EP0259584B1 - Verfahren zur Beschleunigung der Weissgradregeneration hitzebehandelter Papiere - Google Patents
Verfahren zur Beschleunigung der Weissgradregeneration hitzebehandelter Papiere Download PDFInfo
- Publication number
- EP0259584B1 EP0259584B1 EP87110651A EP87110651A EP0259584B1 EP 0259584 B1 EP0259584 B1 EP 0259584B1 EP 87110651 A EP87110651 A EP 87110651A EP 87110651 A EP87110651 A EP 87110651A EP 0259584 B1 EP0259584 B1 EP 0259584B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat
- whiteness
- paper web
- regeneration
- ultraviolet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/04—Physical treatment, e.g. heating, irradiating
Definitions
- the invention relates to a method for accelerating the whiteness regeneration or stability of paper webs of different material compositions which have been subjected to a heat treatment.
- a partial or complete whiteness regeneration of the heat-induced paper should, however, take place as quickly as possible. This is especially true when coloristic aspects have to be considered. For example, in the production of structural foam wallpapers with different colors, a constant comparison of the finished product with a constant color template is carried out and, if necessary, the color of the PVC plastisols used is corrected. A continuous increase in the degree of whiteness (whiteness regeneration) of the finished foam wallpaper, especially when the foam is not applied to the entire surface of the backing paper, considerably complicates the work of the colorists when it comes to color formulation. Even a difference in whiteness of 1.5 to 2% absolutely affects the untrained eye. Coloristically trained people may find even smaller differences in whiteness disturbing.
- the object of the present invention is therefore to propose a method for the accelerated whiteness regeneration of heat-treated papers, which eliminates the disadvantages and shortcomings mentioned above.
- This object is achieved in that the paper web is exposed to high-energy ultraviolet radiation (UV light) with or without an increase in moisture immediately after the heat treatment and before rolling up.
- UV light high-energy ultraviolet radiation
- a process has become known from EP-A 0 120 095, which is used in the production of so-called "cast coated papers". 1-30 g / m 2 of water are applied to the back of the paper, specifically in a nip in which the coating is pressed onto the paper. Humidification is carried out using nozzles or engraved rollers, which take up water from a water supply. This is to prevent the curling of the coated paper that occurs during production.
- Figure 1 demonstrates the partial whiteness regeneration of a conventional, known wallpaper base paper (duplex paper, top layer wood-free, underlay wood-containing), which is used as a substrate for foam wallpapers, after a practical heat treatment of 220 ° C for 42 s.
- the heat-treated paper was stored under daylight.
- a drop in the degree of whiteness (according to Hunter) of 26.1% in absolute terms due to the already mentioned heat effect is followed by the partial whiteness regeneration.
- the whiteness regeneration is only minimal.
- this whiteness recovery is problematic, especially within the first 25 minutes after the heat-induced yellowing.
- a whiteness constancy is reached after only about 10 hours by UV radiation, after about 45 hours when stored under daylight and after about 90 hours when stored in the dark.
- the final whiteness of UV-irradiated paper is also around 15% higher than that of heat-induced paper exposed to daylight.
- the heat ind decorated paper After just 10 minutes of storage, the heat ind decorated paper, which was exposed to a relative humidity of 95%, achieved the desired whiteness constancy. Existing slight increases in whiteness up to a storage period under daylight of 90 min are max. 1% absolute and can no longer be determined with the human eye. Similar results were also obtained by dampening the heat-treated paper with water.
Landscapes
- Paper (AREA)
- Catalysts (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Programmable Controllers (AREA)
- Ladders (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT87110651T ATE59070T1 (de) | 1986-09-10 | 1987-07-23 | Verfahren zur beschleunigung der weissgradregeneration hitzebehandelter papiere. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3630772 | 1986-09-10 | ||
| DE19863630772 DE3630772A1 (de) | 1986-09-10 | 1986-09-10 | Verfahren zur beschleunigung der weissgradregeneration hitzebehandelter papiere |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0259584A1 EP0259584A1 (de) | 1988-03-16 |
| EP0259584B1 true EP0259584B1 (de) | 1990-12-12 |
Family
ID=6309275
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP87110651A Expired - Lifetime EP0259584B1 (de) | 1986-09-10 | 1987-07-23 | Verfahren zur Beschleunigung der Weissgradregeneration hitzebehandelter Papiere |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0259584B1 (enExample) |
| AT (1) | ATE59070T1 (enExample) |
| DD (1) | DD262049A5 (enExample) |
| DE (2) | DE3630772A1 (enExample) |
| ES (1) | ES2001747B3 (enExample) |
| FI (1) | FI873772A7 (enExample) |
| NO (1) | NO873765L (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5622259A (en) * | 1995-06-07 | 1997-04-22 | Church; Jonathan M. | Reduction of discoloration in plastic materials |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0120095A1 (en) * | 1982-09-28 | 1984-10-03 | Kanzaki Paper Manufacturing Company Limited | Method of manufacturing cast-coated paper |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3625743A (en) * | 1967-12-12 | 1971-12-07 | Tamotsu Watanabe | Method for impregnating running paper with moisture |
| DE2808931A1 (de) * | 1977-03-04 | 1978-09-07 | Dynachem Corp | Verfahren zum beschichten oder bedrucken eines substrates |
-
1986
- 1986-09-10 DE DE19863630772 patent/DE3630772A1/de active Granted
-
1987
- 1987-07-23 EP EP87110651A patent/EP0259584B1/de not_active Expired - Lifetime
- 1987-07-23 ES ES87110651T patent/ES2001747B3/es not_active Expired - Lifetime
- 1987-07-23 AT AT87110651T patent/ATE59070T1/de not_active IP Right Cessation
- 1987-07-23 DE DE8787110651T patent/DE3766675D1/de not_active Expired - Lifetime
- 1987-08-20 DD DD87306220A patent/DD262049A5/de unknown
- 1987-08-31 FI FI873772A patent/FI873772A7/fi not_active IP Right Cessation
- 1987-09-09 NO NO873765A patent/NO873765L/no unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0120095A1 (en) * | 1982-09-28 | 1984-10-03 | Kanzaki Paper Manufacturing Company Limited | Method of manufacturing cast-coated paper |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3630772C2 (enExample) | 1988-08-11 |
| FI873772A0 (fi) | 1987-08-31 |
| ATE59070T1 (de) | 1990-12-15 |
| DE3630772A1 (de) | 1988-03-24 |
| FI873772L (fi) | 1988-03-11 |
| DD262049A5 (de) | 1988-11-16 |
| DE3766675D1 (de) | 1991-01-24 |
| NO873765D0 (no) | 1987-09-09 |
| ES2001747B3 (es) | 1991-06-01 |
| NO873765L (no) | 1988-03-11 |
| ES2001747A4 (es) | 1988-06-16 |
| EP0259584A1 (de) | 1988-03-16 |
| FI873772A7 (fi) | 1988-03-11 |
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