EP0371635A3 - Hohle Acrylat-Polymer-Mikrokugeln - Google Patents

Hohle Acrylat-Polymer-Mikrokugeln Download PDF

Info

Publication number
EP0371635A3
EP0371635A3 EP19890311538 EP89311538A EP0371635A3 EP 0371635 A3 EP0371635 A3 EP 0371635A3 EP 19890311538 EP19890311538 EP 19890311538 EP 89311538 A EP89311538 A EP 89311538A EP 0371635 A3 EP0371635 A3 EP 0371635A3
Authority
EP
European Patent Office
Prior art keywords
microspheres
hollow
pressure
sensitive adhesives
diameter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19890311538
Other languages
English (en)
French (fr)
Other versions
EP0371635A2 (de
EP0371635B1 (de
Inventor
Joaquin C/O Minnesota Mining And Delgado
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Publication of EP0371635A2 publication Critical patent/EP0371635A2/de
Publication of EP0371635A3 publication Critical patent/EP0371635A3/de
Application granted granted Critical
Publication of EP0371635B1 publication Critical patent/EP0371635B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/12Powdering or granulating
    • C08J3/16Powdering or granulating by coagulating dispersions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres
    • C08L2205/20Hollow spheres
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
EP89311538A 1988-11-30 1989-11-08 Hohle Acrylat-Polymer-Mikrokugeln Expired - Lifetime EP0371635B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US276767 1988-11-30
US07/276,767 US5045569A (en) 1988-11-30 1988-11-30 Hollow acrylate polymer microspheres

Publications (3)

Publication Number Publication Date
EP0371635A2 EP0371635A2 (de) 1990-06-06
EP0371635A3 true EP0371635A3 (de) 1991-05-29
EP0371635B1 EP0371635B1 (de) 1996-07-17

Family

ID=23057992

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89311538A Expired - Lifetime EP0371635B1 (de) 1988-11-30 1989-11-08 Hohle Acrylat-Polymer-Mikrokugeln

Country Status (14)

Country Link
US (1) US5045569A (de)
EP (1) EP0371635B1 (de)
JP (1) JP2940875B2 (de)
KR (1) KR0155353B1 (de)
AR (1) AR246283A1 (de)
AU (1) AU619350B2 (de)
BR (1) BR8906061A (de)
CA (1) CA1328331C (de)
DE (1) DE68926846T2 (de)
DK (1) DK599989A (de)
ES (1) ES2088899T3 (de)
MX (1) MX169793B (de)
NO (1) NO175154C (de)
ZA (1) ZA897828B (de)

Families Citing this family (204)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE115149T1 (de) * 1989-07-13 1994-12-15 Vernis Valentine Comp D Partikel von hydrophoben polymeren, die hohlräume enthalten.
US5284881A (en) * 1989-09-06 1994-02-08 Nippon Paint Co., Ltd. Composite hollow particles
US4994322A (en) * 1989-09-18 1991-02-19 Minnesota Mining And Manufacturing Pressure-sensitive adhesive comprising hollow tacky microspheres and macromonomer-containing binder copolymer
DE4015753A1 (de) * 1990-05-16 1991-11-21 Basf Ag Farbbildner enthaltende mikrokapseln
US5196246A (en) * 1991-05-17 1993-03-23 Minnesota Mining And Manufacturing Company Wall decorating system
US5198301A (en) * 1991-05-17 1993-03-30 Minnesota Mining And Manufacturing Company Flexible and conformable ionomeric resin based films
ES2090648T3 (es) * 1991-05-17 1996-10-16 Minnesota Mining & Mfg Peliculas basadas en resinas ionomericas, flexibles y amoldables.
EP1475423B9 (de) * 1991-08-09 2006-09-06 3M Company Repositionierbarer Klebestift
KR100210974B1 (ko) * 1991-12-17 1999-07-15 스프레이그 로버트 월터 무점착성 엘라스토머성 아크릴레이트 미소구
US5719247A (en) * 1991-12-17 1998-02-17 Minnesota Mining And Manufacturing Company Tack-free elastomeric acrylate microspheres
TW221061B (de) * 1991-12-31 1994-02-11 Minnesota Mining & Mfg
US5334094A (en) * 1992-09-21 1994-08-02 Minnesota Mining And Manufacturing Company Carbonless pad assembly
TW338043B (en) * 1992-12-11 1998-08-11 Minnesota Mining & Mfg Tacky microspheres having pendant hydrophilic polymeric or oligomeric moieties
JP3928026B2 (ja) * 1993-02-16 2007-06-13 スリーエム カンパニー 剥離剤及び再剥離性接着剤を含む物品
DE4305081C2 (de) 1993-02-19 1996-08-01 Minnesota Mining & Mfg Verfahren und Vorrichtung zum Auftragen von Haftkleber auf Bogen aus Papier oder dergleichen Material
US5468523A (en) * 1993-03-15 1995-11-21 Minnesota Mining And Manufacturing Company Method and apparatus for forming prefabricated self-forming self-adhering pull bow and pull bow formed thereby
US5607763A (en) * 1993-04-07 1997-03-04 Minnesota Mining And Manufacturing Company Decorative film with PSA for easy application
US5571617A (en) * 1993-04-23 1996-11-05 Minnesota Mining And Manufacturing Company Pressure sensitive adhesive comprising tacky surface active microspheres
US5378405A (en) * 1993-07-28 1995-01-03 Minnesota Mining And Manufacturing Company Conductive microparticles and pressure-sensitive adhesive tapes made therefrom
KR960705974A (ko) * 1993-11-16 1996-11-08 테릴 켄트 퀄리 예형된 자가-부착성 나비매듭(preformed self-adhering bow)
US5885722A (en) * 1994-02-15 1999-03-23 Minnesota Mining And Manufacturing Method for applying coating materials to overlapped individuals sheets
US5914186A (en) * 1994-05-06 1999-06-22 Minnesota Mining And Manufacturing Company High temperature resistant antistatic pressure-sensitive adhesive tape
EP0758366B1 (de) * 1994-05-06 1999-01-27 Minnesota Mining And Manufacturing Company Hochtemperaturbeständiges, antistatisches, druckempfindliches klebebeand
US5514122A (en) * 1994-05-16 1996-05-07 Minnesota Mining And Manufacturing Company Feminine hygiene pad
WO1996005065A1 (en) 1994-08-17 1996-02-22 Minnesota Mining And Manufacturing Company Method and apparatus for applying a coating material to sheets
US5863330A (en) * 1994-08-17 1999-01-26 Minnesota Mining And Manufacturing Company Apparatus and method for applying coating materials to individual sheet meters
US5614310A (en) * 1994-11-04 1997-03-25 Minnesota Mining And Manufacturing Company Low trauma wound dressing with improved moisture vapor permeability
US5663241A (en) * 1994-12-13 1997-09-02 Minnesota Mining And Manufacturing Company Removable pressure sensitive adhesive and article
KR100454834B1 (ko) 1995-06-26 2005-06-17 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 광확산성접착제
WO1997003143A1 (en) 1995-07-10 1997-01-30 Minnesota Mining And Manufacturing Company Screen printable adhesive compositions
US20010028953A1 (en) * 1998-11-16 2001-10-11 3M Innovative Properties Company Adhesive compositions and methods of use
US5942461A (en) * 1995-11-06 1999-08-24 Minnesota Mining And Manufacturing Company Polymerizable compositions comprising alpha-olefin hydrocarbon monomers and methods of use therefor
US5578650A (en) * 1995-12-01 1996-11-26 Minnesota Mining And Manufacturing Company Methods of preparing hollow acrylate polymer microspheres
US5696199A (en) * 1995-12-07 1997-12-09 Minnesota Mining And Manufacturing Company Pressure-sensitive adhesive polyacrylate polymer and method of making
JP3908787B2 (ja) * 1996-03-21 2007-04-25 スリーエム カンパニー 感圧接着性微小球を含有する感圧接着フィルム
US6004308A (en) * 1996-04-19 1999-12-21 Mcneil-Ppc, Inc. Adhesive attachment system with a non-tacky surface for sanitary napkins
US5948427A (en) * 1996-04-25 1999-09-07 Point Medical Corporation Microparticulate surgical adhesive
US5888650A (en) * 1996-06-03 1999-03-30 Minnesota Mining And Manufacturing Company Temperature-responsive adhesive article
US5889118A (en) * 1996-06-03 1999-03-30 Minnesota Mining And Manufacturing Company Thermomorphic "smart" pressure sensitive adhesives
US5824748A (en) 1996-06-03 1998-10-20 Minnesota Mining And Manufacturing Company Composite pressure sensitive adhesive microspheres
WO1997048740A1 (en) * 1996-06-20 1997-12-24 Minnesota Mining And Manufacturing Company Polyolefin microspheres
US6368708B1 (en) 1996-06-20 2002-04-09 3M Innovative Properties Company Polyolefin microspheres
US6383591B1 (en) 1996-06-21 2002-05-07 3M Innovative Properties Company Method and apparatus for adhering linerless repositionable sheets onto articles
US5716685A (en) * 1996-10-23 1998-02-10 Minnesota Mining And Manufacturing Company Silicone-containing copolymer and bleed through resistant, ink receptive, and adhesive receptive coatings and coated substrates prepared therefrom
US5874144A (en) * 1996-10-23 1999-02-23 Minnesota Mining And Manufacturing Company Silicon-free copolymer and bleed-through resistant, ink receptive, and adhesive receptive coatings and coated substrates prepared therefrom
US6080418A (en) * 1997-04-07 2000-06-27 3M Innovative Properties Company Suspensions of microcapsules containing biologically active ingredients and adhesive microspheres
US6406244B1 (en) 1998-07-09 2002-06-18 Frederic P. A. Le Riche Stack of sheets with repositionable adhesive alternating between opposite edges and containing one or more sheets different from other sheets
US6444305B2 (en) 1997-08-29 2002-09-03 3M Innovative Properties Company Contact printable adhesive composition and methods of making thereof
US6268032B1 (en) 1997-10-03 2001-07-31 3M Innovative Properties Company Repositionable note sheets and method of formation thereof
US6063229A (en) 1998-02-03 2000-05-16 3M Innovative Properties Company Method of article assembly formation
US6471975B1 (en) * 1998-05-01 2002-10-29 3M Innovative Properties Company Microspheres as a delivery vehicle for bio-active agents useful in agricultural applications
US7354596B1 (en) 1998-05-01 2008-04-08 3M Innovative Properties Company Anti-microbial agent delivery system
US6312715B1 (en) 1998-05-01 2001-11-06 3M Innovative Properties Company Adhesive microsphere drug delivery composition
EP0959176B1 (de) * 1998-05-18 2012-09-05 Rohm And Haas Company Pigmentäre organische Hohlkugelteilchen für Papier oder Papierbeschichtungen
US20010044477A1 (en) * 1998-12-10 2001-11-22 Soane David S. Expandable polymeric microspheres, their method of production, and uses and products thereof
US6296932B1 (en) * 1998-12-14 2001-10-02 3M Innovative Properties Company Microsphere adhesive coated article for use with coated papers
US6235344B1 (en) * 1999-02-05 2001-05-22 Rohm And Haas Company Method of improving an adhesive article
US6548164B1 (en) 1999-06-30 2003-04-15 3M Innovative Properties Company Removable sheeting
US6375968B1 (en) 1999-10-22 2002-04-23 3M Innovative Properties Company Encapsulated active material immobilized in hydrogel microbeads
US6793937B2 (en) 1999-10-22 2004-09-21 3M Innovative Properties Company Method of delivering active material within hydrogel microbeads
US6365189B1 (en) 1999-10-22 2002-04-02 3M Innovative Properties Company Method of delivering and releasing a pheromone
JP5217071B2 (ja) * 2000-05-15 2013-06-19 東亞合成株式会社 粘着剤組成物
US6360466B1 (en) 2000-05-19 2002-03-26 Iomega Corporation Data storage cartridge with multiple labels
CN1216923C (zh) * 2000-06-23 2005-08-31 索罗蒂亚公司 形成实心压敏粘合剂聚合物微球的方法
KR100411188B1 (ko) * 2000-10-20 2003-12-18 한솔제지주식회사 포어 마이크로스피어 점착제용 씨드고분자 입자의 제조방법
KR100369845B1 (ko) * 2000-10-20 2003-01-30 한솔제지주식회사 포어 마이크로스피어 구조의 리포지션어블 점착제 및 그제조방법
US6883908B2 (en) 2001-01-08 2005-04-26 3M Innovative Properties Company Methods and compositions for ink jet printing of pressure sensitive adhesive patterns or films on a wide range of substrates
US6660352B2 (en) 2001-01-09 2003-12-09 3M Innovative Properties Company Adhesive electrostatic sheets
US20030049415A1 (en) 2001-03-12 2003-03-13 Pedginski James J. Film constructions and methods
US6540991B2 (en) 2001-04-06 2003-04-01 3M Innovative Properties Company Stabilized active materials
US6562361B2 (en) 2001-05-02 2003-05-13 3M Innovative Properties Company Pheromone immobilized in stable hydrogel microbeads
US7316832B2 (en) 2001-12-20 2008-01-08 The Procter & Gamble Company Articles and methods for applying color on surfaces
US7709070B2 (en) 2001-12-20 2010-05-04 The Procter & Gamble Company Articles and methods for applying color on surfaces
KR100484125B1 (ko) * 2002-01-11 2005-04-20 티오켐 주식회사 방사선 또는 일렉트론-빔을 이용한 단분산상 고분자미립자의 제조방법
FR2835811B1 (fr) * 2002-02-12 2004-05-21 Pechiney Capsules Insert fonctionnel pour goulot de recipient, typiquement une bouteille, et capsule de bouchage comprenant ledit insert
US6715633B2 (en) 2002-03-06 2004-04-06 Kimberly-Clark Worldwide, Inc. Interfolded sheet dispenser having a starter sheet pull-out system
WO2004074004A1 (en) 2003-02-14 2004-09-02 Avery Dennison Corporation Differential release system for a self-wound multilayer dry paint decorative laminate having a pressure sensitive adhesive
US20040161564A1 (en) 2003-02-14 2004-08-19 Truog Keith L. Dry paint transfer laminate
US7097727B2 (en) * 2003-05-06 2006-08-29 3M Innovative Properties Company Inline accumulating die padder
US20040229193A1 (en) * 2003-05-14 2004-11-18 Larry Wittmeyer Coloring paper having adhesive
US20050196607A1 (en) 2003-06-09 2005-09-08 Shih Frank Y. Multi-layer dry paint decorative laminate having discoloration prevention barrier
US7718241B2 (en) * 2003-11-04 2010-05-18 Larry E. Wittmeyer, Jr. Multi-functional stack of repositionable sheets
US20050233101A1 (en) * 2003-11-04 2005-10-20 Wittmeyer Larry E Jr Multi-functional stack of repositionable sheets
US6908240B1 (en) * 2003-12-16 2005-06-21 International Imaging Materials, Inc Thermal printing and cleaning assembly
US7356884B2 (en) 2003-12-18 2008-04-15 3M Innovative Properties Company Fastener for a display page
JP4681248B2 (ja) * 2004-04-09 2011-05-11 パナソニック株式会社 スクリーン印刷用インク
US20050271849A1 (en) 2004-06-02 2005-12-08 3M Innovative Properties Company Shingled assembly of repositionable devices
US8517329B2 (en) * 2004-07-26 2013-08-27 3M Innovative Properties Company Easel stand mountable display board
US20060024463A1 (en) * 2004-07-27 2006-02-02 3M Innovative Properties Company Dry erase substrate
US20060024461A1 (en) * 2004-07-27 2006-02-02 3M Innovative Properties Company Dry erase substrate
US20060131197A1 (en) * 2004-12-16 2006-06-22 Kimberly-Clark Worldwide, Inc. Disposable package with a repositioning attachment feature
US20060147636A1 (en) * 2004-12-30 2006-07-06 Cooprider Terrence E Method and apparatus of forming a coating fluid pattern
US7625605B2 (en) * 2004-12-30 2009-12-01 3M Innovative Properties Company Method for coating a surface with a pattern of coating fluid
MY146405A (en) * 2005-03-01 2012-08-15 Basf Ag Fast-release microcapsule products
US7749247B2 (en) * 2005-08-04 2010-07-06 St. Jude Medical Puerto Rico, Llc Tissue puncture closure device with coiled automatic tamping system
US8186541B2 (en) * 2005-08-31 2012-05-29 Kimberly-Clark Worldwide, Inc. Tissue sheet dispenser and process for making same
US20070059472A1 (en) * 2005-09-15 2007-03-15 3M Innovative Properties Company Repositionable photo media and photographs
US20070059613A1 (en) * 2005-09-15 2007-03-15 Kitchin Jonathan P Repositionable photo card
US20070059652A1 (en) * 2005-09-15 2007-03-15 Kitchin Jonathan P Repositionable glossy photo media
US20080003383A1 (en) * 2005-09-15 2008-01-03 3M Innovative Properties Company Repositionable photo paper
US20070089832A1 (en) * 2005-09-15 2007-04-26 Kitchin Jonathan P Repositionable matte photo media
US20070059631A1 (en) * 2005-09-15 2007-03-15 Kitchin Jonathan P Repositionable glossy photo media
US7467873B2 (en) * 2005-10-14 2008-12-23 3M Innovative Properties Company Privacy film
US7326504B2 (en) * 2005-10-14 2008-02-05 3M Innovative Properties Company Imaged anti-copy film
GB2432338A (en) * 2005-11-21 2007-05-23 3M Innovative Properties Co Personalised adhesive memoboard
US7661554B2 (en) 2005-12-13 2010-02-16 Kimberly-Clark Worldwide, Inc. Tissue sheet dispenser and process for making same
US20070140597A1 (en) * 2005-12-19 2007-06-21 Eser Ozdeger Donovan Method of making articles for storing and organizing materials
US20070138044A1 (en) * 2005-12-19 2007-06-21 Trotter Byron E Article for storing and organizing materials
US20070147712A1 (en) * 2005-12-19 2007-06-28 3M Innovative Properties Company Method of making articles for storing and organizing materials
US20070148459A1 (en) * 2005-12-28 2007-06-28 Kimberly-Clark Worldwide, Inc. Microencapsulated delivery vehicles
US7914891B2 (en) 2005-12-28 2011-03-29 Kimberly-Clark Worldwide, Inc. Wipes including microencapsulated delivery vehicles and phase change materials
US7442439B2 (en) 2005-12-28 2008-10-28 Kimberly-Clark Worldwide, Inc. Microencapsulated heat delivery vehicles
US20070155859A1 (en) * 2006-01-04 2007-07-05 Zhengzhe Song Reactive polyurethane hot melt adhesive
US7645827B2 (en) * 2006-03-08 2010-01-12 3M Innovative Properties Company High shear pressure-sensitive adhesive
US7531595B2 (en) * 2006-03-08 2009-05-12 3M Innovative Properties Company Pressure-sensitive adhesive containing silica nanoparticles
WO2007112294A1 (en) * 2006-03-24 2007-10-04 Henkel Corporation Sprayable water-based adhesive
TWI422597B (zh) * 2006-03-29 2014-01-11 Kawamura Inst Chem Res 中空聚合物粒子、著色中空聚合物粒子及彼等之製法
US20080092457A1 (en) * 2006-03-31 2008-04-24 Marilyn Malone Articles for Selecting Colors for Surfaces
US7497351B2 (en) 2006-05-30 2009-03-03 Kimberly-Clark Worldwide, Inc. Wet wipe dispensing system
US7654412B2 (en) 2006-05-30 2010-02-02 Kimberly-Clark Worldwide, Inc. Wet wipe dispensing system for dispensing warm wet wipes
US7713375B2 (en) * 2006-08-31 2010-05-11 Avery Dennison Corporation Dry erase writing board and method
US20080063842A1 (en) * 2006-09-12 2008-03-13 3M Innovative Properties Company Repositionable privacy note
US7547155B2 (en) * 2006-09-15 2009-06-16 3M Innovative Properties Company Marking device
US20080087376A1 (en) * 2006-10-11 2008-04-17 3M Innovative Properties Company Method of making a photographic print with an adhesive composite
US20080087379A1 (en) * 2006-10-11 2008-04-17 3M Innovative Properties Company Repositionable adhesive-backed photographs and photo media and methods of making
US20080096150A1 (en) 2006-10-23 2008-04-24 3M Innovative Properties Company Dental articles, methods, and kits including a compressible material
US9539065B2 (en) 2006-10-23 2017-01-10 3M Innovative Properties Company Assemblies, methods, and kits including a compressible material
CN101529957B (zh) * 2006-11-01 2012-07-04 富士通株式会社 无线通信装置和无线通信方法
US7645355B2 (en) * 2006-11-17 2010-01-12 3M Innovative Properties Company Method of making a microsphere transfer adhesive
US7674345B2 (en) * 2006-12-08 2010-03-09 3M Innovative Properties Company Adhesive articles with discontinuities and methods of making the same
US8192841B2 (en) 2006-12-14 2012-06-05 Kimberly-Clark Worldwide, Inc. Microencapsulated delivery vehicle having an aqueous core
US7517582B2 (en) * 2006-12-14 2009-04-14 Kimberly-Clark Worldwide, Inc. Supersaturated solutions using crystallization enthalpy to impart temperature change to wet wipes
EP2114349B1 (de) 2006-12-28 2016-09-14 3M Innovative Properties Company Dentalfüllstoff und verfahren
US20080156444A1 (en) * 2006-12-28 2008-07-03 3M Innovative Properties Company Tape and Masking Material Composite
US7393901B1 (en) 2007-02-16 2008-07-01 3M Innovative Properties Company Acrylate adhesives containing silica nanoparticles crosslinked with polyfunctional aziridines
US20080200587A1 (en) * 2007-02-16 2008-08-21 3M Innovative Properties Company Pressure-sensitive adhesive containing acicular silica particles crosslinked with polyfunctional aziridines
CN101755024B (zh) * 2007-06-13 2013-12-18 3M创新有限公司 可再贴安装材料、污染控制装置及其制造方法
US7652095B2 (en) * 2007-06-20 2010-01-26 3M Innovative Properties Company Pressure-sensitive adhesive containing aziridinyl silanes
US20090050646A1 (en) * 2007-08-22 2009-02-26 3M Innovative Properties Company Compact sheet dispenser
US20090052973A1 (en) * 2007-08-22 2009-02-26 3M Innovative Properties Company Writing instrument with compact sheet dispenser
US20090075007A1 (en) * 2007-09-13 2009-03-19 3M Innovative Properties Company Adhesive composite
US20090075070A1 (en) * 2007-09-13 2009-03-19 3M Innovative Properties Company Photographic print with an adhesive composite
US8378046B2 (en) * 2007-10-19 2013-02-19 3M Innovative Properties Company High refractive index pressure-sensitive adhesives
US20090105437A1 (en) * 2007-10-19 2009-04-23 3M Innovative Properties Company High refractive index pressure-sensitive adhesives
KR101545365B1 (ko) * 2007-10-30 2015-08-18 쓰리엠 이노베이티브 프로퍼티즈 컴파니 고 굴절률 접착제
US8318303B2 (en) 2007-12-18 2012-11-27 3M Innovative Properties Company Microsphere pressure sensitive adhesive composition
US7652103B2 (en) * 2008-02-14 2010-01-26 3M Innovative Properties Company Acrylic pressure-sensitive adhesives with aziridine crosslinking agents
US7714076B2 (en) * 2008-03-27 2010-05-11 3M Innovative Properties Company Acrylic pressure-sensitive adhesives with aziridine crosslinking agents
EP2291478B1 (de) * 2008-06-09 2012-08-01 3M Innovative Properties Company Acrylhaftklebstoffe mit aziridin-vernetzungsmitteln
US7924142B2 (en) 2008-06-30 2011-04-12 Kimberly-Clark Worldwide, Inc. Patterned self-warming wipe substrates
EP2379665A4 (de) * 2008-12-24 2012-07-25 3M Innovative Properties Co Mikrosphärische haftkleberzusammensetzung
KR101708074B1 (ko) * 2009-03-09 2017-02-17 쓰리엠 이노베이티브 프로퍼티즈 컴파니 아크릴계 접착제용 아지리딘 가교결합제
US8067504B2 (en) 2009-08-25 2011-11-29 3M Innovative Properties Company Acrylic pressure-sensitive adhesives with acylaziridine crosslinking agents
JP5439102B2 (ja) * 2009-09-25 2014-03-12 積水化成品工業株式会社 中空粒子、その製造法及びその用途
AU2010321710B2 (en) * 2009-11-23 2013-03-07 Wm. Wrigley Jr. Company Gum bases, chewing gums based thereupon, and methods for making the same
US8148471B2 (en) 2009-11-23 2012-04-03 3M Innovative Properties Company Acrylic pressure-sensitive adhesives with aziridinyl-epoxy crosslinking system
US20110123672A1 (en) * 2009-11-23 2011-05-26 Xiaohu Xia Gum bases, chewing gums based thereupon, and methods for making the same
US20170238576A9 (en) * 2009-11-23 2017-08-24 Xiaohu Xia Gum bases containing non-uniform crosslinked polymer microparticles
CN102108133B (zh) * 2009-12-23 2014-12-10 3M创新有限公司 (甲基)丙烯酰基-氮丙啶交联剂和粘合剂聚合物
CN102127183B (zh) * 2010-01-20 2014-08-20 3M创新有限公司 可交联的丙烯酸酯粘合剂聚合物组合物
USD679753S1 (en) 2010-02-08 2013-04-09 Avery Dennison Corporation Note sheets and related pads of note sheets
US8778474B2 (en) 2010-02-08 2014-07-15 Ccl Label, Inc. Repositionable medium and stack thereof
CA137793S (en) 2010-02-08 2011-06-13 Avery Dennison Corp Note sheet pad
US20110195217A1 (en) * 2010-02-08 2011-08-11 Sato Jay K Note sheet and pads thereof and related method
US8137807B2 (en) * 2010-03-26 2012-03-20 3M Innovative Properties Company Pressure-sensitive adhesives derived from 2-alkyl alkanols
US8222340B2 (en) 2010-04-05 2012-07-17 3M Innovative Properties Company Crosslinkable syrup copolymers with aminoalkyl (meth)acryloyl solvent monomers
CN102959026B (zh) 2010-06-30 2014-12-24 3M创新有限公司 (甲基)丙烯酰压敏泡沫粘合剂
EP2655451B1 (de) 2010-12-21 2015-03-11 3M Innovative Properties Company Polymere aus sekundären alkyl(meth)acrylaten
US9260638B2 (en) 2010-12-29 2016-02-16 3M Innovative Properties Company Pressure-sensitive adhesives with triazine-epoxy crosslinking system
CN103281986B (zh) 2010-12-30 2016-08-17 3M创新有限公司 包括可压缩材料的可粘合牙科用组件和方法
EP2694952B1 (de) 2011-03-28 2017-11-01 3M Innovative Properties Company Sensor mit einem maskierungsschichtklebstoff
DE102011007124B8 (de) 2011-04-11 2019-05-16 Gerd Jürgen Dürhager Innenauskleidung für Boxen
US8785517B2 (en) 2011-05-25 2014-07-22 3M Innovative Properties Company Pressure-sensitive adhesives with onium-epdxy crosslinking system
EP2723812B1 (de) 2011-06-23 2016-04-13 3M Innovative Properties Company Druckempfindliche kleber mit einem onium-epoxidharzvernetzersystem
EP2573150A1 (de) 2011-09-26 2013-03-27 3M Innovative Properties Company Mehrschichtige, druckempfindliche Haftfolien mit druckempfindlichen Klebstoffen enthaltend Ester der (Meth)Acrylsäure mit 2-Alkylalkoholen
CN104093806B (zh) 2011-11-18 2017-04-05 3M创新有限公司 压敏粘合剂组合物
JP6127061B2 (ja) 2011-11-21 2017-05-10 スリーエム イノベイティブ プロパティズ カンパニー 活性剤の貯蔵及び送達のための重合体粒子
CN104995020B (zh) 2012-02-03 2017-12-08 3M创新有限公司 用于保护性膜中的压敏粘合剂共混物
US9222254B2 (en) 2012-03-13 2015-12-29 Schabel Polymer Technology, Llc Structural assembly insulation
CN104781362A (zh) * 2012-11-16 2015-07-15 3M创新有限公司 导电弹性中空微球体、粘合剂组合物和粘合剂制品
EP2938686A1 (de) 2012-12-28 2015-11-04 3M Innovative Properties Company Artikel mit einer klebstofftrennschicht
WO2014164000A1 (en) 2013-03-13 2014-10-09 3M Innovative Properties Company Adhesives comprising epoxy-acid crosslinked groups and methods
WO2014143690A1 (en) 2013-03-15 2014-09-18 3M Innovative Properties Company Method for preparing (meth)acrylates of biobased alcohols and polymers thereof
EP2970093B1 (de) 2013-03-15 2018-12-12 3M Innovative Properties Company Verfahren zur herstellung von (meth)acrylaten aus biobasierten alkoholen und polymere daraus
JP6395815B2 (ja) 2013-05-14 2018-09-26 スリーエム イノベイティブ プロパティズ カンパニー 接着剤組成物
KR102194648B1 (ko) 2013-05-17 2020-12-23 쓰리엠 이노베이티브 프로퍼티즈 컴파니 반응 혼합물, 다공성 입자 및 제조 방법
EP2803712A1 (de) 2013-05-17 2014-11-19 3M Innovative Properties Company Mehrschichtige, druckempfindliche Haftmittelanordnung
WO2014186336A1 (en) 2013-05-17 2014-11-20 3M Innovative Properties Company Release of biologically active agents from polymeric composite particles
KR20170052614A (ko) 2014-09-04 2017-05-12 쓰리엠 이노베이티브 프로퍼티즈 캄파니 나노결정질 셀룰로오스를 함유하는 감압 접착제
US10920116B2 (en) 2015-04-13 2021-02-16 3M Innovative Properties Company Method of preparing crosslinked pressure-sensitive adhesives using a light-emitting diode for crosslinking
CN107771201B (zh) 2015-06-22 2021-06-04 3M创新有限公司 包含(甲基)丙烯酸类聚合物和氨基酸交联剂的压敏粘合剂
EP3156465A1 (de) 2015-10-15 2017-04-19 3M Innovative Properties Company Mehrschichtiges druckempfindliches schaumklebstoffband für aussenanwendungen
EP3156466B1 (de) 2015-10-15 2020-11-25 3M Innovative Properties Company Mehrschichtiges druckempfindliches schaumklebstoffband für aussenanwendungen
US20180304592A1 (en) * 2015-12-29 2018-10-25 3M Innovative Properties Company Mounting tab, dispenser for same, and method of use
CN106893534A (zh) * 2017-03-02 2017-06-27 浙江龙游道明光学有限公司 用于道路标志牌反光膜的热剥离压敏胶及其制备方法
EP3700994A4 (de) 2017-10-26 2021-08-04 3M Innovative Properties Company Zusammensetzung mit einem klebstoff auf silikonbasis und zellulose-nanokristallen sowie verfahren und artikel
KR102470448B1 (ko) * 2017-12-15 2022-11-24 주식회사 엘지화학 의류용 수성 아크릴계 점착제 및 이의 제조 방법
CN111770976A (zh) 2018-02-28 2020-10-13 3M创新有限公司 包含(甲基)丙烯酸仲己酯的聚合单元的粘合剂
CN111936593B (zh) 2018-04-05 2022-08-02 3M创新有限公司 包含聚二有机硅氧烷和丙烯酸类聚合物的交联共混物的凝胶粘合剂
EP3569622B1 (de) 2018-05-14 2021-01-06 3M Innovative Properties Company Mehrschichtige druckempfindliche haftmittelanordnung
EP3569669A1 (de) 2018-05-14 2019-11-20 3M Innovative Properties Company Verfahren zur herstellung einer elektronischen steuerungsvorrichtung
EP3613820A1 (de) 2018-08-24 2020-02-26 3M Innovative Properties Company Mehrschichtige druckempfindliche haftmittelanordnung
US11718121B2 (en) 2018-11-21 2023-08-08 3M Innovative Properties Company Spiral-shaped adhesive notepads and methods and devices for making them
EP3715432A1 (de) 2019-03-27 2020-09-30 3M Innovative Properties Company Druckempfindliche klebstoffzusammensetzung mit transparenzeigenschaften

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034087A2 (de) * 1980-01-30 1981-08-19 Calgon Corporation Ein Emulsionssystem mit drei Phasen verwendendes Polymerisationsverfahren
DE3637057A1 (de) * 1985-11-02 1987-05-07 Lion Corp Verfahren zur herstellung eines poroesen polymeren

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3615972A (en) * 1967-04-28 1971-10-26 Dow Chemical Co Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same
US3620988A (en) * 1968-10-31 1971-11-16 Goodrich Co B F Method of preparing bead-type polymers
US3691140A (en) * 1970-03-09 1972-09-12 Spencer Ferguson Silver Acrylate copolymer microspheres
US3857731A (en) * 1973-04-06 1974-12-31 Minnesota Mining & Mfg Acrylate microsphere-surfaced sheet material
DE2722751C2 (de) * 1977-05-20 1990-06-21 Röhm GmbH, 6100 Darmstadt Perlpolymerisat mit einem Teilchendurchmesser von 5 bis 1000 μm und innerem Hohlraum
US4166152B1 (en) * 1977-08-17 1999-05-18 Minnesota Mining & Mfg Tacky polymeric microspheres
US4495318A (en) * 1984-03-21 1985-01-22 International Cube Corporation Low tack microsphere glue
US4598112A (en) * 1984-09-14 1986-07-01 International Cube Corp. Low tack cationic microsphere glue
JPS6187734A (ja) * 1984-10-03 1986-05-06 Japan Synthetic Rubber Co Ltd 中空ポリマ−粒子の製造方法
US4656218A (en) * 1985-02-08 1987-04-07 Sanyo Kokusaku Pulp Co., Ltd. Adhesive copolymer microspheres-containing aqueous suspension and method for producing the same
US4645783A (en) * 1985-02-08 1987-02-24 Sanyo Kokusaku Pulp Co. Adhesive copolymer microspheres-containing aqueous suspension and method for producing the same
JPH0414434Y2 (de) * 1985-04-08 1992-03-31
JPS61258854A (ja) * 1985-05-13 1986-11-17 Nichiban Co Ltd アクリル酸エステル系架橋重合体微小球及びその製法
DE3677843D1 (de) * 1985-07-13 1991-04-11 Smith & Mclaurin Klebstoffe.
JPS62106902A (ja) * 1985-11-02 1987-05-18 Lion Corp 多孔性ポリマ−の製造方法
JPS6328901A (ja) * 1986-07-17 1988-02-06 ライオン株式会社 吸収性物品
JPH0788410B2 (ja) * 1986-09-01 1995-09-27 ライオン株式会社 表面架橋した多孔性ポリマ−の製造方法
US4839416A (en) * 1987-06-09 1989-06-13 Ampad Corporation Low tack microsphere adhesive
US4944888A (en) * 1987-12-23 1990-07-31 Avery International Corporation Suspension polymerization in an organic medium
US4810763A (en) * 1987-12-23 1989-03-07 Avery International Corporation Suspension polymerization in an organic medium
US4839393A (en) * 1988-07-08 1989-06-13 Wm. T. Burnett & Co., Inc. Polyurethane foams containing organofunctional silanes

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034087A2 (de) * 1980-01-30 1981-08-19 Calgon Corporation Ein Emulsionssystem mit drei Phasen verwendendes Polymerisationsverfahren
DE3637057A1 (de) * 1985-11-02 1987-05-07 Lion Corp Verfahren zur herstellung eines poroesen polymeren

Also Published As

Publication number Publication date
DK599989D0 (da) 1989-11-28
CA1328331C (en) 1994-04-05
ZA897828B (en) 1990-08-29
US5045569A (en) 1991-09-03
NO175154B (no) 1994-05-30
AU619350B2 (en) 1992-01-23
DK599989A (da) 1990-05-31
EP0371635A2 (de) 1990-06-06
MX169793B (es) 1993-07-26
EP0371635B1 (de) 1996-07-17
NO175154C (no) 1994-09-07
DE68926846T2 (de) 1997-02-27
JPH02194079A (ja) 1990-07-31
BR8906061A (pt) 1990-06-26
NO894064D0 (no) 1989-10-11
KR0155353B1 (ko) 1999-02-18
AU4295189A (en) 1990-06-07
AR246283A1 (es) 1994-07-29
JP2940875B2 (ja) 1999-08-25
NO894064L (no) 1990-05-31
DE68926846D1 (de) 1996-08-22
KR900007990A (ko) 1990-06-02
ES2088899T3 (es) 1996-10-01

Similar Documents

Publication Publication Date Title
EP0371635A3 (de) Hohle Acrylat-Polymer-Mikrokugeln
AU5989690A (en) Pressure-sensitive adhesive comprising hollow tacky microspheres and macromonomer-containing binder copolymer
CA2062950A1 (en) Adhesive stick with improved adhesive strength
AU8280891A (en) Repulpable pressure-sensitive adhesive constructions
AU5398194A (en) Fiber-reinforced cycloolefin copolymer material, process forits preparation and shaped articles from the material
CA2285430A1 (en) Calcium phosphate microcarriers and microspheres
CA2306106A1 (en) Biostatic coatings for the reduction and prevention of bacterial adhesion
CA2138314A1 (en) Acrylamide Polymers and Use Thereof
EP0393819A3 (de) Harzzusammensetzung für verbundartiges Antidröhnmaterial, Verfahren zu seiner Herstellung und Verwendung
CA2053564A1 (en) Two-component polyurethane adhesives
EP1690702A3 (de) Klebstoffzusammensetzung, Harzmasse, Gummiteil und Reifen
GR890300082T1 (en) Suspension polymerization process for preparing inherently tacky, elastomeric polymeric microspheres, microsphere adhesive obtained by this process and sheet material substrate comprising said adhesive
AU4167493A (en) Polyfluorohydrocarbon group-containing acrylates, their polymers and applications of the polymers
WO2002038693A3 (de) Uv-beständiger beflockungsklebstoff für polymere substrate
WO1998024856A3 (en) Non aqueous coating composition comprising a crosslinkable oligomer
EP0420988A4 (en) Cross-linked spherical particulate, production thereof, coating composition and releasable pressure-sensitive adhesive produced from said particulate, and article comprising the same as laminar component
AU5699090A (en) High strength fibre reinforced polymeric fasteners having threads, for example a nut and bolt
CA2146480A1 (en) Coating compositions containing 1,4-cyclohexane dimethanol
CA2076795A1 (en) Pressure-sensitive crayon adhesive
EP1475423A3 (de) Repositionierbarer Klebestift
CA2126353A1 (en) Polyurethane block copolymer
CA2090884A1 (en) Cellulosic article containing an olefinic oxide polymer and method of manufacture
AU1243492A (en) High tear strength, high tensile strength paper
AU3799593A (en) Suspension polymerized aqueous absorbent polymer particles
DE69822553D1 (de) Urethanpräpolymer, Verfahren zu dessen Herstellung und dieses enthaltender druckempfindlicher Klebstoff

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): BE CH DE ES FR GB IT LI NL SE

17P Request for examination filed

Effective date: 19910102

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): BE CH DE ES FR GB IT LI NL SE

17Q First examination report despatched

Effective date: 19930119

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

ITF It: translation for a ep patent filed

Owner name: BARZANO' E ZANARDO ROMA S.P.A.

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): BE CH DE ES FR GB IT LI NL SE

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

REF Corresponds to:

Ref document number: 68926846

Country of ref document: DE

Date of ref document: 19960822

ET Fr: translation filed
REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2088899

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: E. BLUM & CO. PATENTANWAELTE

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2088899

Country of ref document: ES

Kind code of ref document: T3

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19981021

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 19981027

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 19981117

Year of fee payment: 10

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19991109

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19991109

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19991130

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19991130

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

EUG Se: european patent has lapsed

Ref document number: 89311538.6

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20001214

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20051016

Year of fee payment: 17

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20051117

Year of fee payment: 17

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20060102

Year of fee payment: 17

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20061122

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20061130

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20061220

Year of fee payment: 18

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070601

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070601

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 20070601

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20070731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20061130

BERE Be: lapsed

Owner name: *MINNESOTA MINING AND MFG CY

Effective date: 20071130

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20071108

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071108

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071108