EP0277577B1 - Feingussschalenform für Aluminium bzw. dessen Legierungen - Google Patents
Feingussschalenform für Aluminium bzw. dessen Legierungen Download PDFInfo
- Publication number
- EP0277577B1 EP0277577B1 EP88101050A EP88101050A EP0277577B1 EP 0277577 B1 EP0277577 B1 EP 0277577B1 EP 88101050 A EP88101050 A EP 88101050A EP 88101050 A EP88101050 A EP 88101050A EP 0277577 B1 EP0277577 B1 EP 0277577B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- metal
- precision
- ceramic shell
- coating
- shell mould
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005495 investment casting Methods 0.000 title claims description 16
- 229910052782 aluminium Inorganic materials 0.000 title claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 12
- 229910045601 alloy Inorganic materials 0.000 title claims description 10
- 239000000956 alloy Substances 0.000 title claims description 10
- 239000004411 aluminium Substances 0.000 title claims 3
- 229910052751 metal Inorganic materials 0.000 claims description 30
- 239000002184 metal Substances 0.000 claims description 30
- 238000000576 coating method Methods 0.000 claims description 17
- 239000011248 coating agent Substances 0.000 claims description 16
- 239000000919 ceramic Substances 0.000 claims description 9
- 239000011833 salt mixture Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 229910000838 Al alloy Inorganic materials 0.000 claims description 8
- 238000005266 casting Methods 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 239000011777 magnesium Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 230000001603 reducing effect Effects 0.000 claims description 7
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 6
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 6
- 229910052787 antimony Inorganic materials 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 229910052790 beryllium Inorganic materials 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052727 yttrium Inorganic materials 0.000 claims description 4
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 4
- 229910010380 TiNi Inorganic materials 0.000 claims description 3
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
- 238000005219 brazing Methods 0.000 claims description 3
- 229910000679 solder Inorganic materials 0.000 claims description 3
- 229910004709 CaSi Inorganic materials 0.000 claims description 2
- 229910005438 FeTi Inorganic materials 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 239000000843 powder Substances 0.000 description 15
- 210000001787 dendrite Anatomy 0.000 description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 230000035784 germination Effects 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 229910052712 strontium Inorganic materials 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- -1 CaAl Inorganic materials 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910001366 Hypereutectic aluminum Inorganic materials 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910010340 TiFe Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021348 calcium disilicide Inorganic materials 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- PFSXARRIPPWGNC-UHFFFAOYSA-J hexafluorotitanium(2-);hydron Chemical compound [H+].[H+].[F-].[F-].[F-].[F-].[F-].[F-].[Ti+4] PFSXARRIPPWGNC-UHFFFAOYSA-J 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002940 palladium Chemical class 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000002255 vaccination Methods 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/02—Sand moulds or like moulds for shaped castings
- B22C9/04—Use of lost patterns
Definitions
- the present invention relates to an investment casting mold, preferably for hypoeutectic aluminum alloys, in which the rough inner mold wall is coated with a salt mixture with reducing properties, the salt coatings consisting of a salt or salt mixture with a liquidus temperature below the casting temperature, the cations of which predominantly consist of those of the Alkali and / or alkaline earth metals and their anions consist predominantly of those of the halogens.
- a method for reducing the dendrite arm distances according to the preamble of claim 1 is known (DE-OS 3 512 118), in which the improvement in the technological properties of the castings is obtained by means of a special salt mixture by applying this salt mixture to a particularly rough inner shell of the molded shell becomes what promotes the germination of the dendrites in metal solidification, so that smaller dendrite arm distances are obtained.
- a large number of germ-active substances are described in the literature.
- hypoeutectic aluminum alloys e.g. AISi7Mgo.6, then have improved strength values if low-gas and clean melts are used, which is best achieved by casting in a vacuum and / or by flushing gas treatment in a rough vacuum and / or filtering the melt.
- Vaccination of the melt with the help of e.g. Strontium or antimony to achieve spherical molding of the eutectic silicon also lead to an improvement in the technological values.
- Metal films can e.g. according to U.S. Patent 3,462,288, U.S. Patent 1,621,227, U.S. Patent 3,639,139, U.S. Patent 3,705,051, U.S. Patent 3,836,385 and U.S. Patent 2,635,798.
- the present invention is based on the object of reducing the dendrite arm spacing when casting hypereutectic aluminum alloys into preheated ones Investment casting bowl shapes can be set correctly and safely.
- the metal coating consists of more than 40 atomic% of one or more metals from the series Al, Ti and / or alkaline earth metals and / or alloys, mixtures or metallic compounds .
- the coating metal optionally in the form of its alloys, mixtures or compounds, is advantageously applied to the inner wall of the mold before, after or simultaneously with the salt coating.
- the coating metal expediently consists of an aluminum alloy which contains 0 to 10% by weight of magnesium and / or 0 to 6% by weight of silicon and / or 0 to 3000 ppm of yttrium and / or one and / or more rare earths and / or beryllium and / or contains bismuth and / or antimony.
- the advantage of the invention is not only the fact that considerably smaller dendrite arm distances and thus better technological values of the cast part, in particular in the case of hypoeutectic aluminum alloys, are obtained, but that at the same time a spherical molding of the silicon is obtained. This is particularly important because it can save additional finishing measures.
- metal films can be applied to the inner wall of the mold using various chemical or physical processes.
- metal powder and salt or salt mixture in the form of a slurry or solution simultaneously by pouring and pouring them onto the inner shell of the mold.
- metal powders have a greater tendency to oxidize than metal films when preheating the molded shell, it has proven to be advantageous to use metallic alloys and / or compounds or mixtures in powder form which either only have a particularly low oxidation due to their composition when preheating the molded shell experienced or used metals, the oxide layer is destroyed in the presence of the cast aluminum at casting temperature by an alloy partner.
- the destruction of the oxide film on the surfaces can be achieved, for example, by using aluminum brazing powder with grain sizes of approx. 10 to 50 11 m.
- Usual hard solders contain, for example, beryllium with about 50 ppm as a reducing additive, some additionally with magnesium with about 1.5% and also bismuth or antimony with about 10 to 100 ppm.
- alloys that are easy to grind due to their hardness and are also germ-active. So far, the following metallic compounds, each with an atomic ratio of approximately 1: 1, have proven themselves: FeAI, FeTi, CaAl, CaSi, TiNi, TiAg.
- the inside of an investment casting shell is coated by pouring in and pouring out and then drying with a slurry consisting of 40 g NaCl, 20 g NaF, 20 g LiCl, 5 g Na 4 Fe (CN) 6 and 20 g metal in 1 liter water .
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Mold Materials And Core Materials (AREA)
- Powder Metallurgy (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3703416A DE3703416A1 (de) | 1987-02-05 | 1987-02-05 | Feingussschalenform fuer aluminium bzw. dessen legierungen |
DE3703416 | 1987-02-05 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0277577A2 EP0277577A2 (de) | 1988-08-10 |
EP0277577A3 EP0277577A3 (en) | 1988-11-30 |
EP0277577B1 true EP0277577B1 (de) | 1990-10-31 |
Family
ID=6320251
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88101050A Expired - Lifetime EP0277577B1 (de) | 1987-02-05 | 1988-01-26 | Feingussschalenform für Aluminium bzw. dessen Legierungen |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0277577B1 (sv) |
JP (1) | JPS63268534A (sv) |
BR (1) | BR8800436A (sv) |
CS (1) | CS71088A3 (sv) |
DE (2) | DE3703416A1 (sv) |
ES (1) | ES2018857B3 (sv) |
IL (1) | IL85274A (sv) |
RU (1) | RU1839646C (sv) |
ZA (1) | ZA88617B (sv) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19929290A1 (de) * | 1999-06-25 | 2000-12-28 | Volkswagen Ag | Verfahren zur Herstellung von magnesiumhaltigen Metallgußteilen |
GB2421207A (en) * | 2004-12-16 | 2006-06-21 | Cosworth Technology Ltd | Casting with a halogen containing compound provided on the mould surface |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3019497A (en) * | 1958-11-21 | 1962-02-06 | Howe Sound Co | Making fine grained castings |
US3476171A (en) * | 1967-02-14 | 1969-11-04 | Reactive Metals Inc | Method for melting refractory metal |
DE3512118A1 (de) * | 1985-04-03 | 1986-10-16 | Thyssen Industrie Ag, 4300 Essen | Verfahren zur erzeugung einer verbesserten feinkoernigkeit des primaergefueges und/oder des eutektikums von gussteilen |
-
1987
- 1987-02-05 DE DE3703416A patent/DE3703416A1/de active Granted
-
1988
- 1988-01-26 DE DE8888101050T patent/DE3860894D1/de not_active Expired - Fee Related
- 1988-01-26 EP EP88101050A patent/EP0277577B1/de not_active Expired - Lifetime
- 1988-01-26 ES ES88101050T patent/ES2018857B3/es not_active Expired - Lifetime
- 1988-01-29 ZA ZA880617A patent/ZA88617B/xx unknown
- 1988-02-01 IL IL85274A patent/IL85274A/xx unknown
- 1988-02-04 RU SU884355239A patent/RU1839646C/ru active
- 1988-02-04 BR BR8800436A patent/BR8800436A/pt unknown
- 1988-02-04 CS CS88710A patent/CS71088A3/cs unknown
- 1988-02-04 JP JP63022972A patent/JPS63268534A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
ZA88617B (en) | 1988-08-02 |
IL85274A0 (en) | 1988-07-31 |
DE3860894D1 (de) | 1990-12-06 |
EP0277577A2 (de) | 1988-08-10 |
IL85274A (en) | 1992-01-15 |
BR8800436A (pt) | 1988-09-20 |
CS71088A3 (en) | 1992-08-12 |
DE3703416C2 (sv) | 1992-01-16 |
EP0277577A3 (en) | 1988-11-30 |
JPS63268534A (ja) | 1988-11-07 |
DE3703416A1 (de) | 1988-08-18 |
RU1839646C (ru) | 1993-12-30 |
ES2018857B3 (es) | 1991-05-16 |
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