EP0195770B1 - Verfahren zur Herstellung von flüssigem Roheisen oder Stahlvorprodukten - Google Patents
Verfahren zur Herstellung von flüssigem Roheisen oder Stahlvorprodukten Download PDFInfo
- Publication number
- EP0195770B1 EP0195770B1 EP86890063A EP86890063A EP0195770B1 EP 0195770 B1 EP0195770 B1 EP 0195770B1 EP 86890063 A EP86890063 A EP 86890063A EP 86890063 A EP86890063 A EP 86890063A EP 0195770 B1 EP0195770 B1 EP 0195770B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- oxygen
- fixed bed
- containing gas
- gas
- bed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0006—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
- C21B13/0013—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state introduction of iron oxide into a bath of molten iron containing a carbon reductant
- C21B13/002—Reduction of iron ores by passing through a heated column of carbon
Definitions
- the invention relates to a process for the production of molten pig iron or intermediate steel products from particulate ferrous material, in particular from pre-reduced iron sponge, and for the production of reducing gas in a melter gasifier by adding coal and by blowing in oxygen-containing gas by means of nozzle pipes penetrating the wall of the melter gasifier, one of which being a fixed bed of coke particles through which the oxygen-containing gas flows and a fluidized bed (fluidized bed) made of coke particles above it, and the iron-containing material is given to the fluidized bed.
- the invention aims at avoiding the difficulties described and has as its object to avoid reoxidation of the molten products in the melter and to reduce the primary energy requirement.
- This object is achieved according to the invention in a method of the type mentioned at the outset in that a non-gassed fixed bed of coke particles is provided below the fixed bed through which oxygen-containing gas flows, and in that the fluidized bed is flowed through by oxygen-free or oxygen-poor gas over the fixed bed through which oxygen-containing gas flows.
- the two fixed bed zones are built up by coke particles with a grain size of 20 to 60 mm, essentially by particles in the size between 30 and 40 mm, while the smaller particles are in the fluidized bed zone.
- the height of the fixed bed through which oxygen-containing gas flows is expediently set and maintained via the particle size distribution of the coal introduced into the melter gasifier.
- the fixed bed can be particularly pronounced if the grain classification of the coarse fraction of the coal introduced is within narrow limits.
- the refractory lined melter 1 has a lower section 1 ', a middle section 1 "and an enlarged upper section 1"'.
- the lower section 1 ' is intended for receiving the molten bath.
- feed lines (nozzle pipes) 2 for oxygen-containing gas and in the upper extended section 1 '" feed lines 3 for lumpy coal or coke and 4 for pre-reduced iron particles, such as sponge iron.
- at least one discharge 5 for the reducing gas formed is provided in the upper section.
- the fixed beds (fixed bed zones) designated I and II are formed from coarser coke particles.
- the melt pool that accumulates underneath consists of the molten metal 6 and the slag 7, wherein a tapping can be provided for both components I does not have a gas supply, so it is not gas-filled, above which the fixed bed II is formed, in which the coke particles are flowed through by the oxygen-containing gas flowing in from the supply lines 2 to form carbon monoxide is also not equipped with any gas supply lines. It is only kept in motion by the carbon monoxide-containing reaction gases generated in fixed bed II. Small coal or coke particles remain in the fluidized bed zone 111. Larger coal or Coke particles for which the empty pipe velocity of the gas flow is below the loosening point for a corresponding particle bed are only braked, fall through the fluid bed III and settle to form the fixed bed II or the fixed bed I.
- zone III As a result of the fact that zone III is not exposed to oxygen or oxygen-containing gas, there is a reducing gas atmosphere in this zone, as a result of which the carbon content of the pre-reduced iron-containing particles, such as sponge iron, introduced from above is retained.
- the heat required for the process is generated in a known manner by gasifying coal, communicated to the sponge iron to be melted in countercurrent, and the melt formed, consisting of slag and metal, is overheated.
- the overheating must be so strong (approx. To 1600 ° C) that it covers the heat required for the endothermic reactions taking place in the fixed bed zones I and II and the melt collected in the lower part of the melter gasifier still has a sufficient temperature for further treatment .
- Another advantage of the method according to the invention is that the assembly or instrumentation effort is lower because, compared to the method of operation mentioned at the beginning, a nozzle plane is eliminated.
- Gas temperature of 1800 ° C or a temperature of the iron-containing particles of 1200 to 1300 ° C and at the transition from Zone II to Zone I set a temperature of the iron carrier of 1600 ° C.
- the slag or metal bath had a temperature of 1400 to 1500 ° C; in the expanded upper section 1 "'of the melter gasifier, a gas temperature of 1500 ° C. was measured at the upper limit of the fluidized bed III, and a gas temperature of 1100 ° C. in the so-called calming zone above it.
- the reducing gas was discharged 5 in a quantity of 1330 m 3 ( deducted under normal conditions) / t pig iron, the pig iron formed had a C content of 3.5%, an Si content of 0.3% and an S content of 0.1%.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Iron (AREA)
- Crucibles And Fluidized-Bed Furnaces (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0084685A AT382390B (de) | 1985-03-21 | 1985-03-21 | Verfahren zur herstellung von fluessigem roheisen oder stahlvorprodukten |
AT846/85 | 1985-03-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0195770A1 EP0195770A1 (de) | 1986-09-24 |
EP0195770B1 true EP0195770B1 (de) | 1988-12-14 |
Family
ID=3501117
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86890063A Expired EP0195770B1 (de) | 1985-03-21 | 1986-03-17 | Verfahren zur Herstellung von flüssigem Roheisen oder Stahlvorprodukten |
Country Status (15)
Country | Link |
---|---|
US (1) | US4708736A (uk) |
EP (1) | EP0195770B1 (uk) |
JP (1) | JPS61221315A (uk) |
KR (1) | KR930007308B1 (uk) |
CN (1) | CN86101817B (uk) |
AT (1) | AT382390B (uk) |
AU (1) | AU574906B2 (uk) |
BR (1) | BR8601242A (uk) |
CA (1) | CA1268633A (uk) |
CS (1) | CS264273B2 (uk) |
DD (1) | DD247025A5 (uk) |
DE (1) | DE3661424D1 (uk) |
IN (1) | IN166414B (uk) |
SU (1) | SU1473716A3 (uk) |
ZA (1) | ZA861922B (uk) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT386007B (de) * | 1986-10-30 | 1988-06-27 | Voest Alpine Ag | Verfahren und anlage zur gewinnung von metallen bzw. metallegierungen |
AT386006B (de) * | 1986-10-30 | 1988-06-27 | Voest Alpine Ag | Verfahren und anlage zur gewinnung von metallen bzw. metallegierungen |
DE3787017T2 (de) * | 1987-06-30 | 1993-11-25 | Kawasaki Steel Co | Verfahren und Vorrichtung zur Erzeugung von flüssigem Metall von Erzpartikeln. |
BE1006828A3 (fr) * | 1991-07-12 | 1995-01-03 | Elsen Tooling Ireland Ltd | Procede en vue de la preparation de metaux, et en particulier de fer, a partir de minerais oxydes, a une temperature de reduction quelconque, dans un four de reduction a gouttes. |
US5354356A (en) * | 1992-10-06 | 1994-10-11 | Bechtel Group Inc. | Method of providing fuel for an iron making process |
US5320676A (en) * | 1992-10-06 | 1994-06-14 | Bechtel Group, Inc. | Low slag iron making process with injecting coolant |
US5397376A (en) * | 1992-10-06 | 1995-03-14 | Bechtel Group, Inc. | Method of providing fuel for an iron making process |
US6197088B1 (en) | 1992-10-06 | 2001-03-06 | Bechtel Group, Inc. | Producing liquid iron having a low sulfur content |
US5958107A (en) * | 1993-12-15 | 1999-09-28 | Bechtel Croup, Inc. | Shift conversion for the preparation of reducing gas |
UA43905C2 (uk) | 1996-11-08 | 2002-01-15 | Фоест-Альпіне Індустріанлагенбау Гмбх | Спосіб отримання розплавленого чавуну або напівфабрикатів сталі |
AT503593B1 (de) * | 2006-04-28 | 2008-03-15 | Siemens Vai Metals Tech Gmbh | Verfahren zur herstellung von flüssigem roheisen oder flüssigen stahlvorprodukten aus feinteilchenförmigem eisenoxidhältigem material |
AT506042A1 (de) | 2007-11-13 | 2009-05-15 | Siemens Vai Metals Tech Gmbh | Verfahren zum schmelzen von roheisen und stahlvorprodukten in einem schmelzvergaser |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3948645A (en) * | 1973-04-30 | 1976-04-06 | Boliden Aktiebolag | Method of carrying out heat-requiring chemical and/or physical processes in a fluidized bed |
SE457265B (sv) * | 1981-06-10 | 1988-12-12 | Sumitomo Metal Ind | Foerfarande och anlaeggning foer framstaellning av tackjaern |
AT378970B (de) * | 1982-12-21 | 1985-10-25 | Voest Alpine Ag | Verfahren und vorrichtung zur herstellung von flùssigem roheisen oder stahlvorprodukten |
AT376241B (de) * | 1983-01-03 | 1984-10-25 | Voest Alpine Ag | Verfahren zum schmelzen von zumindest teilweise reduziertem eisenerz |
DD226157A3 (de) * | 1983-06-01 | 1985-08-14 | Bandstahlkombinat Matern Veb | Verfahren zur erzeugung von fluessigem roheisen und reduktionsgas in einem abstichgenerator |
DE3438487A1 (de) * | 1984-10-17 | 1986-04-24 | Korf Engineering GmbH, 4000 Düsseldorf | Verfahren zur herstellung von roheisen |
SU1479006A3 (ru) * | 1984-11-26 | 1989-05-07 | Фоест-Альпине (Фирма) | Способ получени жидкого чугуна или продуктов стали и восстановительного газа в плавильном газификаторе |
DE3504346C2 (de) * | 1985-02-06 | 1986-11-27 | Korf Engineering GmbH, 4000 Düsseldorf | Verfahren und Vorrichtung zur Erzeugung von Eisenschwammpartikeln und flüssigem Roheisen |
-
1985
- 1985-03-21 AT AT0084685A patent/AT382390B/de not_active IP Right Cessation
-
1986
- 1986-03-11 IN IN225/DEL/86A patent/IN166414B/en unknown
- 1986-03-12 AU AU54664/86A patent/AU574906B2/en not_active Expired
- 1986-03-12 US US06/838,669 patent/US4708736A/en not_active Expired - Lifetime
- 1986-03-14 ZA ZA861922A patent/ZA861922B/xx unknown
- 1986-03-14 CA CA000504112A patent/CA1268633A/en not_active Expired - Fee Related
- 1986-03-17 EP EP86890063A patent/EP0195770B1/de not_active Expired
- 1986-03-17 DE DE8686890063T patent/DE3661424D1/de not_active Expired
- 1986-03-19 DD DD86288040A patent/DD247025A5/de unknown
- 1986-03-20 JP JP61064659A patent/JPS61221315A/ja active Granted
- 1986-03-20 BR BR8601242A patent/BR8601242A/pt not_active IP Right Cessation
- 1986-03-20 SU SU864027155A patent/SU1473716A3/ru active
- 1986-03-20 CN CN86101817A patent/CN86101817B/zh not_active Expired
- 1986-03-20 CS CS861965A patent/CS264273B2/cs not_active IP Right Cessation
- 1986-03-21 KR KR1019860002107A patent/KR930007308B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CS196586A2 (en) | 1988-09-16 |
CN86101817B (zh) | 1988-07-06 |
KR930007308B1 (ko) | 1993-08-05 |
CN86101817A (zh) | 1986-11-05 |
AT382390B (de) | 1987-02-25 |
DD247025A5 (de) | 1987-06-24 |
ATA84685A (de) | 1986-07-15 |
DE3661424D1 (en) | 1989-01-19 |
EP0195770A1 (de) | 1986-09-24 |
SU1473716A3 (ru) | 1989-04-15 |
CA1268633A (en) | 1990-05-08 |
ZA861922B (en) | 1986-11-26 |
AU574906B2 (en) | 1988-07-14 |
KR860007386A (ko) | 1986-10-10 |
US4708736A (en) | 1987-11-24 |
JPS61221315A (ja) | 1986-10-01 |
BR8601242A (pt) | 1986-12-02 |
CS264273B2 (en) | 1989-06-13 |
IN166414B (uk) | 1990-05-05 |
JPS648044B2 (uk) | 1989-02-13 |
AU5466486A (en) | 1986-09-25 |
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