EP0228401A1 - Anti-corrosive pigment composition and process for producing the same - Google Patents

Anti-corrosive pigment composition and process for producing the same

Info

Publication number
EP0228401A1
EP0228401A1 EP86903537A EP86903537A EP0228401A1 EP 0228401 A1 EP0228401 A1 EP 0228401A1 EP 86903537 A EP86903537 A EP 86903537A EP 86903537 A EP86903537 A EP 86903537A EP 0228401 A1 EP0228401 A1 EP 0228401A1
Authority
EP
European Patent Office
Prior art keywords
weight
parts
pigment composition
alumina hydrate
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP86903537A
Other languages
German (de)
English (en)
French (fr)
Inventor
Zsolt Csillag
Tibor Kalman
László KIRALY
Béla KONIORCZYK
Tibor Legat
Lajos Patyi
Géza SZENTGYÖRGYI
László ZSEMBERY
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kemical Epitoanyagipari Vallalat
Magyar Aluminiumipari Troeszt
Original Assignee
Kemical Epitoanyagipari Vallalat
Magyar Aluminiumipari Troeszt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kemical Epitoanyagipari Vallalat, Magyar Aluminiumipari Troeszt filed Critical Kemical Epitoanyagipari Vallalat
Publication of EP0228401A1 publication Critical patent/EP0228401A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/082Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084Inorganic compounds

Definitions

  • Anti-corrosive pigment composition and process for producing the same
  • the invention relates to an active anti-corrosive pigment composition which may be used for the purposes of dyestuff and varnish industry,-primarily for the production of dyestuffs and lutes, as well as corrosion protecting coatings. Further the invention relates to the process for • producing the active anti-corrosive pigment composition.
  • the subject of the invention is an active corrosion protec ⁇ tive pigment composition which comprises: a/ alumina hydrate /Al/OH/.,/, b/ an amount of 10-100 parts by weight of at least one of the atoxic oxides, hydroxides, oxide hydroxides, carbonates or phosphates of amphoteric elements or metals of variable valency possessing less valency than the maximum - in case of aluminium the appropriate oxide of oxide hydroxide - related to lOO parts by weight of alumina hydrate c/ an amount of 0-40 parts by weight of.calcium and/or magnesium carbonate related to 100 parts by weight of alumina hydrate, and its grain size is less than 20 ,um.
  • the object of the invention is providing a pigment compositio which meets the foregoing requirements and is usable in any of the conventional corrosion protecting coatings and can be applied to the surface to be protected by the usual pro ⁇ cedures, respectively.
  • the active corrosion protective pigment composition comprises: a/ alumina hydrate /A1/0H/.,/, b/ an amount of 10-100 parts by weight of at least one of the amphoteric elements or atoxic oxides, hydroxides, oxide hydroxides, carbonates or phosphates of metals of variable valency possessing less valency than the maximum - in case of aluminium the appropriate oxide of oxide hyd- roxide - related to 100 parts by weight of alumina hydrate, c/ calcium and/or magnesium carbonate an amount of 0-40 parts by weight of related to 100 parts by weight of alumina hydrate, and its grain size is less than 20 ,um.
  • atoxic compounds from the point of view of the invention compounds are meant which, applied in addition to alumina hydrate in a ratio usual in the surface protecting coatings
  • the pigment composition ac ⁇ cording to the invention comprises advantageously alumina
  • 15 amount may range up to 60 weight percent of the lot.
  • the pigment composition according to the invention comprises advantageously as component b/ the above enumerated compound of metals which for* stable oxides, hydroxides and oxide hydroxides equally.
  • metals are primarily aluminium, iro
  • the pigment composition accor ⁇ ding to the invention may also comprise the above determined compounds of any other amphoteric elements, e.g. zinc or any other metal of variable valency, i.e. tin, cobalt or copper.
  • the compounds enumerated as components b/ may be industrially produced meterials, possibly industrial by ⁇ products of wastes, however, they are preferably natural mi neral substances. The latter are of particular advantage if ' severeal compounds enumerated as components b/ are contained
  • component b/ of the pigment composition according to the invention the following metarials have been considered to be of advantage: various kinds of bauxites, e.g. gibbsite-, goethite, hematite and particularly siderite bauxites, more ⁇ over, boehmite /AlO/OK//, magnetite /Fe.,0./, siderite /FeCO ⁇ / lepidocrocite / V-' -FeO/OH//, anganite / L ⁇ -Mn/OH/, rhodo- crosite .nCO-./, oyrolusite / .' -Mn0 / and zinc pho ⁇ nhate.
  • gibbsite- gibbsite-, goethite, hematite and particularly siderite bauxites
  • Natural mineral substances which comprise compounds of se ⁇ veral metals are also cinsidered to be advantageous. Con ⁇ sequently for instance, jacobsite / nFe-0./,franklinite /ZnFe-O./ or chromite /FeCrcard0 4 / may advantageously be used for components b/ of the pigment composition according to the invention.
  • the pigment composition according to the invention comprises at least one of the compounds ranked into the lot of components b/. If there is only one compound as component b/ in the composition, its amount is prefe ⁇ rably about 10-50 parts by weight related to 100 parts by weight of alumina hydrate. Were there more compounds cons ⁇ tituting component b/, their amount should preferably come to 20-90 parts- by weight related to 100 parts by weight of alumina hydrate. If there are no restrictions from other consideration, e.g. stipulations for a certain colour, it is advantageous to use a mixture of several compounds for com- . ponent b/.
  • a pigment composition could be of advantage which comprises also calcium and/or magnesium carbonate in an amount of up to 40 parts by weight related to 100 parts by weight of alumina hydrate, beside the com- ponents-a/ and b/ outlined above.
  • These compounds are advan ⁇ tageously also natural mineral substances.
  • the composition advantageously comprises limestone, dolomite, precipitated chalk or chalkstone or verious mistures of the substances enumerated.
  • the grain size of the pigment composition is of importance from the point of view of the use of pigment composition according to the invention and the corrosion preventing effect of. coating materials comprising such pigment.
  • the grain size of the pigment can be maximum 20 ,um. It is preferred, however, that the pigment comprises grains smal ⁇ ler than 10,urn, advantageously those smaller than- 5 ; m. Fine grains of this kind can, of course, be produced by grinding the substance under- appropriate conditions.
  • the aim of the process according to the invention is assu ⁇ ring partly the grain size mentioned above, partly the perfect homogeneity of the components.
  • the pig-ment composition according to the invention is made in a way that preground products having a grain size of subs ⁇ tantially 160-200 ,um are made from components b/ and c/, respectively, the preground products and the alumina hyd ⁇ rate are individually dried to contain a moisture amount less than 1 weight % each, then they are admixed in a ratio required, then homogenized and finally ground to a grain siz less than 20 ,um, advantageously less than 10 ,um, however, most preferably less than 5 ,um.
  • addition of an anti-corrosive inhibitor to the . components during grin ⁇ ding may be advantageous.
  • a 2-10 weight % aqueous solution of an alkyl pyridiniu ⁇ halide , preferably cetyl pyridinium bromide or some kind of other known anti- -corrosive inhibitor is sprayed into the substances.
  • Pregrinding, drying, admeasuring and ho ogenization of the compoments may be carried out by the usual methods and in the usual equipments. Fine grinding, however, should expe ⁇ trans be performed in an air jet mill being advantageously provided ' with an air sizer, the procedure be advantageously carried out in a closed circuit. During fine grinding the components get perfectly mixed, therefore, there is no need for subsequent homogenization.
  • the pigment composition of the invention may be used for making any kinds bf paints, lutes or other coating mate ⁇ rials. It can equally be used for oil-base or artificial
  • the pigment according to the inven ⁇ tion is expediently used in an amount of about 50-85 weight percent for dyestuff compositions and in an amount of about 8-12 weight percent for lutes, however, ratios other than the former may also be adopted, if required.
  • the pigment according to the inven ⁇ tion is expediently used in an amount of about 50-85 weight percent for dyestuff compositions and in an amount of about 8-12 weight percent for lutes, however, ratios other than the former may also be adopted, if required.
  • the pigment composition according to the invention is easy and fast to get intermixed with dyestuffs and lutes.
  • the advantage of the pigment composition according to the invention lies in its anti-corrosive feature. It not only
  • the pigmen composition according to the invention has made the exis ⁇ ting corrosion layer on the treated surface cease within a comparatively short time and after treatment a surface 5 clean to metal was obtained. It ensues from this that ther is no need for properly cleaning the surface to be protec ⁇ ted before the treatment with the dyestuffs, lutes and oth coating materials containing the pigment composition accor ding to the invention. Thus corrosion prevention can be 0 ' solved with considerably less labour compared with the pro cedure applying the conventional anti-corrosive materials. Further advantage of the pigment composition according to the invention is that, provided no fillers or pigments of larger grain size are admixed, the coating material made
  • the paints, lutes and other coating materials made by the use there of may be applied also under the strictest sti ⁇ pulations for health and could be applied by any means e.g spraying to the surface to be protected. Accordingly, the pigment composition according to the invention may be used
  • a pigment composition is prepared for lutes and priming paints with the composition below:
  • a pigment composition is prepared for lutes with the com- position below:
  • a pigment composition is prepared for synthetic base pri ⁇ ming paints, spray lutes and also for the protection aga ⁇ inst strong electrolytes /e.g. sea water/, with the follo- wing composition:
  • a pigment composition is prepared for priming paints, spary lutes in order to obtain smooth surface finis, with the following composition:
  • Example 3 The components are processed by the method given in Example 3 and are formed to obtain the pigment with the exception that fine grinding is made until 5 ,um grain size is obtained.
  • a pigment composition is prepared for the area of appli- cation mentioned is Example 4 with the following compo ⁇ sition:
  • the components are processe ' d and formed to obtain the pigment by the method given in Example 4.
  • a pigment composition is prepared for the purpose of light colour priming paints or lutes for use at moderately corro sive conditions with the following composition: 100 parts of alumina hydrate
  • a pigment composition is prepared for priming paints with the following composition:
  • a pigment composition is prepared with the following composition: 100 parts of alumina hydrate /50 parts therein are carbonized alumina hydrate/ 40 parts of zinc phosphate 40 parts of limestone . The components are processed and formed to obtain the pigment according to Example 3. Fine grinding is perfor ⁇ med till 5 ,um grain size is attained. A pigment appli ⁇ cable for the production of white and coloured paints, respectively, is obtained.
  • a pigment composition is prepared for synthetic resin base light primers with the following composition:
EP86903537A 1985-06-13 1986-06-12 Anti-corrosive pigment composition and process for producing the same Withdrawn EP0228401A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
HU232785 1985-06-13
HU852327A HU198523B (en) 1985-06-13 1985-06-13 Active anticorrosion pigment composition for coating materials and process for its production
HU163586 1986-01-22

Publications (1)

Publication Number Publication Date
EP0228401A1 true EP0228401A1 (en) 1987-07-15

Family

ID=10958851

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86903537A Withdrawn EP0228401A1 (en) 1985-06-13 1986-06-12 Anti-corrosive pigment composition and process for producing the same

Country Status (5)

Country Link
EP (1) EP0228401A1 (un)
JP (1) JPS63500041A (un)
AU (1) AU592355B2 (un)
HU (1) HU198523B (un)
WO (1) WO1986007371A1 (un)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3443883B2 (ja) * 1992-08-14 2003-09-08 ソニー株式会社 記録媒体収納カセット及びカセット保管用ケース
NO312911B1 (no) * 1994-12-22 2002-07-15 Budenheim Rud A Oetker Chemie Antikorrosjonspigment og anvendelse av dette
DE19807808A1 (de) * 1998-02-26 1999-09-02 Budenheim Rud A Oetker Chemie Korrosionsschutzpigment und dessen Verwendung
WO2021183602A1 (en) 2020-03-10 2021-09-16 Sasol (Usa) Corporation Alumina modified with a short chain carboxylic acid for use as a coating and a method for producing the same

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4156613A (en) * 1976-06-05 1979-05-29 Bayer Aktiengesellschaft Anti-corrosion pigments
CH601109A5 (un) * 1976-11-09 1978-06-30 Alusuisse
DE2815306C2 (de) * 1978-04-08 1983-11-10 Bayer Ag, 5090 Leverkusen Aktive Korrosionsschutzpigmente auf Calciumoxid-, Aluminiumoxidbasis und deren Verwendung
FR2470820A1 (fr) * 1979-11-30 1981-06-12 Lafarge Sa Procede de fabrication de charges minerales contenant du monocarboaluminate de calcium hydrate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO8607371A1 *

Also Published As

Publication number Publication date
AU592355B2 (en) 1990-01-11
AU5996986A (en) 1987-01-07
HU198523B (en) 1987-08-28
WO1986007371A1 (en) 1986-12-18
JPS63500041A (ja) 1988-01-07

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Inventor name: CSILLAG, ZSOLT

Inventor name: ZSEMBERY, LASZLO

Inventor name: KIRALY, LASZLO

Inventor name: SZENTGYOERGYI, GEZA

Inventor name: KALMAN, TIBOR

Inventor name: PATYI, LAJOS

Inventor name: KONIORCZYK, BELA

Inventor name: LEGAT, TIBOR