 26 is selected so as to release from binder layer 18 and microspheres 16, after formation of binder layer 18.
  • Carrier 26 should also provide sufficient strength as well as sufficient stability when exposed to heat and chemicals to permit formation of the base sheet as described herein.
  • the surface of carrier 26 on which the base sheet is formed has a very smooth, e.g., glossy, finish.
  • Illustrative examples of materials useful as carrier 26 include polyethylene terephthalate films and certain polymer-coated papers having the properties described herein.
  • microspheres 16 After application of the slurry to carrier 26, microspheres 16 will typically settle to the surface of carrier 26 to become substantially arranged in a monolayer thereon with the microspheres typically being in substantially only tangential contact therewith.
  • binder material 18 preferably tends to conform to the rear surfaces of microspheres 16 so as to result in a layer having substantially uniform thickness thereon.
  • the relative amounts of binder material and microspheres that should be used will be based in part upon the size of the microspheres and the nature of the binder material used. Typically, an amount of binder material that provides a layer, referred to herein as a spacing layer, on the rear surfaces of microspheres 16 that is about as thick as the focal length of microspheres 16 will be useful in such embodiments.
  • the reflector is preferably located at approximately the focus point of the microspheres, i.e., is located behind the microspheres at a distance equivalent to the focal length thereof.
  • the focal length of microspheres in such constructions is dependent in part upon the index of refraction of the microspheres and the index of refraction of the binder layer in which the front surfaces of the microspheres are embedded.
  • the reflector is preferably located directly on the back surfaces of the microspheres (as shown in Figure 6) whereas if the ratio is somewhat lower, the reflector is preferably located at a position somewhat removed from the rear surfaces of the microspheres (as shown in Figure 1).
  • the microspheres are typically preferably substantially uniform in size so that the resultant laminate will exhibit substantially more uniform retroreflective properties and in order to facilitate fabrication of the laminate.
  • the binder material or composition is selected in part to provide a composition which will form, e.g., upon drying or curing, a binder layer which will adhere to microspheres 16, and to later applied lacquer 19, reflector 20, and the cover sheet.
  • resultant binder layer 18 will preferably be flexible, dimensionally stable such that the laminate will maintain its structural integrity when exposed to moderate temperatures and environments, e.g., upon exposure to high humidity, and have a suitable refractive index which will enable the laminate to provide desired retroreflection.
  • Illustrative examples of binder materials which are useful in embodiments of the invention include polyvinyl butyral and polyester resins.
  • the binder layer will have a refractive index of between about 1.4 and about 1.6.
  • microspheres 16 which are substantially spherical and have an index of refraction of about 2.25 and an average diameter of about 60 micrometers will be useful with a binder material that comprises polyvinyl butyral and provides a spacing layer having a thickness of about 12 microns and a refractive index of between about 1.4 and about 1.5.
  • lacquer 19 is used herein to refer to any material, typically substantially transparent, which may be applied as discussed herein in discontinuous or imagewise fashion to delineate the legend areas and is not meant to refer to a particular class of resins.
  • Lacquer 19 may be applied by any of several different well-known techniques, including but not limited to rotogravure or flexographic printing. Lacquer 19 may be applied in any desired image, e.g., in the form of one or more logos or alphanumeric characters.
  • the legend may contain a special message or instructions, or may simply be a pattern of a single or repeating characters. If desired, two or more different lacquers which provide somewhat different resultant retroreflective performance may be used in a single security laminate of the invention to provide special effects.
  • lacquer An illustrative example of a suitable lacquer is FLEXO ROTO Lacquer No. FA 14929 which is commercially available from Consolidated Printing Inks Company.
  • lacquers used herein have a viscosity corresponding to a rating of between about 30 and about 60 seconds in a No. 2 Zahn cup, as such lacquers typically provide an optimum combination of handling characteristics and flow properties to enable formation of high resolution images or legends with reasonable cost and degree of difficulty. It will be understood, however, that lacquers having viscosities outside this range may be used in accordance with the present invention.
  • dielectric reflector 20 is formed over lacquer 19 and the exposed portions of the spacing layer in accordance with the teachings of the aforementioned U.S. Patent No. 3,801,183 which is incorporated herein by reference.
  • a preferred material for use in dielectric mirror 20 is zinc sulfide (ZnS), which can be applied by any of several well known vapor coating techniques.
  • ZnS zinc sulfide
  • the retroreflective efficiency i.e., the fraction of incident light reflected back toward its source, depends in part on the efficiency of reflection of dielectric mirror 20 as well as the degree to which incident light is focused on dielectric mirror 20 by microspheres 16.
  • One method for increasing the retroreflective efficiency of reflector 20 is to form a dielectric mirror comprising two or more layers of alternating high and low refractive index as is discussed in U.S. Patent No. 3,801,183.
  • a layer of zinc sulfide may be applied to the back of binder layer 18 and lacquer 19, and then a layer of a material having a relatively lower refractive index, e.g., cryolite (Na3AlF6) may be applied to the exposed surface of the first formed zinc sulfide and then in turn another layer of zinc sulfide applied to the back of the layer of cryolite. If desired, successive pairs of cryolite or similar material and zinc sulfide or similar material may be applied.
  • reflector 20 may be single layer in some embodiments and may be multi-layer in other embodiments.
  • the thickness of the elements of a dielectric layer may be controlled or "tuned” to preferentially reflect different segments of the color spectrum, i.e., to reflect in a desired color range.
  • the retroreflective performances of the legend and background areas can be controlled so as to provide desired effects such as enhanced legibility by providing for contrasting colors and/or retroreflective efficiency between the legend and background areas. For instance, a yellow legend and purple-blue background can be provided. In some embodiments, the legend may be distinctly brighter than the background under retroreflective viewing conditions.
  • the optical thicknesses of the individual elements of the dielectric reflector preferably correspond to an odd-numbered multiple of one-quarter of one wavelength of light in the desired wavelength range, e.g., typically about 5000 to about 6000 angstroms.
  • U.S. Patent No. 4,099,838 also discloses a property defined therein as a "sticking coefficient" (see column 3, lines 25-49) which relates to the tendency of vapor coated materials, e.g., zinc sulfide, to be deposited more quickly on some surfaces than on others.
  • vapor coated materials e.g., zinc sulfide
  • the zinc sulfide may be deposited upon the exposed portions of the binder layer more quickly than it does on the lacquer. This phenomenon may thus result in a dielectric reflector layer having different optical thickness at different points so as to have different retroreflective properties at those points.
  • attachment adhesive 22 is used to adhere the resultant security laminate to the face of a document, typically over a portion of the document on which information is displayed. Accordingly, attachment adhesive 22 is selected to provide adhesion to the desired substrate and is preferably substantially transparent. If desired, attachment adhesive 22 can be a hot melt adhesive formulation such that the resultant laminate is applied to a document by heat lamination. In some embodiments, attachment adhesive 22 may be pressure-sensitive in nature. Typically, attachment adhesive 22 is preferably substantially colorless, although if desired it may be colored to achieve special effects. Typically, attachment adhesive 22 is preferably quite stable such that it does not change color or substantially weaken in bonding strength as it ages.
  • attachment adhesive 22 is selected to provide bond to reflector 20 and to the ultimate substrate (not shown) which is stronger than the interlayer adhesion of the other elements of security laminate 10 and/or the substrate such that attempts to remove the laminate 10 from the document in order to tamper with the document will result in readily visible damage to the laminate or document.
  • materials useful as attachment adhesives herein include high molecular weight thermoplastics, e.g., ethylene/acrylic acid copolymers, such as PRIMACOR 1410 and DAF 808 which are commercially available from Dow Chemical Company.
  • attachment adhesive 22 will be a substantially continuous layer which is between about 40 and about 80 microns in thickness.
  • attachment adhesive 22 will comprise a layer made up of segments of more than one kind of adhesive.
  • the layer may be made up of a pattern of segments of a first kind of adhesive which preferentially adheres to reflector 20 and a second kind of adhesive which adheres less strongly to reflector 20 such that it preferentially releases from reflector 20 and thus preferentially adheres to the ultimate document to which the laminate is applied such that, after application to the document and upon application of a peel force, attachment adhesive 22 will separate in the aforementioned pattern to provide an indication of attempted removal.
  • attachment adhesive 22 will be covered with temporary release liner 24 prior to application of the laminate to a substrate.
  • it will be desired to impart a matte finish to the bottom surface (i.e., the surface which is bonded to the substrate) of attachment adhesive 22 as a matte finish typically improves the tendency of the adhesive to wet the surface of the document to which the resultant laminate is being applied.
  • the bottom of attachment adhesive 22 has a highly glossy finish, air bubbles may tend to become entrapped, thereby impairing the bond which is achieved.
  • cover sheet 14 is typically multilayer in construction.
  • cover sheet 14 may comprise outer layer 32, support layer 34, and optional bonding layer 36.
  • Outer layer 32 is typically selected to exhibit high resistance to conditions to which the resultant laminate is likely to be subjected, such as abrasion, exposure to deleterious agents, etc.
  • outer layer 32 comprises a durable, tough material.
  • films of many different polymers and copolymers could be used in outer layer 32.
  • Illustrative examples of preferred abrasion resistant materials for use in outer layer 32 include high molecular weight thermoplastic copolymers which are inherently tough, of which ionomeric ethylene methacrylic acid copolymers such as SURLYN 9910 which is commercially available from Du Pont are preferred examples.
  • Other useful examples include ethylene acrylic acid copolymers such as PRIMACOR 1420 which is commercially available from Dow Chemical Company.
  • outer layer 32 is between about 0.5 and about 1.5 mils (10 and 40 microns) thick.
  • abrasion-resistant it is meant that the outer layer is resistant to damage such as a substantial reduction in optical clarity or transparency when subjected to abrasive forces such as encountered by a card being inserted into a wallet. Abrasion resistant outer layers also improve the resistance of the laminate incorporating same to accumulation of dirt by tending to retain a smooth surface rather than easily developing gouges and roughened portions which might readily collect dirt.
  • the term "abrasion-resistant” materials means to materials which, after 100 abrasion cycles in accordance with ASTM D-1044-85, which is incorporated herein by reference, suffer an increase in percent haze of less than about 20 percent and preferably less than about 10 percent. For instance, films of the aforementioned SURLYN 9910 have been observed to suffer an increase in percent haze of only about 8 percent after this test. In comparison, certain conventional polyester films have been observed to suffer increases in percent haze of over 40 percent.
  • Support layer 34 is selected to impart other desired properties to cover sheet 14 and the overall laminate into which it is to be incorporated.
  • structural layer 34 is selected to impart improved resistance to deformation under localized pressure, such as might be encountered by pressing with a pen on a security laminate which is mounted on a document.
  • Another common source of pressure is when a document bearing a laminate of the invention is located next to the face of an embossed credit card in a wallet which is being carried in the hip pocket of a person.
  • the wallet and its contents are typically subjected to compressive forces such that the portions of the document abutting the embossed characters of the credit card may be subjected to substantial point pressures.
  • Such pressures may tend to damage the laminate or cause it to degrade or wear, thereby shortening the effective life of the anti-tampering properties thereof or even damaging the laminate so severely that the document becomes unreadable under diffuse lighting conditions.
  • the support layer should resist deformation under probable point pressures to which the security laminate is expected to be subjected to during use and to which the laminate is intended to withstand. For instance, as mentioned above, a laminate may be written on or it may be pressed against nonplanar objects while subjected to substantial pressures. Thus, the support layer should provide sufficient tensile strength such that the laminate will resist deformation under such pressures, thereby protecting the other elements of the laminate, particularly the critical arrangement of microspheres and reflector from unwanted changes in arrangement.
  • film materials that are at least about 1 mil (25 microns) thick and have a Young's Modulus of between about 2000 and about 6000 MegaPascals (MPa), preferably between about 3500 and about 5500 MPa, will exhibit the desired properties to function as a support layer herein. Accordingly, materials having Young's Moduluses in those ranges are referred to herein as "resistant to deformation under localized pressure”. "Young's Modulus” or modulus of elasticity is defined in the Encyclopedia of Polymer Science & Engineering, 2nd ed., vol. 7, pp. 82-85, as "a measure of the force that is required to deform the film to a certain degree” and is also "a measure of the intrinsic stiffness of the film”.
  • the "resistance to deformation under localized pressure" of a material is indicated by its Knoop Hardness as determined in accordance with ASTM D-1474-85, which is incorporated herein by reference.
  • Film materials that are at least about 1 mil (25 microns) thick and have a Knoop Hardness of at least 10, and preferably at least 20, are considered to be herein "resistant to deformation under localized pressure".
  • support layers in cover sheets of the invention can be made using polyester films having Knoop Hardnesses of at least 15 and in some instances at least 20.
  • Knoop Hardness is a dimensional scale that can be converted to SI units (kg/mm2) by dividing the Knoop Hardness units by 14.23.
  • An illustrative example of a preferred structural layer is film of polyethylene terephthalate, i.e., polyester, typically between about 1 and about 2 mils (25 and 50 microns) thick.
  • Other illustrative examples include cellulose acetate, polystyrene, polycarbonate, and polyvinyl chloride films. Such materials provide increased tensile strength and resistance to distortion under localized pressure.
  • Bonding layer 36 comprises a layer which will provide a strong bond to the adjacent element of cover sheet 14, e.g., support layer 34, and base sheet 12.
  • bonding layer 36 may comprise a layer of adhesive.
  • a preferred adhesive is a layer, between about 0.5 and about 2 mils (15 and 50 microns) thick, of high-melt-index, e.g., between about 10 and 50, thermoplastic film such as PRIMACOR 3440 or 3460 or ethylene/vinyl acetate copolymers such as ELVAX 250 from Du Pont.
  • Such adhesives can be used to join a previously assembled base sheet and cover sheet to yield a security laminate of the invention.
  • cover sheet 14 and base sheet 12 will be joined together by heat lamination to yield the resultant security laminate.
  • a single layer having suitable properties may be used in place of separate support and bonding layers.
  • lamination liner 38 is used as a surface on which to join cover sheet 14 to base sheet 12, typically facilitating handling of cover sheet 14 and providing protection thereto.
  • An illustrative example of lamination liner 38 is a film of polyethylene terephthalate.
  • liner 38 is between about 20 and about 80 microns thick although it will be understood that carriers having thicknesses outside this range may be used if desired.
  • lamination liner 38 i.e., the surface on which cover sheet 14 is carried, preferably has a very smooth, i.e., glossy, finish.
  • laminates of the invention may be applied to documents by methods employing heat to activate attachment adhesive 22. Under such conditions, the outer surface of outer layer 32 may tend to soften so as to assume surface features of lamination liner 38. Accordingly, lamination liner 38 is preferably very smooth so as to yield a glossy outer surface on outer layer 32 which is desired for optimum retroreflection by minimizing the diffuse reflection which is associated with surfaces having matte finishes.
  • lamination liner 38 should be "temperature resistant", i.e., it should not change so as to lose the desired release properties with respect to cover sheet 14 or become dimensionally unstable, e.g., tending to shrink or or stretch so as to spoil laminate 10, when heated to activate a heat-activated attachment adhesive 22.
  • temperature resistant materials are materials which are sufficiently dimensionally stable that when heated to between about 200°F and about 350°F (90°C and 175°C) they shrink or expand only about 3 percent or less.
  • the cover sheet film is a multilayer construction fabricated by extruding thermoplastic outer layer 32 and bonding layer 36 to opposite sides of support layer 34.
  • Strong interfacial adhesion between the various layers can be provided by priming the layers, e.g., by corona or plasma treatment, or utilizing a process for enhancing the adhesion therebetween, such as is disclosed in U.S. Patent Nos. 3,188,265 (Charbonneau) and 3,188,266 (Charbonneau).
  • outer layer 32 and bonding layer 36 may be extruded onto support layer 34 after treating of the latter on one or both sides with adhesion promoting primer(s).
  • the particular means useful for providing the desired interfacial adhesion will depend in part upon the particular materials used in the subject layers and may be readily determined by trial and error.
  • attachment adhesive 22 may be selected so as to provide a compatible bond or adhesion to special surfaces.
  • an additional layer 23 of special adhesive or other material can be applied to provide means for compatibly bonding with documents having special surface characteristics, e.g., photographic emulsions or images prepared by thermal dye transfer techniques.
  • compatibly bond it is meant to bond without undesired degradation of the substrate, e.g., fading or smearing of the information such as by the break down of an imaged photographic emulsion due to agents in the attachment adhesive, but with high adhesion such that the laminate cannot be removed by peeling without visibly damaging the substrate so as to provide readily apparent indication of tampering.
  • Polaroid Corporation's Adhesive Solution No. 2 is rotogravure coated onto attachment adhesive 22 to provide compatibility with Polaroid's wet photographic films.
  • a layer of VITEL 222 polyester resin from Goodyear is solution coated onto attachment adhesive layer 22 to provide compatibility with thermally imaged dye receptive surfaces, which comprise selectively deposited dyes transferred by thermal dye transfer to a dye-receptor treated substrate.
  • secured document is used herein to describe any document to which a security laminate of the invention is applied.
  • document will be understood to include “inserts” designed to be laminated into a pre-assembled identification card pouch, where a security laminate of the invention is over-extensive to, i.e., extends beyond the extent of, the information surface of a document such as the photograph in an identification card, to include identification cards where the security laminate is substantially flush with the edges of the document, and also to include package labels, etc., where the area protected by the security laminate is of lesser extent than the entire object.
  • Figure 4 illustrates a secured document of the invention which comprises retroreflective security laminate 10, enclosed document 40, and backing member 42.
  • Security laminate 10 may optionally comprise an additional special adhesive layer (not shown), as discussed above.
  • Document 40 may comprise paper, coated paper, plastic film, photographic film, thermally-imaged substrates, and other identification card substrate materials, and may contain printed or photographic alphanumeric characters or artwork on its front and back surfaces.
  • backing member 42 bonds to the edges of security laminate 10 thus surrounding and enclosing document 40, and preferably bonds to the document 40 as well.
  • An illustrative backing member is a 1 to 2 mil (25 to 50 microns) thick layer of a high melt index adhesive 46 such Du Pont ELVAX 550 bonded to a 2 to 5 mil (50 to 125 microns) thick sheet 44 of polyester.
  • attachment adhesive 22 is selected to have a relatively low melt index, e.g., about 1.5
  • bonding layer 36 is selected to have a high melt index, e.g., about 10 to about 50, to further frustrate attempts to tamper with the protected document.
  • application of heat to soften attachment adhesive 22 as a means to separate security laminate 10 from the document will first soften bonding layer 36, thereby loosening cover sheet 14 from fragile base sheet 12. Any damage to base sheet 12 is readily apparent under retroreflective viewing conditions, thereby enabling easy detection of tampering.
  • FIG. 5 illustrates another secured document of the invention.
  • secured document 50 comprising security laminate 10 applied to photographic emulsion 52 on photographic paper 54.
  • security laminate 10 may further optionally comprise an additional specialized adhesive layer (not shown) as discussed above.
  • U.S. Patent No. 3,551,025 discloses an enclosed-lens retroreflective sheeting wherein the refractive indices of the microspheres and binder material are such that the reflector layer is in direct contact with the rear surfaces of the microspheres.
  • Figure 6 illustrates an embodiment of security laminate 60 of the invention, wherein dielectric reflector 20 is in direct contact with microspheres 16 except where spacing results from the presence of selectively deposited lacquer 19.
  • microspheres 16 in order for incident light to focus at the rear surfaces of microspheres 16, and accordingly on reflector 20, microspheres 16 must have indices of refraction of about 1.9 times that of the binder material in which the monolayer of microspheres is embedded. For instance, microspheres having an index of refraction of about 2.58 could be used in a binder material having an index of refraction of about 1.38. Many organic resins having refractive indices in this range will be known to those skilled in the art.
  • Laminate 60 illustrated in Figure 6 can be made by coating binder material 18, e.g., a fluorinated resin such as Du Pont VITON A, having an index of refraction of about 1.38, directly onto cover sheet 14 and then cascading microspheres 16 having a refractive index of about 2.58 thereinto such that they are partially, preferably substantially hemispherically, embedded therein. Lacquer 19 is then selectively printed directly on the exposed rear surfaces of microspheres 16, and then dielectric reflector 20, e.g, a vapor coated layer of zinc sulfide, applied thereto. Attachment adhesive 22 can then be applied thereto.
  • binder material 18 e.g., a fluorinated resin such as Du Pont VITON A, having an index of refraction of about 1.38
  • lacquer 19 is then selectively printed directly on the exposed rear surfaces of microspheres 16, and then dielectric reflector 20, e.g, a vapor coated layer of zinc sulfide, applied thereto. Attachment adhesive 22 can
  • the front or outer surface of the cover sheet of the laminate was rubbed for 50 one-direction strokes with #600 wet or dry sandpaper using normal finger pressure of about 6 to about 10 ounces.
  • the laminate was then examined for evidence of penetration of the cover sheet, loss or degradation of legibiltiy of underlaying information under diffuse light conditions, and loss or degradation of retroreflective appearance under retroreflective viewing conditions.
  • a secured document with the subject laminate applied thereto was prepared.
  • the document was placed on a flat surface with the cover sheet of the laminate facing upward.
  • Three 3/16 inch width hexagonal nuts were placed separately on the cover sheet and a 5 pound weight placed thereon such that it was jointly supported by the three nuts.
  • the assembly was then exposed to room temperature, then 120°F (50°C), and then 150°F (65°C), each for a period of 24 hours. After each 24 hour period, the laminate was examined for visible indentation to the cover sheet, dislocation of the microspheres within the laminate, and loss or degradation of the retroreflective appearance of the laminate under retroreflective viewing conditions.
  • a base sheet was formed by notch bar coating a slurry of microspheres in binder composition to a temporary release liner.
  • the binder comprised the following:
  • the microspheres were glass microspheres having an average diameter of about 60 microns and an index of refraction of about 2.25.
  • the slurry was made with a binder to microspheres weight ratio of about 1.86:1.
  • the microspheres settled to the carrier, substantially assuming a monolayer arrangement, and then the binder composition was cured by air drying for about 10 minutes, and then heating in an oven at about 150°F (65°C) for about 5 minutes and then in an oven at about 260°F (125°C) for about 7 minutes to form a binder layer having a spacing layer of about 12 microns thick behind the rear surfaces of the microspheres.
  • a lacquer of FLEXOTUF Varnish, a polyamide ink from Inmont, diluted with ethanol to a viscosity corresponding to a rating of about 30 seconds in a #2 Zahn cup was rotogravure printed in imagewise fashion using a plate press onto the spacing layer and the construction heated in an oven at about 150°F (65°C) for about 2 minutes to dry the printed lacquer.
  • a reflector was then formed by vapor coating a zinc sulfide layer of about one-quarter of one wavelength thickness on the exposed spacing layer and lacquer in a bell jar vacuum chamber according to standard techniques.
  • SCOTCH Brand PSA #966 an acrylic pressure-sensitive adhesive from 3M on a release liner, was cold roll laminated over the reflector to form the attachment adhesive in a layer about 2 mils (50 microns) in thickness.
  • a cover sheet was then formed by bonding together, in accordance with U.S. Patent Nos. 3,188,265 and 3,188,266, an outer layer of a 1 mil (25 microns) thick film of SURLYN 9910 from Du Pont, a support layer of 1.5 mils (40 microns) thick film of polyester, and a bonding layer of a 1 mil (25 microns) thick film of PRIMACOR 1420 from Dow Chemical.
  • the temporary carrier was then removed from the base sheet and the base sheet and the cover sheet then heat laminated together at an interface temperature of about 300°F (150°C) with a lamination liner (50 micron thick polyester film) contacting the outer surface of the outer layer of the cover sheet.
  • the release liner was removed from the attachment adhesive and the security laminate then cold roll laminated to a gelatin-based photograph. The lamination liner was then stripped from the cover sheet.
  • the laminate Under diffuse lighting conditions the laminate was substantially transparent. Under retroreflective viewing conditions, the background region appeared yellow while the legend (the lacquer areas) provided substantially no retroreflection. It is believed that little if any of the zinc sulfide vapor coat clung to the lacquer resulting in nonformation of the reflector therebehind.
  • the outer layer was found to be resistant to abrasion in that the cover film was not penetrated, legibility of underlying information in diffuse light was excellent, and retroreflective apearance was substantially unaffected.
  • SURLYN 9910 outer layers have been found to exhibit an increase in percent haze of only about 8 percent.
  • the laminate was also found to be point pressure resistant after each of the testing conditions. After the conditioning at 150°F (65°C), slight marring of the retroreflective appearance was detected but the retroreflective image was substantially not degraded.
  • the polyester support layer was found to have a Knoop Hardness of about 20.
  • a security laminate was made substantially as in Example 1 except as follows.
  • the lacquer was FLEXOROTO Lacquer, an aliphatic hydrocarbon diluted in ethanol as in Example 1 from Consolidated Printing Ink Company, and was flexographically printed in imagewise fashion using a Webtron press and dried to specifications.
  • the zinc sulfide was vapor coated to a thickness of about one-half of one wavelength.
  • the attachment adhesive was a 1 mil (25 microns) thick film of DAF 808 from Dow Chemical Company which was hot laminated to the reflector.
  • the lamination liner was a 0.5 mil (15 microns) thick film of polyester.
  • the laminate When the laminate was completed, it was heat laminated to a gelatin-based photograph. The lamination liner was then stripped from the cover sheet.
  • the laminate Under diffuse lighting conditions the laminate was substantially transparent. Under retroreflective viewing conditions, the legend areas appeared yellow while the background area appeared purple. In view of the contrast in color between the legend and the background, the legend was quite legible.
  • a security laminate was made as in Example 2 except for the following.
  • the zinc sulfide was applied to a thickness of about five-eighths of one wavelength.
  • POLAROID ADHESIVE Solution No. 2 was rotogravure coated over the exposed surface of the attachment adhesive.
  • the laminate was heat laminated to a wet Polaroid photograph insert on a backing member of comprising a 2 mil (50 microns) thick sheet of ELVAX 550 from DuPont bonded to a 5 mil (125 microns) thick sheet of polyester.
  • the lamination liner was then stripped from the cover sheet.
  • the laminate Under diffuse lighting conditions the laminate was substantially transparent. Under retroreflective viewing conditions, the legend areas appeared yellow while the background area appeared blue. In view of the contrast in color between the legend and the background, the legend was quite legible.
  • a security laminate was prepared as in Example 2, and heat laminated to a gelatin-based photograph on a backing member similar to that used in Example 3 except that it further comprised a stiff paper backing. The lamination liner was then stripped from the cover sheet.
  • the security laminate had the same appearance under both diffuse and retroreflective viewing conditions as it did in Example 2. Attempts to peel the laminate from the photograph/paper substrate resulted in readily visible damage to the photograph and paper. Thus, the laminate was considered to provide a highly secure seal.
  • a security laminate was made as in Example 2 except for the following.
  • the bonding layer comprised a 2 mil (50 microns) thick film of ELVAX 250 from Du Pont
  • the support layer comprised a 2 mil (50 microns) thick polyester film
  • the zinc sulfide was vapor coated to a thickness of about five-eighths of one wavelength.
  • the laminate was heat laminated to a gelatin-based photograph.
  • the lamination liner was then stripped from the cover sheet.
  • the laminate Under diffuse lighting conditions the laminate was substantially transparent. Under retroreflective viewing conditions, the legend areas appeared yellow while the background area appeared blue/green. In view of the contrast in color between the legend and the background, the legend was quite legible.
  • the bonding layer softened before the attachment adhesive such that the laminate suffered readily visible damage.
  • the laminate was thus considered to provide a highly secure seal.
  • a security laminate was formed as in Example 2 except the bonding layer was a 1 mil (25 microns) thick film of PRIMACOR 3460, the lacquer was rotogravure printed, the zinc sulfide was applied to about one-half wavelength thickness, the attachment adhesive was a 1 mil (25 microns) thick layer of PRIMACOR 1410 applied on a polyester release liner, and the lamination liner was a 1 mil (25 microns) thick polyester film.
  • the laminate was heat laminated to a gelatin based photograph.
  • the lamination liner was then stripped from the cover sheet.
  • the laminate Under diffuse lighting conditions the laminate was substantially transparent. Under retroreflective viewing conditions, the legend areas appeared faintly orange while the background area appeared purple thereby providing poor color contrast and poor legibility of the retroreflective image. The poor color contrast is believed to have resulted because of insufficiently thick lacquer deposit.
  • a security laminate was made as in Example 6 except as follows.
  • the lamination liner a 1 mil (25 microns) thick polyester film, was laminated to the outer surface of the outer layer of the cover sheet, and then the slurry of binder material and microspheres was applied directly to the bonding layer of the cover sheet.
  • the lacquer was a flexigraphically printed isooctyl acrylate/acrylic acid adhesive composition (63/35 weight ratio) diluted in ethanol to a viscosity corresponding to a rating of about 30 seconds in a #2 Zahn cup.
  • the laminate was heat laminated to a gelatin-based photograph.
  • the lamination liner was then stripped from the cover sheet.
  • the laminate Under diffuse lighting conditions the laminate was substantially transparent. Under retroreflective viewing conditions, the legend areas appeared faint orange while the background area appeared purple, thereby providing poor contrast and poor legibility of the retroreflective image. The poor contrast was believed to be the result of similar "sticking coefficient" properties of the adhesive which was used as lacquer and the spacing layer.
  • a security laminate adapted to be applied to thermally-imageable dye receptor surface could be made by making a laminate as in Example 6 and applying, e.g., by notch bar coating, a layer of VITEL 222 polyester resin, available from Goodyear Company, having a 2 mil (50 microns) dry thickness over the attachment adhesive used in that Example.
  • Such a security laminate would provide the diffuse and retroreflective appearances described in Example 6 and could be heat laminated to a thermally-imageable surface while yielding high dye stability.
  • a security laminate could be made as described in Example 6 except the cover sheet could comprise only two layers, an outer layer of a 1 mil (25 microns) thick film of SURLYN 9910 and a bonding layer of a 2 mil (50 microns) thick film of PRIMACOR 3460.
  • a security laminate could be made with a cover sheet like that used in Example 6 upon which a layer of VITON A resin from Du Pont as binder material would be notch bar coated and partially dried, following which microspheres having a refractive index of about 2.58 would be cascaded to form a monolayer of partially embedded microspheres therein. The rear surfaces of the microspheres would be exposed, i.e., would protrude from the binder layer.
  • An adhesive ink formulation like that used in Example 7 could be flexographically printed in imagewise fashion thereover and then a layer of zinc sulfide having a thickness of about one quarter of one wavelength vapor coated thereover to provide the reflector.
  • An attachment adhesive like that used in Example 6 could then be laminated over the reflector.
  • the retroreflective performance of such a laminate would be expected to be higher than that of the previous examples wherein the security laminates comprise a spacing layer located between the rear surfaces of the microspheres and the reflector.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Laminated Bodies (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)
  • Road Signs Or Road Markings (AREA)

Claims (12)

  1. Mit einer Beschriftung versehenes, im wesentlichen durchsichtiges Sicherheitslaminat (10), das im wesentlichen auf seiner gesamten Oberfläche rückstrahlend ist, wobei das Laminat rückstrahlende beschriftete Bereiche und rückstrahlende Hintergrundbereiche aufweist, die im wesentlichen durchsichtig und bei der üblichen Betrachtung unter diffusem Licht im wesentlichen nicht voneinander zu unterscheiden sind, wobei die beschrifteten Bereiche und die Hintergrundbereiche optisch differenzierbare Rückstrahlungseigenschaften besitzen, so daß die beschrifteten Bereiche bei der Betrachtung unter rückstrahlendem Licht leicht voneinander zu unterscheiden sind, wobei das Laminat folgendes umfaßt:
    a) eine Basisschicht (12) mit Mikrokügelchen (16), die im wesentlichen in einer Monolage angeordnet sind, wobei teilweise lichtdurchlässige Reflektoren (20) hinter deren Rückseite angeordnet sind, wobei die Mikrokügelchen wenigstens teilweise in einer durchsichtigen Bindemittelschicht (18) eingebettet sind, wobei die Basisschicht des weiteren einen Lack (19) umfaßt, der hinter der Rückseite von einigen der Mikrokügelchen angeordnet ist; und
    b) eine Deckschicht (14), die mit der Vorderseite der Basisschicht verklebt ist, wobei die Deckschicht eine äußere Schicht (32) umfaßt,
    dadurch gekennzeichnet, daß die äußere Schicht (32) eine abriebfeste Außenseite besitzt und auf der Innenseite der äußeren Schicht eine Stützschicht (34) vorgesehen ist, wobei die Stützschicht widerstandsfähig ist gegen eine Verformung unter örtlich ausgeübtem Druck und eine Dicke von mindestens 25 µm und eine Knoop-Härte von mindestens 10 aufweist.
  2. Laminat nach Anspruch 1, bei dem die Deckschicht (14) des weiteren eine Klebeschicht (36) umfaßt, die die Deckschicht mit der Basisschicht (12) verklebt.
  3. Laminat (10) nach Anspruch 1 oder Anspruch 2, bei dem die äußere Schicht (32) ein ionomeres Copolymer umfaßt.
  4. Laminat (10) nach einem der vorhergehenden Ansprüche, bei dem die Stützschicht (34) eine Polyethylenterephthalatfolie umfaßt und/oder eine Knoop-Härte von mindestens etwa 20 besitzt.
  5. Laminat (10) nach einem der vorhergehenden Ansprüche, des weiteren umfassend eine Laminierfolie (38), die lösbar mit der Außenseite der äußeren Schicht (32) verklebt ist.
  6. Laminat (10) nach einem der vorhergehenden Ansprüche, bei dem die beschrifteten Bereiche eine andere Farbverteilung reflektieren als die Hintergrundbereiche, und/oder bei dem die beschrifteten Bereiche und die Hintergrundbereiche eine unterschiedliche Rückstrahlungsleistung besitzen.
  7. Laminat (10) nach einem der vorhergehenden Ansprüche, welches einen Befestigungskleber (22) auf der Rückseite der Basisschicht (12) umfaßt.
  8. Laminat (10) nach Anspruch 7, umfassend eine Klebeschicht (36), die die Deckschicht (14) mit der Basisschicht (12) verklebt, wobei die Klebeschicht einen höheren Schmelzindex besitzt als der Befestigungskleber (22).
  9. Gesichertes Dokument (10, 40, 42, 50) umfassend eine Informationsseite, wo auf mindestens einem Abschnitt derselben Hinweise zu sehen sind, wobei das Dokument ein Sicherheitslaminat (10) nach einem der vorhergehenden Ansprüche umfaßt, welches mit Hilfe eines Befestigungsklebers (22) damit verklebt ist, so daß das Laminat mindestens einen Teil der Hinweise bedeckt.
  10. Verfahren zur Herstellung eines rückstrahlenden Sicherheitslaminats (10), wobei das Verfahren die folgenden Schritte umfaßt:
    a) Auftragen eines Mikrokügelchen (16) und Bindemittel enthaltenden Breis auf einen vorübergehenden Träger (26), so daß die Mikrokügelchen im wesentlichen in einer Monolage angeordnet sind, wobei das Bindemittel eine Bindemittelschicht (18) bildet, die eine beim Aushärten im wesentlichen durchsichtige Abstandsschicht umfaßt, wobei der Träger so gewählt ist, daß sich die Bindemittelschicht davon löst;
    b) Auftragen eines Lacks (19) auf die Abstandsschicht in der Art eines Bildes;
    c) Ausbilden eines dielektrischen Reflektors (20) über dem Lack und den freiliegenden Abschnitten der Abstandsschicht;
    d) Auftragen eines Befestigungsklebers (22) auf die Rückseite des Reflektors;
    so daß man eine Basisschicht (12) erhält, und
    e) Abziehen der Basisschicht von dem Träger; und
    f) Aufkleben einer Deckschicht (14) auf die Vorderseite der Basisschicht, wobei die Deckschicht eine äußere Schicht (32) mit einer abriebfesten Außenseite und eine Stützschicht (34) auf der Innenseite der äußeren Schicht umfaßt, wobei die Stützschicht widerstandsfähig ist gegen eine Verformung unter örtlich ausgeübtem Druck und eine Dicke von mindestens 25 µm und eine Knoop-Härte von mindestens 10 besitzt.
  11. Verfahren nach Anspruch 10, bei dem der Brei direkt auf die Deckschicht (14) und nicht auf den vorübergehenden Träger (26) aufgetragen wird.
  12. Verfahren zur Herstellung eines rückstrahlenden Sicherheitslaminats (10), wobei das Verfahren folgende Schritte umfaßt:
    a) Bereitstellen einer Deckschicht (14) umfassend eine äußere Schicht (32) mit einer abriebfesten Außenseite und eine mit der Innenseite verklebte Stützschicht (34), wobei die Stützschicht widerstandsfähig ist gegen eine Verformung unter örtlich ausgeübtem Druck und eine Dicke von mindestens 25 µm, eine Knoop-Härte von mindestens 10 und wahlweise eine Klebeschicht (36) besitzt, die mit der Stützschicht auf der der äußeren Schicht gegenüberliegenden Seite in Kontakt steht;
    b) Aufbringen einer flüssigen Bindemittelzusammensetzung auf die Deckschicht, wobei die Bindemittelzusammensetzung so gewählt ist, daß sie eine Bindemittelschicht (18) ergibt;
    c) Einleiten einer Vielzahl von Mikrokügelchen (16) in die Bindemittelzusammensetzung, so daß die Mikrokügelchen im wesentlichen in einer Monolage angeordnet sind und teilweise in der Bindemittelzusammensetzung eingebettet sind;
    d) Herstellen einer Bindemittelschicht aus der Bindemittelzusammensetzung, wobei die Mikrokügelchen einen Brechungsindex besitzen, der etwa das 1,5- bis etwa das 2,0-fache des Brechungsindex der Bindemittelschicht beträgt;
    e) Auftragen eines Lacks (19) in der Art eines Bildes auf die freiliegenden Flächen der ausgewählten Mikrokügelchen und der Bindemittelschicht;
    f) Ausbilden eines dielektrischen Reflektors (20) über dem Lack und den freiliegenden Oberflächen der nicht ausgewählten Mikrokügelchen;
    g) Auftragen eines Befestigungsklebers (22) auf die Rückseite des dielektrischen Reflektors.
EP90306724A 1989-06-21 1990-06-20 Retroreflektierende Filme mit Schutzdeckschicht Expired - Lifetime EP0404539B1 (de)

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US36963089A 1989-06-21 1989-06-21
US369630 1989-06-21

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EP0404539A3 EP0404539A3 (de) 1991-02-20
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JP (1) JPH0363602A (de)
KR (1) KR0172599B1 (de)
AU (1) AU632587B2 (de)
CA (1) CA2019274A1 (de)
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ES (1) ES2077029T3 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5060981A (en) * 1989-09-19 1991-10-29 Minnesota Mining And Manufacturing Company Transparent overlay for protecting a document from tampering
US5169707A (en) * 1991-05-08 1992-12-08 Minnesota Mining And Manufacturing Company Retroreflective security laminates with dual level verification
EP0685079B1 (de) * 1993-02-16 1997-10-22 Minnesota Mining And Manufacturing Company Thermodruckempfangsschicht und zerbrechliche retroreflektierende polymerbahnen
US5670005A (en) * 1993-02-16 1997-09-23 Minnesota Mining And Manufacturing Company Method for manufacturing improved data display retroreflective sheeting
US5656360A (en) * 1996-02-16 1997-08-12 Minnesota Mining And Manufacturing Company Article with holographic and retroreflective features
JPH10170710A (ja) * 1996-12-12 1998-06-26 Minnesota Mining & Mfg Co <3M> 光再帰性反射シート
US6024455A (en) * 1998-01-13 2000-02-15 3M Innovative Properties Company Reflective article with concealed retroreflective pattern
US6157486A (en) * 1998-01-13 2000-12-05 3M Innovative Properties Company Retroreflective dichroic reflector
KR200459750Y1 (ko) * 2009-07-27 2012-04-13 정용탁 비즈전사효과를 구비한 전사지
CN105473325B (zh) * 2013-08-19 2019-05-07 3M创新有限公司 包括基本上为无定形的聚合物层的回射片材
KR20200065062A (ko) 2017-10-27 2020-06-08 쓰리엠 이노베이티브 프로퍼티즈 캄파니 1차 반사 층 및 2차 반사 층을 포함하는 재귀반사 요소를 포함하는 재귀반사 물품
US11366252B2 (en) 2017-10-27 2022-06-21 3M Innovative Properties Company Retroreflective article comprising locally-laminated reflective layers
CN111263902A (zh) 2017-10-27 2020-06-09 3M创新有限公司 包括嵌入反射层的回射制品

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3188265A (en) * 1957-11-12 1965-06-08 Minnesota Mining & Mfg Packaging films
NL133265C (de) * 1959-11-02
US3188266A (en) * 1963-09-03 1965-06-08 Minnesota Mining & Mfg Interface bonding of polymers and product thereof
US3551025A (en) * 1969-03-28 1970-12-29 Minnesota Mining & Mfg Highly flexible reflex reflecting constructions
US3801183A (en) * 1973-06-01 1974-04-02 Minnesota Mining & Mfg Retro-reflective film
US4099838A (en) * 1976-06-07 1978-07-11 Minnesota Mining And Manufacturing Company Reflective sheet material
AU581288B2 (en) * 1985-03-01 1989-02-16 Minnesota Mining And Manufacturing Company Flat transparent top coat for retroreflective coating
US4721649A (en) * 1985-05-08 1988-01-26 Minnesota Mining And Manufacturing Company Retroreflective sheeting
US4663213A (en) * 1985-11-18 1987-05-05 Minnesota Mining And Manufacturing Company Transparent multi-layer cover film for retroreflective sheeting

Also Published As

Publication number Publication date
EP0404539A2 (de) 1990-12-27
KR0172599B1 (ko) 1999-05-01
DE69022488D1 (de) 1995-10-26
ES2077029T3 (es) 1995-11-16
DE69022488T2 (de) 1996-05-09
JPH0363602A (ja) 1991-03-19
AU632587B2 (en) 1993-01-07
KR910000354A (ko) 1991-01-29
EP0404539A3 (de) 1991-02-20
CA2019274A1 (en) 1990-12-21
AU5766890A (en) 1991-01-03

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