EP0385216A1 - Compositions détergentes liquides blanchissantes - Google Patents

Compositions détergentes liquides blanchissantes Download PDF

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Publication number
EP0385216A1
EP0385216A1 EP90103139A EP90103139A EP0385216A1 EP 0385216 A1 EP0385216 A1 EP 0385216A1 EP 90103139 A EP90103139 A EP 90103139A EP 90103139 A EP90103139 A EP 90103139A EP 0385216 A1 EP0385216 A1 EP 0385216A1
Authority
EP
European Patent Office
Prior art keywords
weight
composition according
sodium
less
soap
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP90103139A
Other languages
German (de)
English (en)
Inventor
Karl Schwadtke
Eduard Dr. Smulders
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0385216A1 publication Critical patent/EP0385216A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • the invention relates to an aqueous liquid detergent containing builder salts, which contains hydrogen peroxide as a bleaching agent and is distinguished by high storage stability and easy meterability.
  • non-aqueous and aqueous liquid detergents containing bleaching per-compounds are known.
  • the stabilization of the per-compounds is usually not a problem.
  • the stabilization of the anti-segregation agents often presents difficulties.
  • sedimentation stabilizers still have to be added.
  • Another disadvantage is that often larger amounts of flammable organic solvents have to be added.
  • Means of the type mentioned are described for example in DE 12 79 878 (GB 12 05 711), DE 22 33 771 (US 38 50 831), DE 28 25 218 (US 43 16 812) and EP 30 086.
  • EP 38 101 proposes encapsulating the bleaching agent granules and suspending them in the agent in this form.
  • the alkylbenzenesulfonate is preferably in the form of the sodium salt. Its proportion is preferably 7 to 12% by weight.
  • Suitable amine oxides are e.g. B. dodecyldimethylamine oxide, tridecyldimethylamine oxide, tetradecyldimethylamine oxide, pentadecyldimethylamine oxide and hexadecyldimethylamine oxide and mixtures thereof. Their proportion is preferably 2 to 5% by weight.
  • Suitable soaps are preferably those from natural fatty acid mixtures, such as coconut or palm kernel fatty acid.
  • the fatty acids with 10 and fewer carbon atoms are previously separated off in a proportion of less than 5% by weight, preferably less than 3% by weight (based on soap). It is also advisable to separate the stearic acid to a stearate content below 20% by weight, preferably below 15% by weight (based on soap).
  • the proportion of unsaturated fatty acid soaps, such as oleate is advantageously also less than 10%, based on soap.
  • the soaps are preferably in the form of sodium salts, the proportion of which is preferably 2 to 5% by weight.
  • the proportion of potassium pyrophosphate which is preferably used as tetrapotassium pyrophosphate, is preferably 15 to 21% by weight. Higher proportions, i.e. H. those up to 25% by weight are possible in principle, but are less recommendable for reasons of phosphate restrictions in waste water.
  • Suitable hydrotropes are toluenesulfonate, xylene sulfonate and cumene sulfonate, each in the form of the sodium salts. Their proportion is preferably 5 to 10% by weight.
  • the hydrogen peroxide is calculated as 100% H2O2. Its proportion is preferably 1 to 4% by weight.
  • the water should be deionized and in particular free of heavy metal ions. Its proportion is preferably 50 to 57% by weight. In addition, small amounts of those constituents which are insensitive to oxidation, such as dyes or opacifiers, can be present. Additional stabilizing agents are not required since the agents themselves have a surprisingly high storage stability. After all, small proportions, i.e. H. a maximum of 0.5 to 1% by weight of oxidation-insensitive sequestering stabilizers, such as 1-hydroxyethane-1,1-diphoshonic acid, ethylenediamine-tetra- (methylenephosphonic acid and diethylenetriamine-penta- (methylenephosphonic acid), in each case in the form of Na - or K salt.
  • oxidation-insensitive sequestering stabilizers such as 1-hydroxyethane-1,1-diphoshonic acid, ethylenediamine-tetra- (methylenephosphonic acid and diethylenetriamine-penta- (methylenephosphonic acid), in
  • the agents are very stable in storage.
  • the loss of active oxygen is less than 1% even after storage for several months at room temperature (20 - 25 ° C).
  • they are characterized by a high washing and bleaching effect, especially in relation to colored stains.
  • a clear, homogeneous, easily pourable liquid detergent had the following composition (in% by weight): 9% C10 ⁇ 13 alkylbenzenesulfonate (Na salt) 3% C13 ⁇ 15 alkyl dimethyl amine oxide 4% coconut soap (Na salt) with 2% C10, 55% C12, 22% C14, 12% C16, 9% C18 20% K4P2O7 8% Na toluenesulfonate 3% H2O2 53% water
  • washing tests were carried out in the landerometer.
  • a commercial liquid detergent (comparable to an agent according to EP 28 866) containing alkylbenzenesulfonate, nonionic surfactants, coconut soap, enzymes, enzyme stabilizers and water was used.
  • the following were used as textile samples: T1 cotton, soiled with dust and skin fat, T2 mixed fabric made of polyester and finished cotton (wash and wear), soiled with dust and skin oil, T3 cotton (refined) soiled with red wine, T4 cotton (refined) soiled with tea stains.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
EP90103139A 1989-02-27 1990-02-19 Compositions détergentes liquides blanchissantes Withdrawn EP0385216A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3906044 1989-02-27
DE19893906044 DE3906044A1 (de) 1989-02-27 1989-02-27 Bleichendes fluessigwaschmittel

Publications (1)

Publication Number Publication Date
EP0385216A1 true EP0385216A1 (fr) 1990-09-05

Family

ID=6375014

Family Applications (1)

Application Number Title Priority Date Filing Date
EP90103139A Withdrawn EP0385216A1 (fr) 1989-02-27 1990-02-19 Compositions détergentes liquides blanchissantes

Country Status (4)

Country Link
EP (1) EP0385216A1 (fr)
DE (1) DE3906044A1 (fr)
PT (1) PT93238A (fr)
WO (1) WO1990010055A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996030483A1 (fr) * 1995-03-24 1996-10-03 Warwick International Group Limited Detergent liquide isotropique alcalin contenant du peroxyde
WO1996030484A1 (fr) * 1995-03-24 1996-10-03 Warwick International Group Limited Detergent liquide isotrope alcalin contenant du peroxyde
WO1996030486A1 (fr) * 1995-03-24 1996-10-03 Warwick International Group Limited Detergent liquide isotrope alcalin avec du peroxyde
WO1996030485A1 (fr) * 1995-03-24 1996-10-03 Warwick International Group Limited Detergent liquide isotrope alcalin avec du peroxyde
EP0779357A1 (fr) * 1995-12-16 1997-06-18 The Procter & Gamble Company Emulsions stables contenant un ingrédient hydrophobe liquide
EP0962520A1 (fr) * 1998-05-29 1999-12-08 The Procter & Gamble Company Compositions liquides de blanchiment
GB2339789A (en) * 1998-07-16 2000-02-09 Reckitt & Colman Inc Aqueous cleaning and surface treatment compositions
WO2000023555A1 (fr) * 1998-10-22 2000-04-27 Colgate-Palmolive Company Composition de blanchiment liquide epaissie a base de peroxyde d'azote
EP1065262A1 (fr) * 1999-06-29 2001-01-03 The Procter & Gamble Company Compositions de blanchiment

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2766724B1 (fr) * 1997-07-31 1999-10-22 Irdec Sa Compositions decontaminantes non agressives
US6010729A (en) 1998-08-20 2000-01-04 Ecolab Inc. Treatment of animal carcasses
JP2004508291A (ja) 2000-04-28 2004-03-18 イーコラブ　インコーポレイティド 抗菌組成物
US7150884B1 (en) 2000-07-12 2006-12-19 Ecolab Inc. Composition for inhibition of microbial growth
US6479454B1 (en) 2000-10-05 2002-11-12 Ecolab Inc. Antimicrobial compositions and methods containing hydrogen peroxide and octyl amine oxide
US6514556B2 (en) 2000-12-15 2003-02-04 Ecolab Inc. Method and composition for washing poultry during processing
US7622606B2 (en) 2003-01-17 2009-11-24 Ecolab Inc. Peroxycarboxylic acid compositions with reduced odor
US7771737B2 (en) 2004-01-09 2010-08-10 Ecolab Inc. Medium chain peroxycarboxylic acid compositions
US7507429B2 (en) 2004-01-09 2009-03-24 Ecolab Inc. Methods for washing carcasses, meat, or meat products with medium chain peroxycarboxylic acid compositions
JP2007520479A (ja) 2004-01-09 2007-07-26 イーコラブ インコーポレイティド 中鎖ペルオキシカルボン酸組成物
US7887641B2 (en) 2004-01-09 2011-02-15 Ecolab Usa Inc. Neutral or alkaline medium chain peroxycarboxylic acid compositions and methods employing them
US7504123B2 (en) 2004-01-09 2009-03-17 Ecolab Inc. Methods for washing poultry during processing with medium chain peroxycarboxylic acid compositions
US7754670B2 (en) 2005-07-06 2010-07-13 Ecolab Inc. Surfactant peroxycarboxylic acid compositions
US7547421B2 (en) 2006-10-18 2009-06-16 Ecolab Inc. Apparatus and method for making a peroxycarboxylic acid
US8075857B2 (en) 2006-10-18 2011-12-13 Ecolab Usa Inc. Apparatus and method for making a peroxycarboxylic acid
JP7334174B2 (ja) 2018-02-14 2023-08-28 エコラボ ユーエスエー インコーポレイティド 膜からバイオフィルムおよび胞子を低減するための組成物および方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE657865A (fr) * 1964-01-04 1965-07-05
US4298492A (en) * 1979-06-21 1981-11-03 Lever Brothers Company Built liquid detergent composition
DE3519689A1 (de) * 1985-06-01 1986-12-04 Henkel KGaA, 4000 Düsseldorf Fluessiges waschmittelkonzentrat

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE657865A (fr) * 1964-01-04 1965-07-05
US4298492A (en) * 1979-06-21 1981-11-03 Lever Brothers Company Built liquid detergent composition
DE3519689A1 (de) * 1985-06-01 1986-12-04 Henkel KGaA, 4000 Düsseldorf Fluessiges waschmittelkonzentrat

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996030483A1 (fr) * 1995-03-24 1996-10-03 Warwick International Group Limited Detergent liquide isotropique alcalin contenant du peroxyde
WO1996030484A1 (fr) * 1995-03-24 1996-10-03 Warwick International Group Limited Detergent liquide isotrope alcalin contenant du peroxyde
WO1996030486A1 (fr) * 1995-03-24 1996-10-03 Warwick International Group Limited Detergent liquide isotrope alcalin avec du peroxyde
WO1996030485A1 (fr) * 1995-03-24 1996-10-03 Warwick International Group Limited Detergent liquide isotrope alcalin avec du peroxyde
EP0910465A4 (fr) * 1995-12-16 1999-04-28
EP0910465A1 (fr) * 1995-12-16 1999-04-28 The Procter & Gamble Company Emulsions stables comportant un ingredient liquide hydrophobe
EP0779357A1 (fr) * 1995-12-16 1997-06-18 The Procter & Gamble Company Emulsions stables contenant un ingrédient hydrophobe liquide
EP0962520A1 (fr) * 1998-05-29 1999-12-08 The Procter & Gamble Company Compositions liquides de blanchiment
WO1999063033A1 (fr) * 1998-05-29 1999-12-09 The Procter & Gamble Company Compositions de blanchiment liquides
US6482786B1 (en) 1998-05-29 2002-11-19 The Procter & Gamble Company Liquid bleaching compositions comprising hydrogen peroxide, betaine, and ethoxylated nonionic surfactant
GB2339789A (en) * 1998-07-16 2000-02-09 Reckitt & Colman Inc Aqueous cleaning and surface treatment compositions
US6531437B1 (en) 1998-07-16 2003-03-11 Reckitt Benckiser Inc Shelf stable, aqueous hydrogen peroxide containing carpet cleaning and treatment compositions
WO2000023555A1 (fr) * 1998-10-22 2000-04-27 Colgate-Palmolive Company Composition de blanchiment liquide epaissie a base de peroxyde d'azote
EP1065262A1 (fr) * 1999-06-29 2001-01-03 The Procter & Gamble Company Compositions de blanchiment
WO2001000774A1 (fr) * 1999-06-29 2001-01-04 The Procter & Gamble Company Compositions de blanchiment

Also Published As

Publication number Publication date
WO1990010055A1 (fr) 1990-09-07
DE3906044A1 (de) 1990-08-30
PT93238A (pt) 1990-08-31

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