EP0170598A1 - Verfahren zur Herstellung von Stäben oder Walzdraht aus martensitischem rostfreiem Stahl und so hergestellte Gegenstände - Google Patents
Verfahren zur Herstellung von Stäben oder Walzdraht aus martensitischem rostfreiem Stahl und so hergestellte Gegenstände Download PDFInfo
- Publication number
- EP0170598A1 EP0170598A1 EP85420123A EP85420123A EP0170598A1 EP 0170598 A1 EP0170598 A1 EP 0170598A1 EP 85420123 A EP85420123 A EP 85420123A EP 85420123 A EP85420123 A EP 85420123A EP 0170598 A1 EP0170598 A1 EP 0170598A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mpa
- hot rolling
- bars
- temperature
- resilience
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 229910001105 martensitic stainless steel Inorganic materials 0.000 title claims abstract 4
- 238000005098 hot rolling Methods 0.000 claims abstract description 26
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 10
- 239000010959 steel Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000003595 mist Substances 0.000 claims 1
- 239000012535 impurity Substances 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 230000007246 mechanism Effects 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 16
- 229910000859 α-Fe Inorganic materials 0.000 description 16
- 238000005096 rolling process Methods 0.000 description 12
- 229910000734 martensite Inorganic materials 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 7
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 238000007792 addition Methods 0.000 description 5
- 238000010791 quenching Methods 0.000 description 5
- 230000000171 quenching effect Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- 238000005266 casting Methods 0.000 description 3
- 238000005496 tempering Methods 0.000 description 3
- 230000009931 harmful effect Effects 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000013021 overheating Methods 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 235000013405 beer Nutrition 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229940082150 encore Drugs 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D7/00—Modifying the physical properties of iron or steel by deformation
- C21D7/13—Modifying the physical properties of iron or steel by deformation by hot working
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
- C21D8/065—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
Definitions
- the method of the present invention relates to a method of manufacturing bars or wire rod from stainless steel.
- martensitic stainless steels with good mechanical resistance correspond to the designations according to standard NF A 35-575 : "Z12C13”. "Z20C13” - “Z30C13”, with overall C 0.08 to 0.34% and Cr 11.5 at 14.0%. They are martensitic steels, that is to say having a predominantly martensite structure.
- the invention consists in a selection of composition and in the setting of hot rolling conditions which surprisingly lead to the desired levels of properties in the raw hot rolling state.
- compositions and the conditions of rolling are both necessary for obtaining these properties.
- the metallurgical examinations carried out make it possible to give qualitative indications on the effects of these conditions, effects which appear complex, and to indicate practical limits for the conditions of the process of the invention and the characteristics of the corresponding products.
- the "other elements" are in the usual contents for an elaboration in electric steelworks from scrap, their total is usually less than 0.5%. In particular, the residual Al content is less than 0.1%.
- the adjustment of the total content "C + N" is an essential point of the invention: it makes it possible to increase the mechanical resistance (R, E 0.2) of the product obtained and to maintain good resilience (KCU). An example will show the harmful influence on the resilience of a too high "C + N”.
- the method of the invention makes it possible to obtain raw hot rolling bars or wire rod which still have very interesting mechanical characteristics. With improved machinability. these products indeed have mechanical properties (R, E) of a very good level with a resilience that is lower the higher the S content, but overall greater than 40 J / cm2.
- Nb ⁇ 0.1% and V ⁇ 0.1% have a hardening effect, essentially resulting in an improvement in the breaking load "R” and especially in the elastic limit at 0.2% “E 0.2".
- An addition of nickel can be made if the cost is not considered excessive, mainly to improve the resilience. Such an addition tends to decrease the proportion of ferrite in the martensite / ferrite structure.
- the rolling conditions necessary to obtain the mechanical characteristics of the bars or machine wires according to the invention are as follows: after the possible hot coarse-graining of the product, whether or not followed by a cooling, the product must be brought to a temperature between 1050 ° C and 1160 ° C before undergoing the final hot rolling, this preliminary setting to temperature being obtained either by preheating or reheating, or by roughing conditions causing this temperature when the product arrives at the final rolling.
- the final hot rolling of the product thus brought to between 1050 and 1160 ° C is then carried out in practice at a temperature less than or equal to 1150 ° C (the product cools down by 10 ° C or more during the initiation of this rolling), and it must produce a reduction in section "S / s", where "S” is the cross section of the product at the initiation of this final hot rolling and "s" the cross section obtained at the end of said final hot rolling , at least equal to 3. Tests have shown that the final hot rolling should preferably be finished between 1050 and 950 ° C, product temperatures. Finally, the final hot rolling must be followed by homogeneous air cooling.
- Accelerated cooling means such as blown air or mists (water + air) can be used, provided that the cooling remains homogeneous, that is to say that the cooling rates must differ little from one section right to another of the product.
- Preheating before the final hot rolling can also be carried out below 1050 ° C, for example between 1000 ° C and 1050 ° C, but the process while remaining applicable becomes more difficult to implement.
- the rods or wire rod according to the invention are recognizable by all of their mechanical characteristics and their analysis. These mechanical characteristics being singular for such an analysis. They are also characterized in addition by a proportion of ferrite in martensite less than 30% and typically between 15 and 25%, as well as by an average grain or phase diameter (martensite and ferrite) equivalent to 5 to 10 ASTM (specification ASTM E 112 ), i.e. 65 ⁇ m to 11 ⁇ m. These structural characteristics are largely responsible for the mechanical characteristics.
- the bars according to the invention are in the form of raw hot rolling bars, or hot rolled then erected with optionally a surface finish, of diameter or thickness between 15 and 250 mm and preferably between 15 and 120 mm .
- the wire rod with a diameter between 5 and 35 mm according to the invention is usually in the form of a crown or erect bars.
- the cooling is mainly done in offset crowns or turns.
- the hot roughing was carried out in blooming as usual at about 1200-1250 ° C, transforming the 250 mm squares into 148 mm squares.
- the cooled 148 mm squares were then preheated in an oven at various temperatures as indicated in the table and then hot-rolled in the final by successive passes to the diameters shown in the table and cooled in air. From the measurements carried out with an optical pyrometer, it was estimated that the temperature of the bars at the end of the rolling was in all cases between 950 and 1000 ° C.
- the maximum section reduction is that of the A1 20 mm ⁇ bars with S / s - 69.
- the adjustment of the preheating and rolling temperature is certainly important for the adjustment of the ferrite content.
- the ferrite content must be minimized to obtain good resilience and good mechanical resistance, therefore preheat and laminate in a limited temperature range depending on both of this effect under real dynamic conditions and other very important factors: dissolution and maintenance of C and N in solution to strengthen the matrix. obtaining a fine-grained structure (preheating and recrystallization during rolling).
- the cast squares of 250 ⁇ 250 mm were hot transformed as before and similar tests were carried out starting from squares of 148 mm, with air cooling of the bars obtained.
- the temperature of the bars at the end of the rolling was between 950 and 1000 ° C.
- the preheating temperatures and the mechanical characteristics obtained on the bars are collated in the Table below:
- This graph shows that in the range of ferrite content ⁇ % from 18 to 35%, a reduction of ⁇ % of 10% corresponds on average to an increase of E 0.2 of approximately 100 MPa.
- Figure 3 locates on the one hand the figurative points (C%, N%) of the flows (A) - (B) and (D), on the other hand the domain (E) of contents (C%, N%) according to the invention as well as the narrowest preferential domain (F).
- the hardening of the bars depends significantly on the content of (C + N) dissolved. Small additions of Nb ⁇ 0.1% and / or V ⁇ 0.1% also play a hardening role.
- the good characteristics R and E 0.2 are linked to the high content of (C + N) and to the small additions of Nb and of V, but the contents in (C. N) are outside the scope of the invention and the resilience is very low.
- the process is particularly suitable for the production of rods or wire rod with continuous hot rolling means.
- the bars or machine wires of the invention are used in particular for the manufacture of mechanical parts resistant to corrosion, working in contact water, steam, wine or beer: such as trees, pistons, liners, valves or hardware.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Heat Treatment Of Steel (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT85420123T ATE49238T1 (de) | 1984-07-04 | 1985-07-03 | Verfahren zur herstellung von staeben oder walzdraht aus martensitischem rostfreiem stahl und so hergestellte gegenstaende. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8411050A FR2567151B1 (fr) | 1984-07-04 | 1984-07-04 | Procede de fabrication de barres ou de fil machine en acier inoxydable martensitique et produits correspondants |
FR8411050 | 1984-07-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0170598A1 true EP0170598A1 (de) | 1986-02-05 |
EP0170598B1 EP0170598B1 (en) | 1990-01-03 |
Family
ID=9306034
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85420123A Expired - Lifetime EP0170598B1 (en) | 1984-07-04 | 1985-07-03 | Process for manufacturing hot-rolled martensitic stainless steel rods or rod wire, and products obtained |
Country Status (6)
Country | Link |
---|---|
US (1) | US4594115A (de) |
EP (1) | EP0170598B1 (de) |
JP (1) | JPS6119734A (de) |
AT (1) | ATE49238T1 (de) |
CA (1) | CA1254062A (de) |
FR (1) | FR2567151B1 (de) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0508574A1 (de) * | 1991-04-11 | 1992-10-14 | Crucible Materials Corporation | Gegenstand aus martensitisches rostfreies Stahl und Verfahren zu ihrer Herstellung |
EP0945520A1 (de) * | 1998-03-23 | 1999-09-29 | Hans Kohler AG | Hochfester, korrosionsbeständiger Stahlwerkstoff für Einsätze im Bauwesen, der Geotechnik und im allgemeinen Maschinenbau |
EP1233080A1 (de) * | 2001-02-14 | 2002-08-21 | BÖHLER Edelstahl GmbH | Stahl für Kunststofformen und Verfahren zur Wärmebehandlung desselben |
US6488813B2 (en) * | 2000-08-01 | 2002-12-03 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Blocked urethane prepolymers as paper wet strength agent |
CN102676941A (zh) * | 2012-04-25 | 2012-09-19 | 李小强 | 一种碳化钨颗粒增强的耐磨耐蚀不锈钢及其制备方法 |
WO2017182896A1 (fr) * | 2016-04-22 | 2017-10-26 | Aperam | Procédé de fabrication d'une pièce en acier inoxydable martensitique à partir d'une tôle |
WO2019002924A1 (fr) * | 2017-06-30 | 2019-01-03 | Aperam | Procédé de soudage par points de tôles d'acier inoxydable martensitique |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19755409A1 (de) * | 1997-12-12 | 1999-06-17 | Econsult Unternehmensberatung | Nichtrostender Baustahl und Verfahren zu seiner Herstellung |
WO1999036584A1 (en) * | 1998-01-16 | 1999-07-22 | Crs Holdings, Inc. | Free-machining martensitic stainless steel |
JP3491030B2 (ja) * | 2000-10-18 | 2004-01-26 | 住友金属工業株式会社 | ディスクブレ−キロ−タ−用ステンレス鋼 |
DE10237446B4 (de) * | 2002-08-16 | 2004-07-29 | Stahlwerk Ergste Westig Gmbh | Verwendung eines Chrom-Stahls und dessen Herstellung |
JP3920185B2 (ja) * | 2002-09-27 | 2007-05-30 | 日新製鋼株式会社 | 耐たわみ性に優れたステンレス鋼製の二輪車用タイヤリム材および二輪車用フレーム材 |
US6899773B2 (en) * | 2003-02-07 | 2005-05-31 | Advanced Steel Technology, Llc | Fine-grained martensitic stainless steel and method thereof |
JP2005241457A (ja) | 2004-02-26 | 2005-09-08 | Hamamatsu Photonics Kk | 赤外線センサ及びその製造方法 |
US8557059B2 (en) * | 2009-06-05 | 2013-10-15 | Edro Specialty Steels, Inc. | Plastic injection mold of low carbon martensitic stainless steel |
CN103725954B (zh) * | 2013-12-16 | 2017-01-04 | 泰州俊宇不锈钢材料有限公司 | 一种高强度耐腐蚀钢丝及其制造工艺 |
WO2016100839A1 (en) | 2014-12-19 | 2016-06-23 | Nucor Corporation | Hot rolled light-gauge martensitic steel sheet and method for making the same |
CN105132820B (zh) * | 2015-09-21 | 2017-05-17 | 舞阳钢铁有限责任公司 | 高强度马氏体不锈钢板及其生产方法 |
JP7320936B2 (ja) * | 2018-11-16 | 2023-08-04 | 日鉄ステンレス株式会社 | 棒状鋼材 |
CN113604737B (zh) * | 2021-07-30 | 2022-07-12 | 山东钢铁股份有限公司 | 一种q550d高强钢板及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1786297A (en) * | 1929-11-20 | 1930-12-23 | Howard M Givens | Process of rolling alloy steel |
US2384566A (en) * | 1940-12-13 | 1945-09-11 | Rustless Iron & Steel Corp | Method of working alloy steel and products thereof |
GB883712A (en) * | 1958-06-16 | 1961-12-06 | Carpenter Steel Co | An alloy steel |
US3832244A (en) * | 1968-05-28 | 1974-08-27 | Crucible Inc | Stainless steel |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2337185A (en) * | 1942-09-09 | 1943-12-21 | John J Caugherty | Method of drawing stainless steel wire |
US2795519A (en) * | 1954-03-27 | 1957-06-11 | Sandvikens Jernverks Ab | Method of making corrosion resistant spring steel and product thereof |
US3154412A (en) * | 1961-10-05 | 1964-10-27 | Crucible Steel Co America | Heat-resistant high-strength stainless steel |
US4042423A (en) * | 1975-12-03 | 1977-08-16 | Union Carbide Corporation | Method for providing strong wire and strip |
US4161415A (en) * | 1978-02-01 | 1979-07-17 | Union Carbide Corporation | Method for providing strong wire |
US4265679A (en) * | 1979-08-23 | 1981-05-05 | Kawasaki Steel Corporation | Process for producing stainless steels for spring having a high strength and an excellent fatigue resistance |
JPS58123822A (ja) * | 1982-01-18 | 1983-07-23 | Daido Steel Co Ltd | 直接焼入方法 |
-
1984
- 1984-07-04 FR FR8411050A patent/FR2567151B1/fr not_active Expired
-
1985
- 1985-06-28 CA CA000485855A patent/CA1254062A/fr not_active Expired
- 1985-07-01 JP JP60144428A patent/JPS6119734A/ja active Pending
- 1985-07-01 US US06/750,190 patent/US4594115A/en not_active Expired - Fee Related
- 1985-07-03 EP EP85420123A patent/EP0170598B1/fr not_active Expired - Lifetime
- 1985-07-03 AT AT85420123T patent/ATE49238T1/de not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1786297A (en) * | 1929-11-20 | 1930-12-23 | Howard M Givens | Process of rolling alloy steel |
US2384566A (en) * | 1940-12-13 | 1945-09-11 | Rustless Iron & Steel Corp | Method of working alloy steel and products thereof |
GB883712A (en) * | 1958-06-16 | 1961-12-06 | Carpenter Steel Co | An alloy steel |
US3832244A (en) * | 1968-05-28 | 1974-08-27 | Crucible Inc | Stainless steel |
Non-Patent Citations (1)
Title |
---|
PATENTS ABSTRACTS OF JAPAN, vol. 7, no. 232 (C-190) [1377], 14 octobre 1983, page 70 C 190; & JP - A - 58 123 822 (DAIDO TOKUSHUKO K.K.) 23-07-1983 * |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0508574A1 (de) * | 1991-04-11 | 1992-10-14 | Crucible Materials Corporation | Gegenstand aus martensitisches rostfreies Stahl und Verfahren zu ihrer Herstellung |
EP0945520A1 (de) * | 1998-03-23 | 1999-09-29 | Hans Kohler AG | Hochfester, korrosionsbeständiger Stahlwerkstoff für Einsätze im Bauwesen, der Geotechnik und im allgemeinen Maschinenbau |
US6488813B2 (en) * | 2000-08-01 | 2002-12-03 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Blocked urethane prepolymers as paper wet strength agent |
CN100558926C (zh) * | 2001-02-14 | 2009-11-11 | 博哈里尔特种钢有限公司 | 一种塑料成型模具用钢和其热处理方法 |
US6893608B2 (en) | 2001-02-14 | 2005-05-17 | Boehler Edelstahl Gmbh | Steel for plastic molds and process for their heat treatment |
KR100500263B1 (ko) * | 2001-02-14 | 2005-07-11 | 뵈러 에델스탈 게엠베하 | 마레이징 강 및 그 마레이징 강의 열처리 방법 |
EP1233080A1 (de) * | 2001-02-14 | 2002-08-21 | BÖHLER Edelstahl GmbH | Stahl für Kunststofformen und Verfahren zur Wärmebehandlung desselben |
CN102676941A (zh) * | 2012-04-25 | 2012-09-19 | 李小强 | 一种碳化钨颗粒增强的耐磨耐蚀不锈钢及其制备方法 |
WO2017182896A1 (fr) * | 2016-04-22 | 2017-10-26 | Aperam | Procédé de fabrication d'une pièce en acier inoxydable martensitique à partir d'une tôle |
RU2724767C2 (ru) * | 2016-04-22 | 2020-06-25 | Аперам | Способ изготовления из листа детали из мартенситной нержавеющей стали |
US11001916B2 (en) | 2016-04-22 | 2021-05-11 | Aperam | Method for manufacturing a martensitic stainless steel part from a sheet |
WO2019002924A1 (fr) * | 2017-06-30 | 2019-01-03 | Aperam | Procédé de soudage par points de tôles d'acier inoxydable martensitique |
CN110809632A (zh) * | 2017-06-30 | 2020-02-18 | 艾普伦 | 用于马氏体不锈钢钢板点焊的方法 |
CN110809632B (zh) * | 2017-06-30 | 2021-10-08 | 艾普伦 | 用于马氏体不锈钢钢板点焊的方法 |
US11478873B2 (en) | 2017-06-30 | 2022-10-25 | Aperam | Method for welding using points of martensitic stainless steel sheets |
Also Published As
Publication number | Publication date |
---|---|
ATE49238T1 (de) | 1990-01-15 |
EP0170598B1 (en) | 1990-01-03 |
US4594115A (en) | 1986-06-10 |
FR2567151B1 (fr) | 1986-11-21 |
CA1254062A (fr) | 1989-05-16 |
JPS6119734A (ja) | 1986-01-28 |
FR2567151A1 (fr) | 1986-01-10 |
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