EP0235291A4 - Verfahren zur herstellung von vanadiumschlacke. - Google Patents
Verfahren zur herstellung von vanadiumschlacke.Info
- Publication number
- EP0235291A4 EP0235291A4 EP19860900680 EP86900680A EP0235291A4 EP 0235291 A4 EP0235291 A4 EP 0235291A4 EP 19860900680 EP19860900680 EP 19860900680 EP 86900680 A EP86900680 A EP 86900680A EP 0235291 A4 EP0235291 A4 EP 0235291A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- oxide
- vanadium
- iron
- slag
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052720 vanadium Inorganic materials 0.000 title claims description 132
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title claims description 130
- 239000002893 slag Substances 0.000 title claims description 88
- 238000000034 method Methods 0.000 title claims description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 80
- 229910052751 metal Inorganic materials 0.000 claims description 55
- 239000002184 metal Substances 0.000 claims description 55
- 229910001018 Cast iron Inorganic materials 0.000 claims description 54
- 239000000203 mixture Substances 0.000 claims description 47
- 229910052742 iron Inorganic materials 0.000 claims description 41
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 33
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
- 229910052799 carbon Inorganic materials 0.000 claims description 18
- 239000008187 granular material Substances 0.000 claims description 14
- 229910000831 Steel Inorganic materials 0.000 claims description 13
- 239000010959 steel Substances 0.000 claims description 13
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 12
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 12
- 239000011575 calcium Substances 0.000 claims description 12
- 229910052791 calcium Inorganic materials 0.000 claims description 12
- 229910052748 manganese Inorganic materials 0.000 claims description 12
- 239000011572 manganese Substances 0.000 claims description 12
- 229910001935 vanadium oxide Inorganic materials 0.000 claims description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims description 10
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 10
- 239000010936 titanium Substances 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- 239000011521 glass Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000007800 oxidant agent Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 239000011029 spinel Substances 0.000 claims description 5
- 229910052596 spinel Inorganic materials 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000292 calcium oxide Substances 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- -1 brown Chemical compound 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 239000010450 olivine Substances 0.000 claims description 2
- 229910052609 olivine Inorganic materials 0.000 claims description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 229940098465 tincture Drugs 0.000 claims 1
- 238000007664 blowing Methods 0.000 description 21
- 239000002253 acid Substances 0.000 description 16
- 235000013980 iron oxide Nutrition 0.000 description 16
- 230000008569 process Effects 0.000 description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 239000000155 melt Substances 0.000 description 5
- 229910000805 Pig iron Inorganic materials 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 241000207836 Olea <angiosperm> Species 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910002090 carbon oxide Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- LIDGFHXPUOJZMK-UHFFFAOYSA-N 2,6-dimethyl-1-oxidopyridin-1-ium Chemical compound CC1=CC=CC(C)=[N+]1[O-] LIDGFHXPUOJZMK-UHFFFAOYSA-N 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229910000756 V alloy Inorganic materials 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 238000003339 best practice Methods 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- PNXOJQQRXBVKEX-UHFFFAOYSA-N iron vanadium Chemical compound [V].[Fe] PNXOJQQRXBVKEX-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/36—Processes yielding slags of special composition
Definitions
- ⁇ anadaevy shla ⁇ ⁇ luchaemy ⁇ i ⁇ islvnii vayaadays ⁇ de ⁇ zhaschi ⁇ chuguya ⁇ v in ⁇ nve ⁇ e ⁇ a ⁇ or d ⁇ u ⁇ i ⁇ ag ⁇ ega ⁇ a ⁇
- yavlyae ⁇ sya is ⁇ dnym sy ⁇ em for ⁇ lucheniya ⁇ en ⁇ sida vanadium ⁇ y ⁇ eimusches ⁇ venn ⁇ is ⁇ l- zue ⁇ sya in che ⁇ n ⁇ y me ⁇ allu ⁇ gii for ⁇ lucheniya ⁇ e ⁇ va- vanadium and d ⁇ u ⁇ i ⁇ , b ⁇ ga ⁇ y ⁇ vanadaem, s ⁇ lav ⁇ v.
- vayaadya slag which is not suitable for the manufacture of light metal vanadium, steel, alloys.
- the resulting vanadium slag was produced in bulk: vanadium oxide -27.8 oxide of oxide - 17.3 iron oxide -22.4 oxide of aluminum * 3.5 oxide of calcium-0.5 carbon oxide - 3.5 magnesium oxide - 0.3 impurities - other
- vanadium cast iron is not available; vanadium slurry is removed;
- Advantages of this benefit from the Canada 20 slag are that the combination of alkali and carbon oxides results in an improvement in the rate of improvement.
- the average size of the vanadium slag is increasing, which is the size of the largest, vanadium-containing slag.
- Another effect of 25 seconds of the influence of these components is the generation of a pure spinelide microstructure.
- the proposed vanadium slag is produced - 7 - b ⁇ m, v ⁇ lyuchayuschim zaliv ⁇ u in ⁇ nve ⁇ te ⁇ vanadg- ⁇ ev ⁇ g ⁇ iron i ⁇ isad ⁇ u zhelez ⁇ s ⁇ de ⁇ naschi ⁇ and (id ⁇ ) ⁇ lyusuyuschi ⁇ ⁇ m ⁇ nen ⁇ v, ⁇ duv ⁇ u u ⁇ azann ⁇ g ⁇ iron gaz ⁇ b ⁇ az- 5 nym ⁇ isli ⁇ elem with ⁇ lucheniem ⁇ lu ⁇ du ⁇ a and whether or s ⁇ a- ⁇ anadiev ⁇ g ⁇ ⁇ la ⁇ a, ⁇ y, s ⁇ glasn ⁇ iz ⁇ b ⁇ e ⁇ e- NIJ, ⁇ a ⁇ a ⁇ e ⁇ izue ⁇ sya That is, in most cases, the original Canada cast iron is used by the cast iron of the following United States of America mass #: U vanadium 0.35-0.90 ⁇ m
- the Canada slag composition as indicated above, is obtained from vanadium cast iron by its oxidation by a gas oxidizing agent. We found that the indicated slag composition is shared chemically
- composition of cast iron which, according to the invention, is as indicated above, the following composition of the masses. : vanadium 0.35-0.90, ⁇ dite ⁇ 0.02-0.10 carbon ores 3.8-4.8 copper 0.0 -0.32 ⁇ cr
- Cast iron is usually smelted in ordinary ordinary furnaces, but also in small useful ones.
- vanadium cast iron has a composition of 5 va, as indicated above, poured into.
- a gaseous oxidizer such as an acid
- the predominantly magnetic fraction of vanadium sludge in the mixture is limited by the time of its dissolution.
- the vanadium cast iron is poured on the burner after 15 other compositions: mass. $: 4,2-4, C; 0.10-0, 2051; 0.40-0, 60 V; 0.10-0, 20 ⁇ , 0.10-0.20 ⁇ ? 0.05-0.15 Cg; 0,03-0,06- ?; 0.02-0.0433; 0.08-0, ⁇ 2 ⁇ ; 0.08-0, ⁇ 2 ⁇ 1; 0.001-0.12 C ⁇ .
- Personally cast iron should be provided with a 20-unit area to prevent irradiation. in ⁇ days, 0.15-0.25 m / ⁇ .
- the cast iron machine after filling in the pan, is ⁇ 270- ⁇ 280 ° ⁇ .
- nav ⁇ d ⁇ i shla ⁇ a is ⁇ lzuyu ⁇ shla- mixture ⁇ b ⁇ azuyuschuyu d s ⁇ de ⁇ zhaschuyu wt. 25 heavy vanadium-containing hydrocarbons 3.0-5.0 magnetic fraction of vanadium-slag 15-20 calcined glass other
- the resulting metal product is drained to the bottom through a failure, and the vanadium slag is delivered to the vessel.
- the described cycle transfers and after the end of the blowing of acid, the metal is blown away with argon or other inert gas with a minimum of 2.0 or less.
- the grains of the vanadium spinelide are crystallized in the form of suitable geo- logical bodies, and their size is 30-60 microns.
- the resulting metal after draining, processes slag-forming mixtures and liquefies or uses yutas for making steel in the iron ore furnace.
- vanadium cast iron was poured, containing mass. : 3.8-C; 0.35 - 31; 0.35 - ⁇ ; 5 0.07- ⁇ ; 0.12 - ⁇ ; 0.03 - Cr; 0,02 - ⁇
- the pig iron was ⁇ 300 ° ⁇ .
- the intensity of the supplied oxygen was 3 m 3 / ⁇ “min, and the specific sewing capacity of 15 liquid metal was 0.3 m 3 / ⁇ .
- vanadium oxide - 16 vanadium oxide - 16; acid oxide - 24, manganese oxide - 6; oxides ⁇ ma - I; titanium oxide - 6 calcium oxide - 0.3; granules of metallic iron - 8; Iron Oxide - Other.
- the mineralogical composition was as follows, - 18 - mass. : spinelid-40; glass 2; ⁇ i ⁇ sen and olivine-58.
- the size of the vanadium spinelida grains was approximately 25–35 ⁇ m, and, moreover, they have a capacity of 5 geometrical bodies.
- the slag accumulated from the two feeds contained the masses: vanadium oxide-20.4; acid oxide; -14.2; manganese oxide-10.4; oxycid ⁇ ma-2,; 35 oxy ⁇ titanium-8.6; calcium oxide-1.5; granules of metal iron-10.2, oxide of iron - the rest.
- Its auger system was as follows: - 19 - wt.% Pyrphenylide - 55, glass - 5; There are 40 springs and rivulets.
- the size of the vanadium spinelida is 30–40 ⁇ m. They are very crystalline and have a well-functioning factory. 5 The degree of vanishing of vanadium was 94.3%.
- vanadium oxide - 30 (of the one part), comprised the masses,%: vanadium oxide - 30; acid oxide - 10; manganese oxide - 6.4; titanium oxide - 7, 4; Oxide ⁇ court - 12; calcium oxide - 2.1; granules of metallic iron - 6.2; alkali metal oxide - 9, 0; carbon ratio - 0, 1; Iron Oxide - Other.
- the mineralogical composition was as follows, mass. : sh ⁇ inelid-70; glass- ⁇ ; ⁇ i ⁇ sen and olivine-20.
- the grain size of the vanadium spinelide was approximately 30–50 ⁇ m and had a correct shape.
- the degree of dismissal of the occupation was 95.
- the degree of separation of the slag is 97%.
- vanadium recovered from cast iron to 92% slag.
- the vanadium Before cast iron pouring, the vanadium was installed in the amount of 92 kg / t. The separate area of the bathtub was 0.24 m / t. the intensity supplied from the bottom of the air (in terms of oxygen) was 3 m / t.min.
- the temperature was ⁇ 4 ⁇ 0 ° ⁇ , and the content of vanadium and carbon in it was equal to, mass%: 0.03 and 2.6.
- the pig iron furnace in the inverter was 80280 ° ⁇ .
- the yield of cast iron isadil is a slag-friendly mixture of the following mass composition ⁇ : heavy hydrocarbons-4,2; magnetic fraction of vanadium slag - $ 15; The downstream hookah is the rest.
- the mixture yield was 62 kg / ⁇ .
- Intensity of the supply of acid 15 at the turn-over of the metal from the above through wet water was 1.5 m 3 / t.min.
- the specific surface area of the metal was • 0.18 m 2 / t.
- the metal After the end of the blowdown, the metal had a temperature of 20 ° C at 470 ° C, and the content of vanadium and carbon in the metal after the end of the devavation was 0.03 and g_g%.
- the metal was merged, and the slag was delivered completely in the process and the operation was reversed or the same as the original 2 parameters.
- the metal smelter in the second smelter was 1480 ° C and the same vanadium content. Carbon content was reduced to 2.1.
- the size of the grain of spinelide was 40-60 microns. - 22 -
- the cast iron was filled with 162 ⁇ of cast iron, which was also 5 composition, which was also performed in step 5.
- the cast iron filler was ⁇ 275 ° ⁇ .
- the provincial government introduced 6.5 ⁇ (4) steel bar.
- the intensity of the supplied oxygen was 2.5 m 3 / t.min, while the specific area was 10% of the metal 0.18 m / t.
- the metal After 6 minutes ($ 25 at the time of injection), the metal was replaced with 7.2 ⁇ (4.5) oxides and continued to be charged with the same intensity. 15 At the end of the blowdown, the metal comprised $ 0.12 C and $ 0.01 ⁇ and a temperature of ⁇ 650 ° ⁇ . The degree of deletion of vanadium was in this version 98.2. Likewise, the masses of $: oxides of vanadium-$ 28.4; oxycid ⁇ menia- ⁇ 8, ⁇ ; manganese oxide-8.2; titanium oxide-10.8; 20 oxycid ⁇ ma-2,3; Oxide Calcium-1.4; granules of metallic iron-3.2; Iron oxide is other.
- Example 7 30 taxable nostically wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome wholesome ⁇ 275 ° ⁇ . In the forefront, they pre-paid 1.6 t ($ 1) of steel steel.
- the intensity of the supplied overhead oxygen 35 was 2.5 m 3 / t.min. and the specific area of the earth became 0.20 m / ⁇ . - 23 - After 3 minutes of blowing (15 times during blowing), they planted 9.6 ⁇ of burns ($ 6) and went on blowing.
- the organic composition of the slag remained the same, the size of the spinel grains of the correct form was 60-80 microns.
- the metal has a temperature of ⁇ 620 ° ⁇ and contains ' ,. $ 0.44 C, 0.04 ⁇ and $ 0.028 ⁇ .
- the slag contained the masses: 26.8- vanadium oxide; 14, 1-oxide ⁇ pamnium, iron granule -3, 8; calcium oxide-6.4; iron oxide-18, 6; oxides ⁇ , Cr, ⁇ -other.
- the degree of mismatch 5 vanadium amounted to 89, 5 $.
- the inventive invention may be used in the case of a black metal and in the processing of titanium-magnetic material without iron. 10
- a method of compartmentalizing the device and successfully failing to be implemented in existing processes is inadequate. 25 Use, and also the use of the proposed products gives a significant economy of the original reaction.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/SU1985/000072 WO1987001136A1 (en) | 1985-08-22 | 1985-08-22 | Vanadium slag and method for obtaining it |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0235291A1 EP0235291A1 (de) | 1987-09-09 |
| EP0235291A4 true EP0235291A4 (de) | 1988-01-20 |
| EP0235291B1 EP0235291B1 (de) | 1990-02-07 |
Family
ID=21616937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19860900680 Expired - Lifetime EP0235291B1 (de) | 1985-08-22 | 1985-08-22 | Verfahren zur herstellung von vanadiumschlacke |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0235291B1 (de) |
| JP (1) | JPS63500873A (de) |
| DE (1) | DE3575949D1 (de) |
| WO (1) | WO1987001136A1 (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR007955A1 (es) * | 1996-07-24 | 1999-11-24 | Holderbank Financ Glarus | Procedimiento para separar titanio y/o vanadio de hierro bruto |
| KR20020057680A (ko) * | 2001-01-03 | 2002-07-12 | 최한천 | 오산화 바나듐 브리케트 제조방법 |
| DE102007001098A1 (de) * | 2007-01-04 | 2008-07-10 | Sms Demag Ag | Verfahren und Anlage zur Erzeugung von Stahl |
| RU2442827C2 (ru) * | 2010-01-11 | 2012-02-20 | Открытое акционерное общество "ЕВРАЗ Нижнетагильский металлургический комбинат" (ОАО "ЕВРАЗ НТМК") | Способ извлечения ванадия при конвертерном переделе природно-легированного чугуна |
| RU2465338C2 (ru) * | 2010-08-24 | 2012-10-27 | Открытое акционерное общество "ЕВРАЗ Нижнетагильский металлургический комбинат" (ОАО "ЕВРАЗ НТМК") | Способ повышения степени извлечения ванадия при конвертировании природно-легированных чугунов |
| RU2656125C2 (ru) * | 2016-05-04 | 2018-06-01 | Акционерное общество "ЕВРАЗ Нижнетагильский металлургический комбинат", (АО "ЕВРАЗ НТМК") | Способ получения твердого чугуна |
| RU2641436C1 (ru) * | 2016-10-06 | 2018-01-17 | Открытое акционерное общество "ЕВРАЗ Нижнетагильский металлургический комбинат", ОАО "ЕВРАЗ НТМК" | Способ извлечения ванадия из природнолегированного ванадиевого чугуна |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1598744A (de) * | 1968-12-26 | 1970-07-06 | ||
| DE2509650A1 (de) * | 1975-03-05 | 1976-09-16 | Tsnii Tschernoj Metallurg Im I | Verfahren zur herstellung von legierungen, enthaltend vanadin |
| DE2810458A1 (de) * | 1978-03-10 | 1979-09-20 | N Proizv Ob Tulatschermet | Verfahren zur herstellung von ferrovanadin-legierungen |
| DE3006287A1 (de) * | 1980-02-20 | 1981-10-08 | Stahlwerke Peine-Salzgitter Ag, 3150 Peine | Verfahren zur gewinnung von vanadinpentoxid-hydrat und duengemittel aus fluessigem, phosphorhaltigem roheisen mit einem siliziumgehalt von kleiner/gleich 0,1% |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE878501C (de) * | 1951-05-10 | 1953-06-05 | Huettenwerke Phoenix Ag | Verfahren zum Frischen von Thomasroheisen, bei dem eine vanadinreiche Schlacke gewonnen wird |
| NO115556B (de) * | 1967-05-31 | 1968-10-21 | Christiania Spigerverk | |
| SU1067057A1 (ru) * | 1982-10-25 | 1984-01-15 | Нижнетагильский металлургический комбинат | Флюс дл обработки ванадийсодержащего чугуна |
-
1985
- 1985-08-22 DE DE8686900680T patent/DE3575949D1/de not_active Expired - Fee Related
- 1985-08-22 WO PCT/SU1985/000072 patent/WO1987001136A1/ru active IP Right Grant
- 1985-08-22 EP EP19860900680 patent/EP0235291B1/de not_active Expired - Lifetime
- 1985-08-22 JP JP86500587A patent/JPS63500873A/ja active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1598744A (de) * | 1968-12-26 | 1970-07-06 | ||
| DE2509650A1 (de) * | 1975-03-05 | 1976-09-16 | Tsnii Tschernoj Metallurg Im I | Verfahren zur herstellung von legierungen, enthaltend vanadin |
| DE2810458A1 (de) * | 1978-03-10 | 1979-09-20 | N Proizv Ob Tulatschermet | Verfahren zur herstellung von ferrovanadin-legierungen |
| DE3006287A1 (de) * | 1980-02-20 | 1981-10-08 | Stahlwerke Peine-Salzgitter Ag, 3150 Peine | Verfahren zur gewinnung von vanadinpentoxid-hydrat und duengemittel aus fluessigem, phosphorhaltigem roheisen mit einem siliziumgehalt von kleiner/gleich 0,1% |
Non-Patent Citations (1)
| Title |
|---|
| See also references of WO8701136A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3575949D1 (de) | 1990-03-15 |
| WO1987001136A1 (en) | 1987-02-26 |
| JPS63500873A (ja) | 1988-03-31 |
| EP0235291A1 (de) | 1987-09-09 |
| EP0235291B1 (de) | 1990-02-07 |
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