EP0168700A1 - Système de régulation pour générateur de vapeur - Google Patents
Système de régulation pour générateur de vapeur Download PDFInfo
- Publication number
- EP0168700A1 EP0168700A1 EP85108086A EP85108086A EP0168700A1 EP 0168700 A1 EP0168700 A1 EP 0168700A1 EP 85108086 A EP85108086 A EP 85108086A EP 85108086 A EP85108086 A EP 85108086A EP 0168700 A1 EP0168700 A1 EP 0168700A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- probe
- patent application
- sheet
- control method
- european patent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 32
- 230000033228 biological regulation Effects 0.000 title description 2
- 239000000523 sample Substances 0.000 claims abstract description 34
- 238000005259 measurement Methods 0.000 claims abstract description 23
- 239000000567 combustion gas Substances 0.000 claims abstract description 22
- 238000002485 combustion reaction Methods 0.000 claims abstract description 13
- 238000012937 correction Methods 0.000 claims abstract description 10
- 239000007800 oxidant agent Substances 0.000 claims abstract description 7
- 239000000446 fuel Substances 0.000 claims abstract description 6
- 239000007789 gas Substances 0.000 claims description 17
- 238000004458 analytical method Methods 0.000 claims description 14
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 7
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 7
- 239000012080 ambient air Substances 0.000 claims description 6
- 239000007784 solid electrolyte Substances 0.000 claims description 6
- 230000001276 controlling effect Effects 0.000 claims 1
- 230000001105 regulatory effect Effects 0.000 claims 1
- 238000004868 gas analysis Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 23
- 239000001301 oxygen Substances 0.000 description 23
- 229910052760 oxygen Inorganic materials 0.000 description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 21
- 239000001257 hydrogen Substances 0.000 description 21
- 229910052739 hydrogen Inorganic materials 0.000 description 21
- 239000000919 ceramic Substances 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 14
- 230000008901 benefit Effects 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000011088 calibration curve Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N5/00—Systems for controlling combustion
- F23N5/003—Systems for controlling combustion using detectors sensitive to combustion gas properties
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N1/00—Regulating fuel supply
- F23N1/02—Regulating fuel supply conjointly with air supply
- F23N1/022—Regulating fuel supply conjointly with air supply using electronic means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N2225/00—Measuring
- F23N2225/04—Measuring pressure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N5/00—Systems for controlling combustion
- F23N5/18—Systems for controlling combustion using detectors sensitive to rate of flow of air or fuel
Definitions
- the invention relates to a control method for a steam generator for controlling mass flows of an oxidizer and a fuel supplied to a combustion in stoichiometric ratios.
- the invention is therefore based on the object, a Re g of the initially described type elungshabilit to develop that allows control of the mass flows in substantially stoichiometric ratios.
- control variables for control are determined on the basis of measurements of the supplied mass flows and their comparison with theoretically predetermined stoichiometric ratios, and errors in these measurements are made continuously by an analysis of combustion gases carried out after combustion be determined by means of a probe that these errors are used to correct the control variables and that the correction is carried out with a time constant which is smaller than the time constant of dynamic changes in the errors.
- control variables for the control are first determined on the basis of direct measurements of the mass flows supplied to the combustion, so that a rough specification of the control variables can be made very quickly by the direct control without large control-related dead times and the ratios of the mass flows approximately stoichiometric Conditions.
- direct measurements are in principle has an error which is essentially caused by variations in the thermodynamic state variables of the oxidizer and the fuel and at the same time is also subject to dynamic changes.
- Another advantage of the control according to the invention is that this error is detected by the subsequent analysis of the combustion gases by means of the probe and leads to a correction of the control variables within a time interval that is smaller than the time constant of the dynamic changes in the error.
- the control method according to the invention can thus correct systematic errors occurring in the rough specification of the control variables with sufficient speed and consequently regulate the mass flows to essentially stoichiometric ratios. Furthermore, the proposed control method also makes it possible to control unsteady operating states, such as starting the steam generator, with the required accuracy on the basis of the continuous determination of the errors.
- a very precise specification of the control variables on the basis of direct measurements is possible if the measurements of the mass flows supplied are carried out by means of a differential pressure method, so that subsequent corrections are only required to an extremely small extent.
- the differential pressure method is particularly preferable to other measuring methods for gases under high absolute pressure and can work with an error of approximately 1% if the individual components are carefully selected and designed.
- the probes that can be used to analyze the combustion gases generally place certain requirements on the state variables of the combustion gases to be examined, i.e. a precise analysis of these gases is only possible at a certain temperature and a certain pressure. For this reason, it is advantageous if the combustion gases are removed for analysis by means of the probe at a point in the steam generator at which they have suitable state variables for the analysis by means of the probe, these state variables without energy being supplied within the framework of the general gas equation Relationships, e.g. by expanding, can be changed.
- This has the advantage that complex processing of the combustion gases to be examined, e.g. heating or cooling, which generally has a detrimental effect on the time constant when determining the error by means of the probe, is omitted before an analysis by the probe.
- the combustion gases are mostly present in the steam generator under pressures that are too high for the probe.
- a very simple and inexpensive adaptation to the probe is possible if the combustion gases are expanded to a pressure suitable for them before reaching the probe.
- the combustion gases are removed at a point in the steam generator at which they have a significantly higher pressure and a significantly higher temperature than are suitable for the probe, but the pressure and temperature are simultaneously reduced by the expansion, so that both state variables meet the requirements of the probe.
- the point in the steam generator described above, at which the combustion gases are removed, must therefore be selected so that the temperature minus the cooling that occurs when the pressure is reduced corresponds to the operating temperature of the probe.
- Different analysis methods can be used to analyze the combustion gases in the probe.
- zirconium oxide (Zr 0 2 ) is used as the solid electrolyte.
- the advantage of this zirconium oxide probe is that its sensitivity and, above all, its speed make it superior to the options mentioned above. It allows an analysis of the combustion gases with a time constant in the range of tenths of a second.
- Another advantage of the solid electrolyte probe is that it has a drastic change in its characteristic curve in the area of the stoichiometric point, i.e. at the point of transition between an excess of oxidizer and an excess of unburned fuel, and consequently the stoichiometric point is exceeded or fallen short of using simple means and extremely high accuracy can be demonstrated.
- FIG. 1 A block diagram shown in FIG. 1 of a hydrogen / oxygen steam generator system according to the invention for the thermal conversion of hydrogen (H 2 ) and oxygen (0 2 ) to H 2 0 has a reaction space 10, which has a first feed device 12 for hydrogen and a second feed device 14 represents oxygen.
- a third feed device 16 for water opens into the reaction space 10.
- a measuring point 20 is provided in the first feed device 12 to determine a mass flow of hydrogen introduced into the reaction chamber 10 from the first feed device 12 by means of an differential pressure method.
- the differential pressure method works with orifice systems inserted in a supply line and provides for a measurement of the absolute pressure PH 2 in front of the orifice system, the differential pressure DPH 2 between the absolute pressure in front of the orifice system and a pressure determined in the area of the orifice system and the absolute temperature TH 2 of the hydrogen gas.
- the mass flow of the hydrogen MH 2 delivered from the first feed device 12 to the reaction space 10 can be determined by means of a first program 22.
- a second measuring point 24 determines the quantities PO 2 , DP0 2 and TO 2 of the oxygen supplied to the reaction space 10 in an analogous manner to the first measuring point 20 by means of the differential pressure method, and a second program 26 of the computer system calculates the mass flow MO 2 therefrom.
- a line 34 for branching off a small amount of hot steam provided from the reaction space 10.
- This line 34 leads via a throttle 36 to a probe 38, which is used to analyze the hot steam with regard to an excess of hydrogen or oxygen contained therein.
- the throttle 36 is necessary because the hot steam branched off from the reaction chamber 10 through the line 34 has a pressure greater than 50 bar and a temperature in the range from 500 to 2000.degree.
- the probe 38 only works properly when it is exposed to gas at a pressure of approximately 1 bar and a temperature of approximately 800 ° C. Such a reduction in pressure is possible by relaxing the hot steam in the throttle 36, it being advantageous if the hot steam cools down to an operating temperature of approximately 800 ° C. which is optimal for the probe 38 during expansion.
- the probe 38 In accordance with the excess oxygen or hydrogen present in the branched hot steam, the probe 38 generates an electromotive force and consequently a measurement variable F, which in turn depends on the measurement errors in the first measurement point 20 and the second measurement point 24 and the deviations from a stoichiometric ratio between hydrogen and indicates oxygen.
- This measured variable F is incorporated into the third program 28 via an algorithm based on an error model and leads to a correction of the control variable SH 2 and S0 2 calculated by this program 28 and consequently to a correction of the positions of the slides 30 or 32.
- the probe 38 shown in FIG. 2 comprises an outer tube-like housing 42, in which the Line 34 for supplying the hot steam opens, the mouth of line 34 being simultaneously provided with a constriction 44 for throttling a hot steam flow.
- openings 56 are arranged in the wall surfaces thereof for discharging the hot steam.
- a first tube 46 is arranged coaxially to the tube-like housing 42 and has an outer diameter which is smaller than the inner diameter of the tube-like housing 42 and is closed at its end facing the mouth of the line 34 by a ceramic plate 48 made of zirconium oxide. This ceramic plate 48 separates the hot steam flowing into the interior of the housing 42 via the line 34 from an interior of the tube 46.
- a baffle plate 50 is provided coaxially to the housing 42 between the latter and the mouth of the line 34.
- the first tube 46 has a plurality of heating windings 52 on its circumference, which allow the tube 46 and thus indirectly the ceramic plate 48 held thereon to be heated.
- a second tube 54 which is arranged coaxially to the tube 46 and enables a blowing of a side of the ceramic plate 48 facing away from the hot steam with ambient air.
- the hot steam then flows in a space between the first tube 46 and the inner wall of the housing 42 and escapes from the housing through the openings 56.
- the ceramic plate 48 is kept at its optimal operating temperature by the hot steam. If this is not the case, there is the possibility of heating the ceramic plate 48 to the operating temperature by means of the heating windings 52.
- the side of the plate 48 facing away from the hot steam is continuously blown with ambient air, which is then discharged again in a space between the second tube 54 and an inner wall of the first tube 46.
- the ceramic plate 48 made of zirconium oxide represents the actual solid electrolyte which, depending on the difference between an oxygen / hydrogen concentration of the hot steam and the oxygen concentration of the ambient air, now has an electromotive force (EMF), i.e. creates a voltage between the side with hot steam and the side with the ambient air.
- EMF electromotive force
- both sides of the ceramic plate 48 are provided with a porous platinum layer 58, 60.
- Each of these platinum layers 58, 60 is connected to one of two electrical lines 62, 64 leading out of the housing 42, which lead to a measuring device 66 arranged outside the housing 42 for determining the electromotive force.
- the intersection of these two straight lines with different slopes is exactly the stoichiometric point, ie the point at which both the oxygen and the hydrogen excess concentration are zero and the hot steam contains pure water vapor.
- the strong change in the EMF when the stoichiometry point is exceeded from excess oxygen concentration to excess hydrogen concentration is used to determine the error in the measurement of the mass flow ratios at the measuring points 20, 24 and enables the combustion processes in the reaction space to be kept in the stoichiometric range in a simple manner.
- the EMF determined with the measuring device 66 is digitized in the usual way and is then available as error F for the corrector of the control variables SH 2 and S0 2 by the third program 28.
- the quantity F is as short as possible after the combustion of the mass flows determined by the first measuring point 20 and the second measuring point 24, so that the respective control variables SH 2 and S0 2 are corrected as quickly as possible can be done.
- a time delay between the measurement of the respective mass flows at the measuring points 20 and 24 and the presence of the quantity F is due to the time period which the gases need to get from the individual measuring points 20 or 24 to the reaction space 10, the time period which the combustion gases need to get to the confluence of line 34 in the reaction space, the time it takes for the combustion gases or hot steam to flow through line 34 to the ceramic plates 48 and the time it takes to build up the EMF, ie the voltage in the ceramic plate 48 is necessary.
- Time constants of the measuring device and a subsequent digitization of the measured voltages will generally be negligible compared to the previously mentioned time periods.
- the sum of all the time periods mentioned was determined experimentally in the preferred exemplary embodiment and is approximately 300 to 400 milliseconds. Such a time delay is used to correct the systems that generally occur in the differential pressure method Technical measurement errors are sufficient, since these are essentially due to variations in the state variables of the measured gases, which are usually subject to fluctuations with time constants in the minute range.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Control Of Steam Boilers And Waste-Gas Boilers (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Regulation And Control Of Combustion (AREA)
- Investigating Or Analyzing Materials Using Thermal Means (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT85108086T ATE50355T1 (de) | 1984-07-02 | 1985-06-29 | Regelungsverfahren fuer dampferzeuger. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3424314A DE3424314C1 (de) | 1984-07-02 | 1984-07-02 | Regelungsverfahren fuer Dampferzeuger |
DE3424314 | 1984-07-02 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0168700A1 true EP0168700A1 (fr) | 1986-01-22 |
EP0168700B1 EP0168700B1 (fr) | 1990-02-07 |
Family
ID=6239641
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85108086A Expired - Lifetime EP0168700B1 (fr) | 1984-07-02 | 1985-06-29 | Système de régulation pour générateur de vapeur |
Country Status (6)
Country | Link |
---|---|
US (1) | US4655392A (fr) |
EP (1) | EP0168700B1 (fr) |
JP (1) | JPH0756364B2 (fr) |
AT (1) | ATE50355T1 (fr) |
CA (1) | CA1229144A (fr) |
DE (1) | DE3424314C1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5367470A (en) * | 1989-12-14 | 1994-11-22 | Exergetics Systems, Inc. | Method for fuel flow determination and improving thermal efficiency in a fossil-fired power plant |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3243116A (en) * | 1962-06-21 | 1966-03-29 | Shell Oil Co | Combustion control by means of smoke density |
FR2260751A1 (fr) * | 1974-02-08 | 1975-09-05 | Peugeot & Renault | |
FR2392327A1 (fr) * | 1977-05-25 | 1978-12-22 | Telegan Ltd | Systeme de regulation pour bruleur |
GB2022263A (en) * | 1978-05-31 | 1979-12-12 | Westinghouse Electric Corp | Oxygen/combustibles monitoring device |
DE3221660A1 (de) * | 1981-06-11 | 1983-01-05 | Paul G. Dipl.-Ing. Dr.techn. 8010 Graz Gilli | Verfahren zum zwecke der optimalen verbrennung bei feuerungen |
DE3125513A1 (de) * | 1981-06-29 | 1983-01-13 | Siemens AG, 1000 Berlin und 8000 München | "verfahren zum betrieb einer vergasungsbrenner/heinzkesselanlage" |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5332201A (en) * | 1976-09-03 | 1978-03-27 | Westinghouse Electric Corp | Boiler controlling apparatus |
JPS5479301A (en) * | 1977-12-05 | 1979-06-25 | Japan Atom Energy Res Inst | Method of producing steam and its device |
US4303194A (en) * | 1980-02-28 | 1981-12-01 | U.S. Steel Corporation | Smoke prevention apparatus |
US4360336A (en) * | 1980-11-03 | 1982-11-23 | Econics Corporation | Combustion control system |
JPS58127001A (ja) * | 1982-01-25 | 1983-07-28 | 運輸省船舶技術研究所長 | 水素酸素内燃式蒸気ボイラ |
JPS5984022A (ja) * | 1982-11-08 | 1984-05-15 | Ebara Corp | 都市ごみ焼却設備の運転方法 |
JPS59212620A (ja) * | 1983-05-16 | 1984-12-01 | Toshiba Corp | 燃焼排気ガス中の酸素濃度制御方法 |
-
1984
- 1984-07-02 DE DE3424314A patent/DE3424314C1/de not_active Expired
-
1985
- 1985-06-27 CA CA000485458A patent/CA1229144A/fr not_active Expired
- 1985-06-28 US US06/750,535 patent/US4655392A/en not_active Expired - Lifetime
- 1985-06-29 AT AT85108086T patent/ATE50355T1/de not_active IP Right Cessation
- 1985-06-29 EP EP85108086A patent/EP0168700B1/fr not_active Expired - Lifetime
- 1985-07-01 JP JP60142667A patent/JPH0756364B2/ja not_active Expired - Lifetime
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3243116A (en) * | 1962-06-21 | 1966-03-29 | Shell Oil Co | Combustion control by means of smoke density |
FR2260751A1 (fr) * | 1974-02-08 | 1975-09-05 | Peugeot & Renault | |
FR2392327A1 (fr) * | 1977-05-25 | 1978-12-22 | Telegan Ltd | Systeme de regulation pour bruleur |
GB2022263A (en) * | 1978-05-31 | 1979-12-12 | Westinghouse Electric Corp | Oxygen/combustibles monitoring device |
DE3221660A1 (de) * | 1981-06-11 | 1983-01-05 | Paul G. Dipl.-Ing. Dr.techn. 8010 Graz Gilli | Verfahren zum zwecke der optimalen verbrennung bei feuerungen |
DE3125513A1 (de) * | 1981-06-29 | 1983-01-13 | Siemens AG, 1000 Berlin und 8000 München | "verfahren zum betrieb einer vergasungsbrenner/heinzkesselanlage" |
Also Published As
Publication number | Publication date |
---|---|
EP0168700B1 (fr) | 1990-02-07 |
JPS6149904A (ja) | 1986-03-12 |
US4655392A (en) | 1987-04-07 |
CA1229144A (fr) | 1987-11-10 |
JPH0756364B2 (ja) | 1995-06-14 |
ATE50355T1 (de) | 1990-02-15 |
DE3424314C1 (de) | 1986-01-09 |
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