EP0364060A3 - Procédé pour le moulage à injection et l'extrusion de ionomères hygroscopiques mouillés - Google Patents
Procédé pour le moulage à injection et l'extrusion de ionomères hygroscopiques mouillés Download PDFInfo
- Publication number
- EP0364060A3 EP0364060A3 EP19890250055 EP89250055A EP0364060A3 EP 0364060 A3 EP0364060 A3 EP 0364060A3 EP 19890250055 EP19890250055 EP 19890250055 EP 89250055 A EP89250055 A EP 89250055A EP 0364060 A3 EP0364060 A3 EP 0364060A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- ionomers
- methods
- injection molding
- extruding wet
- hygroscopic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000554 ionomer Polymers 0.000 title abstract 2
- 238000001746 injection moulding Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 230000004888 barrier function Effects 0.000 abstract 2
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/46—Means for plasticising or homogenising the moulding material or forcing it into the mould
- B29C45/58—Details
- B29C45/60—Screws
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/40—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft
- B29B7/42—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft with screw or helix
- B29B7/428—Parts or accessories, e.g. casings, feeding or discharging means
- B29B7/429—Screws
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/46—Means for plasticising or homogenising the moulding material or forcing it into the mould
- B29C45/58—Details
- B29C45/63—Venting or degassing means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/505—Screws
- B29C48/53—Screws having a varying channel depth, e.g. varying the diameter of the longitudinal screw trunk
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/505—Screws
- B29C48/64—Screws with two or more threads
- B29C48/65—Screws with two or more threads neighbouring threads or channels having different configurations, e.g. one thread being lower than its neighbouring thread
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/76—Venting, drying means; Degassing means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/46—Means for plasticising or homogenising the moulding material or forcing it into the mould
- B29C45/58—Details
- B29C45/60—Screws
- B29C2045/605—Screws comprising a zone or shape enhancing the degassing of the plastic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S425/00—Plastic article or earthenware shaping or treating: apparatus
- Y10S425/812—Venting
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/255,883 US4944906A (en) | 1988-10-11 | 1988-10-11 | Methods of injection molding and extruding wet hygroscopic ionomers |
US255883 | 1988-10-11 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0364060A2 EP0364060A2 (fr) | 1990-04-18 |
EP0364060A3 true EP0364060A3 (fr) | 1991-01-30 |
EP0364060B1 EP0364060B1 (fr) | 1994-08-24 |
Family
ID=22970254
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89250055A Expired - Lifetime EP0364060B1 (fr) | 1988-10-11 | 1989-10-11 | Procédé pour le moulage à injection et l'extrusion de ionomères hygroscopiques mouillés |
Country Status (6)
Country | Link |
---|---|
US (1) | US4944906A (fr) |
EP (1) | EP0364060B1 (fr) |
JP (1) | JPH02171225A (fr) |
AU (1) | AU627506B2 (fr) |
CA (1) | CA2000412A1 (fr) |
DE (1) | DE68917673T2 (fr) |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5088914A (en) * | 1990-05-11 | 1992-02-18 | Romano Brambilla | Double flighted extrusion screw |
US5035509A (en) * | 1990-08-13 | 1991-07-30 | Hpm Corporation | Multi-channel extrusion screw with a zig-zag undercut barrier |
JP3170757B2 (ja) * | 1990-08-31 | 2001-05-28 | 東芝機械株式会社 | バリヤスクリュ |
ES2111635T3 (es) * | 1991-03-04 | 1998-03-16 | Dow Chemical Co | Metodo de mejorar la estabilidad termica oxidativa de polimeros de etileno. |
US5215764A (en) * | 1991-06-10 | 1993-06-01 | Westland Corporation | Extruder mixing screw |
US5342125A (en) * | 1992-05-14 | 1994-08-30 | Great Lakes Feedscrews, Inc. | Feedscrew for injection molding and extrusion |
US5281384A (en) * | 1992-06-15 | 1994-01-25 | Western Container Corporation | Improved method for transfer of molding material in two stage injection molding units during molding of preforms |
US5318357A (en) * | 1992-06-16 | 1994-06-07 | Spirex Corporation | Extruder injection apparatus |
US5486425A (en) * | 1993-03-30 | 1996-01-23 | Seibert; George M. | Shooting range target |
IL109386A (en) * | 1993-04-30 | 1996-10-31 | A K Tech Lab Inc | Method for printing by injecting polyethylene terephthalate |
JP2673491B2 (ja) * | 1994-03-07 | 1997-11-05 | 日精樹脂工業株式会社 | 不定形な成形材料の供給方法 |
US5534204A (en) * | 1993-08-24 | 1996-07-09 | Nissei Plastic Industrial Co., Ltd. | Method of injection molding polyethylene terephthalate |
JP3573380B2 (ja) * | 1995-08-14 | 2004-10-06 | 株式会社青木固研究所 | ポリエステル樹脂のプリフォーム射出成形方法及び延伸ブロー成形方法 |
US5599097A (en) * | 1995-12-14 | 1997-02-04 | The Black Clawson Company | Extruder screw for plastic extruders |
US5798077A (en) * | 1996-11-04 | 1998-08-25 | Spirex Corporation | Screw for plasticating apparatus and method of use |
JP3104860B2 (ja) * | 1996-12-27 | 2000-10-30 | 日精樹脂工業株式会社 | 射出スクリュ |
US5823668A (en) * | 1997-05-29 | 1998-10-20 | Spirex Corporation | Extruder and extrusion screw therefor |
US5961209A (en) * | 1997-06-11 | 1999-10-05 | Royal Feed Screws, Inc. | Feed screw |
US6227692B1 (en) * | 1997-08-12 | 2001-05-08 | Husky Injection Molding Systems Ltd. | Double wave screw |
US6136246A (en) * | 1997-11-07 | 2000-10-24 | Rauwendaal Extrusion Engineering | Screw extruder with improved dispersive mixing elements |
US6234659B1 (en) | 1998-09-25 | 2001-05-22 | Hpm Corporation | Surge suppressor for vented injection molding machine screw |
US6132075A (en) * | 1998-09-25 | 2000-10-17 | Hpm Corporation | Multichannel wave screw with a slush channel barrier section |
US6056430A (en) * | 1998-09-25 | 2000-05-02 | Hpm Corporation | Plasticating apparatus having a multichannel wave screw with a cross channel solids transition |
US6328919B1 (en) * | 1999-02-16 | 2001-12-11 | The Dow Chemical Company | Method for extruding polycarbonate of low bulk density |
US6139179A (en) * | 1999-09-03 | 2000-10-31 | Davis-Standard Corporation | Extruder screw having multi-channeled barrier section |
DE19961334A1 (de) * | 1999-12-17 | 2001-06-21 | Roehm Gmbh | Spritzgußverfahren für neutrale und säuregruppenhaltige (Meth)acrylat-Copolymere |
GB0102342D0 (en) | 2001-01-30 | 2001-03-14 | Smithkline Beecham Plc | Pharmaceutical formulation |
US7883721B2 (en) | 2001-01-30 | 2011-02-08 | Smithkline Beecham Limited | Pharmaceutical formulation |
US7014353B2 (en) * | 2002-02-25 | 2006-03-21 | New Castle Industries, Inc. | Plasticating screw and apparatus |
JP4034124B2 (ja) * | 2002-06-05 | 2008-01-16 | 株式会社ブリヂストン | 押出機用スクリュー及びその製造方法 |
US6988821B2 (en) * | 2002-12-30 | 2006-01-24 | Dray Sr Robert F | Plastics screw with barrier members |
US7032843B1 (en) | 2003-04-24 | 2006-04-25 | Westland Corporation U.S.A., Inc. | Mixing nozzle |
CN1787905B (zh) * | 2003-06-19 | 2011-03-23 | 赫斯基注射器成型系统有限公司 | 用于塑化螺杆的改进的混合部 |
TW200526274A (en) | 2003-07-21 | 2005-08-16 | Smithkline Beecham Plc | Pharmaceutical formulations |
PE20060003A1 (es) | 2004-03-12 | 2006-03-01 | Smithkline Beecham Plc | Formulacion farmaceutica polimerica para moldear por inyeccion |
ES2272119A1 (es) * | 2004-03-31 | 2007-04-16 | Talleres Pena, S.A. | Husillo para la inyeccion de termoplasticos. |
US20070092591A1 (en) * | 2005-10-24 | 2007-04-26 | Cyberonics, Inc. | Vacuum mandrel for use in fabricating an implantable electrode |
US20090297747A1 (en) * | 2008-05-30 | 2009-12-03 | E.I. Du Pont De Nemours And Company | Molded articles comprising ionomer compositions |
AU2009308728B2 (en) * | 2008-10-31 | 2016-02-04 | Performance Materials Na, Inc. | High-clarity ionomer compositions and articles comprising the same |
KR101643791B1 (ko) | 2008-12-30 | 2016-07-28 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 블렌딩된 고투명성 이오노머 조성물 및 그를 포함하는 용품 |
CN102325812A (zh) * | 2008-12-31 | 2012-01-18 | 纳幕尔杜邦公司 | 具有低雾度和高耐湿性的离聚物组合物以及包含该组合物的制品 |
US8177413B2 (en) * | 2010-03-05 | 2012-05-15 | Chung Chan I | Scientifically designed barrier screw |
DE102012008023B4 (de) * | 2012-04-21 | 2016-06-02 | Kraussmaffei Technologies Gmbh | Einschneckenextruder |
WO2015107422A1 (fr) | 2014-01-17 | 2015-07-23 | Reifenhauser Gmbh & Co. Kg, Maschinenfabrik | Section de mélange pour une vis d'extrusion de plastique |
US20150376310A1 (en) | 2014-06-26 | 2015-12-31 | E.I. Du Pont De Nemours And Company | Ethylene acid copolymers, their ionomers, and their use in packaging films and injection molded articles |
US10675598B2 (en) * | 2015-03-24 | 2020-06-09 | South Dakota Board Of Regents | High shear thin film machine for dispersion and simultaneous orientation-distribution of nanoparticles within polymer matrix |
CN109666874B (zh) * | 2018-12-28 | 2020-06-09 | 广州阿旺斯复合材料技术有限公司 | 一种高强度螺杆 |
JP6754018B1 (ja) * | 2020-01-23 | 2020-09-09 | 中田エンヂニアリング株式会社 | スクリュー、押出機及び押出方法 |
WO2022097076A1 (fr) * | 2020-11-09 | 2022-05-12 | Pomini Rubber & Plastics S.R.L. | Ensemble vis et vis jumelle destiné à être utilisé dans des extrudeuses à mélange élastomère et procédé associé pour l'extrusion de mélanges élastomères |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3445890A (en) * | 1966-12-08 | 1969-05-27 | Nrm Corp | Two-stage extruder |
FR2201969A1 (fr) * | 1972-10-09 | 1974-05-03 | Maillefer Sa | |
DE2403989A1 (de) * | 1974-01-29 | 1975-08-14 | Dietmar Dipl Ing Weber | Schneckenpresse zum verarbeiten von elastomeren und thermoplasten |
US4367190A (en) * | 1980-12-10 | 1983-01-04 | Phillips Cables Limited | Screw extruder |
US4752136A (en) * | 1986-07-23 | 1988-06-21 | Spirex Corporation | Extruder injection apparatus and method |
DE3741034A1 (de) * | 1987-05-25 | 1988-12-15 | Mitsubishi Heavy Ind Ltd | Plastifizierschnecke |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US28901A (en) * | 1860-06-26 | Improvement in making eaves-troughs | ||
US3375549A (en) * | 1961-04-05 | 1968-04-02 | Uniroyal Inc | Method and apparatus for refining and separating plastic materials |
NL128027C (fr) * | 1961-08-31 | 1900-01-01 | ||
US3271819A (en) * | 1962-02-26 | 1966-09-13 | Nrm Corp | Extruder |
US3653637A (en) * | 1968-11-29 | 1972-04-04 | Hans A Eckhardt | Apparatus for processing plastic materials |
US3826477A (en) * | 1971-04-13 | 1974-07-30 | Meiki Seisakusho Kk | Injection molding machine with a venting device |
US3698541A (en) * | 1971-08-11 | 1972-10-17 | Midland Ross Corp | Extruder, or extruder-like melting apparatus |
USRE28901E (en) | 1972-08-10 | 1976-07-13 | The B. F. Goodrich Company | Apparatus for refining polymeric material |
JPS5217816B2 (fr) * | 1973-07-18 | 1977-05-18 | ||
US4006209A (en) * | 1975-02-10 | 1977-02-01 | Egan Machinery Company | Method for additive feeding |
US4129386A (en) * | 1976-06-01 | 1978-12-12 | Akzona Incorporated | Extrusion apparatus |
US4128341A (en) * | 1977-04-29 | 1978-12-05 | Ingersoll-Rand Co. | Extruder screw |
US4185060A (en) * | 1978-03-17 | 1980-01-22 | Ladney M Jr | Method of manufacturing structural foam plastic products free from undesirable contaminant constituents |
US4330214A (en) * | 1980-02-19 | 1982-05-18 | W. H. Willert, Inc. | Plasticizing screw |
US4341474A (en) * | 1980-08-27 | 1982-07-27 | Wheeler Jr Norton C | Extruder screw |
CH649738A5 (fr) * | 1982-12-21 | 1985-06-14 | Maillefer Sa | Extrudeuse a vis pour matieres plastiques. |
US4557852A (en) * | 1984-04-09 | 1985-12-10 | S. C. Johnson & Son, Inc. | Polymer sheet for delivering laundry care additive and laundry care product formed from same |
JPS6143532A (ja) * | 1984-08-08 | 1986-03-03 | Yamashiro Seiki Seisakusho:Kk | 射出成形機のベント装置 |
US4797221A (en) * | 1985-09-12 | 1989-01-10 | S. C. Johnson & Son, Inc. | Polymer sheet for delivering laundry care additive and laundry care product formed from same |
US4770539A (en) * | 1987-07-06 | 1988-09-13 | Husky Injection Molding Systems Ltd. | Barrier screw |
-
1988
- 1988-10-11 US US07/255,883 patent/US4944906A/en not_active Expired - Lifetime
-
1989
- 1989-10-10 CA CA002000412A patent/CA2000412A1/fr not_active Abandoned
- 1989-10-11 AU AU42791/89A patent/AU627506B2/en not_active Ceased
- 1989-10-11 EP EP89250055A patent/EP0364060B1/fr not_active Expired - Lifetime
- 1989-10-11 DE DE68917673T patent/DE68917673T2/de not_active Expired - Fee Related
- 1989-10-11 JP JP1270555A patent/JPH02171225A/ja active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3445890A (en) * | 1966-12-08 | 1969-05-27 | Nrm Corp | Two-stage extruder |
FR2201969A1 (fr) * | 1972-10-09 | 1974-05-03 | Maillefer Sa | |
DE2403989A1 (de) * | 1974-01-29 | 1975-08-14 | Dietmar Dipl Ing Weber | Schneckenpresse zum verarbeiten von elastomeren und thermoplasten |
US4367190A (en) * | 1980-12-10 | 1983-01-04 | Phillips Cables Limited | Screw extruder |
US4752136A (en) * | 1986-07-23 | 1988-06-21 | Spirex Corporation | Extruder injection apparatus and method |
DE3741034A1 (de) * | 1987-05-25 | 1988-12-15 | Mitsubishi Heavy Ind Ltd | Plastifizierschnecke |
Non-Patent Citations (1)
Title |
---|
PLASTIC ENGINEERING, vol. 40. no. 12, December 1984, pages 25-28, Brookfield Center, CT, US; R.E. NUNN et al.: "Upgrading vented-barrel injection melding" * |
Also Published As
Publication number | Publication date |
---|---|
AU627506B2 (en) | 1992-08-27 |
CA2000412A1 (fr) | 1990-04-11 |
EP0364060A2 (fr) | 1990-04-18 |
JPH02171225A (ja) | 1990-07-02 |
EP0364060B1 (fr) | 1994-08-24 |
AU4279189A (en) | 1990-04-26 |
DE68917673T2 (de) | 1994-12-15 |
US4944906A (en) | 1990-07-31 |
DE68917673D1 (de) | 1994-09-29 |
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Legal Events
Date | Code | Title | Description |
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