EP0247209B1 - Dispositif et procédé de polissage électrochimique de surfaces intérieures de tubes - Google Patents
Dispositif et procédé de polissage électrochimique de surfaces intérieures de tubes Download PDFInfo
- Publication number
- EP0247209B1 EP0247209B1 EP86106812A EP86106812A EP0247209B1 EP 0247209 B1 EP0247209 B1 EP 0247209B1 EP 86106812 A EP86106812 A EP 86106812A EP 86106812 A EP86106812 A EP 86106812A EP 0247209 B1 EP0247209 B1 EP 0247209B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- polishing head
- electrolyte
- dielectric
- cathode
- polishing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005498 polishing Methods 0.000 title claims abstract description 53
- 238000000034 method Methods 0.000 title claims abstract description 14
- 239000003792 electrolyte Substances 0.000 claims abstract description 43
- 238000005554 pickling Methods 0.000 claims abstract description 8
- 244000089486 Phragmites australis subsp australis Species 0.000 description 9
- 239000002184 metal Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F7/00—Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F3/00—Electrolytic etching or polishing
- C25F3/16—Polishing
Definitions
- the invention relates to a device for electrochemical polishing and / or pickling the inner surfaces of pipes with a flowing electrolyte which at least partially passes through a cathode arranged inside the anodically connected pipe, and a corresponding method for electrochemical polishing and / or pickling pipe inner surfaces .
- a device for electropolishing the inner walls of pipes in which a pipe lance is introduced into the pipe, which has a cathodic area between its tip and a retaining ring, the pipe lance with bores for the passage of the electrolyte liquid is provided.
- a device for electropolishing the inner walls of pipes is known from US Pat. No. 3,202,598, a gap being present for the electrolyte between a cathode moving in the pipe and the inner surface of the pipe. In this device, however, no dielectric is printed between the cathode and the inner wall.
- the known methods and devices for electrochemical polishing and / or pickling of inner tube surfaces have the disadvantage that a very high consumption of electrolyte is required for complete filling, flushing and cooling of the tube.
- the gases (hydrogen and oxygen) generated during electrolytic polishing also have to be removed, which likewise results in a very high electrolyte throughput through the tube.
- the invention has for its object to provide a device and a method for electrochemical polishing and / or pickling the inner surfaces of pipes, which enables both a reduction in the amount of electrolyte used and an improvement in the polishing and pickling quality. It is also intended by the invention that a considerably greater variety of electrolyte compositions can be used compared to conventional processes.
- the device according to the invention for solving this problem is characterized by a polishing head which is movable through the tube and has feed lines for the electrolyte and for electric current, a cathode arranged in the interior of the polishing head and a dielectric which at least partially forms the outer wall of the polishing head, the passes the electrolyte stream and leaves a working gap for the electrolyte stream between itself and the pipe inner surface to be polished or to be etched.
- the method according to the invention for solving the problem is characterized in that the electrolyte stream is pumped into a polishing head provided with a cathode and out of it by a dielectric into a working gap formed between the dielectric and the inner surface of the tube.
- a polishing head is thus moved through the tube. It is essential that a so-called working gap is formed between a wall of the polishing head formed from a dielectric and the inner surface of the tube, into which the electrolyte is pressed by the dielectric.
- Electrolytes that can be regenerated via ion exchangers or electrolytic separation cells can be used. It is possible to keep the metal content of the electrolyte so low that the cathode surfaces cannot be passivated by deposited metal sludge.
- the electrolyte stream flowing into the polishing head is divided into an anodic partial stream and a cathodic partial stream, the anodic partial stream passing through the dielectric and the inner surface of the tube, but not the cathode, while the cathodic partial stream passes Cathode, but not the inner surface of the tube.
- the polishing head (12) is slowly moved through the tube 10.
- the polishing head 12 is sometimes also referred to as a "tampon".
- the polishing head 12 is moved through the tube 10 by means of a guide 14, which is designed as a tube with a much smaller diameter than the tube 10 to be cleaned.
- the polishing head 12 is approximately cylindrical and lies concentrically in the pipe 10 to be cleaned.
- the jacket of the cylindrical polishing head 12 is formed by a dielectric 18 which is uniformly spaced from the inner surface 16 of the tube 10.
- the polishing head 12 can be moved in the direction of the arrow 20, that is to say in both directions, through the tube 10.
- the electrolyte flow 22 in FIGS. 1 and 2 enters the polishing head 12 from the right through the guide 14 and in the exemplary embodiment according to FIG. 1 is pressed radially outwards by the dielectric 18 according to the arrows.
- the guide 14 receives the electrical supply lines 25 for the cathodes 26.
- a uniform, narrow working gap 28 is formed between the cylindrical jacket-shaped dielectric outer walls of the polishing head 12 and the inner surface 16 of the tube 10.
- the electrolyte stream 22 'passes through the working gap 28 and, in a known manner, effects the electrochemical removal and polishing on the inner surface 16.
- the electrolyte stream 22 entering the polishing head 12 is divided into a cathodic and an anodic partial stream 30 or 32.
- the cathodic partial stream 30 passes only the cathodes 26, but not the dielectric 18 and the working gap 28.
- the hydrogen gas formed on the cathodes 26 does not reach the dielectric 18 and also not to the inner surface 16 to be polished, which on the one hand prevents that Dielectric 18 is loaded with hydrogen gas and on the other hand harmful effects of the hydrogen on the inner surface 16 are avoided.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Claims (8)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP86106812A EP0247209B1 (fr) | 1986-05-20 | 1986-05-20 | Dispositif et procédé de polissage électrochimique de surfaces intérieures de tubes |
AT86106812T ATE54681T1 (de) | 1986-05-20 | 1986-05-20 | Vorrichtung und verfahren zum elektrochemischen polieren der innenflaechen von rohren. |
DE8686106812T DE3672831D1 (de) | 1986-05-20 | 1986-05-20 | Vorrichtung und verfahren zum elektrochemischen polieren der innenflaechen von rohren. |
US07/047,653 US4772367A (en) | 1986-05-20 | 1987-05-08 | Apparatus for and a method of electrochemically polishing pipe inside surfaces |
JP62120323A JPH0765240B2 (ja) | 1986-05-20 | 1987-05-19 | 管の内面を電気化学的に研摩および/または酸洗する方法および装置 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP86106812A EP0247209B1 (fr) | 1986-05-20 | 1986-05-20 | Dispositif et procédé de polissage électrochimique de surfaces intérieures de tubes |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0247209A1 EP0247209A1 (fr) | 1987-12-02 |
EP0247209B1 true EP0247209B1 (fr) | 1990-07-18 |
Family
ID=8195133
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86106812A Expired - Lifetime EP0247209B1 (fr) | 1986-05-20 | 1986-05-20 | Dispositif et procédé de polissage électrochimique de surfaces intérieures de tubes |
Country Status (5)
Country | Link |
---|---|
US (1) | US4772367A (fr) |
EP (1) | EP0247209B1 (fr) |
JP (1) | JPH0765240B2 (fr) |
AT (1) | ATE54681T1 (fr) |
DE (1) | DE3672831D1 (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8201619B2 (en) | 2005-12-21 | 2012-06-19 | Exxonmobil Research & Engineering Company | Corrosion resistant material for reduced fouling, a heat transfer component having reduced fouling and a method for reducing fouling in a refinery |
US8286695B2 (en) | 2005-12-21 | 2012-10-16 | Exxonmobil Research & Engineering Company | Insert and method for reducing fouling in a process stream |
DE102016100558A1 (de) * | 2016-01-14 | 2017-07-20 | Plasotec Gmbh | Polierkopf und Verfahren zum Plasmapolieren einer Innenfläche eines Werkstücks |
EP4309811A1 (fr) * | 2022-07-18 | 2024-01-24 | Hammann GmbH | Procédé d'élimination électromécanique des dépôts dans les conduites tubulaire ou les appareils |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0730692Y2 (ja) * | 1988-11-14 | 1995-07-12 | 石川島播磨重工業株式会社 | 小口径管内面の電解腐食装置 |
JPH0794090B2 (ja) * | 1989-11-01 | 1995-10-11 | 工業技術院長 | 小径管内面の電解砥粒超鏡面仕上げ方法 |
JPH06959B2 (ja) * | 1989-11-22 | 1994-01-05 | 工業技術院長 | 高速電解粗仕上げ法 |
US5413463A (en) * | 1991-12-30 | 1995-05-09 | General Electric Company | Turbulated cooling passages in gas turbine buckets |
US5320721A (en) * | 1993-01-19 | 1994-06-14 | Corning Incorporated | Shaped-tube electrolytic polishing process |
US5507923A (en) * | 1993-11-09 | 1996-04-16 | Stouse; Henry J. | Method and apparatus for electrolytic polishing of tubular products |
US5819400A (en) * | 1996-06-25 | 1998-10-13 | Smith & Wesson Corp. | Method of manufacturing an electrode assembly for electrochemically etching rifling in gun barrels |
US6168691B1 (en) * | 1996-08-09 | 2001-01-02 | Atotech Deutschland Gmbh | Device for electrochemical treatment of elongate articles |
US6217726B1 (en) * | 1997-05-22 | 2001-04-17 | Therma Corporation, Inc. | Tube inner surface electropolishing device with electrolyte dam |
US5958195A (en) * | 1997-05-22 | 1999-09-28 | Therma Corporation, Inc. | Tube inner surface electropolishing device |
JPH11138350A (ja) * | 1997-11-10 | 1999-05-25 | Kobe Steel Ltd | アルミ中空押出形材の円筒部内面の研磨方法及び装置並びにアルミ中空押出形材 |
IT1311147B1 (it) * | 1999-11-04 | 2002-03-04 | Edk Res Ag | Macchina per pulizia localizzata con cella, elettrolitica e/o adultrasuoni, di decapaggio e/o lucidatura |
US6402908B1 (en) | 2000-02-02 | 2002-06-11 | Therma Corporation, Inc. | Pipe electropolishing apparatus using an electrolyte heater and cooler |
US6277264B1 (en) | 2000-02-02 | 2001-08-21 | Therma Corporation, Inc. | System and method for using multiple lead connections in an electropolishing process |
US6547950B1 (en) | 2000-02-02 | 2003-04-15 | Therma Corporation, Inc. | Cathode rinsing station and method |
US6523615B2 (en) | 2000-03-31 | 2003-02-25 | John Gandy Corporation | Electropolishing method for oil field tubular goods and drill pipe |
US6712668B2 (en) | 2000-12-06 | 2004-03-30 | Therma Corporation, Inc. | System and method for electropolishing nonuniform pipes |
US6428681B1 (en) | 2000-12-06 | 2002-08-06 | Therma Corporation, Inc. | System and method for reversing electrolyte flow during an electropolishing operation |
TW572063U (en) * | 2001-11-28 | 2004-01-11 | Ind Tech Res Inst | An electropolishing process means for an inner surface of a long tube |
TW530717U (en) * | 2001-12-13 | 2003-05-01 | Ind Tech Res Inst | An apparatus for electrolyzing polishing/grinding internal surface of long tube |
US8492489B2 (en) | 2004-02-13 | 2013-07-23 | Total Petrochemicals Research Feluy | Double loop technology |
WO2010142550A1 (fr) * | 2009-06-08 | 2010-12-16 | Novo Nordisk A/S | Procédé de fabrication d'une canule à aiguille dont les propriétés d'écoulement sont améliorées |
US20190177872A1 (en) * | 2016-06-21 | 2019-06-13 | Extrude Hone Gmbh | Electrolytic polishing method and device and method for producing a cathode |
US10864567B2 (en) | 2018-04-17 | 2020-12-15 | Government Of The United States As Represented By The Secretary Of The Army | Systems and methods for electroprocessing a gun barrel using a moving electrode |
CN115122227B (zh) * | 2022-06-20 | 2023-06-27 | 沈阳理工大学 | 一种金属管类零件异形截面螺旋深孔内表面移动式等离子电化学抛光装置 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2764540A (en) * | 1952-09-10 | 1956-09-25 | William G Farin | Method and means for electropolishing inner surfaces |
DE1202607B (de) * | 1961-01-20 | 1965-10-07 | Nyby Bruk Ab | Verfahren zur anodischen Oberflaechenbehandlung von Metallgegenstaenden |
US3202598A (en) * | 1963-03-22 | 1965-08-24 | Titanium Metals Corp | Electrolytic polishing tool |
DE1496727B2 (de) * | 1963-06-18 | 1972-03-02 | Benteler Werke AG, Werk Neuhaus, 4794 Schloß Neuhaus | Verfahren zur elektrolytischen behandlung der innen und aussenflaeche von rohren |
JPS5691380U (fr) * | 1979-12-14 | 1981-07-21 | ||
US4369101A (en) * | 1980-05-02 | 1983-01-18 | Nukem Gmbh | Apparatus for electropolishing tubes |
JPS6050878A (ja) * | 1983-08-30 | 1985-03-20 | 日本電気株式会社 | コネクタ |
DE3343396A1 (de) * | 1983-11-30 | 1985-06-05 | Kraftwerk Union AG, 4330 Mülheim | Verfahren zum dekontaminieren metallischer komponenten einer kerntechnischen anlage |
FR2561672B1 (fr) * | 1984-03-21 | 1989-09-01 | Travaux Milieu Ionisant | Dispositif d'electrolyse, utilisable notamment pour la decontamination radioactive de surfaces metalliques |
US4601802A (en) * | 1984-07-31 | 1986-07-22 | The Upjohn Company | Apparatus for internally electropolishing tubes |
-
1986
- 1986-05-20 EP EP86106812A patent/EP0247209B1/fr not_active Expired - Lifetime
- 1986-05-20 AT AT86106812T patent/ATE54681T1/de active
- 1986-05-20 DE DE8686106812T patent/DE3672831D1/de not_active Expired - Fee Related
-
1987
- 1987-05-08 US US07/047,653 patent/US4772367A/en not_active Expired - Fee Related
- 1987-05-19 JP JP62120323A patent/JPH0765240B2/ja not_active Expired - Lifetime
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8201619B2 (en) | 2005-12-21 | 2012-06-19 | Exxonmobil Research & Engineering Company | Corrosion resistant material for reduced fouling, a heat transfer component having reduced fouling and a method for reducing fouling in a refinery |
US8286695B2 (en) | 2005-12-21 | 2012-10-16 | Exxonmobil Research & Engineering Company | Insert and method for reducing fouling in a process stream |
US8469081B2 (en) | 2005-12-21 | 2013-06-25 | Exxonmobil Research And Engineering Company | Corrosion resistant material for reduced fouling, a heat transfer component having reduced fouling and a method for reducing fouling in a refinery |
DE102016100558A1 (de) * | 2016-01-14 | 2017-07-20 | Plasotec Gmbh | Polierkopf und Verfahren zum Plasmapolieren einer Innenfläche eines Werkstücks |
DE102016100558B4 (de) | 2016-01-14 | 2023-08-10 | Plasotec Gmbh | Polierkopf und Verfahren zum Plasmapolieren einer Innenfläche eines Werkstücks |
EP4309811A1 (fr) * | 2022-07-18 | 2024-01-24 | Hammann GmbH | Procédé d'élimination électromécanique des dépôts dans les conduites tubulaire ou les appareils |
Also Published As
Publication number | Publication date |
---|---|
JPS62290899A (ja) | 1987-12-17 |
JPH0765240B2 (ja) | 1995-07-12 |
EP0247209A1 (fr) | 1987-12-02 |
US4772367A (en) | 1988-09-20 |
DE3672831D1 (de) | 1990-08-23 |
ATE54681T1 (de) | 1990-08-15 |
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