EP0383972B1 - Transducteur ultrasonore à éléments de vibration trapézoidaux, et procédé et dispositif pour leur fabrication - Google Patents
Transducteur ultrasonore à éléments de vibration trapézoidaux, et procédé et dispositif pour leur fabrication Download PDFInfo
- Publication number
- EP0383972B1 EP0383972B1 EP89103112A EP89103112A EP0383972B1 EP 0383972 B1 EP0383972 B1 EP 0383972B1 EP 89103112 A EP89103112 A EP 89103112A EP 89103112 A EP89103112 A EP 89103112A EP 0383972 B1 EP0383972 B1 EP 0383972B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- laser light
- laser
- electrode
- ceramic
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 16
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000000463 material Substances 0.000 claims abstract description 12
- 230000008878 coupling Effects 0.000 claims abstract description 8
- 238000010168 coupling process Methods 0.000 claims abstract description 8
- 238000005859 coupling reaction Methods 0.000 claims abstract description 8
- 238000013016 damping Methods 0.000 claims abstract description 8
- 238000002604 ultrasonography Methods 0.000 claims description 34
- 239000000919 ceramic Substances 0.000 claims description 17
- 230000005855 radiation Effects 0.000 claims description 14
- 239000007772 electrode material Substances 0.000 claims description 5
- 238000003698 laser cutting Methods 0.000 claims description 3
- 238000003491 array Methods 0.000 description 8
- 230000003071 parasitic effect Effects 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000003384 imaging method Methods 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
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- 229910010293 ceramic material Inorganic materials 0.000 description 1
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- 238000006880 cross-coupling reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
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- 150000002500 ions Chemical class 0.000 description 1
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- 238000003754 machining Methods 0.000 description 1
- 230000009022 nonlinear effect Effects 0.000 description 1
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- 238000013021 overheating Methods 0.000 description 1
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Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B06—GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS IN GENERAL
- B06B—METHODS OR APPARATUS FOR GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS OF INFRASONIC, SONIC, OR ULTRASONIC FREQUENCY, e.g. FOR PERFORMING MECHANICAL WORK IN GENERAL
- B06B1/00—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency
- B06B1/02—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy
- B06B1/06—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy operating with piezoelectric effect or with electrostriction
- B06B1/0644—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy operating with piezoelectric effect or with electrostriction using a single piezoelectric element
- B06B1/0648—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy operating with piezoelectric effect or with electrostriction using a single piezoelectric element of rectangular shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B06—GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS IN GENERAL
- B06B—METHODS OR APPARATUS FOR GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS OF INFRASONIC, SONIC, OR ULTRASONIC FREQUENCY, e.g. FOR PERFORMING MECHANICAL WORK IN GENERAL
- B06B1/00—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency
- B06B1/02—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy
- B06B1/06—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy operating with piezoelectric effect or with electrostriction
- B06B1/0607—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy operating with piezoelectric effect or with electrostriction using multiple elements
- B06B1/0622—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy operating with piezoelectric effect or with electrostriction using multiple elements on one surface
Definitions
- the invention relates to an ultrasound array with a number of adjacent oscillator elements, which are coated with electrode material on a first and second electrode surface, which are opposite one another, all oscillator elements being arranged with their second electrode surface in a base surface, which oscillation elements are a first and have a second boundary surface, which lie opposite one another and are aligned non-parallel to one another, and which oscillator elements are aligned such that their cross section changes in the same way from the first electrode surface to the second electrode surface.
- the invention also relates to a method for producing such an array.
- An ultrasound array of the type mentioned at the outset is from PATENT ABSTRACTS OF JAPAN, Vol. 6, No. 132 (E-119) (1010), July 17, 1982 & JP-A-57-58 498.
- the oscillating elements forming an array are trapezoidal and are lined up with alternating polarity directions so that they form an arc.
- the reception sensitivity is increased by the same shape, but different polarization direction of the oscillating elements.
- the arcuate arrangement of the vibrating elements allows sector scanning by means of continuous activation of the vibrating elements, the receiving surface being arranged on the outer side of the arc.
- the converter elements cannot be arranged in such a way that they have a maximum possible opening angle or acceptance angle, which is a prerequisite for the construction of a phased array.
- FIG 5 of DE-C-28 29 570 Another ultrasound array is known from FIG 5 of DE-C-28 29 570.
- This is an ultrasound array which has a number of ultrasound transducer or oscillating elements of a trapezoidal cross section lying next to one another on a carrier or damping body.
- the first and second electrode surfaces, which are covered with electrode material and lie opposite one another in parallel, are each rectangular. Two flat boundary surfaces run towards each other in a wedge shape.
- two types of vibrating elements are used alternately side by side: those in which the first electrode area serving as the radiation area is larger than the second electrode area facing the damping body or arranged in a base area, and those in which, conversely, the first electrode area serving as the radiation area Electrode area is smaller than the second electrode area parallel to it.
- an ultrasound array in particular one with fine division of the individual transducer elements, can be used in a sawing technique, e.g. B. by means of a laser cutting beam.
- Such an ultrasound array is not suitable as a phased-array applicator, since the two types of oscillating element that are adjacent to each other have different radiation characteristics.
- the width of the radiation area of each vibrating element must be less than or equal to ⁇ / 2, where ⁇ is the wavelength of the ultrasound emitted in the propagation medium. This condition cannot be met or can only be met incompletely in an ultrasound array with two different types of vibrating elements.
- the invention is therefore based on the requirement that only identical oscillator elements should be used in an ultrasound array used as a phased array applicator.
- the older German patent application P DE-A-37 39 226 states that acoustic cross-couplings between the individual ultrasonic transducers of an ultrasonic transducer array can be reduced if the second electrode base surfaces facing the carrier body are larger than their end faces or first electrode surfaces facing away from the carrier body.
- ultrasound transducers are thus produced, the cross-sectional area of which runs parallel to the longitudinal direction of the array and has the shape of an isosceles trapezoid.
- the opposite side surfaces of the parting lines located between the ultrasonic transducers are then no longer parallel and the cross-sectional area of the parting line then has a trapezoidal shape.
- Such separating joints with a trapezoidal cross section can be produced, for example, by means of two saw cuts inclined at an acute angle to one another.
- the angle of attack of the saw blade is limited relative to the end face of the array.
- exact bevel cuts can only be achieved with great technical effort.
- the invention has set itself the goal of specifying an ultrasound array constructed from individual oscillator elements, which enables the generation of short ultrasound pulses with a center frequency in the range from 1 to 50 MHz with a high bandwidth.
- the vibrating elements which consist of a piezoelectric ceramic material covered on both sides with electrode material, are intended to work as thickness transducers.
- the directional diagrams of the individual oscillator elements, namely all of the oscillator elements, should have the largest possible opening angle so that the ultrasound array can be used as a linear phased array antenna which is used to scan (scan) acoustically transparent media with the aid of ultrasound pulses , preferably for Ultrasound examination of patients.
- the individual vibrating elements should have high transmission and reception transmission factors.
- the invention is therefore based on the object of specifying an ultrasound array of the type mentioned at the outset, which can be used as a phased array antenna for scanning acoustically transparent media. Furthermore, a method for the production of such an ultrasound array and a device for the production are to be specified.
- the first-mentioned object is achieved according to the invention with the characterizing features of claim 1 for AT, CH, GB, FR, LI and NL.
- All similar vibrating elements with non-parallel boundary surfaces are used. All transducer elements thus have the same directional characteristic and - with a suitable dimensioning - all the same opening angle of a suitable size.
- the arrangement is such that the first electrode area facing the radiation area of the oscillating elements is smaller than the second electrode area facing the damping body.
- the method for producing such an ultrasound array is based on a method in which a piezoelectric material is irradiated with a laser cutting beam on lines spaced in parallel.
- the second object is achieved on the basis of this method according to the invention (claim 1 for DE and claim 7 for AT, CH, GB, FR, LI and NL.) That a piezoelectric ceramic on only one side with converging laser light on the parallel spaced lines is irradiated such that in the Ceramic incisions next to each other with non-parallel walls are created.
- a device for carrying out the method contains a laser, the laser beam of which can be directed onto a piezoelectric material.
- a focusing device is arranged between the piezoelectric material and the laser and generates a converging laser light cutting beam on the piezoelectric material.
- an ultrasound array 2 suitable as a phased array for medical purposes contains a number of juxtaposed vibrating elements 4.
- the core of each vibrating element 4 is a piezoelectric material 6, in particular a piezoceramic such as, for. B. of the PZT-5 type, the opposite to each other in parallel first and second electrode surfaces are covered with an electrode material 8 and 10, respectively.
- All (non-cuboid) vibrating elements 4 are the same and are aligned so that their cross-section changes continuously in the direction from the first to the second electrode surface 8 or 10 in the same way, here the first electrode surface 8 is smaller than the second electrode surface 10.
- All Vibrator elements are arranged with their second electrode surface 10 in a base surface.
- oscillator elements 4 with mutually opposite, non-parallel first and second boundary surfaces 12 and 14 in the transverse direction x are used.
- the third and fourth boundary surfaces in the longitudinal direction y of each oscillating element 4, which are designated 16 and 18 in FIG. 1, are preferably non-parallel to one another.
- the respective longitudinal section may also be trapezoidal.
- the individual vibrating elements 4 are located on a common damping body 20, the surface of which represents the base area in which the second electrode surfaces 10 of the vibrating elements 4 are arranged. This can be known from a particle-filled plastic, the z. B. based on epoxy or polyurethane exist.
- the individual vibrating elements 4 with essentially smooth boundary surfaces 12, 14 are separated from one another by V-shaped gaps or incisions 22. It is noteworthy that the V-shaped incisions 22 each extend into the damping body 20 in the present embodiment.
- Each oscillating element 4 is provided with a coupling layer 24 on the radiation side. It should therefore be emphasized that in the present embodiment, a common coupling layer covering all oscillator elements 4 is not used.
- the individual coupling layers 24 are also separated from one another by the V-shaped gap 22. This ensures good acoustic decoupling.
- the incision 22 common to all layers 24, 8, 6, 10 and 20 is produced in one operation in each case during the production of the ultrasound array 2.
- the ultrasonic radiation area on each coupling layer 24 is designated by 26.
- the first electrode surface 8 facing the radiation surface of the oscillating elements 4 is smaller than the effective second electrode surface 10 facing the damping layer 20.
- the wedge angle was 2.5 °
- the thickness t of the individual vibrating element 4 t 0.4 mm
- the length l 12 mm
- the width w u 0.2 mm.
- the thickness t to be used depends on the piezo material and the width w u on the medium in which the ultrasound propagates after coupling.
- the width w u should be less than or equal to ⁇ / 2, where ⁇ is the wavelength.
- the thickness t and the width w u should differ by a factor of 2 or larger. In the present case, a factor of almost exactly 2 was chosen for the dimensioning.
- Fig. 2 In the reduced side view of Fig. 2 is shown schematically that the radiation-side first electrode 8 is bent sideways on both edges and electrically from the edges via a ground line 28 to a common point 30, z. B. to a grounded terminal 32, is performed.
- the rear second electrode 10 has a center tap which is connected to a further connection 36 via a line 34.
- Vibrating elements 4 with non-parallel boundary surfaces 12, 14 and / or 16, 18 can only be produced with great difficulty with the usual machining methods (mechanical sawing or cut-off grinding). Therefore, this problem is solved in the present case by using a device with laser sawing technology ("laser saw”).
- laser saw a device with laser sawing technology
- different types of lasers can be used for this, such as. B. Argon ion and Nd-YAG lasers.
- the prepared layer package 40 consististing of layers 24, 8, 6, 10, 20 with piezoceramic 6
- the ceramic 6 is principally transparent to the light from the abovementioned lasers, the absorption of the laser radiation takes place only on the basis of nonlinear effects. This means that the cut surfaces do not become very smooth and 22 beads are formed on the edges.
- an excimer laser 42 is therefore used to avoid overheating and to achieve smooth surfaces, the light in the ultraviolet range of which is directly absorbed by the piezoceramic 6 in the layer package 40.
- the radiation 44 emerging from the laser 42 is focused with a focusing device 46, which generates a point focus 48, that is, preferably with a converging lens, and is irradiated onto the location of the ceramic 6 in the package 40 that is to be removed.
- the desired V-shape of the incisions 22 and thus the trapezoidal shape of the vibrating elements 4 can be selected by the focusing device 46.
- the incisions 22 now result from a relative movement of the piezoelectric ceramic 6 and the laser light with the point focus 48 during the irradiation.
- the layer package 40 is moved to produce the incisions 22.
- the layer package 40 is mounted on a holder 50 which is moved in the direction of arrow 52.
- the device according to FIG. 5 is constructed similarly to the device according to FIG. 4.
- the focusing device 46 here consists of a cylindrical lens which converges the laser light 44 to a line focus 54 which has the length of the incision 22.
- the relative movement which is indicated by the arrow 52 in FIG. 4, can be avoided.
- the distance of the incisions (22, ie the width w of the oscillating elements 4) is set in FIGS. 4 and 5 by appropriate mechanical (stepwise) advancement of the package 40 transversely to the main beam direction s of the laser beam moved in the direction of arrow 56.
- FIG. 6 A further device for producing V-shaped incisions is shown in FIG. 6.
- the radiation 44 emerging from the laser 42 is broadened via the beam expansion device 58, so that the expanded laser beam 59 irradiates the entire array area.
- the laser beam 59 then passes through a mask 60 which is provided with slots 62.
- the arrangement of the slots 62 represents an image of the incisions 22 lying next to one another in the ceramic 6.
- This mask 60 is imaged on the surface of the layer package 40 with the focusing device 46, which now represents an imaging system, so that the expanded laser beam 59 likewise Many line foci are generated at the same time as incisions 22 are to be made in the ceramic 6.
- the device according to FIG. 6 thus allows all incisions 22 in the ultrasound array 2, which are spaced apart in parallel, to be produced in one operation.
- the depth of cut of the incisions 22 is set by the number of laser pulses. This is possible with very high repeatability.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Ultra Sonic Daignosis Equipment (AREA)
- Transducers For Ultrasonic Waves (AREA)
- Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
Claims (15)
- Procédé pour fabriquer un réseau à ultrasons comportant un certain nombre d'éléments oscillateurs (4) disposés côte-à-côte, selon lequel on expose un matériau piézoélectrique à un faisceau laser de coupe le long de traits parallèles, caractérisé par le fait qu'on expose une céramique piézoélectrique (6), uniquement sur une face, avec une lumière laser convergente (44), sur des lignes parallèles de manière à former, dans la céramique (6), des encoches (22) disposées côte-à-côte et à parois (12,14; 16,18) non parallèles, ainsi que les éléments oscillateurs.
- Procédé suivant la revendication 1, caractérisé que la lumière laser (44) converge en un foyer (48) et que l'encoche (22) est formée sous l'effet d'un déplacement relatif entre la céramique piézoélectrique (6) et la lumière laser, pendant l'exposition.
- Procédé suivant la revendication 1, caractérisé par le fait que la lumière laser (44) converge en un foyer en forme de trait (54), qui possède la longueur de l'encoche (22).
- Procédé suivant la revendication 2 ou 3, caractérisé par le fait qu'après chaque exposition, on déplace la céramique (6) d'un pas transversalement par rapport à la direction de rayonnement principale (s).
- Procédé suivant la revendication 3 ou 4, caractérisé par le fait que pour la production de la lumière laser, qui converge au foyer en forme de trait (47), il est prévu un laser (42), dont le faisceau (44) est dévié sur une lentille cylindrique.
- Procédé suivant la revendication 1, caractérisé par le fait que la lumière laser (44) est déviée au moyen d'un masque (60), qui comporte des fentes (62), la disposition des fentes (62) étant une reproduction des encoches (22) disposées côte-à-côte dans la céramique (6), et que pendant l'exposition, l'image de ce masque (60) est formée sur la céramique (6) de sorte que l'on obtient des encoches (22) disposées côte-à-côte.
- Procédé suivant l'une des revendications 1 à 6, caractérisé par le fait que plusieurs impulsions de lumière laser sont projetées dans la céramique (6) sur chacune des lignes parallèles.
- Procédé suivant l'une des revendications 1 à 7, caractérisé par le fait que pour la production de la lumière laser, il est prévu un laser (42), dont la lumière laser (44) est située dans le domaine ultraviolet.
- Procédé suivant la revendication, caractérisé par le fait que le laser (42) est un laser excimère, dont la lumière laser (44) est absorbée par la céramique piézoélectrique (6).
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT89103112T ATE98530T1 (de) | 1989-02-22 | 1989-02-22 | Ultraschall-array mit trapezfoermigen schwingerelementen sowie verfahren und vorrichtung zu seiner herstellung. |
DE89103112T DE58906448D1 (de) | 1989-02-22 | 1989-02-22 | Ultraschall-Array mit trapezförmigen Schwingerelementen sowie Verfahren und Vorrichtung zu seiner Herstellung. |
EP89103112A EP0383972B1 (fr) | 1989-02-22 | 1989-02-22 | Transducteur ultrasonore à éléments de vibration trapézoidaux, et procédé et dispositif pour leur fabrication |
JP2039535A JP2960093B2 (ja) | 1989-02-22 | 1990-02-19 | 超音波アレー及びその加工方法と装置 |
US07/484,352 US5045746A (en) | 1989-02-22 | 1990-02-22 | Ultrasound array having trapezoidal oscillator elements and a method and apparatus for the manufacture thereof |
US08/116,800 USRE35011E (en) | 1989-02-22 | 1993-09-03 | Ultrasound array having trapezoidal oscillator elements and a method and apparatus for the manufacture thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP89103112A EP0383972B1 (fr) | 1989-02-22 | 1989-02-22 | Transducteur ultrasonore à éléments de vibration trapézoidaux, et procédé et dispositif pour leur fabrication |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0383972A1 EP0383972A1 (fr) | 1990-08-29 |
EP0383972B1 true EP0383972B1 (fr) | 1993-12-15 |
Family
ID=8200994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89103112A Expired - Lifetime EP0383972B1 (fr) | 1989-02-22 | 1989-02-22 | Transducteur ultrasonore à éléments de vibration trapézoidaux, et procédé et dispositif pour leur fabrication |
Country Status (5)
Country | Link |
---|---|
US (2) | US5045746A (fr) |
EP (1) | EP0383972B1 (fr) |
JP (1) | JP2960093B2 (fr) |
AT (1) | ATE98530T1 (fr) |
DE (1) | DE58906448D1 (fr) |
Families Citing this family (41)
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US5329202A (en) * | 1991-11-22 | 1994-07-12 | Advanced Imaging Systems | Large area ultrasonic transducer |
US5329496A (en) * | 1992-10-16 | 1994-07-12 | Duke University | Two-dimensional array ultrasonic transducers |
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US5744898A (en) * | 1992-05-14 | 1998-04-28 | Duke University | Ultrasound transducer array with transmitter/receiver integrated circuitry |
US5281887A (en) * | 1992-06-15 | 1994-01-25 | Engle Craig D | Two independent spatial variable degree of freedom wavefront modulator |
US5282005A (en) * | 1993-01-13 | 1994-01-25 | Xerox Corporation | Cross process vibrational mode suppression in high frequency vibratory energy producing devices for electrophotographic imaging |
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JP6052233B2 (ja) * | 2014-05-26 | 2016-12-27 | Tdk株式会社 | 積層型圧電素子 |
US11417309B2 (en) * | 2018-11-29 | 2022-08-16 | Ascent Venture, Llc. | Ultrasonic transducer with via formed in piezoelectric element and method of fabricating an ultrasonic transducer including milling a piezoelectric substrate |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB595154A (en) * | 1941-04-03 | 1947-11-27 | Submarine Signal Co | Improvements in or relating to piezoelectric vibrators |
US2716708A (en) * | 1950-11-17 | 1955-08-30 | Nat Res Dev | Apparatus for launching ultrasonic waves |
US2833999A (en) * | 1953-09-28 | 1958-05-06 | Douglas H Howry | Transducer |
US3059130A (en) * | 1957-10-03 | 1962-10-16 | United Insulator Company Ltd | Electromechanical transducers |
DE2829570C2 (de) * | 1978-07-05 | 1979-12-20 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Ultraschallkopf |
US4211948A (en) * | 1978-11-08 | 1980-07-08 | General Electric Company | Front surface matched piezoelectric ultrasonic transducer array with wide field of view |
US4211949A (en) * | 1978-11-08 | 1980-07-08 | General Electric Company | Wear plate for piezoelectric ultrasonic transducer arrays |
JPS5927560B2 (ja) * | 1980-09-26 | 1984-07-06 | 株式会社日立製作所 | 圧電セラミック振動子による超音波送受波器の製造方法 |
JPS57113700A (en) * | 1980-12-30 | 1982-07-15 | Nippon Dempa Kogyo Co Ltd | Array type ultrasonic wave probe and its manufacture |
JPS57148247A (en) * | 1981-03-09 | 1982-09-13 | Matsushita Electric Ind Co Ltd | Manufacture of ultrasonic probing contact |
US4604542A (en) * | 1984-07-25 | 1986-08-05 | Gould Inc. | Broadband radial vibrator transducer with multiple resonant frequencies |
US4825116A (en) * | 1987-05-07 | 1989-04-25 | Yokogawa Electric Corporation | Transmitter-receiver of ultrasonic distance measuring device |
DE3739226A1 (de) * | 1987-11-19 | 1989-06-01 | Siemens Ag | Verfahren zur herstellung eines ultraschallwandler-arrays |
-
1989
- 1989-02-22 EP EP89103112A patent/EP0383972B1/fr not_active Expired - Lifetime
- 1989-02-22 AT AT89103112T patent/ATE98530T1/de not_active IP Right Cessation
- 1989-02-22 DE DE89103112T patent/DE58906448D1/de not_active Expired - Fee Related
-
1990
- 1990-02-19 JP JP2039535A patent/JP2960093B2/ja not_active Expired - Fee Related
- 1990-02-22 US US07/484,352 patent/US5045746A/en not_active Ceased
-
1993
- 1993-09-03 US US08/116,800 patent/USRE35011E/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
USRE35011E (en) | 1995-08-08 |
EP0383972A1 (fr) | 1990-08-29 |
JPH02246700A (ja) | 1990-10-02 |
ATE98530T1 (de) | 1994-01-15 |
US5045746A (en) | 1991-09-03 |
DE58906448D1 (de) | 1994-01-27 |
JP2960093B2 (ja) | 1999-10-06 |
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