EP0304764B1 - Méthode de préparation de matériau cellulosique défibré, en particulier des fibres de bois, pour la fabrication des panneaux de fibres - Google Patents
Méthode de préparation de matériau cellulosique défibré, en particulier des fibres de bois, pour la fabrication des panneaux de fibres Download PDFInfo
- Publication number
- EP0304764B1 EP0304764B1 EP88113246A EP88113246A EP0304764B1 EP 0304764 B1 EP0304764 B1 EP 0304764B1 EP 88113246 A EP88113246 A EP 88113246A EP 88113246 A EP88113246 A EP 88113246A EP 0304764 B1 EP0304764 B1 EP 0304764B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steam
- resin
- fiber particles
- fiber
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 27
- 229920002522 Wood fibre Polymers 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000002245 particle Substances 0.000 claims abstract description 33
- 229920005989 resin Polymers 0.000 claims abstract description 33
- 239000011347 resin Substances 0.000 claims abstract description 33
- 238000001035 drying Methods 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 229920002678 cellulose Polymers 0.000 claims abstract description 7
- 239000001913 cellulose Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 6
- 239000012670 alkaline solution Substances 0.000 claims abstract description 5
- 238000000465 moulding Methods 0.000 claims abstract 2
- 239000002025 wood fiber Substances 0.000 claims description 24
- 239000002023 wood Substances 0.000 claims description 17
- 239000012792 core layer Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims 1
- 238000004537 pulping Methods 0.000 claims 1
- 239000002344 surface layer Substances 0.000 claims 1
- 229920003002 synthetic resin Polymers 0.000 claims 1
- 239000000057 synthetic resin Substances 0.000 claims 1
- 238000010792 warming Methods 0.000 claims 1
- 229920001187 thermosetting polymer Polymers 0.000 abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 238000007664 blowing Methods 0.000 description 11
- 229920003043 Cellulose fiber Polymers 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 241001070941 Castanea Species 0.000 description 1
- 235000014036 Castanea Nutrition 0.000 description 1
- 241001070947 Fagus Species 0.000 description 1
- 235000010099 Fagus sylvatica Nutrition 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 239000013502 plastic waste Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002916 wood waste Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
- B27N1/02—Mixing the material with binding agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
Definitions
- the invention relates to a process for the production of shredded cellulose material, in particular wood fibers, up to a fiber length of 20 mm, which is provided with a high proportion of thermosetting resin.
- the glued wood fibers are suitable for the production of decorative molded parts, whereby they are first formed into a fiber mat and then pressed at high temperature.
- the method according to the invention is based on the known methods in which wood chips are first softened with steam and then, e.g. between two grinding disks, into wood fibers with a length of up to 20 mm. An aqueous alkaline solution of a thermosetting resin is then applied to the moist wood fibers and the glued wood fibers e.g. dried with hot air to a residual moisture content below 15% by weight (EP-B-0 081 147).
- this known method is carried out, however, there is a risk that the resinous particles stick to the wall of the drying tube during drying and, in extreme cases, clog the drying tube, whereby self-ignition easily occurs.
- the invention further relates to a decorative plate comprising a core layer and a decorative layer on one or both sides, in which the core layer consists of the fiber particles produced according to claim 1.
- the plate is a flat body, the surface shape and surface structure of which is adapted to the application and which e.g. can also have a curved shape.
- the plate is preferably a body with a substantially flat surface. Their thickness is in particular in the range from 0.5 to 30 mm. Plates of this type are described in particular in EP-B-0 081 147.
- the plate according to the invention expediently has a scratch-resistant surface as described in EP-A-0 166 153 and EP-A-0 216 269.
- Fibrous cellulose material is to be understood in particular as fibrous wood particles.
- You will be out Produced wood types that allow defibering for example from softwood, such as spruce or pine, or hardwood, such as chestnut or beech wood.
- cellulose fibers and industrial wood, paper and cellulose waste for example also wood flour or wood pulp, can be used; Waste from woodworking workshops is also suitable. It is also possible to replace part of the wood fibers, cellulose fibers or wood waste, preferably up to 20% by weight, with plastic waste, for example in the form of fibers or granules.
- the wood is washed to remove traces of metal, stone or sand, then crushed into wood chips in a mill.
- the wood chips are softened in a digestor (steam boiler) with water vapor under steam pressure of 1 to 10 bar in a few minutes and then, e.g. between two grinding disks in a refiner, chopped into wood fibers.
- a digestor steam boiler
- the wood fibers thus digested have a length of 0.3 to 20 mm, an average length of 0.5 to 3 mm and an average diameter of 0.025 to 0.05 mm.
- the diameter range is between 0.01 and 1 mm, depending on the raw wood used and the defibration conditions.
- the length and diameter of the cellulose fibers used are in the same dimensional range.
- the fiber particles emerging from the fiberizing machine are blown in a hot steam stream in a blowing system transported under increased pressure, preferably at 2 to 10 bar, in particular 4 to 6 bar, in turbulent flow.
- thermosetting resin is added in an aqueous, preferably alkaline solution, which is sprayed into the blowing system. Due to the turbulent flow, caused by a correspondingly small dimensioning of the blow pipe ("blow line") and an applied pressure difference over the length of the blow pipe, an optimal mixture between resin and fiber particles takes place, even with very large amounts of resin, which are 200 to 1,000 g, in particular 300 to 600 g, can be 1,000 g of dry fibers.
- the thermosetting resin is preferably a phenol-formaldehyde resin, as is customary for the production of decorative building boards (EP-B-0 081 147).
- the mixture of water vapor and resinous fiber particles is led from the blowing system to a unit, where the resinous fiber particles are removed from the water vapor.
- the water vapor is preferably completely separated off.
- the fiber particles then still have a water content of 15 to 35% by weight, in particular 18 to 25% by weight.
- This stage is advantageously carried out in a cyclone separator at atmospheric pressure, in particular without energy supply, but in principle other devices are also suitable with which systems made of solid particles, such as dust, and gases can be separated from one another.
- Such devices are, for example, devices that work on the principle of gravity or centrifugal force and / or are constructed from filters or mechanical separators (cf. Perry's Chemical Engineers' Handbook, 6th ed.
- the fiber particles are expediently blown through a drying tube heated with warm air, and are finely distributed by the air flow.
- the warm air preferably has a temperature of 60 to 110 ° C.
- the dried fibers leave the drying stage, for example, via a further cyclone separator or a similar device and are passed on for further processing, in particular for the production of decorative building boards, as described, for example, in EP-B-0 081 147.
- the method surprisingly shows a combination of advantages. This largely prevents the presence of water vapor in the dryer, which means that the energy requirement is relatively low. The risk of fire is also significantly reduced. There is no danger in the blowing system or in the dryer that their function will be disturbed by adhering material.
- the method does not require a great deal of equipment, and additional units for mixing and / or conveying the fiber particles are not required.
- the fibers obtained after the drying stage are not agglomerated, so that they can be easily formed into compressible fiber mats.
- the invention is illustrated by the following example and the figure.
- the figure schematically shows the process flow.
- Wood chips with approximately the same weight of water are continuously fed into a container 1 and treated in the boiler 2 with hot steam. After a dwell time of a few minutes, the softened wood chips are transported on to a refiner 3, where they are shredded into wood fibers between two grinding disks.
- the wood fibers are passed on with hot water steam in a blowing system 4, into which thermosetting phenol-formaldehyde resin in aqueous alkaline solution is sprayed via the resin injector 5.
- the blowing system 4 is cooled from the outside with water (cooling jacket 6).
- the mixture of water vapor and resinous wood fibers obtained then passes into a cyclone separator 7 under atmospheric pressure.
- the resin-coated or impregnated wood fibers are passed through a cell lock 9 into a drying tube 10 for the remaining drying, which they leave with a residual moisture content of 7% by weight.
- the wood fibers are conveyed further into a cyclone separator 11 by the dryer air and transported via a cell lock to a forming station 12, where they are deposited on a belt and pre-compressed into a fiber mat.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Paper (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Prostheses (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Removal Of Floating Material (AREA)
- Photoreceptors In Electrophotography (AREA)
Claims (10)
- Procédé de fabrication de matériau cellulosique défibré, de préférence en fibres de bois dont la longueur peut, en particulier, aller jusqu'a 20 mm, qui comporte une forte proportion de résine thermodurcissable et qui convient spécialement pour la fabrication de pièces moulées à base de fibres, la résine thermodurcissable étant ajoutée en solution aqueuse, de préférence alcaline, à un mélange de particules fibreuses et de vapeur d'eau et la vapeur d'eau étant séparée, dans un séchoir, d'avec les particules fibreuses enrobées de résine, procédé caractérisé en ce que la vapeur d'eau est, après l'addition de résine, séparée, dans une installation, de son mélange avec les particules fibreuses et que les particules fibreuses sont ensuite séchées, au cours d'une étape de séchage, jusqu'à l'obtention d'un degré d'humidité inférieur à 12 % en poids, en particulier de 3 à 10 % en poids.
- Procédé selon la revendication 1, caractérisé en ce que la séparation de la vapeur d'eau est effectuée dans un cyclone, de préférence sans apport d'énergie.
- Procédé selon la revendication 1 ou 2, caractérisé en ce que l'étape de séchage se déroule en présence d'air chaud, de préférence à une température de 60 à 110°C.
- Procédé selon une des revendications 1 à 3, caractérisé en ce qu'on dépose la résine thermodurcissable en solution aqueuse sur les particules fibreuses amenées dans un courant de vapeur d'eau, on transporte, par un tuyau refroidi de l'extérieur, le mélange de particules fibreuses imprégnées, on élimine ensuite complètement la vapeur d'eau et on réalise finalement le séchage.
- Procédé selon une des revendications 1 à 4, caractérisé en ce que le courant de vapeur d'eau est acheminé avec les particules fibreuses sous haute pression, de préférence de 2 à 10 bar, en particulier de 4 à 6 bar, en écoulement turbulent.
- Procédé selon une des revendications 1 à 5, caractérisé en ce que la proportion de résine ajoutée est de 200 à 1000 g, de préférence de 300 à 600 g, pour 1000 g de particules fibreuses (poids sec).
- Procédé selon une des revendications 1 à 6, caractérisé en ce que la vapeur d'eau séparée est utilisée pour le chauffage des copeaux de bois restant encore à défibrer.
- Procédé selon une des revendications 1 à 7, caractérisé en ce que les particules fibreuses sont, après l'étape de séchage, séparées de l'air de séchage, de préférence dans un cyclone supplémentaire.
- Procédé selon une des revendications 1 à 8, caractérisé en ce que, pour le défibrage du matériau cellulosique, on fragmente, sous pression de vapeur d'eau, des particules de cellulose, en particulier des copeaux de bois, jusqu'à une longueur maximale des fibres de 20 mm, on entraîne les particules fibreuses obtenues, mélangées à la vapeur d'eau sous pression élevée, de préférence de 2 à 10 bar, en particulier de 4 à 6 bar, dans une soufflerie et on pulvérise la solution aqueuse de résine dans ladite soufflerie.
- Panneau décoratif, comportant une couche interne et des couches superficielles, décoratives sur une ou deux faces, caractérisé en ce que la couche interne se compose des fibres de bois fabriquées d'après la revendication 1, fibres qui sont comprimées à chaud avec une résine artificielle thermodurcissable.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT88113246T ATE86166T1 (de) | 1987-08-22 | 1988-08-16 | Verfahren zur herstellung von zerfasertem zellulosematerial, insbesondere holzfasern, fuer die herstellung von faserplatten. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3728123 | 1987-08-22 | ||
DE19873728123 DE3728123A1 (de) | 1987-08-22 | 1987-08-22 | Verfahren zur herstellung von zerfasertem zellulosematerial, insbesondere holzfasern, fuer die herstellung von faserplatten |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0304764A2 EP0304764A2 (fr) | 1989-03-01 |
EP0304764A3 EP0304764A3 (en) | 1989-11-29 |
EP0304764B1 true EP0304764B1 (fr) | 1993-03-03 |
Family
ID=6334325
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88113246A Revoked EP0304764B1 (fr) | 1987-08-22 | 1988-08-16 | Méthode de préparation de matériau cellulosique défibré, en particulier des fibres de bois, pour la fabrication des panneaux de fibres |
Country Status (10)
Country | Link |
---|---|
US (1) | US4937100A (fr) |
EP (1) | EP0304764B1 (fr) |
JP (1) | JPS6471704A (fr) |
AT (1) | ATE86166T1 (fr) |
AU (1) | AU601868B2 (fr) |
CA (1) | CA1295441C (fr) |
DE (2) | DE3728123A1 (fr) |
DK (1) | DK167428B1 (fr) |
FI (1) | FI883833A (fr) |
NO (1) | NO170465C (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10037983B4 (de) * | 2000-08-03 | 2006-04-13 | Stefan Zikeli | Polymerzusammensetzung und daraus hergestellter Formkörper mit einem Gehalt an Alkaloid |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3891143T1 (de) * | 1987-12-16 | 1990-09-20 | Sunds Defibrator | Verfahren und vorrichtung zum herstellen von faserplatten |
US5064689A (en) | 1989-03-20 | 1991-11-12 | Weyerhaeuser Company | Method of treating discontinuous fibers |
US5432000A (en) | 1989-03-20 | 1995-07-11 | Weyerhaeuser Company | Binder coated discontinuous fibers with adhered particulate materials |
US5230959A (en) | 1989-03-20 | 1993-07-27 | Weyerhaeuser Company | Coated fiber product with adhered super absorbent particles |
US5498478A (en) | 1989-03-20 | 1996-03-12 | Weyerhaeuser Company | Polyethylene glycol as a binder material for fibers |
AU665532B2 (en) * | 1991-04-26 | 1996-01-11 | Enviroflex Pty. Ltd. | Insulation pellets and a process for producing same |
CA2126240A1 (fr) | 1991-12-17 | 1993-06-24 | Paul Gaddis | Melangeur a tremie et methode de revetement de fibres |
DE19515734A1 (de) * | 1995-05-03 | 1996-11-07 | Schenkmann & Piel Verfahrenste | Verfahren zur Herstellung von Holzfasern |
DE19746383A1 (de) * | 1997-10-21 | 1999-04-22 | Hofa Homann Gmbh & Co Kg | Verfahren und Vorrichtung zur Herstellung von Faserplatten sowie nach dem Verfahren hergestellte Faserplatten |
IE990100A1 (en) | 1998-10-30 | 2000-05-03 | Masonite Corp | Method of making molded Composite articles |
US7410687B2 (en) * | 2004-06-08 | 2008-08-12 | Trex Co Inc | Variegated composites and related methods of manufacture |
DE102004062649C5 (de) | 2004-12-21 | 2013-06-06 | Kronotec Ag | Verfahren zur Herstellung einer Holzfaserdämmstoffplatte bzw.-matte und nach diesem Verfahren hergestellte Holzfaserdämmstoffplatten bzw.-matten |
WO2006092603A1 (fr) * | 2005-03-02 | 2006-09-08 | University Of Wales, Bangor | Traitement de fibres longues dans un flux gazeux à haute pression |
DE102008026677B3 (de) * | 2008-06-04 | 2009-10-22 | Kronotec Ag | Verfahren zum Trocknen von lignocellulosehaltigen Fasern und Dampfabscheider zur Verwendung in dem Verfahren |
DE102008056650A1 (de) * | 2008-11-10 | 2010-05-12 | Martin Dreisman | Zusammensetzung und Verfahren zur Herstellung einer Holz- oder Holzfaserplatte |
AT509429B1 (de) * | 2010-01-20 | 2016-09-15 | Erema | Verfahren zur herstellung eines mit längeren fasern gefüllten polymeren materials |
IT1399772B1 (it) | 2010-04-30 | 2013-05-03 | Imal Srl | Apparato per l'iniezione di componenti chimici in un flusso di materiale legnoso incoerente |
UA114281C2 (uk) * | 2010-10-01 | 2017-05-25 | Кроноплас Текнікел Аг | Спосіб і установка для склеювання деревних часток |
CA2872839A1 (fr) * | 2012-06-01 | 2013-12-05 | Dieffenbacher GmbH Maschinen- und Anlagenbau | Coude pour introduire un courant de vapeur et de fibres dans un sechoir ou un cuvier de stockage de la pulpe d'une usine de traitement de fibres, installation de soufflage avec un coude, et usine de traitement de fibres avec une installation de soufflage |
AT514330B1 (de) * | 2013-08-01 | 2014-12-15 | Andritz Ag Maschf | Anlage und Verfahren zum Verarbeiten von Faserstoffen |
AT514329B1 (de) * | 2013-08-01 | 2014-12-15 | Andritz Ag Maschf | Anlage und Verfahren zum Verarbeiten von Faserstoffen |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2817617A (en) * | 1953-03-19 | 1957-12-24 | Hugh R Rogers | Process of manufacturing board-like articles |
DE3147989A1 (de) | 1981-12-04 | 1983-06-16 | Hoechst Ag, 6230 Frankfurt | Dekoratives, insbesondere plattenfoermiges formteil, verfahren zu seiner herstellung und seine verwendung |
DE3418282A1 (de) * | 1984-05-17 | 1985-11-21 | Hoechst Ag, 6230 Frankfurt | Dekorative platte mit verbesserten oberflaecheneigenschaften |
DE3609506A1 (de) * | 1985-03-25 | 1986-10-30 | Koppers Co., Inc., Pittsburgh, Pa. | Verfahren zum herstellen einer masse aus zelluloseteilchen und harz fuer die herstellung von faserplatten |
DE3533737A1 (de) * | 1985-09-21 | 1987-03-26 | Hoechst Ag | Dekorative platte mit verbesserten oberflaecheneigenschaften |
-
1987
- 1987-08-22 DE DE19873728123 patent/DE3728123A1/de not_active Withdrawn
-
1988
- 1988-08-09 US US07/230,049 patent/US4937100A/en not_active Expired - Fee Related
- 1988-08-15 CA CA000574708A patent/CA1295441C/fr not_active Expired - Fee Related
- 1988-08-16 DE DE8888113246T patent/DE3878785D1/de not_active Revoked
- 1988-08-16 EP EP88113246A patent/EP0304764B1/fr not_active Revoked
- 1988-08-16 AT AT88113246T patent/ATE86166T1/de not_active IP Right Cessation
- 1988-08-16 AU AU21074/88A patent/AU601868B2/en not_active Ceased
- 1988-08-18 FI FI883833A patent/FI883833A/fi not_active Application Discontinuation
- 1988-08-19 NO NO883735A patent/NO170465C/no unknown
- 1988-08-19 DK DK465988A patent/DK167428B1/da not_active IP Right Cessation
- 1988-08-22 JP JP63206518A patent/JPS6471704A/ja active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10037983B4 (de) * | 2000-08-03 | 2006-04-13 | Stefan Zikeli | Polymerzusammensetzung und daraus hergestellter Formkörper mit einem Gehalt an Alkaloid |
Also Published As
Publication number | Publication date |
---|---|
DK465988A (da) | 1989-02-23 |
DE3878785D1 (de) | 1993-04-08 |
ATE86166T1 (de) | 1993-03-15 |
NO883735L (no) | 1989-02-23 |
EP0304764A2 (fr) | 1989-03-01 |
FI883833A0 (fi) | 1988-08-18 |
FI883833A (fi) | 1989-02-23 |
JPS6471704A (en) | 1989-03-16 |
DE3728123A1 (de) | 1989-03-02 |
US4937100A (en) | 1990-06-26 |
AU2107488A (en) | 1989-02-23 |
NO170465C (no) | 1992-10-21 |
NO883735D0 (no) | 1988-08-19 |
DK465988D0 (da) | 1988-08-19 |
AU601868B2 (en) | 1990-09-20 |
EP0304764A3 (en) | 1989-11-29 |
CA1295441C (fr) | 1992-02-11 |
NO170465B (no) | 1992-07-13 |
DK167428B1 (da) | 1993-11-01 |
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