EP0206513A1 - Composition détergente pour le linge - Google Patents
Composition détergente pour le linge Download PDFInfo
- Publication number
- EP0206513A1 EP0206513A1 EP86303780A EP86303780A EP0206513A1 EP 0206513 A1 EP0206513 A1 EP 0206513A1 EP 86303780 A EP86303780 A EP 86303780A EP 86303780 A EP86303780 A EP 86303780A EP 0206513 A1 EP0206513 A1 EP 0206513A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition according
- integer
- compositions
- moieties
- polyamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
- C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
Definitions
- the present invention relates to cleaning compositions which contain low levels of certain alkoxylated polyamines.
- the compositions further contain C 12 -C 18 fatty acids; alkyl- or alkenyl- carboxylate materials, especially alkyl- or alkenyl- succinates; citric acid or citrate; polyester soil release agents; or mixtures of these optional ingredients.
- EP-PA 0 112 593 published July 4,1984, describes alkoxylated amines having clay-soil removal/anti-redeposition properties when used in detergent compositions.
- EP-PA 0 137 615 published April 17,1985 describes solvent-based liquid detergent compositions containing alkoxylated polyamines. It has now been discovered that, when used at the levels exemplified in the patent literature, the alkoxylated amines may negatively affect overall cleaning performance.
- the present invention relates to detergent compositions designed especially for laundering fabrics.
- Said compositions may be formulated in liquid, solid, or granular form; the liquid form is preferred and such liquid-form compositions are hereinafter referred to as "heavy-duty liquids" or "HDL's” since they are designed to remove even the "heaviest” soil loads from fabrics when used in a conventional laundering operation.
- HDL's heavy-duty liquids
- this invention relates to laundry detergent compositions comprising conventional detersive surfactants and, optionally, conventional detersive adjuncts, characterized in that they contain from 0.1% to 0.9 %, preferably from 0.3 % to 0.7 %, of an alkoxylated polyamine of the formula: wherein R is hydrocarbyl having from 2 to 6 carbon atoms, R' is C 1 to C 20 hydrobarbon, alkoxy is selected from ethoxy, propoxy, butoxy, or mixtures thereof, wherein y is 2-30, n is an integer of at least 2, and X ⁇ is an anion.
- the present invention is based on the discovery that art-disclosed alkoxylated amine compounds, when used in detergent compositions at levels exemplified in the art, tend to negatively affect the overall cleaning performance of such compositions.
- the negative effects tend to occur when the detergent compositions are used under "stress" conditions, e.g. high water hardness (more than 20 gpg, or more than about 3.4 mnol Ca per liter), and/or high fabric softener load of the fabric, and/or low clay soil load.
- detergent compositions can be formulated which contain the alkoxy polyamine compounds at relatively low levels, whereby the intended performance benefit is obtained without causing undesirable side effects, even under "stress" conditions.
- Alkoxylated polyamines suitable as clay-soil removal/anti-redeposition agents, as well as their preparation, are disclosed in EP-PA 0 112 593, the disclosures of which are incorporated herein by reference.
- polyamines as used herein represents generically the alkoxylated polyamines, both in their amine form and in their quaternarized form.
- Such materials can conveniently be represented as molecules of the empirical structures with repeating units: and Wherein R is a hydrocarbyl group, usually of 2-6 carbon atoms; R 1 may be a C l -C 20 hydrocarbon; the alkoxy groups are ethoxy, propoxy, and the like, and y is 2-30, most preferably 10-20; n is an integer of at least 2, preferably from 2-20, most preferably 3-5; and X is an anion such as halide or methylsulfate, resulting from the quaternization reaction.
- polyamines for use herein are the so-called ethoxylated polyethylene imines, i.e., the polymerized reaction product of ethylene oxide with ethylene-imine, having the general formula: wherein n is an integer of 3 to 5 and y is an integer of 10 to 20.
- compositions herein contain organic surface-active agents ("surfactants") to provide the usual cleaning benefits associated with the use of such materials.
- surfactants organic surface-active agents
- Water-soluble detersive surfactants useful herein include well-known synthetic anionic, nonionic, anphoteric and zwitterionic surfactants. Typical of these are the alkyl benzene sulfonates, alkyl- and alkylether- sulfates, paraffin sulfonates, olefin sulfonates, alkoxylated (especially ethoxylated) alcohols and alkyl phenols, amine oxides, alpha-sulfonates of fatty acids and of fatty acid esters, and the like, which are well-known from the detergency art.
- detersive surfactants contain an alkyl group in the C 9 -C 18 range; the anionic detersive surfactants are most commonly used in the form of their sodium, potassium or triethanolammonium salts; the nonionics generally contain from about 5 to about 17 ethylene oxide groups.
- U.S. Patent 4.111.855 contains detailed listings of such typical detersive surfactants.
- C 11 -C 16 alkyl benzene sulfonates, C12-C18 paraffin-sulfonates and alkyl sulfates, and the ethoxylated alcohols and alkyl phenols are especially preferred in the compositions of the present type.
- the surfactant component can comprise as little as 1 % of the compositions herein, but preferably the compositions will contain 1 % to 40 %, preferably 5 % to 30 %, of surfactant. Mixtures of the ethoxylated nonionics with anionics such as the alkyl benzene sulfonates, alkyl sulfates and paraffin sulfonates are preferred for through-the-wash cleansing of a broad spectrum of soils and stains from fabrics.
- Fatty Acid/Soap Ingredient - Fatty acids generally C12-C18 chain length
- water-soluble salts i.e., common "soaps", especially alkali metal soaps
- the fatty acids are highly desirable components of the compositions herein. They are typically used at 5-30 % by weight of the composition.
- compositions herein can contain other ingredients which aid in their cleaning performance.
- detergent compositions contain a detergent builder and/or metal ion sequestrant.
- Compounds classifiable and well-known in the art as detergent builders include the nitrilotriacetates, polycarboxylates, citrates, water soluble phosphates such as tri-polyphosphate and sodium ortho- and pyro-phosphates, silicates, and mixtures thereof.
- Metal ion sequestrants include all of the above, plus materials like ethylenediaminetetraacetate, the amino polyphosphonates and phosphates (DEQUEST) and a wide variety of other poly-functional organic acids and salts too numerous to mention in detail here. See U.S. Patent 3.579.454 for typical examples of the use of such materials in various cleaning compositions.
- the builder/sequestrant will comprise about 0.5 % to 15 % of the composition.
- Citrate is one of the most preferred builders since it is readily soluble in the aqueous phase of heavy-duty liquid detergent compositions.
- Suitable builders are those of the general formula R-CH(COOH)CH 2 (COOH) i.e. derivatives of succinic acid, wherein R is C10-C20 alkyl or alkenyl, preferably C 12 -C 16' or wherein R may be substituted with hydroxyl, sulfo, sulfoxy or sulfone substituents.
- the succinate builders are preferably used in the form of their water-soluble salts, including the sodium, potassium, ammonium and alkanolammonium salts.
- succinate builders include: lauryl succinate, myristyl succinate, palmityl succinate, 2-dodecenyl succinate (preferred), 2-pentadecenyl succinate, and the like.
- compositions herein also preferably contain enzymes to enhance their through-the-wash cleaning performance on a variety of soils and stains.
- Amylase and protease enzymes suitable for use in detergents are well-known in the art and in commercially available liquid and granular detergents.
- Commercial detersive enzymes preferably a mixture of amylase and protease
- Ingredients such as propane diol and/or formate, calcium and boric acid, can be added to help stabilize the enzymes in well-known fashion, according to the desires of the formulator.
- compositions herein also preferably contain soil release polymers having the generic formula : in which X can be any suitable capping group, with each X being selected from the group consisting of H, and alkyl or acyl groups containing from 1 to about 4 carbon atoms, in particular methyl.
- n is selected for water solubility and generally is from about 6 to about 120, preferably from about 10 to about 50.
- u is critical to formulation in a liquid detergent having a relatively high ionic strength. There should be little material, preferably, less than 5%, having u greater than 5.
- the weight average value of u preferably is in the range of from 1 to 2.
- the R 1 moieties are essentially 1,4-phenylene moieties.
- the term "the R moieties are essentially 1,4-phenylene moieties” refers to compounds where the R moieties consist entirely of 1,4-phenylene moieties, or are partially substituted with other arylene or alkarylene moieties, alkylene moieties, alkenylene moieties, or mixtures thereof.
- Arylene and alkarylene moieties which can be partially substituted for 1,4-phenylene include 1,3-phenylene, 1,2-phenylene, 1,8-naphtylene, 1,4-naphtylene, 2,2-biphenylene, 4,4-biphenylene and mixtures thereof.
- Alkylene and alkenylene moieties which can be partially substituted include ethylene, 1,2 propylene, 1,4-butylene, 1,5-pentylene, 1,6-hexamethylene, 1,7-heptamethylene, 1,8-octamethylene, 1,4-cyclohexylene, and mixtures thereof.
- the degree of partial substitution with moieties other than 1,4-phenylene should be such that the soil release properties of the compound are not adversely affected to any great extent.
- the degree of partial substitution which can be tolerated will depend upon the backbone length of the compound, i.e., longer backbones can have greater partial substitution for 1,4-phenylene moieties.
- compounds where the R comprise from about 50 to 100 % 1,4-phenylene moieties (from 0 to about 50 % moieties other than 1,4-phenylene) have adequate soil release activity.
- polyesters made according to the present invention with a 40:60 mole ratio of isophtalic (1,3-phenylene) to terephtalic (1,4-phenylene) acid have adequate soil release activity.
- the R moieties consist entirely of (i.e., comprise 100 %) 1,4-phenylene moieties, i.e. each R 1 moiety is 1,4-phenylene.
- suitable ethylene or substituted ethylene moieties include ethylene, 1,2-propylene, 1,2-butylene, 1,2-hexylene, 3-methoxy-l,2-propylene and mixtures thereof.
- the R 2 moieties are essentially ethylene moieties, 1,2-propylene moieties or mixtures thereof. Inclusion of a greater percentage of ethylene moieties tends to improve the soil release activity of the compounds. Surprisingly, inclusion of a greater percentage of 1,2-propylene moieties tends to improve the water solubility of the compounds.
- compositions herein can contain, in addition to ingredients already mentioned, various other optional ingredients typically used in commercial products to provide aesthetic or additional product performance benefits.
- Typical ingredients include pH regulants, perfumes, dyes, bleaches, optical brighteners, soil suspending agents, hydrotropes and gel-control agents, freeze-thaw stabilizers, bactericides, preservatives, suds control agents, bleach activators and the like.
- the compositions are typically used at a concentration of at least 500 ppm, preferably 0.10 % to 2.5 %, in an aqueous laundry bath at pH 7-11 to launder fabrics.
- the laundering can be carried out by agitating fabrics with the present compositions over the range from 5°C to the boil, with excellent results.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB858512638A GB8512638D0 (en) | 1985-05-18 | 1985-05-18 | Laundry detergent compositions |
GB8512638 | 1985-05-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0206513A1 true EP0206513A1 (fr) | 1986-12-30 |
Family
ID=10579371
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86303780A Withdrawn EP0206513A1 (fr) | 1985-05-18 | 1986-05-19 | Composition détergente pour le linge |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0206513A1 (fr) |
CA (1) | CA1309925C (fr) |
GB (1) | GB8512638D0 (fr) |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0269169A2 (fr) * | 1986-11-21 | 1988-06-01 | The Procter & Gamble Company | Compositions détergentes contenant de la cellulose |
GB2245000A (en) * | 1987-09-17 | 1991-12-18 | Colgate Palmolive Co | Fabric softening detersive article |
US5565145A (en) * | 1994-05-25 | 1996-10-15 | The Procter & Gamble Company | Compositions comprising ethoxylated/propoxylated polyalkyleneamine polymers as soil dispersing agents |
WO1997042288A1 (fr) * | 1996-05-03 | 1997-11-13 | The Procter & Gamble Company | Compositions detergentes pour lessive et procedes pour faciliter le lavage des tissus de coton |
WO1997042286A1 (fr) * | 1996-05-03 | 1997-11-13 | The Procter & Gamble Company | Compositions detergentes liquides pour la lessive contenant des polymeres facilitant le lavage des cotons |
WO1997042287A1 (fr) * | 1996-05-03 | 1997-11-13 | The Procter & Gamble Company | Compositions detergentes liquides contenant des polymeres a polyamines modifiees specialement selectionnes |
EP0832968A1 (fr) * | 1996-09-27 | 1998-04-01 | The Procter & Gamble Company | Compositions pour trempage |
WO1998015608A2 (fr) * | 1996-10-07 | 1998-04-16 | The Procter & Gamble Company | Polyamines quaternisees alkoxyles utilisees comme ingredients dans des compositions detergentes |
US5747440A (en) * | 1996-01-30 | 1998-05-05 | Procter & Gamble Company | Laundry detergents comprising heavy metal ion chelants |
WO1998038276A1 (fr) * | 1997-02-28 | 1998-09-03 | The Procter & Gamble Company | Compositions detergentes comportant des agents protecteurs des couleurs |
US5858948A (en) * | 1996-05-03 | 1999-01-12 | Procter & Gamble Company | Liquid laundry detergent compositions comprising cotton soil release polymers and protease enzymes |
WO1999067353A1 (fr) * | 1998-06-23 | 1999-12-29 | The Procter & Gamble Company | Compositions de lessive comprenant des dispersants polyalkylene-imine alcoxyle |
US6046153A (en) * | 1996-08-26 | 2000-04-04 | The Procter & Gamble Company | Spray drying process for producing detergent compositions involving premixing modified polyamine polymers |
WO2000031234A1 (fr) * | 1998-11-25 | 2000-06-02 | The Procter & Gamble Company | Procede de formation d'une particule agglomeree |
US6087316A (en) * | 1996-05-03 | 2000-07-11 | The Procter & Gamble Company | Cotton soil release polymers |
US6093690A (en) * | 1996-08-26 | 2000-07-25 | The Procter & Gamble Company | Agglomeration process for producing detergent compositions involving premixing modified polyamine polymers |
US6143713A (en) * | 1996-05-03 | 2000-11-07 | The Procter & Gamble Company | Polyamines having fabric appearance enhancement benefits |
US6291415B1 (en) | 1996-05-03 | 2001-09-18 | The Procter & Gamble Company | Cotton soil release polymers |
US6514929B1 (en) | 1998-11-25 | 2003-02-04 | The Procter & Gamble Company | Process for forming an agglomerated particle |
US6559116B1 (en) | 1999-09-27 | 2003-05-06 | The Procter & Gamble Company | Antimicrobial compositions for hard surfaces |
US6964943B1 (en) | 1997-08-14 | 2005-11-15 | Jean-Luc Philippe Bettiol | Detergent compositions comprising a mannanase and a soil release polymer |
JP2013253258A (ja) * | 2006-05-22 | 2013-12-19 | Procter & Gamble Co | 改善されたグリース洗浄用液体洗剤組成物 |
US9540596B2 (en) | 2013-08-26 | 2017-01-10 | The Procter & Gamble Company | Compositions comprising alkoxylated polyamines having low melting points |
EP2961822B1 (fr) | 2013-02-28 | 2017-04-12 | Basf Se | Formules, leur utilisation comme détergent pour lave-vaisselle ou destinées à sa fabrication, ainsi que leur fabrication |
EP2961821B1 (fr) | 2013-02-28 | 2017-04-12 | Basf Se | Utilisation de polypropylenimine alcoxylée pour soin de linge et compositions à cet effet |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0111984A2 (fr) * | 1982-12-23 | 1984-06-27 | THE PROCTER & GAMBLE COMPANY | Polymères d'amines éthoxylées ayant des propriétés pour enlever des taches et la contre-redéposition utilisables dans des compositions détergentes |
EP0112593A2 (fr) * | 1982-12-23 | 1984-07-04 | THE PROCTER & GAMBLE COMPANY | Compositions détergentes contenant des amines éthoxylées ayant des propriétés pour enlever des taches et la contre-redéposition |
EP0137615A1 (fr) * | 1983-08-11 | 1985-04-17 | The Procter & Gamble Company | Compositions de nettoyage de tissus pour enlever des taches |
-
1985
- 1985-05-18 GB GB858512638A patent/GB8512638D0/en active Pending
-
1986
- 1986-05-15 CA CA000509248A patent/CA1309925C/fr not_active Expired - Fee Related
- 1986-05-19 EP EP86303780A patent/EP0206513A1/fr not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0111984A2 (fr) * | 1982-12-23 | 1984-06-27 | THE PROCTER & GAMBLE COMPANY | Polymères d'amines éthoxylées ayant des propriétés pour enlever des taches et la contre-redéposition utilisables dans des compositions détergentes |
EP0112593A2 (fr) * | 1982-12-23 | 1984-07-04 | THE PROCTER & GAMBLE COMPANY | Compositions détergentes contenant des amines éthoxylées ayant des propriétés pour enlever des taches et la contre-redéposition |
EP0137615A1 (fr) * | 1983-08-11 | 1985-04-17 | The Procter & Gamble Company | Compositions de nettoyage de tissus pour enlever des taches |
Cited By (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0269169A3 (en) * | 1986-11-21 | 1989-06-07 | The Procter & Gamble Company | Detergent compositions containing cellulase |
EP0269169A2 (fr) * | 1986-11-21 | 1988-06-01 | The Procter & Gamble Company | Compositions détergentes contenant de la cellulose |
GB2245000A (en) * | 1987-09-17 | 1991-12-18 | Colgate Palmolive Co | Fabric softening detersive article |
GB2245000B (en) * | 1987-09-17 | 1992-06-03 | Colgate Palmolive Co | Liquid detergent composition |
US5565145A (en) * | 1994-05-25 | 1996-10-15 | The Procter & Gamble Company | Compositions comprising ethoxylated/propoxylated polyalkyleneamine polymers as soil dispersing agents |
US5747440A (en) * | 1996-01-30 | 1998-05-05 | Procter & Gamble Company | Laundry detergents comprising heavy metal ion chelants |
US5929010A (en) * | 1996-01-30 | 1999-07-27 | Procter & Gamble Company | Laundry detergents comprising heavy metal ion chelants |
US6291415B1 (en) | 1996-05-03 | 2001-09-18 | The Procter & Gamble Company | Cotton soil release polymers |
US6087316A (en) * | 1996-05-03 | 2000-07-11 | The Procter & Gamble Company | Cotton soil release polymers |
WO1997042288A1 (fr) * | 1996-05-03 | 1997-11-13 | The Procter & Gamble Company | Compositions detergentes pour lessive et procedes pour faciliter le lavage des tissus de coton |
WO1997042287A1 (fr) * | 1996-05-03 | 1997-11-13 | The Procter & Gamble Company | Compositions detergentes liquides contenant des polymeres a polyamines modifiees specialement selectionnes |
US6191093B1 (en) | 1996-05-03 | 2001-02-20 | The Procter & Gamble Company | Cotton soil release polymers |
US6143713A (en) * | 1996-05-03 | 2000-11-07 | The Procter & Gamble Company | Polyamines having fabric appearance enhancement benefits |
US5968893A (en) * | 1996-05-03 | 1999-10-19 | The Procter & Gamble Company | Laundry detergent compositions and methods for providing soil release to cotton fabric |
US5858948A (en) * | 1996-05-03 | 1999-01-12 | Procter & Gamble Company | Liquid laundry detergent compositions comprising cotton soil release polymers and protease enzymes |
JPH11508318A (ja) * | 1996-05-03 | 1999-07-21 | ザ、プロクター、エンド、ギャンブル、カンパニー | コットン汚れ放出ポリマーおよびプロテアーゼ酵素を含んだ液体洗濯洗剤組成物 |
WO1997042286A1 (fr) * | 1996-05-03 | 1997-11-13 | The Procter & Gamble Company | Compositions detergentes liquides pour la lessive contenant des polymeres facilitant le lavage des cotons |
JPH11509266A (ja) * | 1996-05-03 | 1999-08-17 | ザ、プロクター、エンド、ギャンブル、カンパニー | 防汚性を綿布帛に与えるための洗濯洗剤組成物および方法 |
JPH11509265A (ja) * | 1996-05-03 | 1999-08-17 | ザ、プロクター、エンド、ギャンブル、カンパニー | 綿防汚重合体を含む液体洗濯洗剤組成物 |
US6046153A (en) * | 1996-08-26 | 2000-04-04 | The Procter & Gamble Company | Spray drying process for producing detergent compositions involving premixing modified polyamine polymers |
US6093690A (en) * | 1996-08-26 | 2000-07-25 | The Procter & Gamble Company | Agglomeration process for producing detergent compositions involving premixing modified polyamine polymers |
EP0832968A1 (fr) * | 1996-09-27 | 1998-04-01 | The Procter & Gamble Company | Compositions pour trempage |
WO1998015608A3 (fr) * | 1996-10-07 | 1998-05-22 | Procter & Gamble | Polyamines quaternisees alkoxyles utilisees comme ingredients dans des compositions detergentes |
WO1998015608A2 (fr) * | 1996-10-07 | 1998-04-16 | The Procter & Gamble Company | Polyamines quaternisees alkoxyles utilisees comme ingredients dans des compositions detergentes |
US5827813A (en) * | 1997-02-28 | 1998-10-27 | Procter & Gamble Company | Detergent compositions having color care agents |
WO1998038276A1 (fr) * | 1997-02-28 | 1998-09-03 | The Procter & Gamble Company | Compositions detergentes comportant des agents protecteurs des couleurs |
US6964943B1 (en) | 1997-08-14 | 2005-11-15 | Jean-Luc Philippe Bettiol | Detergent compositions comprising a mannanase and a soil release polymer |
WO1999067353A1 (fr) * | 1998-06-23 | 1999-12-29 | The Procter & Gamble Company | Compositions de lessive comprenant des dispersants polyalkylene-imine alcoxyle |
WO2000031234A1 (fr) * | 1998-11-25 | 2000-06-02 | The Procter & Gamble Company | Procede de formation d'une particule agglomeree |
US6514929B1 (en) | 1998-11-25 | 2003-02-04 | The Procter & Gamble Company | Process for forming an agglomerated particle |
US6559116B1 (en) | 1999-09-27 | 2003-05-06 | The Procter & Gamble Company | Antimicrobial compositions for hard surfaces |
US6730654B2 (en) | 1999-09-27 | 2004-05-04 | The Procter & Gamble Company | Antimicrobial compositions for hard surfaces containing biguanide compounds |
JP2013253258A (ja) * | 2006-05-22 | 2013-12-19 | Procter & Gamble Co | 改善されたグリース洗浄用液体洗剤組成物 |
EP2961822B1 (fr) | 2013-02-28 | 2017-04-12 | Basf Se | Formules, leur utilisation comme détergent pour lave-vaisselle ou destinées à sa fabrication, ainsi que leur fabrication |
EP2961821B1 (fr) | 2013-02-28 | 2017-04-12 | Basf Se | Utilisation de polypropylenimine alcoxylée pour soin de linge et compositions à cet effet |
US10301576B2 (en) | 2013-02-28 | 2019-05-28 | Basf Se | Formulations, their use as or for producing dishwashing detergents and their production |
US9540596B2 (en) | 2013-08-26 | 2017-01-10 | The Procter & Gamble Company | Compositions comprising alkoxylated polyamines having low melting points |
US9540595B2 (en) | 2013-08-26 | 2017-01-10 | The Procter & Gamble Company | Compositions comprising alkoxylated polyalkyleneimines having low melting points |
Also Published As
Publication number | Publication date |
---|---|
CA1309925C (fr) | 1992-11-10 |
GB8512638D0 (en) | 1985-06-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0206513A1 (fr) | Composition détergente pour le linge | |
US5030378A (en) | Liquid detergents containing anionic surfactant, builder and proteolytic enzyme | |
JP2968340B2 (ja) | 柔軟化性の改良された安定な洗濯用水性洗浄剤組成物 | |
JP2716522B2 (ja) | アニオン系及びノニオン系界面活性剤、ビルダー並びにタンパク質分解酵素を含有した強力液体洗濯洗剤 | |
EP0199405B1 (fr) | Détergents liquides contenant un composé tensioactif, une enzyme protéolytique et de l'acide borique | |
US4561998A (en) | Near-neutral pH detergents containing anionic surfactant, cosurfactant and fatty acid | |
EP0160762B1 (fr) | Microémulsion de nettoyage huile dans l'eau stabilisées | |
US5587356A (en) | Thickened, highly aqueous, cost effective liquid detergent compositions | |
EP0269169B1 (fr) | Compositions détergentes contenant de la cellulose | |
EP0201124B1 (fr) | Compositions de nettoyage | |
EP0199403A2 (fr) | Compositions détergentes liquides stables | |
EP0164467B1 (fr) | Composition de nettoyage avec un solvant | |
US4714565A (en) | Homogeneous concentrated liquid detergent compositions containing a monoester of a dicarboxylic acid | |
CN1265135A (zh) | 洗衣预处理方法和漂白组合物 | |
EP0203626B1 (fr) | Détergent contenant un adoucissant pour le linge | |
WO1994001520A1 (fr) | Detergent liquide aqueux concentre contenant de la polyvinylpyrrolidone | |
EP0163352B1 (fr) | Détergent avec contrôle de mousse | |
EP0199404B1 (fr) | Détergents liquides contenant un agent tensioactif anionique, un renforçateur et une enzyme protéolytique | |
US4321166A (en) | Liquid detergent compositions containing corrosion inhibiting system | |
EP0212723B1 (fr) | Détergents liquides renforcés | |
US20210261728A1 (en) | Soil Release Polyesters For Use In Detergent Compositions | |
JPH11512770A (ja) | アミンとアルキルサルフェートと他の陰イオン界面活性剤とを含有する洗剤組成物 | |
EP0155421B1 (fr) | Adoucissants pour le linge | |
US5565135A (en) | Highly aqueous, cost effective liquid detergent compositions | |
JPH11512769A (ja) | 選ばれたアルキルアミドアルコイル第四級アンモニウム化合物を含有する液体洗濯洗剤 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE FR GB IT LI LU NL SE |
|
17P | Request for examination filed |
Effective date: 19870620 |
|
17Q | First examination report despatched |
Effective date: 19880419 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 19890810 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: WALKER, JOHN RICHARD Inventor name: YAP, TJAY YONG |