EP0150431B1 - Treibladung für Rohrwaffen und Verfahren zu ihrer Herstellung - Google Patents
Treibladung für Rohrwaffen und Verfahren zu ihrer Herstellung Download PDFInfo
- Publication number
- EP0150431B1 EP0150431B1 EP84115678A EP84115678A EP0150431B1 EP 0150431 B1 EP0150431 B1 EP 0150431B1 EP 84115678 A EP84115678 A EP 84115678A EP 84115678 A EP84115678 A EP 84115678A EP 0150431 B1 EP0150431 B1 EP 0150431B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- propellant charge
- powder
- powders
- homogeneous
- firing temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003380 propellant Substances 0.000 title claims description 38
- 238000000034 method Methods 0.000 title description 2
- 239000000843 powder Substances 0.000 claims description 67
- 239000008187 granular material Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 238000010304 firing Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 238000004880 explosion Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920001220 nitrocellulos Polymers 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 1
- IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical compound NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000000028 HMX Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006396 nitration reaction Methods 0.000 description 1
- UZGLIIJVICEWHF-UHFFFAOYSA-N octogen Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 UZGLIIJVICEWHF-UHFFFAOYSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
Definitions
- the invention relates to propellant charges from propellant charge powders, the energy sources of which are nitrocelluloses or nitrocelluloses and explosive oils or nitrocelluloses, explosive oils, nitroguanidine and / or hexogen, octogen, i.e. H. from propellant powders, which as one, two or. three-base propellant powder are called.
- Propellant powder of these compositions can be manufactured as a full strand, perforated or tube powder.
- Single-base propellant powders must be prepared with suitable solvents such as ether, alcohol, acetone to gelatinize the nitrocelluloses.
- Two and three-base propellant powders can be manufactured without solvents if the composition is appropriate. They are called PoL powder.
- the surface treatment that may be used for bulk powders can be disregarded in this consideration.
- a characteristic of "homogeneous powders” is that their burning speed increases with increasing bombardment or ambient temperatures. This has the consequence that with propellant charges from “homogeneous powders” in the gun bombardment the projectile speeds at a bombardment temperature of z. B. - 40 ° C are significantly smaller than at a bombardment temperature of z. B. + 60 ° C.
- the temperature-dependent performance of the propellant charges has considerable disadvantages, e.g. B. in terms of first strike safety and projectile performance, which by the at high temperatures of z. B. + 60 ° C occurring weapon pressure is limited.
- Propellant powders which do not have the characteristic increase in burning speeds with increasing temperatures, which have been highlighted for "homogeneous powder", are described in DE-PS-1 771 087, DE-PS-2 042 457 and DE-OS-3 008 196 .
- the energy sources of these propellant powders are the same as for the classic "homogeneous powders".
- the decisive difference is the material structure of the powder mass.
- One-, two- or three-base bulk powder called granules
- suitable dimensions are e.g. B. incorporated into the plasticine, called the base, of a single-base propellant powder.
- the degree of nitration of the nitrocelluloses used to produce the granules and base material is such that the granules are retained as granules in the course of the production of these powders.
- HET powder Because of the materially heterogeneous structure in the powder grain, which is given by embedding a granulate in a powder base, these powder types are called "HET powder”.
- HET powders have a fundamentally different temperature dependency than “homogeneous powders”. With increasing bombardment temperatures their burning speed decreases.
- HET powders that burn off in a temperature-neutral manner would be advantageous. However, this cannot be achieved with the known powder types in a larger bombardment temperature range of several tens of degrees Celsius with the specification of heat of explosion, force and propellant powder dimensions.
- propellant charges are obtained in a surprisingly simple manner with a combustion behavior which is temperature-neutral over a large bombardment temperature range or can be influenced in a targeted manner as a function of temperature by one or more material-homogeneous propellant charge powders (“homogeneous powder”) with one or more material-inhomogeneous propellant charge powders (“HET- Powder ”) mixes to form the propellant charge.
- homogeneous powder material-homogeneous propellant charge powders
- HET- Powder material-inhomogeneous propellant charge powders
- combustion behavior which can be specifically influenced in the temperature dependency should take into account here that occasionally a weapon pressure drop is deliberately sought at extremely low firing temperatures in order to have security against an accidental increase in weapon pressure due to powder embrittlement occurring at extremely low temperatures. Likewise, a bombardment temperature which occurs comparatively high and therefore rarely or not at all occurs occasionally Weapon pressure drop may be acceptable. It is essential that it is possible the finished i 'b tbiadung easily set so with the inventive measure, by appropriate choice of powder types and used for the mixture of their mixing ratio, the combustion behavior that the burnup characteristics such as weapons pressure and projectile velocity to a greater bombardment temperature-rated range in about are constant and in any case do not become larger outside the nominal range.
- 1 and 2 show the measured values for weapon pressure and projectile speed obtained on a 2 cm machine gun in the bombardment temperature range between -40.degree. C. and + 60.degree.
- Part A shows the projectile speeds measured at 16 m weapon distance
- part B the measured weapon pressures.
- HET powder is developed for a "homogeneous powder” that is used in a type of ammunition to build up the propellant charge. This means that the heat of explosion, the force and the dimensions of the "HET powder” can be set to the same or comparable values as for the "homogeneous powder” by appropriate choice of basic composition and granulate composition and quantity of granulate.
- the HET powder is adapted to the" homogeneous powder "in such a way that for a reference value of the bombardment temperature of, for example, -5 to -10.degree - “or” HET powder "build up propellant charges. If this is fulfilled, the pressure and speed curves of the two powders are mirror images of each other after rising and falling bombardment temperatures.
- propellant charge is built up from a mixture of equal parts by weight of "homogeneous” and this "HET powder" adapted in the above manner, weapon pressure and projectile speed remain practically constant in the bombardment temperature range of - 40 ° C to + 60 ° C.
- the curves labeled 1 represent the values for weapon pressure and projectile speed which were obtained with the "homogeneous propellant powder" introduced for this ammunition.
- the curves labeled 2 represent the values obtained with the adjusted "HET powder”.
- the curves denoted by 3 represent the values obtained with a mixture of the same weight fractions of both powders.
- Example 2 It differs from Example 1 in that the "HET powder" used was constructed in such a way that the weapon pressure drops from higher and lower temperatures from the reference value of 0 ° C. to the bombardment temperature.
- the curves labeled 1 again represent the values of the "homogeneous powder”
- the curves labeled 2 represent the values of the "HET powder”
- the curves labeled 3 represent the values obtained with a mixture of the same proportions by weight of both powders were obtained.
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Medicinal Preparation (AREA)
- Ceramic Products (AREA)
- Cosmetics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19833346287 DE3346287A1 (de) | 1983-12-21 | 1983-12-21 | Treibladung fuer rohrwaffen und verfahren zu ihrer herstellung |
DE3346287 | 1983-12-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0150431A1 EP0150431A1 (de) | 1985-08-07 |
EP0150431B1 true EP0150431B1 (de) | 1989-12-06 |
Family
ID=6217613
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP84115678A Expired EP0150431B1 (de) | 1983-12-21 | 1984-12-18 | Treibladung für Rohrwaffen und Verfahren zu ihrer Herstellung |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0150431B1 (pt) |
CA (1) | CA1265344A (pt) |
DE (2) | DE3346287A1 (pt) |
ES (1) | ES8800120A1 (pt) |
IL (1) | IL73741A (pt) |
PT (1) | PT79719B (pt) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0767155B1 (en) * | 1995-10-06 | 2000-08-16 | Autoliv Asp, Inc. | Heterogeneous gas generant charges |
DE19635795C2 (de) * | 1996-09-04 | 2002-09-26 | Rheinmetall W & M Gmbh | Treibladung für Rohrwaffen |
DE19907809C2 (de) | 1999-02-24 | 2002-10-10 | Nitrochemie Gmbh | Verfahren zur Herstellung von ein-, zwei- oder dreibasigen Triebladungspulvern für Rohrwaffenmunition |
DE102011118547B4 (de) * | 2011-11-16 | 2013-06-27 | Diehl Bgt Defence Gmbh & Co. Kg | Verfahren zur Vorhersage des Abbrandverhaltens eines Treibladungspulvers |
EP3495338A1 (en) | 2017-12-08 | 2019-06-12 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO | Propellant charge |
CN113149796A (zh) * | 2021-05-10 | 2021-07-23 | 雷存炬 | 一种一体钉发射药及其制备方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3718094A (en) * | 1962-07-30 | 1973-02-27 | North American Aviation Inc | Gas generator charge with decreased temperature sensitivity |
DE2042457C3 (de) * | 1968-04-01 | 1975-06-19 | Wilhelm Dipl.-Chem Dr. 5400 Koblenz Oversohl | Verfahren zur Herstellung eines eln- oder mehrbasigen Treibladungspulvers |
DE1771087C3 (de) * | 1968-04-01 | 1973-09-27 | Wilhelm Dipl.-Chem Dr. 5400 Koblenz Oversohl | Ein- oder mehrbasiges Treibladungspulver und Verfahren zu seiner Herstellung |
FR2234246B1 (pt) * | 1973-06-19 | 1976-09-17 | Poudres & Explosifs Ste Nale | |
DE3008196A1 (de) * | 1980-03-04 | 1981-09-17 | Wilhelm Dipl.-Chem. Dr. 5400 Koblenz Oversohl | Ein- oder mehrbasiges treibladungspulver und verfahren zu seiner herstellung |
-
1983
- 1983-12-21 DE DE19833346287 patent/DE3346287A1/de not_active Withdrawn
-
1984
- 1984-12-05 IL IL73741A patent/IL73741A/xx not_active IP Right Cessation
- 1984-12-18 EP EP84115678A patent/EP0150431B1/de not_active Expired
- 1984-12-18 ES ES538754A patent/ES8800120A1/es not_active Expired
- 1984-12-18 DE DE8484115678T patent/DE3480649D1/de not_active Expired - Fee Related
- 1984-12-19 CA CA000470528A patent/CA1265344A/en not_active Expired - Fee Related
- 1984-12-20 PT PT79719A patent/PT79719B/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE3346287A1 (de) | 1985-07-04 |
ES8800120A1 (es) | 1987-11-01 |
IL73741A (en) | 1989-12-15 |
IL73741A0 (en) | 1985-03-31 |
ES538754A0 (es) | 1987-11-01 |
PT79719A (en) | 1985-01-01 |
PT79719B (en) | 1987-07-13 |
DE3480649D1 (de) | 1990-01-11 |
EP0150431A1 (de) | 1985-08-07 |
CA1265344A (en) | 1990-02-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0718591B1 (de) | Anzündsystem für Treibladungen und Verfahren zur Herstellung derartiger Anzündsysteme | |
DE3500784A1 (de) | Verfahren zur herstellung von progressiv brennendem artillerietreibladungspulver und hierfuer geeignetes agens | |
EP0150431B1 (de) | Treibladung für Rohrwaffen und Verfahren zu ihrer Herstellung | |
DE2323709C3 (de) | Verfahren zur Herstellung gehäusefreier Treibsätze | |
DE3610424C1 (de) | Selbsttragender Treibladungskoerper und daraus hergestellte Kompaktladung | |
EP1031548B1 (de) | Verfahren zur Herstellung von ein-, zwei- oder dreibasigen Treibladungspulvern für Rohrwaffenmunition | |
DE4307731C2 (de) | Treibladungspulver für Waffen | |
DE3243425C2 (pt) | ||
DE4126981C1 (pt) | ||
EP2951137B1 (de) | Pulver zur beschleunigung von geschossen für mörsersysteme | |
EP1164116B1 (de) | Verfahren zur Herstellung eines funktionalen hochenergetischen Materials | |
DE2756259C3 (de) | Einstückige Pulver-Treibladung, ihre Herstellung und Verwendung | |
DE10027413B4 (de) | Verfahren zum Herstellen einer Treibmittelzusammensetzung unter Anwendung eines Trockenmischverfahrens | |
DE1446919A1 (de) | Pulver fuer Treibladungen,Zuendladungen,Beiladungen od.dgl. | |
CH644831A5 (de) | Verfahren zur herstellung eines mehrbasigen treibladungspulvers. | |
DE69106994T2 (de) | Zündvorrichtung für unempfindliche Sprengladungen. | |
EP0499244B1 (de) | Treibladungsmodul | |
DE3242106C1 (de) | Treibladungsmassen für Rohrwaffen | |
DE2809279C3 (de) | Treibladungsmassen für Rohrwaffen | |
DE3244444C1 (de) | Zweibasige Propergolblöcke mit erhöhtem Nitramingehalt und Verfahren zu ihrer Herstellung | |
DE4143310C2 (de) | Extrudierbare Treibladungszusammensetzung und daraus hergestellte Treibladung für Geschützmunition | |
DE3027361C1 (de) | Sprengstoff,insbesondere fuer Hohlladungen | |
DE69906978T2 (de) | Hochenergetische treibstoffe für geschossmunition | |
DE2709949C2 (de) | Kristalliner Hochleistungssprengstoff | |
DE2921212C2 (pt) |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Designated state(s): BE CH DE FR GB IT LI NL SE |
|
17P | Request for examination filed |
Effective date: 19850820 |
|
17Q | First examination report despatched |
Effective date: 19861017 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): BE CH DE FR GB IT LI NL SE |
|
ITF | It: translation for a ep patent filed | ||
REF | Corresponds to: |
Ref document number: 3480649 Country of ref document: DE Date of ref document: 19900111 |
|
ET | Fr: translation filed | ||
GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) | ||
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
ITTA | It: last paid annual fee | ||
EAL | Se: european patent in force in sweden |
Ref document number: 84115678.9 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20011116 Year of fee payment: 18 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20011120 Year of fee payment: 18 Ref country code: CH Payment date: 20011120 Year of fee payment: 18 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20011203 Year of fee payment: 18 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20011208 Year of fee payment: 18 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20011211 Year of fee payment: 18 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20011220 Year of fee payment: 18 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20021218 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20021219 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20021231 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20021231 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20021231 |
|
BERE | Be: lapsed |
Owner name: *WNC NITROCHEMIE G.M.B.H. Effective date: 20021231 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030701 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030701 |
|
EUG | Se: european patent has lapsed | ||
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20021218 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee |
Effective date: 20030701 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030901 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |