Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/39—Organic or inorganic per-compounds
  • C11D3/3942—Inorganic per-compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
  • C11D17/0047—Detergents in the form of bars or tablets
  • C11D17/0065—Solid detergents containing builders
  • C11D17/0073—Tablets
  • C11D17/0091—Dishwashing tablets
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/38—Products with no well-defined composition, e.g. natural products
  • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
  • C11D3/38609—Protease or amylase in solid compositions only

Definitions

• the present invention relates to machine dishwashing products in tablet form. More particularly it relates to tablet systems wherein incompatible ingredients are formulated into separate tablets, the tablets then being mixed to provide a product having all the desired ingredients.
• the most common type of machine dishwashing cleanser is a powder or granulate.
• the average particle size varies between approximately 0.05 and 2mm diameter.
• the formulations usually contain alkali-metal polyphosphates, alkali-metal silicates, a bleach and a detergent.
• the silicates usually sodium metasilicate, are hygroscopic, and consequently they are difficult to formulate into a spray-dried powder. Compositions are instead produced by a mixing and absorption technique.
• the powder In use, the powder is dosed into a small dispenser in the dishwashing machine. During the washing cycle, it is flushed out by a water flow. However, due to the hygroscopicity, the powder can form lumps in the dispenser, resulting in low dosage into the wash. Anticaking ingredients such as paraffin have been added, but without complete success.
• thixotropic liquids e.g. as described in GB 1 527 706 and GB 2 140 450.
• the cleaning power of such compositions is not in general as good as conventional powder forms.
• a third form of machine dishwashing product comprises tablets. Such forms have been disclosed in, e.g. FR 1 472 680, DE-OS-2 857 001 and DE-OS-3 315 950. These tablets may contain conventional ingredients. The disadvantages caused by caking and lump-formation can be substantially eliminated by production of a high relative mass solid tablet.
• a detergent composition in tablet form comprising in combination at least two tablet types, incompatible components being distributed amongst said tablets such that no substantially incompatible ingredients are formulated within the same tablet type.
• the basic composition of all the tablets may be the same. However, silicate components may be incorporated into half the tablets, enzyme components into the other half. Likewise, substantially incompatible ingredients such as bleaches and dyes could be kept separate. After manufacture, the tablets would be mixed to give a final product containing all the required ingredients.
• the mixture of tablets generally a random mixture, may be filled directly from a package into the dishwashing machine cup dispenser.
• compositions may contain one or more alkali salts commonly used in dishwashing compositions.
• they may contain organic and/or inorganic builder salts such as alkali metal ortho-, pyro- and tripolyphosphates and hexametaphosphates, silicates, carbonates, borates, citrates, carboxymethyloxy-succinates, nitroloacetates and ethylenediaminetetra-acetates, polymeric polyelectrolytes such as polyacrylates, polymaleates and other known organic and inorganic builder compounds. Silicates and enzymes will usually be kept separate.
• the total amount of alkali salts distributed throughout the tablets varies from 10-90% by weight, generally from 30-70% by weight.
• compositions of the invention may also contain a detergent-active compound. If a detergent-active compound is included, it usually is in an amount of from 0.5-10%, usually 1-5%. Any well known type of detergent-active compound may be used, such as soaps, synthetic anionic, nonionic, amphoteric detergent surfactant and mixtures thereof. Preferably, a nonionic detergent surfactant is used, especially a low-foaming one. Suitable examples of such nonionic detergent surfactants can easily be found in M.Schick "Nonionic Surfactants" (1967).
• the detergent-active compound may be present by itself in a single tablet type or in one or more tablet types having other components. Preferably the detergent-active compound is incorporated in each tablet type such that each tablet type has at least some detergent-active compound and one other component of the composition.
• the tablet forms according to the present invention are of particular use in the formulation of enzymic detergents compositions.
• enzymes proteolytic, amylolytic, lipolytic and cellulolytic enzymes can be used, as well as mixtures of such enzymes.
• the enzymes may be of any suitable origin, such as vegetable, animal, bacterial, fungal and yeast origin. Preferably they are of bacterial and fungal origin.
• subtilisins which are obtained from particular strains of B. subtilis and B. licheniformis , such as the commercially available Maxatase (R) (ex Gist-Brocades N.V., Delft, Holland) and Alcalase (R) (ex Novo Industri A/S, Copenhagen, Denmark).
• R Maxatase
• R Alcalase
• proteases obtained from a strain of Bacillus having maximum activity in the pH range of 8-12, developed and sold by Novo Industri A/S under the registred trade-names Esperase (R) and Savinase (R) .
• the preparation of such enzymes is described in British patent specification 1 243 784.
• amylolytic enzymes are conmercially available amylases such as Maxamyl (R) (ex Gist-Brocades) and Termamyl (R) (ex Novo Industri A/S). Amylases as described in British patent specification 1 296 839 are also suitable.
• Typical examples of commercial lipolytic enzymes are e.g. Lipase YL, Amano CE, Wallerstein AW, Lipase MY etc. and typical examples of cellulolytic enzymes are cellulases ex Humiscola insolens as described in German patent specification 3 117 250.
• compositions of the invention preferably contain proteolytic and/or amylolytic enzymes, and especially preferably a mixture of proteolytic and amylolytic enzymes.
• the amount of enzymes present in the composition is dictated by the enzymatic activity of the enzymes. The higher the activity, the lower the level of enzymes required in the composition. In general, the amount will vary between 0.001 and 10%, and for most practical purposes between 0.1 and 5% by total weight of the composition.
• compositions may be formulated which also contain bleaching agents.
• the amount of bleach may be 0.02 to 15% by weight.
• Layered clays may be included within the tablets in order to reduce spot and film formation.
• Suitable clays belong to the geological classes of the smectites, the kaolins, the illites, the attapulgites and the mixed layer clays. Particularly preferred are the hectorites, members of the smectite family.
• the use of clays in machine dishwashing compositions is discussed in EP 0 139 329.
• the clays may be present at from 0.01 to 60% by weight, preferably 0.5 to 25% by weight, most preferably 0.5 to 5% by weight of the total composition.
• compositions may furthermore contain other useful additives such as, bleaching agent activators, enzyme-stabilising agents, hydrotropes, perfumes, colouring agents, germicides, soil-suspending agents, aminopolyphosphonic acids and alkali metal or alkaline earth metal salts thereof, anti-corrosion agents such as fatty acids, benztriazole and so on, additionally, the compositions may contain filler materials; suitable fillers include alkali metal salts of sulphate and carbonate, and polymeric materials such as polyethylene glycol having molecular weight of 400-10,000.
• compositions according to the present invention are particularly useful in forming coloured compositions, dyes often being unstable in the presence of bleaches or metasilicates.
• Dyes may be formulated into separate tablets from incompatible components. Thus the end product would be, for example, green and white or red and white tablets.
• the products of the present invention are formulated such that they provide a wash liquor with a pH of between 7 and 12, preferably between 9 and 11.
• Hygroscopic materials may be coated with, e.g. water soluble resin coatings after pressing in order to prevent premature tablet decomposition.
• the tablets may also incorporate effervescent compounds, such as sodium bicarbonate and citric acid. These compounds assist in dissolution of the tablets. It may also be desirable to incorporate materials which swell in contact with water, thus disrupting the tablet structure and increasing the rate of dissolution as the area in contact with the aqueous wash bath increases.
• effervescent compounds such as sodium bicarbonate and citric acid. These compounds assist in dissolution of the tablets. It may also be desirable to incorporate materials which swell in contact with water, thus disrupting the tablet structure and increasing the rate of dissolution as the area in contact with the aqueous wash bath increases.
• the tablets may contain from 0.2 to 40g of preformulation composition, preferably from 0.5 to 5g. They may be of various shapes, but are preferably cylindrical, about 1cm long and 0.5 cm diameter. These small sizes assist in solubility of the product.
• the tablets may be made by any conventional process known in the art. They are generally made by pressing together finely divided powders of the individual components. Compaction pressures can range from 1 x 103 to 1 x 107 N m ⁇ 2, selection of a suitable pressure being made to produce a soluble tablet. Tablet densities may range from 0.5 to 2 g/ml. Conventional tabletting ingredients, such as gums, magnesium silicate and polyethylene glucol may be included within the compositions.
• the tablets may be packaged after pressing into some suitable container. In general, a random mixture of tablet types will be mixed together. However, the proportions of the different tablets can be varied according to the amounts of different ingredients which are required. It could fall within the scope of the present invention that the tablet types are packaged separately, and added by the consumer to the wash. Thus, the detergent formulation can be tailored to the requirements of each wash.
• a pack comprising a container and, packed thereinto, a first set of tablets comprising a synthetic organic detergent component and at least one other set of tablets comprising further detergent components, components being distributed amongst said tablet sets such that no substantially incompatible ingredients are within the same tablet set.
• the invention further relates to a method of cleaning dishes which comprises admixing into a wash bath a plurality of tablets, the tablets being of differing types wherein substantially incompatible components are not within the same tablet type so as to produce an aqueous washing bath of dissolved detergent composition components.
• Enzyme activity was measured as an integral of activity over a period of time.
• Tablet combinations 1, 2 and 3 above were investigated, either crushed and added together as a powder, or added in tablet form.
• Theoretical 100% activity 159. It is seen that at high metasilicate levels, integral enzyme activity is higher (i.e. higher activity for a longer period of time) when the detergent composition is added in the form of tablets rather than as a powder.

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• Chemical & Material Sciences (AREA)
• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Wood Science & Technology (AREA)
• Organic Chemistry (AREA)
• Inorganic Chemistry (AREA)
• Detergent Compositions (AREA)

Applications Claiming Priority (2)

Publications (1)

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Cited By (26)

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Citations (4)

• 1987
  • 1987-11-19 GB GB878727135A patent/GB8727135D0/en active Pending
• 1988
  • 1988-11-16 ZA ZA888565A patent/ZA888565B/xx unknown
  • 1988-11-16 AU AU25624/88A patent/AU2562488A/en not_active Abandoned
  • 1988-11-17 JP JP1500067A patent/JPH02501489A/ja active Pending
  • 1988-11-17 BR BR888807311A patent/BR8807311A/pt unknown
  • 1988-11-17 EP EP88310845A patent/EP0318204A1/de not_active Withdrawn
  • 1988-11-17 WO PCT/GB1988/001009 patent/WO1989004863A1/en unknown

Patent Citations (4)

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