EP0383184B1 - Verfahren zur Reduzierung von Staubemission und freiem Luftzutritt im Abstichbereich eines Hochofens - Google Patents
Verfahren zur Reduzierung von Staubemission und freiem Luftzutritt im Abstichbereich eines Hochofens Download PDFInfo
- Publication number
- EP0383184B1 EP0383184B1 EP90102432A EP90102432A EP0383184B1 EP 0383184 B1 EP0383184 B1 EP 0383184B1 EP 90102432 A EP90102432 A EP 90102432A EP 90102432 A EP90102432 A EP 90102432A EP 0383184 B1 EP0383184 B1 EP 0383184B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- blast furnace
- reduction
- region
- snow
- ferromanganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 238000000034 method Methods 0.000 title claims abstract description 10
- 230000003247 decreasing effect Effects 0.000 title 1
- 239000003517 fume Substances 0.000 title 1
- 238000010079 rubber tapping Methods 0.000 claims abstract description 12
- 239000000428 dust Substances 0.000 claims abstract description 10
- 229910000616 Ferromanganese Inorganic materials 0.000 claims abstract description 9
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 claims abstract description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000005266 casting Methods 0.000 claims abstract description 5
- 229910052742 iron Inorganic materials 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 2
- 239000012768 molten material Substances 0.000 claims 1
- 230000009467 reduction Effects 0.000 abstract description 9
- 238000005121 nitriding Methods 0.000 abstract description 5
- 239000011819 refractory material Substances 0.000 abstract description 4
- 239000013058 crude material Substances 0.000 abstract 1
- 238000010410 dusting Methods 0.000 abstract 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 24
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
- 229910000805 Pig iron Inorganic materials 0.000 description 18
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000007788 liquid Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/10—Supplying or treating molten metal
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/14—Discharging devices, e.g. for slag
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0037—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by injecting powdered material
Definitions
- the invention relates to a method according to the preamble of the main patent claim for reducing the dust emission and free air access in the tapping channel of a blast furnace and, if necessary, the further conveying and decanting devices for the liquid material tapped from the blast furnace until the bed is reached.
- Liquid nitrogen is cryogenic. This requires extensive safety measures regarding storage and handling. Furthermore, the cooling effect is too intense if very special precautionary measures are not taken. Unfortunately, however, the use of liquid nitrogen also leads to nitriding of the pig iron. However, this has an undesirable effect on the quality of the steel material and runs counter to efforts in the blast furnace and steel sector to strive for an ever lower content of dissolved nitrogen in the future.
- the invention has for its object to achieve a reduction in dust emissions in the tapping area of a blast furnace up to the casting bed while reducing the free air access and without increasing the metallurgical nitrogen uptake.
- the invention consists in a method for reducing the dust emission and free air access in the tapping channel of a blast furnace, the subsequent tipping channel, if necessary.
- the subsequent torpedo pan or in the area of the pouring bed when emptying the torpedo pan in that CO2 snow and possibly CO2 Gas is applied to the molten pig iron or ferromanganese and / or is introduced into the said channels or vessels before and / or when it comes into contact with the molten pig iron / ferromanganese.
- a simple advantageous possibility of applying the CO2 snow or a mixture of CO2 snow and CO2 gas consists in the use of one or more cannons, which run in the tapping channel. Tilting channel, torpedo pan and / or glazed bed onto which molten pig iron or slag can be placed.
- tapping channel (s) including iron and slag channel (s)
- snow-like and gaseous carbonic acid (CO2)
- CO2 snow-like and gaseous carbonic acid
- cannon By feeding snow-like and gaseous carbonic acid (CO2), for example using a special cannon, both directly on the tapping side and in several places along the channel, the CO2 snow floats on the slag or pig iron until it enters the tipping channel. Evaporating carbonic acid continuously releases new gaseous carbonic acid, which lowers the partial pressure of harmful atmospheric oxygen and atmospheric nitrogen.
- snow-shaped carbonic acid makes it easy to control the air exclusion and to adapt it to the current situation.
- the pouring jet at the transition of the pig iron from the tapping channel to the tipping channel and also during the transition from the tipping channel to the torpedo pan increases the specific surface area of the pig iron many times over. So far, there has been an inevitable intensification of the oxidation and dust development as well as increased nitriding.
- the gaseous CO2 displaces the harmful atmospheric oxygen and nitrogen if snow-like carbonic acid is simultaneously given to both the liquid pig iron within the tipping channel and to the pouring stream from the pig iron channel to the tipping channel.
- a combined use of gaseous and snow-like carbonic acid can also bring about a significant improvement in this area, especially if both the glazing chamber and the entire glazing bed are protected against the free entry of air by releasing CO2 snow or gas.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Blast Furnaces (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT9090102432T ATE105588T1 (de) | 1989-02-14 | 1990-02-07 | Verfahren zur reduzierung von staubemission und freiem luftzutritt im abstichbereich eines hochofens. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3904415 | 1989-02-14 | ||
DE3904415A DE3904415C1 (enrdf_load_stackoverflow) | 1989-02-14 | 1989-02-14 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0383184A1 EP0383184A1 (de) | 1990-08-22 |
EP0383184B1 true EP0383184B1 (de) | 1994-05-11 |
Family
ID=6374060
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90102432A Revoked EP0383184B1 (de) | 1989-02-14 | 1990-02-07 | Verfahren zur Reduzierung von Staubemission und freiem Luftzutritt im Abstichbereich eines Hochofens |
Country Status (8)
Country | Link |
---|---|
US (1) | US5683652A (enrdf_load_stackoverflow) |
EP (1) | EP0383184B1 (enrdf_load_stackoverflow) |
JP (1) | JPH02282409A (enrdf_load_stackoverflow) |
AT (1) | ATE105588T1 (enrdf_load_stackoverflow) |
CA (1) | CA2010040A1 (enrdf_load_stackoverflow) |
DD (1) | DD292025A5 (enrdf_load_stackoverflow) |
DE (2) | DE3904415C1 (enrdf_load_stackoverflow) |
ES (1) | ES2052985T3 (enrdf_load_stackoverflow) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6460742B1 (en) | 1989-02-14 | 2002-10-08 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for reducing fume emissions during molten metal transfer |
DE4033482C1 (enrdf_load_stackoverflow) * | 1990-10-20 | 1992-02-20 | Kloeckner Stahl Gmbh, 4100 Duisburg, De | |
AU644694B2 (en) * | 1990-10-20 | 1993-12-16 | Klockner Stahl Gmbh | Apparatus and method for delivering inert gas into a molten metal transportation vessel |
US5196072A (en) * | 1990-12-12 | 1993-03-23 | Liquid Air Corporation | Method and apparatus for controlling metal oxide fume generation during subdivision of a body containing metal values |
DK0544967T3 (da) * | 1991-11-28 | 1995-10-16 | Von Roll Ag | Fremgangsmåde til at undertrykke støv og røg ved fremstillingen af elektrostål |
DE19532040C2 (de) * | 1995-08-31 | 1999-05-27 | Schloemann Siemag Ag | Vorrichtung zum Flüssigmetall-Transport in der Gießhalle eines Schachtofens und Verfahren zum Betrieb dieser Vorrichtung |
JP2001503817A (ja) * | 1996-11-08 | 2001-03-21 | レール・リキード・ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード | 溶融金属の移動のあいだの煙霧の放出を減少させる方法 |
DE102011008894A1 (de) | 2011-01-19 | 2012-07-19 | Air Liquide Deutschland Gmbh | Verfahren und Düse zur Unterdrückung einer Entwicklung von eisenhaltigem Dampf |
CN102692327B (zh) * | 2011-03-22 | 2014-06-18 | 上海宝钢设备检修有限公司 | 熔融还原炼铁炉关键设备综合试验方法 |
US9107906B1 (en) | 2014-10-28 | 2015-08-18 | Adma Biologics, Inc. | Compositions and methods for the treatment of immunodeficiency |
US10259865B2 (en) | 2017-03-15 | 2019-04-16 | Adma Biologics, Inc. | Anti-pneumococcal hyperimmune globulin for the treatment and prevention of pneumococcal infection |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1603119A (en) * | 1977-11-21 | 1981-11-18 | Lodge Cottrell Ltd | Fume containment |
US4357003A (en) * | 1980-09-24 | 1982-11-02 | Jones & Laughlin Steel Corporation | Blast furnace cast house pollutant suppression |
EP0071359A1 (en) * | 1981-07-23 | 1983-02-09 | Uss Engineers And Consultants, Inc. | Methods and apparatus for molten metal fume supression |
ZA85911B (en) * | 1984-02-24 | 1985-09-25 | Liquid Air Canada | Molten metal casting |
US4657587A (en) * | 1985-02-21 | 1987-04-14 | Canadian Liquid Air Ltd./Air Liquide Canada Ltee | Molten metal casting |
FR2579495B1 (fr) * | 1985-04-01 | 1987-09-11 | Air Liquide | Procede de protection d'un jet de coulee de metal |
FR2607039B1 (fr) * | 1986-11-26 | 1989-03-31 | Air Liquide | Procede de coulee d'acier comportant un inertage du bain d'acier par de l'anhydride carbonique sous forme de neige |
FR2607829A1 (fr) * | 1986-12-09 | 1988-06-10 | Cootec Deutschland Gmbh | Procede de traitement d'acier en poche |
US4723997A (en) * | 1987-04-20 | 1988-02-09 | L'air Liquide | Method and apparatus for shielding a stream of liquid metal |
-
1989
- 1989-02-14 DE DE3904415A patent/DE3904415C1/de not_active Expired - Lifetime
-
1990
- 1990-02-07 EP EP90102432A patent/EP0383184B1/de not_active Revoked
- 1990-02-07 AT AT9090102432T patent/ATE105588T1/de not_active IP Right Cessation
- 1990-02-07 DE DE59005658T patent/DE59005658D1/de not_active Revoked
- 1990-02-07 ES ES90102432T patent/ES2052985T3/es not_active Expired - Lifetime
- 1990-02-14 CA CA002010040A patent/CA2010040A1/en not_active Abandoned
- 1990-02-14 DD DD90337848A patent/DD292025A5/de not_active IP Right Cessation
- 1990-02-14 JP JP2033629A patent/JPH02282409A/ja active Pending
-
1995
- 1995-06-07 US US08/474,197 patent/US5683652A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ES2052985T3 (es) | 1994-07-16 |
EP0383184A1 (de) | 1990-08-22 |
JPH02282409A (ja) | 1990-11-20 |
ATE105588T1 (de) | 1994-05-15 |
DE59005658D1 (de) | 1994-06-16 |
DE3904415C1 (enrdf_load_stackoverflow) | 1990-04-26 |
DD292025A5 (de) | 1991-07-18 |
CA2010040A1 (en) | 1990-08-14 |
US5683652A (en) | 1997-11-04 |
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RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: L'AIR LIQUIDE S.A. Owner name: INTRACON HANDELSGESELLSCHAFT FUER INDUSTRIEBEDARF |
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Inventor name: WINTER, HARALD Inventor name: FUENDERS, DIETER, DR.-ING. |
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