EP0316768B1 - Procédé de séparation d'air par rectification à basse température - Google Patents
Procédé de séparation d'air par rectification à basse température Download PDFInfo
- Publication number
- EP0316768B1 EP0316768B1 EP88118753A EP88118753A EP0316768B1 EP 0316768 B1 EP0316768 B1 EP 0316768B1 EP 88118753 A EP88118753 A EP 88118753A EP 88118753 A EP88118753 A EP 88118753A EP 0316768 B1 EP0316768 B1 EP 0316768B1
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- European Patent Office
- Prior art keywords
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04187—Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
- F25J3/04193—Division of the main heat exchange line in consecutive sections having different functions
- F25J3/042—Division of the main heat exchange line in consecutive sections having different functions having an intermediate feed connection
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04187—Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
- F25J3/04218—Parallel arrangement of the main heat exchange line in cores having different functions, e.g. in low pressure and high pressure cores
- F25J3/04224—Cores associated with a liquefaction or refrigeration cycle
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04278—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using external refrigeration units, e.g. closed mechanical or regenerative refrigeration units
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
- F25J3/04296—Claude expansion, i.e. expanded into the main or high pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04333—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/04339—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of air
- F25J3/04345—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of air and comprising a gas work expansion loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04333—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/04351—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen
- F25J3/04357—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen and comprising a gas work expansion loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04375—Details relating to the work expansion, e.g. process parameter etc.
- F25J3/04393—Details relating to the work expansion, e.g. process parameter etc. using multiple or multistage gas work expansion
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04406—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
- F25J3/04412—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/90—External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S62/00—Refrigeration
- Y10S62/939—Partial feed stream expansion, air
- Y10S62/94—High pressure column
Definitions
- the invention relates to a method for air separation by low-temperature rectification, in which the stream of gases involved in the air separation is passed through a cooling stage in which process cooling is produced by compression and expansion of at least part of this gas stream, the gas stream being compressed in the cooling stage and in two Partial streams is divided, which are at least partially cooled and relieved of work, the relaxation of the first partial stream being carried out at a higher temperature and that of the second partial stream being carried out at a lower temperature, in which at least one partial stream is further compressed before the expansion using the work obtained in the expansion is, and in which at least one of the two substreams is at least partially fed to the rectification.
- This method has the disadvantage that the proportion of the mechanical energy recovered during the expansion processes is unsatisfactory when using the expansion turbines which are usually used.
- the object of the present invention is to develop a method with a cooling stage mentioned at the outset which works particularly economically in terms of energy.
- This object is achieved in that the post-compression of the second partial stream is carried out in two stages and that the work obtained in the expansion of the two partial streams is used in the two stages for post-compression of the second partial stream.
- the procedure according to the invention causes a high pressure difference between the point of branching in the two partial flows and the entry of the second partial flow into the expansion process.
- the pressure and thus also the enthalpy difference is high on the expansion device operating at a lower temperature, and a high proportion of the mechanical energy of the highly compressed partial flow can be obtained as work during the expansion and fed back into the process.
- the pressure at the branching point can be chosen to be low and energy saved from outside for compression can thus be saved.
- the work which is obtained in the expansion of the first partial flow is used in the second stage of the post-compression of the second partial flow.
- the first partial stream is expanded to perform the work without post-compression.
- the pressure difference between the inlet and outlet of the expansion device operating at a higher temperature is therefore relatively small, which is why the expansion process can be carried out with high efficiency. This means that a high proportion of the energy released during relaxation can be obtained as work and returned to the process.
- both partial flows are fed completely to the rectification.
- the outlay on equipment can thus be kept lower than in the version with a circuit.
- At least some of the partial flows are cooled by heat exchange with an external coolant.
- cold can additionally be introduced into the process from the outside in a particularly economical manner.
- the heat exchange with the external coolant is carried out to a temperature which is greater than or equal to the temperature at which the expansion of the first partial stream begins.
- This cold can be supplied particularly cheaply if the temperature difference between the inlet and outlet is particularly high during heat exchange with the external coolant.
- the maximum of this difference is essentially that Difference between ambient temperature and inlet temperature in the relaxation device operating at a higher temperature. This temperature is particularly low if, according to an inventive feature mentioned above, the pressure difference when the expansion of the first partial flow is chosen to be low.
- pre-compressed and pre-cleaned air is used as the working gas for the cooling stage.
- This version proves to be particularly favorable if a small part of the products, based on the broken down air volume, is to be obtained in the liquid state.
- nitrogen-rich gas which is removed from the rectification is used as the working gas for the cooling stage. If a larger proportion of the products is removed in the liquid state, this version of the method is particularly useful.
- air to be broken down is fed via a line 1 to a compressor 2, in which it is compressed to a pressure of 6 to 7 bar, preferably 6.4 bar.
- the compressed air is passed via an aftercooler 3 to a molecular sieve adsorber 4 in order to separate water vapor and carbon dioxide therefrom.
- the air stream is then passed into the cooling stage, where it is compressed to a pressure of 28 to 32 bar in a compressor 5 and cooled in an aftercooler 6.
- the air flow then separates into a first partial flow 7 and a second partial flow 8.
- the second partial flow is compressed in two post-compression stages 9, 11 to 45 to 60 bar.
- the heat of compression is dissipated in the associated aftercoolers 10, 12.
- the first partial flow is fed directly to a heat exchanger 13 and there cooled in countercurrent to decomposition products to 230 to 280 K and expanded to 5.4 to 6.5 bar in an expansion device 14.
- the work obtained in this way is delivered to the post-compression stage 11.
- the first partial flow has a temperature of 150 to 170 K and is returned to the compressor 5 via the heat exchanger 13.
- a side stream 16 is branched off from the second partial stream behind the aftercooler 12 and is cooled to the temperature of the first partial stream upstream of the expansion device 14 by means of heat exchange with an external coolant, preferably halogenated hydrocarbons, and in the heat exchanger 13 is combined again with the remaining second partial stream.
- the heat exchange with the external coolant is carried out here specifically in two stages 17. This cooling could just as well be carried out in one stage.
- a side stream of the partial stream 7 or a side stream of each of the two partial streams 7, 8 could be cooled by means of heat exchange with the external coolant.
- a further partial flow 18 is branched off from the second partial flow and expanded in the expansion device 19 to 5.6 to 6.6 bar.
- the work obtained in this way is handed over to post-compression stage 9.
- the relaxed side stream 18 is then partly fed to the first stage 21 of a two-stage rectification column 20, and partly returned to the compressor 5 via the heat exchangers 15 and 13.
- the remaining second partial flow is throttled after further cooling in the heat exchanger 15 and fed to the first stage 21 of the rectification column.
- the first stage 21 of the rectification is operated at a pressure of 5.6 to 6.6 bar. It is connected to a second stage 22, which operates at a pressure of 1.5 to 1.7 bar, via a condenser-evaporator 23 in a heat-exchanging manner.
- Oxygen-rich liquid 24 is removed from the bottom of the first stage, and nitrogen-rich liquid 25 is removed from the top of the first stage.
- the two streams 24, 25 are subcooled in heat exchange with gaseous nitrogen 27 from the top of the second stage and with residual gas 33 in a heat exchanger 26, then relaxed throttle and introduced into the second stage 22 according to their composition.
- the nitrogen stream 27 and the residual gas stream 33 are heated in the heat exchanger 26.
- oxygen in the gaseous state is removed via a line 28.
- the two product streams 27 and 28 are then passed together with the residual gas stream 33 through the heat exchangers 15 and 13 and warmed to almost ambient temperature.
- FIG. 2 A further example is shown in FIG. 2 in which the cooling stage is operated with nitrogen-rich gas from the rectification column as the working gas. This method is very similar to that shown in Figure 1. The different process parts are mainly described below.
- the pre-compressed and pre-cleaned air is not fed to the cooling stage, but is cooled to about saturation temperature in the heat exchange 29 with gaseous decomposition products and a compensating stream 34 and is fed to the first stage 21 of the rectification column 20.
- nitrogen is withdrawn via line 30 and fed as working gas to the cooling stage, which is constructed essentially like the cooling stage in FIG. 1.
- the working gas Before entering the compressor 5, the working gas is heated. One part is passed through the heat exchangers 15, 13, another part through the equalizing flow 34 through the heat exchanger 29. A part of the equalizing flow 34 is branched off in the heat exchanger 29 and led to the heat exchanger 13 via the line 35. After heating, all branch flows of the working gas are combined again and fed to the compression in compressor 5.
- the entire second partial flow 8 is introduced into the heat exchanger 13 after the compression, without using an external coolant for the additional supply of cold. All versions with or without external coolant can optionally be used for both working gases.
- the side stream 18 of the second partial stream is largely returned to the compressor 5 after the expansion.
- Liquid oxygen 31 and liquid nitrogen 32 are taken as products from the first and second stages of the rectification column.
Claims (10)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19873738559 DE3738559A1 (de) | 1987-11-13 | 1987-11-13 | Verfahren zur luftzerlegung durch tieftemperaturrektifikation |
DE3738559 | 1987-11-13 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0316768A2 EP0316768A2 (fr) | 1989-05-24 |
EP0316768A3 EP0316768A3 (en) | 1989-08-09 |
EP0316768B1 true EP0316768B1 (fr) | 1991-06-19 |
Family
ID=6340422
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88118753A Revoked EP0316768B1 (fr) | 1987-11-13 | 1988-11-10 | Procédé de séparation d'air par rectification à basse température |
Country Status (4)
Country | Link |
---|---|
US (1) | US4883518A (fr) |
EP (1) | EP0316768B1 (fr) |
JP (1) | JPH01239376A (fr) |
DE (2) | DE3738559A1 (fr) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0383994A3 (fr) * | 1989-02-23 | 1990-11-07 | Linde Aktiengesellschaft | Procédé et dispositif de rectification d'air |
FR2652409A1 (fr) * | 1989-09-25 | 1991-03-29 | Air Liquide | Procede de production frigorifique, cycle frigorifique correspondant et leur application a la distillation d'air. |
GB9008752D0 (en) * | 1990-04-18 | 1990-06-13 | Boc Group Plc | Air separation |
FR2685460B1 (fr) * | 1991-12-20 | 1997-01-31 | Maurice Grenier | Procede et installation de production d'oxygene gazeux sous pression par distillation d'air |
DE4109945A1 (de) * | 1991-03-26 | 1992-10-01 | Linde Ag | Verfahren zur tieftemperaturzerlegung von luft |
GB9124242D0 (en) * | 1991-11-14 | 1992-01-08 | Boc Group Plc | Air separation |
CN1071444C (zh) * | 1992-02-21 | 2001-09-19 | 普拉塞尔技术有限公司 | 生产气体氧的低温空气分离系统 |
FR2692664A1 (fr) * | 1992-06-23 | 1993-12-24 | Lair Liquide | Procédé et installation de production d'oxygène gazeux sous pression. |
FR2697325B1 (fr) * | 1992-10-27 | 1994-12-23 | Air Liquide | Procédé et installation de production d'azote et d'oxygène. |
DE4301100C2 (de) * | 1993-01-18 | 2002-06-20 | Alstom Schweiz Ag Baden | Verfahren zum Betrieb eines Kombikraftwerkes mit Kohle- oder Oelvergasung |
FR2703140B1 (fr) * | 1993-03-23 | 1995-05-19 | Air Liquide | Procédé et installation de production d'oxygène gazeux et/ou d'azote gazeux sous pression par distillation de l'air. |
US5379598A (en) * | 1993-08-23 | 1995-01-10 | The Boc Group, Inc. | Cryogenic rectification process and apparatus for vaporizing a pumped liquid product |
FR2711778B1 (fr) * | 1993-10-26 | 1995-12-08 | Air Liquide | Procédé et installation de production d'oxygène et/ou d'azote sous pression. |
CA2142317A1 (fr) * | 1994-02-24 | 1995-08-25 | Anton Moll | Methode et appareil pour la recuperation d'argon pur |
US6006545A (en) * | 1998-08-14 | 1999-12-28 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes | Liquefier process |
US7533540B2 (en) * | 2006-03-10 | 2009-05-19 | Praxair Technology, Inc. | Cryogenic air separation system for enhanced liquid production |
FR2913759B1 (fr) * | 2007-03-13 | 2013-08-16 | Air Liquide | Procede et appareil de production de gaz de l'air sous forme gazeuse et liquide a haute flexibilite par distillation cryogenique. |
US20090320520A1 (en) * | 2008-06-30 | 2009-12-31 | David Ross Parsnick | Nitrogen liquefier retrofit for an air separation plant |
DE102009048456A1 (de) * | 2009-09-21 | 2011-03-31 | Linde Aktiengesellschaft | Verfahren und Vorrichtung zur Tieftemperaturzerlegung von Luft |
EP2312247A1 (fr) | 2009-10-09 | 2011-04-20 | Linde AG | Procédé et dispositif de production d'azote liquide par décomposition de l'air à basse température |
CN103322770B (zh) * | 2013-07-01 | 2015-05-13 | 首钢京唐钢铁联合有限责任公司 | 一种能耗分摊的计算方法 |
DE102013019504A1 (de) | 2013-11-21 | 2015-05-21 | Linde Aktiengesellschaft | Verfahren zur Gewinnung eines flüssigen Stickstoffprodukts durch Tieftemperaturzerlegung von Luft und Luftzerlegungsanlage |
EP2963367A1 (fr) * | 2014-07-05 | 2016-01-06 | Linde Aktiengesellschaft | Procédé et dispositif cryogéniques de séparation d'air avec consommation d'énergie variable |
US20160245585A1 (en) | 2015-02-24 | 2016-08-25 | Henry E. Howard | System and method for integrated air separation and liquefaction |
CN106621684B (zh) * | 2016-12-13 | 2019-09-27 | 大连欧科膜技术工程有限公司 | 一种聚烯烃尾气回收方法 |
EP3339277A1 (fr) * | 2016-12-22 | 2018-06-27 | Linde Aktiengesellschaft | Procédé et installation de production d'une oléfine |
EP3385248A1 (fr) | 2017-04-07 | 2018-10-10 | Linde Aktiengesellschaft | Procédé et installation de fabrication d'un ou de plusieurs oléfines |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1520103A (en) * | 1977-03-19 | 1978-08-02 | Air Prod & Chem | Production of liquid oxygen and/or liquid nitrogen |
DE3367023D1 (en) * | 1982-05-03 | 1986-11-20 | Linde Ag | Process and apparatus for obtaining gaseous oxygen at elevated pressure |
US4595405A (en) * | 1984-12-21 | 1986-06-17 | Air Products And Chemicals, Inc. | Process for the generation of gaseous and/or liquid nitrogen |
US4705548A (en) * | 1986-04-25 | 1987-11-10 | Air Products And Chemicals, Inc. | Liquid products using an air and a nitrogen recycle liquefier |
-
1987
- 1987-11-13 DE DE19873738559 patent/DE3738559A1/de not_active Withdrawn
-
1988
- 1988-11-10 DE DE8888118753T patent/DE3863345D1/de not_active Revoked
- 1988-11-10 EP EP88118753A patent/EP0316768B1/fr not_active Revoked
- 1988-11-11 JP JP63285585A patent/JPH01239376A/ja active Pending
- 1988-11-14 US US07/270,606 patent/US4883518A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US4883518A (en) | 1989-11-28 |
DE3863345D1 (de) | 1991-07-25 |
JPH01239376A (ja) | 1989-09-25 |
EP0316768A2 (fr) | 1989-05-24 |
DE3738559A1 (de) | 1989-05-24 |
EP0316768A3 (en) | 1989-08-09 |
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