Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
  • B29D30/00—Producing pneumatic or solid tyres or parts thereof
  • B29D30/06—Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
  • B29D30/52—Unvulcanised treads, e.g. on used tyres; Retreading
  • B29D30/66—Moulding treads on to tyre casings, e.g. non-skid treads with spikes
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B60—VEHICLES IN GENERAL
  • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
  • B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
  • B60C11/14—Anti-skid inserts, e.g. vulcanised into the tread band
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K9/00—Use of pretreated ingredients
  • C08K9/10—Encapsulated ingredients
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
  • B29D30/00—Producing pneumatic or solid tyres or parts thereof
  • B29D30/06—Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
  • B29D30/52—Unvulcanised treads, e.g. on used tyres; Retreading
  • B29D30/66—Moulding treads on to tyre casings, e.g. non-skid treads with spikes
  • B29D2030/665—Treads containing inserts other than spikes, e.g. fibers or hard granules, providing antiskid properties

Definitions

• the present invention relates to a process for stably incorporating granules of high-hardness materials, substantially granules of ceramic type, into the tread of tires for motor vehicles and the like. It is known that several processes are already used in the art in order to coat with hi gh-fri ct i ona l-coeffi c i ent materials the tires for motor vehicles, in order to endow said tires with a particularly high resistance to skidding on wet, ice- covered or snow-covered roadbeds.
• the most widely used processes provide for hard bodies, as irregular polyhedral granules, to be incorporated inside a support and e last i c- retent i on matrix, such as natural or synthetic rubber, or a synthetic resin of epoxy type.
• the granules used are generally constituted by substances selected from among the carbides and/or nitrides and/or oxides of si licon, titanium, tungsten, aluminium, zirconium, boron, magnesium, chrome, mixtures of said substances and sti ll other ceramic or cermet materials, and the like.
• the techniques of incorporation of the granules provide for a compound of vulcanisable rubber, or epoxy resin, single-component or double-component polyurethane resin, or the like, to be formed; with granules having pre-established size being incorporated into said compound, in the preestabl i shed amount, by weight, before the end moulding and curing or cross linki ng.
• the granules, before being charged to the rubber compound are coated with a thin layer of an adhesive selected from among those adhesives which show a good compatibi lity and affinity with both the rubber and the granules.
• a purpose of the present invention is to provide a process for incorporating granules of ceramic type into either natural or synthetic rubber, or into synthetic resins of epoxy type, of polyurethane type, and the like, in particular into the tread of tires in general, which is easy and simple to be practiced, and is such as to reduce the possible detaching of granules down to negligible percent values.
• a further purpose of the present invention is to provide a tire which comprises a tread provided with ceramic granules, by means of a process of incorporation of said ceramic granules, which is capable of giving said granules a reliable and long-lasting stability inside their rubber support under any stress conditions the tire may be submitted to, with the drawbacks and the serious dangers which the detaching of the granules may cause, being thus prevented.
• the present Applicant was able to observe that if the granules of ceramic type, having a suitable, properly selected average size, are previously coated with a coating constituted by compounds endowed with high covering and adhesive properties, which compounds are already known and used in order to bond various metals to either natural or synthetic rubber, or to several synthetic resins, during the end vulcan sation or crosslinking step, a reliable and long-lasting stabi lity of incorporation of the granules inside the tire tread is obtained, without any danger of expulsion of the same granules from their respective seats.
• a coating adhesive which is constituted by organic polymers in solution with solid matter in dispersion in an organic solvent
• a second layer of coating material or "cover-coat”, constituted by a polymeric solution also dispersed in a solvent.
• the formulations of the coating compounds known from the prior art, which showed to be the most suitable for stably incorporating ceramic granules inside the treads of tires, are the following: for_t he_fjrst_coatjng_ layer, i.e., the_ ⁇ rimer : the products known under the trade marks "CHEMOSIL 211" and "CHEMOSIL X 1400", available from HUGHSON Che.
• the present invention provides a process for stably incorporating granules of ceramic type, such as corundum, carbides, nitrides, borides and oxides of various metals and/or mixtures thereof, into the tread of tires, and the like, which process consists in treating the ceramic granules inside a tumbling barrel, or a similar mixer, with at least one primer selected from among CHEMOSIL 211, CHEMOSIL X 1400, MEGUM 3270, THIXON P10, THIXON P6-1, ANCHOR TP/6 and similar t*pes, so as to form on said granules a first coating layer, with the thickness of said coating layer being preestabli shed as a function of the weight and of the chemical and physical characteristics of the adhesive used, and in subsequently treating the so-coated granules with at least one cover- coat selected from among CHEMOSIL 221, CHEMOSIL X 4400, MEGUM 100
• the thickness of the first primer layer, once dried, should be comprised, according to the type, the weight and the size of the product, at least within the range of from 5 to 40 microns, preferably of from 10 to 20 microns, and the thickness of the covering layer (i.e., the "cover-coat"), should be comprised at least within the range of from 5 to 60 microns, preferably of from 20 to 40 microns.
• the preferred ratio of the volume of the coated granules to the volume of the rubber compound should be substantially comprised within the range of from 10 to 15J.
• said first primer layer can be replaced by a layer, having the same thickness, which is constituted by the same material as of the second cover-coat layer, or even by another material, of different type, sti ll selected from among the group consisting of the cover-coat covering materi a Is.
• the process according to the present invention can be practically embodied in a particularly simple and cheap way, in that neither special equipment pieces, nor particular temperatures are required.
• the initial selection of the average size of the ceramic granules is carried out in relationship with the type of use the tires are designed for.
• the granules are charged to a tumbling drum and are treated with a primer (a high-performance coating adhesive), e.g., with Chemosil 211, in such mutual propo ⁇ rtions as to form on the outer surface of the granu ⁇ les a first coating Layer having a thickness comprised within the range of from 10 to 20 microns (as referred to the dry coating), and the coated granules are subse ⁇ quently treated, still inside the tumbling drum, with a covei—coat, e.g.
• Chemosil 221 in such a way as to form on said first layer a second coating Layer having a thickness comprised within the range of from 20 to 40 mi ⁇ crons (still referred to the dry coating).
• a drying is then carried out at a temperature of about 50-60°C, pre ⁇ ferably with hot air, and the granules are then submit ⁇ ted to a sieving, also this step be ng preferably car- ried out in a hot air stream, in order to complete the evaporation of the solvent, and to prevent the granules from forming clots, in order to sort the same granules, to separate them from one another, and to eliminate any possible clots and fragmented granules generated by the action of the treatment inside the tumbling drum.
• a compound of raw, either na ural or synthetic, rubber, or of suitable resins is then prepared, and the sieved granules are mixed inside an open mixer, preferably of the calendei—pass type, or the like, with the rubber already containing all of the necessary fillers and the necessary amount of sulphur and/or of suitable crosslinking agents.
• the ratio of the granules to the rubber by volume is mantained comprised within the range of from 5 to 15%.
• SUBSTITUTESHEET present Applicant was able to observe that by means of the coating method according to the present invention, a bonding of the granules to the rubber can be obtained, which is so highly efficacious, even in corri spondence of the edges or sides of the tread, that, after the application of strong and long-lasting stresses to the tire, a loss of granules is observed, which is practically negligible, i.e., is of about 7-9% of total granules, after a run ⁇ ning test correspond ng to a covered distance of 1,000 Km. and without any variation of said rate also after an additional run of 1,000 Km.
• the present Applicant was also able to observe that, by force ⁇ dly removing some granules from the surface of the tire, the part of rubber which enclosed the granule was torn, with said rubber part remaining bonded to the same granu ⁇ le, instead of being detached from it.
• the shape of the granules is of considerable importance for the purposes of the efficac ousness and of the Life of the same granules inside the tire.
• the granule is of long shape, for example, is of either cylind r ical or prismatic shape, or has a* flat shape, e.g., a "noodles" - or "tile” - or “flake”- like shape, or the like, it tends to arrange itself in a radial orientation when the compound which contains it is charged to the mould; in other terms, preferably presenting the edge of the noodle or tile, or either of the bases, on the outer surface of the finished tire obtained, with this particular orientation being favoured by the presence of the blades, or of the other vertical elements installed inside the same mould in order to
• SUBSTITUTE SHEET accomplish the tread pattern.
• the granule offers a much higher resistance to the removal by friction and to the detachment, and furthermore shows a much more regular and progressive wear, practically corresponding to the progressive wear of the same tread.
• the granules of ceramic type obtained by extrusion, drawing or suitable processes and subsequent sintering; with it being possible the shape, width or diameter, and length thereof to be varied as desired and according to the use requirements; have shown to be particularly usefu I.

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• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Chemical & Material Sciences (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Compositions Of Macromolecular Compounds (AREA)
• Tyre Moulding (AREA)

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• 1988
  • 1988-01-19 IT IT8819104A patent/IT1233839B/it active
• 1989
  • 1989-01-12 WO PCT/EP1989/000029 patent/WO1989006670A1/en not_active Application Discontinuation
  • 1989-01-12 EP EP89901548A patent/EP0398914A1/en not_active Withdrawn
  • 1989-01-12 JP JP1501449A patent/JPH03504021A/ja active Pending
• 1990
  • 1990-07-19 DK DK173190A patent/DK173190A/da active IP Right Grant
  • 1990-07-19 FI FI903659A patent/FI903659A0/fi not_active IP Right Cessation

Non-Patent Citations (1)

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