EP0375474A1 - Flüssiges Reinigungsmittel auf der Basis von Terpenderivaten für harte Oberflächen und Verfahren zu dessen Herstellung - Google Patents
Flüssiges Reinigungsmittel auf der Basis von Terpenderivaten für harte Oberflächen und Verfahren zu dessen Herstellung Download PDFInfo
- Publication number
- EP0375474A1 EP0375474A1 EP89403090A EP89403090A EP0375474A1 EP 0375474 A1 EP0375474 A1 EP 0375474A1 EP 89403090 A EP89403090 A EP 89403090A EP 89403090 A EP89403090 A EP 89403090A EP 0375474 A1 EP0375474 A1 EP 0375474A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- acid
- terpene
- composition according
- water
- fatty acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Definitions
- the present invention relates to a liquid cleaning composition based on terpene deviates, in particular for washing solid surfaces, and to a process for its manufacture.
- liquid compositions suitable for the use specified above containing saponified tall oil fatty acids, a detergent of the nonionic type, ethyl alcohol, terpene derivatives (carbides and / or terpene alcohols), alkaline mineral salts (especially sodium tripolyphosphate), a colorant and water.
- compositions are relatively sensitive to alkaline earth ions contained in hard water and the formation of calcium salts of fatty acids can be the cause of the traces or streaks observed under certain conditions of use.
- their high phosphate content makes them undesirable because of the eutrophication of lakes and rivers.
- the Applicant has now found a composition of liquid cleaner based on derivatives terpene which has better resistance to alkalon earth ions, does not contain phosphate, while having a low pH. It has indeed established: - A pH of about 10.5 can be advantageously obtained by carrying out the saponification of tall oil fatty acids with a mixture of sodium carbonate and soda; the fraction of sodium carbonate which has not been used as a saponification agent serves as a "mild alkaline reserve" and as a viscosity regulator in the cleaning composition; and - better efficiency in the presence of hard water is obtained by using, instead of phosphates, an organic sequestrant.
- the present invention therefore relates to a liquid cleaner composition, in particular for washing solid surfaces, comprising (% by weight) from 4 to 5% of one or more tall oil fatty acids, from 4 to 6% of derivatives terpenics, from 3 to 5% of a C1-C4 alkanol, from 1.5 to 3.0% of a nonionic surfactant, from 0.3 to 0.6% of sodium or potassium hydroxide, if necessary additives in sufficient quantity, the remainder consisting of water, characterized in that it contains 1.5 to 3% of sodium carbonate and 1 to 3% of a selected organic sequestering agent among the sodium salts of nitrilotriacetic acid (NTA), ethylenediamine-tetraacetic acid (EDTA), diethylene-triamine-pentaacetic acid (DETA), diethylene-triamine-pentamethylene-phosphonic acid ( DTPMP) of ethylene diamine-tetramethylene phosphonic acid (EDITEMPA) and citric acid.
- NTA nitrilo
- Tall oil fatty acids are in particular fatty acids containing 2% resin acids.
- Terpene derivatives are defined as a mixture of carbides and terpene alcohols, in particular in the proportions 50/50 to 5/95, preferably 80 to 95%.
- Terpene alcohols contain in particular 70 to 100% of terpineols, preferably 80 to 95%.
- Alcohols are essentially terpineols, originating from the distillation of coniferous essences or obtained by hydration of these essences.
- the C1-C4 alkanol can in particular be ethanol.
- Additives are the products usually added in small amounts to detergent compositions of the type envisaged, and consist in particular of an antioxidant, a perfume and / or a perfume enhancer, a colorant, etc.
- nonionic surfactant is understood to mean conventional synthetic detergents having no active ion.
- the organic sequestering agent may preferably be the tetrasodium salt of ethylene diamine tetracetic acid (Na4EDTA), the trisodium salt of nitrilotriacetic acid (Na3NTA) or sodium citrate.
- the liquid compositions according to the invention When used with medium hard water, the liquid compositions according to the invention have good cleaning power and do not leave marks on hard surfaces, even during an accidental overdose. In addition, they are a non-aggressive product for the skin.
- liquid cleaning composition according to the invention can be offered in a concentrated version in order to reduce the weight of water transported. This consists of a reduction in the percentage of water contained in the formulation. This reduction has been studied so that the concentrate is in stable form and having an adequate viscosity. The necessary water is then added at the stage of producing the final ready-to-use composition.
- the process for manufacturing the cleaning composition according to the invention is as follows: - dissolution of sodium carbonate, sodium or potassium hydroxide and organic sequestering agent in water; - simultaneous addition of alcohol, terpene derivatives, tall oil fatty acid, and optionally perfume or perfume enhancer; so that the saponification of fatty acids is total, agitation should last 1 to 2 hours, - addition of the nonionic surfactant, the antioxidant and optionally the dye, - stirring until total homogenization.
- the final ready-to-use composition is obtained by adding 15 parts of water to 85 parts of this concentrate.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8816746A FR2640637A1 (fr) | 1988-12-19 | 1988-12-19 | Nettoyant liquide pour surfaces solides a base de derives terpeniques et procede pour sa fabrication |
FR8816746 | 1988-12-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0375474A1 true EP0375474A1 (de) | 1990-06-27 |
Family
ID=9373106
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89403090A Withdrawn EP0375474A1 (de) | 1988-12-19 | 1989-11-08 | Flüssiges Reinigungsmittel auf der Basis von Terpenderivaten für harte Oberflächen und Verfahren zu dessen Herstellung |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0375474A1 (de) |
FI (1) | FI895782A0 (de) |
FR (1) | FR2640637A1 (de) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0512328A1 (de) * | 1991-05-06 | 1992-11-11 | Miles Inc. | Nahrungsmittelunschädliches Reinigungsmittel |
WO2000068351A1 (en) * | 1999-05-07 | 2000-11-16 | Kay Chemical Company | Heavy duty degreaser cleaning compositions and methods of using the same |
WO2011036032A1 (de) * | 2009-09-22 | 2011-03-31 | Henkel Ag & Co. Kgaa | Parfümfreier reiniger |
WO2011117079A1 (de) * | 2010-03-24 | 2011-09-29 | Henkel Ag & Co. Kgaa | Wasch-, reinigungs- oder vorbehandlungsmittel mit erhöhter fettlösekraft |
ITCR20110012A1 (it) * | 2011-09-23 | 2013-03-24 | B A E Elettromeccanica Di Barbiani Angelo | Prodotto detergente |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0040882A1 (de) * | 1980-05-27 | 1981-12-02 | THE PROCTER & GAMBLE COMPANY | Flüssige Reinigungsmittelzusammensetzungen |
FR2564105A1 (fr) * | 1984-05-10 | 1985-11-15 | Saint Marc Lessives | Composition detergente liquide et procede pour sa preparation. |
US4576738A (en) * | 1984-12-21 | 1986-03-18 | Colgate-Palmolive Company | Hard surface cleaning compositions containing pianane |
EP0216416A2 (de) * | 1985-09-24 | 1987-04-01 | The Procter & Gamble Company | Flüssige, viskose, phasenstabile, ein Lösungsmittel enthaltendes Reinigungsmittel |
-
1988
- 1988-12-19 FR FR8816746A patent/FR2640637A1/fr active Granted
-
1989
- 1989-11-08 EP EP89403090A patent/EP0375474A1/de not_active Withdrawn
- 1989-12-04 FI FI895782A patent/FI895782A0/fi not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0040882A1 (de) * | 1980-05-27 | 1981-12-02 | THE PROCTER & GAMBLE COMPANY | Flüssige Reinigungsmittelzusammensetzungen |
FR2564105A1 (fr) * | 1984-05-10 | 1985-11-15 | Saint Marc Lessives | Composition detergente liquide et procede pour sa preparation. |
US4576738A (en) * | 1984-12-21 | 1986-03-18 | Colgate-Palmolive Company | Hard surface cleaning compositions containing pianane |
EP0216416A2 (de) * | 1985-09-24 | 1987-04-01 | The Procter & Gamble Company | Flüssige, viskose, phasenstabile, ein Lösungsmittel enthaltendes Reinigungsmittel |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0512328A1 (de) * | 1991-05-06 | 1992-11-11 | Miles Inc. | Nahrungsmittelunschädliches Reinigungsmittel |
WO2000068351A1 (en) * | 1999-05-07 | 2000-11-16 | Kay Chemical Company | Heavy duty degreaser cleaning compositions and methods of using the same |
WO2011036032A1 (de) * | 2009-09-22 | 2011-03-31 | Henkel Ag & Co. Kgaa | Parfümfreier reiniger |
WO2011117079A1 (de) * | 2010-03-24 | 2011-09-29 | Henkel Ag & Co. Kgaa | Wasch-, reinigungs- oder vorbehandlungsmittel mit erhöhter fettlösekraft |
ITCR20110012A1 (it) * | 2011-09-23 | 2013-03-24 | B A E Elettromeccanica Di Barbiani Angelo | Prodotto detergente |
Also Published As
Publication number | Publication date |
---|---|
FR2640637B1 (de) | 1994-04-22 |
FR2640637A1 (fr) | 1990-06-22 |
FI895782A0 (fi) | 1989-12-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0479908B1 (de) | Verbesserte wässrige reinigungs-/entfettungszusammensetzungen | |
EP0254653B1 (de) | Viskoses, verdünnbares Reinigungsmittel und Verfahren zu dessen Herstellung | |
BE1001742A5 (fr) | Compositions nettoyantes liquides en microemulsion. | |
JP5071687B2 (ja) | フォーマー容器用液体洗浄剤組成物 | |
EP1735417B1 (de) | Voc-freier bis -armer glas- und allzweckreiniger | |
JPH07505669A (ja) | 酵素を含む,チキソトロピー性の液体自動皿洗い用組成物 | |
FR2479256A1 (fr) | Composition de blanchiment aqueuse | |
JPH0559957B2 (de) | ||
EP0273472A1 (de) | Wässerige Detergenszusammensetzungen, die Diäthylenglykol-monohexyläther als Lösungsmittel enthalten | |
JPS58132097A (ja) | 液体洗剤組成物 | |
LU86968A1 (fr) | Compositions aqueuses thixotropes a base d'argile,procede pour stabiliser de telles compositions et leur procede d'utilisation pour nettoyer de la vaisselle | |
EP0375474A1 (de) | Flüssiges Reinigungsmittel auf der Basis von Terpenderivaten für harte Oberflächen und Verfahren zu dessen Herstellung | |
US5804541A (en) | Floor treating composition comprising a glycine N,N-diacetic acid | |
LU86731A1 (fr) | Composition nettoyante liquide aqueuse thixotrope analogue a un gel et procede l'utilisant pour laver de la vaisselle en lave-vaisselle automatique | |
FR2497226A1 (fr) | Composition de savon liquide | |
EP0455522B1 (de) | Phosphatfreies Waschmittel | |
FR2773812A1 (fr) | Composition pour decaper les peintures a base d'un ether aromatique | |
EP0598693A1 (de) | Stabile, nichtionische Tensideemulsionen welche Viskositätskontrollmittel enthalten | |
EP0165885B1 (de) | Flüssige Zusammensetzung zum Reinigen von harten Oberflächen | |
JPH02212599A (ja) | 液体洗浄漂白剤組成物 | |
FR2640647A1 (fr) | Procede d'elimination de depots d'etain, de plomb ou d'alliages etain/plomb de substrats de cuivre et compositions pour cet usage | |
JP4005353B2 (ja) | 液体洗浄剤組成物 | |
JP2951755B2 (ja) | 硬質表面用洗浄剤組成物 | |
JPH07504704A (ja) | 硬質表面の希釈クリーニングのための組成物および方法 | |
FR2564105A1 (fr) | Composition detergente liquide et procede pour sa preparation. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE ES GB IT LI LU NL SE |
|
17P | Request for examination filed |
Effective date: 19901210 |
|
17Q | First examination report despatched |
Effective date: 19931119 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
18W | Application withdrawn |
Withdrawal date: 19950522 |