EP0371635A3 - Hohle Acrylat-Polymer-Mikrokugeln - Google Patents
Hohle Acrylat-Polymer-Mikrokugeln Download PDFInfo
- Publication number
- EP0371635A3 EP0371635A3 EP19890311538 EP89311538A EP0371635A3 EP 0371635 A3 EP0371635 A3 EP 0371635A3 EP 19890311538 EP19890311538 EP 19890311538 EP 89311538 A EP89311538 A EP 89311538A EP 0371635 A3 EP0371635 A3 EP 0371635A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- microspheres
- hollow
- pressure
- sensitive adhesives
- diameter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/16—Powdering or granulating by coagulating dispersions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
- C08L2205/20—Hollow spheres
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/276,767 US5045569A (en) | 1988-11-30 | 1988-11-30 | Hollow acrylate polymer microspheres |
US276767 | 1988-11-30 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0371635A2 EP0371635A2 (de) | 1990-06-06 |
EP0371635A3 true EP0371635A3 (de) | 1991-05-29 |
EP0371635B1 EP0371635B1 (de) | 1996-07-17 |
Family
ID=23057992
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89311538A Expired - Lifetime EP0371635B1 (de) | 1988-11-30 | 1989-11-08 | Hohle Acrylat-Polymer-Mikrokugeln |
Country Status (14)
Country | Link |
---|---|
US (1) | US5045569A (de) |
EP (1) | EP0371635B1 (de) |
JP (1) | JP2940875B2 (de) |
KR (1) | KR0155353B1 (de) |
AR (1) | AR246283A1 (de) |
AU (1) | AU619350B2 (de) |
BR (1) | BR8906061A (de) |
CA (1) | CA1328331C (de) |
DE (1) | DE68926846T2 (de) |
DK (1) | DK599989A (de) |
ES (1) | ES2088899T3 (de) |
MX (1) | MX169793B (de) |
NO (1) | NO175154C (de) |
ZA (1) | ZA897828B (de) |
Families Citing this family (204)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE115149T1 (de) * | 1989-07-13 | 1994-12-15 | Vernis Valentine Comp D | Partikel von hydrophoben polymeren, die hohlräume enthalten. |
US5284881A (en) * | 1989-09-06 | 1994-02-08 | Nippon Paint Co., Ltd. | Composite hollow particles |
US4994322A (en) * | 1989-09-18 | 1991-02-19 | Minnesota Mining And Manufacturing | Pressure-sensitive adhesive comprising hollow tacky microspheres and macromonomer-containing binder copolymer |
DE4015753A1 (de) * | 1990-05-16 | 1991-11-21 | Basf Ag | Farbbildner enthaltende mikrokapseln |
US5196246A (en) * | 1991-05-17 | 1993-03-23 | Minnesota Mining And Manufacturing Company | Wall decorating system |
WO1992020534A1 (en) * | 1991-05-17 | 1992-11-26 | Minnesota Mining And Manufacturing Company | Flexible and conformable ionomeric resin based films |
US5198301A (en) * | 1991-05-17 | 1993-03-30 | Minnesota Mining And Manufacturing Company | Flexible and conformable ionomeric resin based films |
AU660702B2 (en) * | 1991-08-09 | 1995-07-06 | Minnesota Mining And Manufacturing Company | Repositionable coated substrate adhesive |
US5719247A (en) * | 1991-12-17 | 1998-02-17 | Minnesota Mining And Manufacturing Company | Tack-free elastomeric acrylate microspheres |
ES2092805T3 (es) * | 1991-12-17 | 1996-12-01 | Minnesota Mining & Mfg | Microesferas de acrilato, elastomericas y exentas de pegajosidad. |
TW221061B (de) * | 1991-12-31 | 1994-02-11 | Minnesota Mining & Mfg | |
US5334094A (en) * | 1992-09-21 | 1994-08-02 | Minnesota Mining And Manufacturing Company | Carbonless pad assembly |
TW338043B (en) * | 1992-12-11 | 1998-08-11 | Minnesota Mining & Mfg | Tacky microspheres having pendant hydrophilic polymeric or oligomeric moieties |
CA2156164A1 (en) * | 1993-02-16 | 1994-09-01 | Lori A. Bilski | System comprising release agent and high peel adhesion repositionable adhesive |
DE4305081C2 (de) * | 1993-02-19 | 1996-08-01 | Minnesota Mining & Mfg | Verfahren und Vorrichtung zum Auftragen von Haftkleber auf Bogen aus Papier oder dergleichen Material |
US5468523A (en) * | 1993-03-15 | 1995-11-21 | Minnesota Mining And Manufacturing Company | Method and apparatus for forming prefabricated self-forming self-adhering pull bow and pull bow formed thereby |
US5607763A (en) * | 1993-04-07 | 1997-03-04 | Minnesota Mining And Manufacturing Company | Decorative film with PSA for easy application |
US5571617A (en) * | 1993-04-23 | 1996-11-05 | Minnesota Mining And Manufacturing Company | Pressure sensitive adhesive comprising tacky surface active microspheres |
US5378405A (en) * | 1993-07-28 | 1995-01-03 | Minnesota Mining And Manufacturing Company | Conductive microparticles and pressure-sensitive adhesive tapes made therefrom |
BR9408052A (pt) * | 1993-11-16 | 1996-12-24 | Minnesota Mining & Mfg | Botão-de-laço auto-adesivo pré-formado para a aplicação em um objeto |
US5885722A (en) * | 1994-02-15 | 1999-03-23 | Minnesota Mining And Manufacturing | Method for applying coating materials to overlapped individuals sheets |
US5914186A (en) * | 1994-05-06 | 1999-06-22 | Minnesota Mining And Manufacturing Company | High temperature resistant antistatic pressure-sensitive adhesive tape |
WO1995030720A1 (en) * | 1994-05-06 | 1995-11-16 | Minnesota Mining And Manufacturing Company | High temperature resistant antistatic pressure-sensitive adhesive tape |
US5514122A (en) * | 1994-05-16 | 1996-05-07 | Minnesota Mining And Manufacturing Company | Feminine hygiene pad |
US6551654B1 (en) | 1994-08-17 | 2003-04-22 | 3M Innovative Properties Company | Apparatus and method for applying coating materials to individual sheet members |
EP1234682B1 (de) | 1994-08-17 | 2006-02-22 | Minnesota Mining And Manufacturing Company | Verfahren und Vorrichtung zum Aufbringen einer Beschichtung auf Bögen |
US5614310A (en) * | 1994-11-04 | 1997-03-25 | Minnesota Mining And Manufacturing Company | Low trauma wound dressing with improved moisture vapor permeability |
US5663241A (en) * | 1994-12-13 | 1997-09-02 | Minnesota Mining And Manufacturing Company | Removable pressure sensitive adhesive and article |
DE69626018D1 (de) | 1995-06-26 | 2003-03-06 | Minnesota Mining & Mfg | Lichtstreuender klebstoff |
WO1997003143A1 (en) | 1995-07-10 | 1997-01-30 | Minnesota Mining And Manufacturing Company | Screen printable adhesive compositions |
US20010028953A1 (en) * | 1998-11-16 | 2001-10-11 | 3M Innovative Properties Company | Adhesive compositions and methods of use |
US5942461A (en) * | 1995-11-06 | 1999-08-24 | Minnesota Mining And Manufacturing Company | Polymerizable compositions comprising alpha-olefin hydrocarbon monomers and methods of use therefor |
US5578650A (en) * | 1995-12-01 | 1996-11-26 | Minnesota Mining And Manufacturing Company | Methods of preparing hollow acrylate polymer microspheres |
US5696199A (en) * | 1995-12-07 | 1997-12-09 | Minnesota Mining And Manufacturing Company | Pressure-sensitive adhesive polyacrylate polymer and method of making |
AU2277897A (en) * | 1996-03-21 | 1997-10-10 | Minnesota Mining And Manufacturing Company | Pressure sensitive adhesive film comprising tacky microspheres |
US6004308A (en) * | 1996-04-19 | 1999-12-21 | Mcneil-Ppc, Inc. | Adhesive attachment system with a non-tacky surface for sanitary napkins |
US5948427A (en) * | 1996-04-25 | 1999-09-07 | Point Medical Corporation | Microparticulate surgical adhesive |
US5888650A (en) * | 1996-06-03 | 1999-03-30 | Minnesota Mining And Manufacturing Company | Temperature-responsive adhesive article |
US5824748A (en) * | 1996-06-03 | 1998-10-20 | Minnesota Mining And Manufacturing Company | Composite pressure sensitive adhesive microspheres |
US5889118A (en) * | 1996-06-03 | 1999-03-30 | Minnesota Mining And Manufacturing Company | Thermomorphic "smart" pressure sensitive adhesives |
US6368708B1 (en) | 1996-06-20 | 2002-04-09 | 3M Innovative Properties Company | Polyolefin microspheres |
WO1997048740A1 (en) * | 1996-06-20 | 1997-12-24 | Minnesota Mining And Manufacturing Company | Polyolefin microspheres |
US6383591B1 (en) * | 1996-06-21 | 2002-05-07 | 3M Innovative Properties Company | Method and apparatus for adhering linerless repositionable sheets onto articles |
US5874144A (en) * | 1996-10-23 | 1999-02-23 | Minnesota Mining And Manufacturing Company | Silicon-free copolymer and bleed-through resistant, ink receptive, and adhesive receptive coatings and coated substrates prepared therefrom |
US5716685A (en) * | 1996-10-23 | 1998-02-10 | Minnesota Mining And Manufacturing Company | Silicone-containing copolymer and bleed through resistant, ink receptive, and adhesive receptive coatings and coated substrates prepared therefrom |
US6080418A (en) * | 1997-04-07 | 2000-06-27 | 3M Innovative Properties Company | Suspensions of microcapsules containing biologically active ingredients and adhesive microspheres |
US6406244B1 (en) | 1998-07-09 | 2002-06-18 | Frederic P. A. Le Riche | Stack of sheets with repositionable adhesive alternating between opposite edges and containing one or more sheets different from other sheets |
US6444305B2 (en) | 1997-08-29 | 2002-09-03 | 3M Innovative Properties Company | Contact printable adhesive composition and methods of making thereof |
US6268032B1 (en) | 1997-10-03 | 2001-07-31 | 3M Innovative Properties Company | Repositionable note sheets and method of formation thereof |
US6063229A (en) * | 1998-02-03 | 2000-05-16 | 3M Innovative Properties Company | Method of article assembly formation |
US7354596B1 (en) * | 1998-05-01 | 2008-04-08 | 3M Innovative Properties Company | Anti-microbial agent delivery system |
US6471975B1 (en) | 1998-05-01 | 2002-10-29 | 3M Innovative Properties Company | Microspheres as a delivery vehicle for bio-active agents useful in agricultural applications |
US6312715B1 (en) | 1998-05-01 | 2001-11-06 | 3M Innovative Properties Company | Adhesive microsphere drug delivery composition |
EP0959176B1 (de) * | 1998-05-18 | 2012-09-05 | Rohm And Haas Company | Pigmentäre organische Hohlkugelteilchen für Papier oder Papierbeschichtungen |
US20010044477A1 (en) * | 1998-12-10 | 2001-11-22 | Soane David S. | Expandable polymeric microspheres, their method of production, and uses and products thereof |
US6296932B1 (en) * | 1998-12-14 | 2001-10-02 | 3M Innovative Properties Company | Microsphere adhesive coated article for use with coated papers |
US6235344B1 (en) * | 1999-02-05 | 2001-05-22 | Rohm And Haas Company | Method of improving an adhesive article |
US6548164B1 (en) | 1999-06-30 | 2003-04-15 | 3M Innovative Properties Company | Removable sheeting |
US6793937B2 (en) | 1999-10-22 | 2004-09-21 | 3M Innovative Properties Company | Method of delivering active material within hydrogel microbeads |
US6365189B1 (en) | 1999-10-22 | 2002-04-02 | 3M Innovative Properties Company | Method of delivering and releasing a pheromone |
US6375968B1 (en) | 1999-10-22 | 2002-04-23 | 3M Innovative Properties Company | Encapsulated active material immobilized in hydrogel microbeads |
JP5217071B2 (ja) * | 2000-05-15 | 2013-06-19 | 東亞合成株式会社 | 粘着剤組成物 |
US6360466B1 (en) | 2000-05-19 | 2002-03-26 | Iomega Corporation | Data storage cartridge with multiple labels |
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US6883908B2 (en) | 2001-01-08 | 2005-04-26 | 3M Innovative Properties Company | Methods and compositions for ink jet printing of pressure sensitive adhesive patterns or films on a wide range of substrates |
US6660352B2 (en) | 2001-01-09 | 2003-12-09 | 3M Innovative Properties Company | Adhesive electrostatic sheets |
US20030049415A1 (en) | 2001-03-12 | 2003-03-13 | Pedginski James J. | Film constructions and methods |
US6540991B2 (en) | 2001-04-06 | 2003-04-01 | 3M Innovative Properties Company | Stabilized active materials |
US6562361B2 (en) | 2001-05-02 | 2003-05-13 | 3M Innovative Properties Company | Pheromone immobilized in stable hydrogel microbeads |
US7709070B2 (en) | 2001-12-20 | 2010-05-04 | The Procter & Gamble Company | Articles and methods for applying color on surfaces |
US7316832B2 (en) | 2001-12-20 | 2008-01-08 | The Procter & Gamble Company | Articles and methods for applying color on surfaces |
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FR2835811B1 (fr) * | 2002-02-12 | 2004-05-21 | Pechiney Capsules | Insert fonctionnel pour goulot de recipient, typiquement une bouteille, et capsule de bouchage comprenant ledit insert |
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JP2006517874A (ja) | 2003-02-14 | 2006-08-03 | アベリー・デニソン・コーポレイション | 感圧接着剤を有する自己巻きされた装飾用多層ドライペイント積層体のための示差剥離系 |
US20040161564A1 (en) | 2003-02-14 | 2004-08-19 | Truog Keith L. | Dry paint transfer laminate |
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US20040229193A1 (en) * | 2003-05-14 | 2004-11-18 | Larry Wittmeyer | Coloring paper having adhesive |
US20050196607A1 (en) | 2003-06-09 | 2005-09-08 | Shih Frank Y. | Multi-layer dry paint decorative laminate having discoloration prevention barrier |
US7718241B2 (en) * | 2003-11-04 | 2010-05-18 | Larry E. Wittmeyer, Jr. | Multi-functional stack of repositionable sheets |
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US8517329B2 (en) * | 2004-07-26 | 2013-08-27 | 3M Innovative Properties Company | Easel stand mountable display board |
US20060024461A1 (en) * | 2004-07-27 | 2006-02-02 | 3M Innovative Properties Company | Dry erase substrate |
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US20060147636A1 (en) * | 2004-12-30 | 2006-07-06 | Cooprider Terrence E | Method and apparatus of forming a coating fluid pattern |
US7625605B2 (en) * | 2004-12-30 | 2009-12-01 | 3M Innovative Properties Company | Method for coating a surface with a pattern of coating fluid |
AR053819A1 (es) * | 2005-03-01 | 2007-05-23 | Basf Ag | Productos de microcapsiula de liberacion rapida |
US7749247B2 (en) * | 2005-08-04 | 2010-07-06 | St. Jude Medical Puerto Rico, Llc | Tissue puncture closure device with coiled automatic tamping system |
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US20080003383A1 (en) * | 2005-09-15 | 2008-01-03 | 3M Innovative Properties Company | Repositionable photo paper |
US20070089832A1 (en) * | 2005-09-15 | 2007-04-26 | Kitchin Jonathan P | Repositionable matte photo media |
US20070059631A1 (en) | 2005-09-15 | 2007-03-15 | Kitchin Jonathan P | Repositionable glossy photo media |
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US20070059472A1 (en) * | 2005-09-15 | 2007-03-15 | 3M Innovative Properties Company | Repositionable photo media and photographs |
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US7713375B2 (en) * | 2006-08-31 | 2010-05-11 | Avery Dennison Corporation | Dry erase writing board and method |
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US20080087379A1 (en) * | 2006-10-11 | 2008-04-17 | 3M Innovative Properties Company | Repositionable adhesive-backed photographs and photo media and methods of making |
US20080087376A1 (en) * | 2006-10-11 | 2008-04-17 | 3M Innovative Properties Company | Method of making a photographic print with an adhesive composite |
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- 1989-11-08 ES ES89311538T patent/ES2088899T3/es not_active Expired - Lifetime
- 1989-11-08 DE DE68926846T patent/DE68926846T2/de not_active Expired - Fee Related
- 1989-11-23 AR AR89315522A patent/AR246283A1/es active
- 1989-11-28 DK DK599989A patent/DK599989A/da not_active Application Discontinuation
- 1989-11-29 KR KR1019890017382A patent/KR0155353B1/ko not_active IP Right Cessation
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Also Published As
Publication number | Publication date |
---|---|
JP2940875B2 (ja) | 1999-08-25 |
KR0155353B1 (ko) | 1999-02-18 |
AU4295189A (en) | 1990-06-07 |
NO175154B (no) | 1994-05-30 |
DK599989A (da) | 1990-05-31 |
DE68926846T2 (de) | 1997-02-27 |
US5045569A (en) | 1991-09-03 |
AU619350B2 (en) | 1992-01-23 |
BR8906061A (pt) | 1990-06-26 |
NO894064D0 (no) | 1989-10-11 |
NO894064L (no) | 1990-05-31 |
EP0371635A2 (de) | 1990-06-06 |
DK599989D0 (da) | 1989-11-28 |
JPH02194079A (ja) | 1990-07-31 |
NO175154C (no) | 1994-09-07 |
KR900007990A (ko) | 1990-06-02 |
ES2088899T3 (es) | 1996-10-01 |
DE68926846D1 (de) | 1996-08-22 |
EP0371635B1 (de) | 1996-07-17 |
CA1328331C (en) | 1994-04-05 |
AR246283A1 (es) | 1994-07-29 |
MX169793B (es) | 1993-07-26 |
ZA897828B (en) | 1990-08-29 |
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