EP0248822A1 - Reinigungsmittel - Google Patents
ReinigungsmittelInfo
- Publication number
- EP0248822A1 EP0248822A1 EP86906385A EP86906385A EP0248822A1 EP 0248822 A1 EP0248822 A1 EP 0248822A1 EP 86906385 A EP86906385 A EP 86906385A EP 86906385 A EP86906385 A EP 86906385A EP 0248822 A1 EP0248822 A1 EP 0248822A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition according
- composition
- water
- terpenes
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004140 cleaning Methods 0.000 title claims description 4
- 239000000203 mixture Substances 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 235000019499 Citrus oil Nutrition 0.000 claims description 5
- 239000010500 citrus oil Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 2
- 239000012876 carrier material Substances 0.000 claims 2
- 150000003505 terpenes Chemical class 0.000 abstract description 20
- 235000007586 terpenes Nutrition 0.000 abstract description 20
- 239000007788 liquid Substances 0.000 abstract description 5
- 235000020971 citrus fruits Nutrition 0.000 abstract description 4
- 241000207199 Citrus Species 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 3
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 229920001213 Polysorbate 20 Polymers 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- -1 polyoxyethylene Polymers 0.000 description 2
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 2
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 2
- 229940068977 polysorbate 20 Drugs 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 240000000560 Citrus x paradisi Species 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 241001516739 Platonia insignis Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 1
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4993—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
Definitions
- CLEANING PRODUCT This invention relates to products for use in cleaning, and especially for stain removal.
- Citrus oil is useful as a stain remover.
- Citrus 5 oil e.g. orange terpenes, the residue of extraction of perfumery products from citrus fruits, dissolves and thus removes ink or other stains from the skin or from clothing.
- aqueous compositions comprising an antiseptic and a small concentration of a perfume, 25 absorbed in a serrated roll of non-woven paper material, are available in a dispenser for tearing and application as individual "wipes" .
- a composition according to the present invention comprises orange or other citrus fruit terpenes and a 30 solubilising agent which has a HLB-value of at least 10. It has been found that orange terpenes, in such a
- an aqueous composition of the invention can be absorbed in a suitable carrier, e.g. a non-woven paper or other fabric, as in conventional "wipes".
- a suitable carrier e.g. a non-woven paper or other fabric
- the products of the invention provide the effective properties of, say, orange terpenes at an economical level, i.e. at less than 20% w/w, more preferably less than 10% w/w, of the aqueous composition.
- the minimum level of terpenes in the aqueous composition is usually 0.5% w/w, and preferably at least 1% w/w.
- non-aqueous compositions of the invention are storage-stable concentrates well adapted to mere dilution with water, for further use.
- the solubilising agent used in the present invention is an essential component.
- the HLB value of this agent is preferably from 12 to 18, e.g. 13 to 17.
- polyoxyalkylene ester copolymers e.g. polyoxyethylene fatty acid copolymers such as Polysorbate 20 (HLB 16.7) and a polyethylene glycol mono-ester having a molecular weight of about 600, which is a wax-like non-ionic surfactant, e.g. as sold under the trade name Cithrol 6 S (HLB 14) .
- the weight ratio of this component to the terpenes may be, for example, 0.01:10, 0.05:5 or 0.1:1.
- a mixture of HLB>10 surfactants may sometimes be preferred.
- a HLB ⁇ 10 (e.g. 2 to 8) material may be used, e.g. a polyol ester such as glyceryl monostearate.
- Another desirable additive is an amphoteric surfactant such as a low viscosity coconut imadazoline betaine, e.g.
- compositions of the invention may comprise various other ingredients, depending on the desired end use. It will often be desirable to ensure that the composition is topically-acceptable, e.g. for use as a hand cleanser.
- the composition may comprise components such as propylene glycol and a water-soluble lanolin, e.g. an ethoxylated lanolin, for example the hydrophilic wax sold as Solan.
- compositions of the invention It will also often be desirable to include a preservative in compositions of the invention.
- Conventional preservatives may be used; one which has been found to act satisfactorily is a mixture of methyl isothiazolinone and methyl chloroisothiazolinone sold under the trade name Kathon.
- the predominant component of aqueous compositions of the invention is water.
- the amount of water is usually at least 70% w/w and often at least 75% w/w.
- the terpenes often provide the next greatest amount o.f the composition.
- the total amount of solubilising agents and other components may be, for example, 2 to 20% w/w of the composition.
- Aqueous compositions of the invention may be prepared by mixing the terpenes and the solubilising agent together with, if desired, a small proportion of water, to prepare a thick mass. This mass is then mixed with the, or the remaining proportion of the, water, suitably while warming the components of the mixture, to obtain the desired composition.
- An aqueous composition of the invention may be used to impregnate a "log" of absorbent . non-woven material in conventional manner.
- the roll of material can then be dispensed through a conventional "wipe" dispenser, to give one-use tissues or "wipes" which are effective to remove stains from hands or material by virtue of the effective concentration of orange terpenes.
- the following Examples illustrate the invention. All percentages are by weight. Example 1
- Example 1 The procedure of Example 1 was successfully repeated, using grapefruit terpenes rather than orange terpenes.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dermatology (AREA)
- Biomedical Technology (AREA)
- Emergency Medicine (AREA)
- Zoology (AREA)
- Detergent Compositions (AREA)
- Body Washing Hand Wipes And Brushes (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB858526051A GB8526051D0 (en) | 1985-10-22 | 1985-10-22 | Cleaning product |
| GB8526051 | 1985-10-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0248822A1 true EP0248822A1 (de) | 1987-12-16 |
Family
ID=10587079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP86906385A Withdrawn EP0248822A1 (de) | 1985-10-22 | 1986-10-22 | Reinigungsmittel |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0248822A1 (de) |
| JP (1) | JPS63501363A (de) |
| KR (1) | KR880700053A (de) |
| GB (1) | GB8526051D0 (de) |
| WO (1) | WO1987002698A1 (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5025069A (en) * | 1988-12-19 | 1991-06-18 | Kao Corporation | Mild alkyl glycoside-based detergent compositions, further comprising terpene and isothiazolone derivatives |
| CA2062075A1 (en) * | 1991-05-06 | 1992-11-07 | Patrizia Barone | Food safe cleaning composition |
| DE19724106A1 (de) * | 1997-06-07 | 1999-04-01 | Sandner Herbert Dipl Ing | Verfahren zur Vorbehandlung von durch Schweiß verunreinigten Bereichen von Textilien vor einer allgemeinen Reinigung sowie Eiweißlösemittel insbesondere hierfür |
| EP1275370A1 (de) * | 2001-07-13 | 2003-01-15 | Johnson and Johnson GmbH | Eine Folie und eine Lipid- und eine Wasserphase enthaltende, Produkte |
| FR2853325B1 (fr) * | 2003-04-04 | 2007-08-31 | Teinturerie Leschaeve | Composition aqueuse pour nettoyage a sec naturel, procede et appareil de nettoyage a sec |
| SE526170C2 (sv) * | 2003-05-07 | 2005-07-19 | Akzo Nobel Nv | Vattenhaltig komposition innehållande en alkylenoxid addukt, en hexylglukosid och en aktiv nonionisk alkylenoxid addukt som vätmedel |
| GB2405639A (en) * | 2003-09-08 | 2005-03-09 | R Mc Power Recovery Ltd | Metal cleaning compositions |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2262692B1 (de) * | 1974-02-28 | 1977-03-04 | Raffinage Cie Francaise | |
| US4330422A (en) * | 1977-02-01 | 1982-05-18 | Minnesota Mining And Manufacturing Company | Treating composition containing white oil |
| US4414128A (en) * | 1981-06-08 | 1983-11-08 | The Procter & Gamble Company | Liquid detergent compositions |
| US4438009A (en) * | 1981-08-14 | 1984-03-20 | S. C. Johnson & Son, Inc. | Low solvent laundry pre-spotting composition |
| DE3144168A1 (de) * | 1981-11-06 | 1983-05-19 | Robert Cornelius 32750 Longwood Fla. Ghegan | Wasserloses, terpen aus zitrusoel enthaltendes handreinigungsmittel |
| US4530781A (en) * | 1983-10-12 | 1985-07-23 | S. C. Johnson & Son, Inc. | Metastable prespotting composition |
| US4511488A (en) * | 1983-12-05 | 1985-04-16 | Penetone Corporation | D-Limonene based aqueous cleaning compositions |
-
1985
- 1985-10-22 GB GB858526051A patent/GB8526051D0/en active Pending
-
1986
- 1986-10-22 JP JP61505612A patent/JPS63501363A/ja active Pending
- 1986-10-22 WO PCT/GB1986/000652 patent/WO1987002698A1/en not_active Ceased
- 1986-10-22 EP EP86906385A patent/EP0248822A1/de not_active Withdrawn
-
1987
- 1987-06-22 KR KR870700530A patent/KR880700053A/ko not_active Withdrawn
Non-Patent Citations (1)
| Title |
|---|
| See references of WO8702698A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| KR880700053A (ko) | 1988-02-15 |
| GB8526051D0 (en) | 1985-11-27 |
| JPS63501363A (ja) | 1988-05-26 |
| WO1987002698A1 (en) | 1987-05-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): CH DE FR GB IT LI NL SE |
|
| 17P | Request for examination filed |
Effective date: 19871022 |
|
| 17Q | First examination report despatched |
Effective date: 19880706 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19890217 |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: TAYLOR, GEORGE, EDWARD |