EP0135193B1 - Lubrifiant pour le traitement de métal - Google Patents

Lubrifiant pour le traitement de métal Download PDF

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Publication number
EP0135193B1
EP0135193B1 EP84110944A EP84110944A EP0135193B1 EP 0135193 B1 EP0135193 B1 EP 0135193B1 EP 84110944 A EP84110944 A EP 84110944A EP 84110944 A EP84110944 A EP 84110944A EP 0135193 B1 EP0135193 B1 EP 0135193B1
Authority
EP
European Patent Office
Prior art keywords
lubricant
calcium carbonate
coated
adhesion promoter
lubricant according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP84110944A
Other languages
German (de)
English (en)
Other versions
EP0135193A2 (fr
EP0135193A3 (en
Inventor
Yoshio Nagae
Kouji Hetsugi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nihon Parkerizing Co Ltd
Original Assignee
Nihon Parkerizing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nihon Parkerizing Co Ltd filed Critical Nihon Parkerizing Co Ltd
Priority to AT84110944T priority Critical patent/ATE34998T1/de
Publication of EP0135193A2 publication Critical patent/EP0135193A2/fr
Publication of EP0135193A3 publication Critical patent/EP0135193A3/de
Application granted granted Critical
Publication of EP0135193B1 publication Critical patent/EP0135193B1/fr
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/04—Fatty oil fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/10—Metal oxides, hydroxides, carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M139/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing atoms of elements not provided for in groups C10M127/00 - C10M137/00
    • C10M139/04—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing atoms of elements not provided for in groups C10M127/00 - C10M137/00 having a silicon-to-carbon bond, e.g. silanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/12—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic compound containing atoms of elements not provided for in groups C10M141/02 - C10M141/10
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/401—Fatty vegetable or animal oils used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C10M2207/4045—Fatty vegetable or animal oils obtained from genetically modified species used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel

Definitions

  • the invention relates to a lubricant for the cold working of metals containing fatty oils and / or mineral oils and calcium carbonate dispersed therein and its application to the cold working of steel, stainless steel, copper or zinc.
  • Lubrication is required to reduce the friction and wear between metal molds and tools and the workpiece when cold working metals, and to prevent cold welding.
  • lubrication has mainly been carried out by forming a phosphate coating on the surface and applying soap thereon.
  • Certain disadvantages in the pretreatment of metal surfaces before the cold forming by phosphating and soaping are that the phosphating is carried out at elevated temperatures (energy consumption) and requires several work steps.
  • Another working method for cold working is to treat the metal surfaces with lubricating oils containing high-pressure additives.
  • lubricating oils which are suitable for drawing in cold working, there is the problem with high deformation work that the adhesive strength of the oil film on the metal surface is not sufficient, so that cold welding occurs and damage points occur on the metal molds and tools as well as on workpieces.
  • solid lubricant additives such as molybdenum disulfide, graphite, Teflon powder, resin acid-coated calcium carbonate are also used.
  • molybdenum disulphide and graphite are very expensive materials, and moreover, they are insufficiently effective in cold working with high deformation work, so that additives with higher performance are required.
  • Resin acid-coated calcium carbonate is inexpensive and, within certain limits, also has good lubricating properties, but in order to achieve good lubricating performance, it must be mixed with at least 30% by weight of the lubricating oil.
  • the viscosity of the lubricant increases extraordinarily, it is difficult to supply it and the work performance decreases. After processing, it is difficult to remove the lubricant adhering to the products. If the lubricant is used repeatedly in a recycle process, the properties of the resin acid-coated calcium carbonate are impaired due to the temporary heating during processing, the viscosity has risen to 3 to 10 times that of the fresh lubricant and the work output has decreased accordingly.
  • the object of the invention is to avoid the disadvantages of the known methods for pretreatment before cold machining or that of the known lubricants and to provide a lubricant which is inexpensive, saves energy in lubrication, shortens the machining process, improves the surface quality of cold-machined workpieces and the subsequent degreasing easier.
  • the lubricant of the type mentioned at the outset is designed in accordance with the invention in such a way that it contains 5 to 50% by weight of calcium carbonate coated with silane coupling agent and with an average grain diameter of up to 3 ⁇ m.
  • Calcium carbonate of the required fineness can be produced by crushing and grinding in colloid mills or by wet precipitation processes with subsequent drying.
  • Silane coupling agents are known compounds and are described, for example, in Ullmann "Encyclopedia of Industrial Chemistry", 4th edition, volume 21, page 496 ff.
  • Amino and vinyl silane are particularly suitable silane coupling agents.
  • a lubricant is advantageously used which contains spindle-shaped calcium carbonate coated with silane coupling agent.
  • the average grain diameter of the coated calcium carbonate of up to 3 .mu.m is important insofar as the larger diameter of the lubricant tears strongly during high deformation work, so that it does not penetrate between the mold and the workpiece and the lubricating effect remains low.
  • coated calcium carbonate With regard to the content of coated calcium carbonate, it should be pointed out that below 5% by weight, frictional contact between the mold and the workpiece cannot be ruled out with certainty. With a content of more than 50% by weight, there is a high coefficient of friction, the lubricating properties decrease and the viscosity rises sharply, so that the work performance deteriorates.
  • a lubricant which contains 10 to 30% by weight of calcium carbonate coated with silane coupling agent.
  • the lubricant according to the invention can be used within the process sequence pickling with acid, rinsing with water, optionally in 2 stages, drying and lubrication.
  • a further advantageous embodiment of the invention provides for the surfactant to be added to the lubricant.
  • Nonionic, anionic, cationic or zwitterionic surfactants, in particular nonionic surfactants, are suitable for this.
  • the lubricant according to the present invention is applied at temperatures from room temperature to 60 ° C. It can be applied to the workpiece by dipping, brushing, pouring, spraying, etc.
  • the lubricant according to the present invention is universally applicable. In particular, it is for the Cold machining of steel, stainless steel, copper or zinc suitable.
  • the advantages of the lubricant according to the invention are to save energy in the cold working of the metals, to shorten the process, to increase the surface quality of the workpieces and to improve the removability of the lubricant after the cold working. In addition, there is no significant increase in viscosity when the lubricant is used repeatedly.
  • the aforementioned lubricants were tested by the point contact method in the SRV vibration friction and wear tester. Steel balls with a diameter of 10 mm and discs with a thickness of 8 mm and 24 mm were used to determine the coefficient of friction and the depth of wear.
  • the test conditions were:
  • lubricants 1 and 2 according to the invention had a low coefficient of friction with good stability. They were also advantageous due to the low depth of wear. In contrast, the stability of the friction coefficient of the known lubricants was particularly unsatisfactory and the depth of wear was poor.
  • the lubricants in Table 2 were measured for the change in their viscosity after heating to 130 ° C. for 6 days.
  • the SRV test was carried out analogously to Example 1.
  • the results of the tests are set out in Table 3.
  • the lubricants 7 to 9 correspond to the invention, the lubricants 10 and 11 are conventional.
  • the lubricants according to the present invention had an advantageous coefficient of friction in the SRV test with good stability even at low viscosity; the changes in viscosity were also small and therefore favorable.
  • the pipes processed with the lubricant according to the present invention showed no damage, and they were also of low surface roughness. Finally, the lubricant removal properties were also good.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Lubricants (AREA)
  • Metal Extraction Processes (AREA)
  • Forging (AREA)

Claims (6)

1. Agent lubrifiant pour le formage à froid de métaux, ayant une certaine teneur en huiles grasses et/ou en huiles minérales et du carbonate de calcium dispersé en son sein, caractérisé en ce qu'il contient de 5 à 50 % en poids de carbonate de calcium enrobé d'adhésiphore silanique et ayant un diamètre moyen de grain allant jusqu'à 3 um.
2. Agent lubrifiant selon la revendication 1, caractérisé en ce qu'il contient du carbonate de calcium enrobé d'un adhésiphore aminosilanique et/ou vinylsilanique.
3. Agent lubrifiant selon la revendication 1 ou 2, caractérisé en ce qu'il contient du carbonate de calcium enrobé d'un adhésiphore silanique et en forme de fuseau.
4. Agent lubrifiant selon la revendication 1, 2 ou 3, caractérisé en ce qu'il contient de 10 à 30 % en poids de carbonate de calcium enrobé d'un adhésiphore silanique.
5. Agent lubrifiant selon la revendication 1, 2, 3 ou 4, caractérisé en ce qu'il contient un composé surfactif, notamment un agent tensioactif non ionique.
6. Utilisation de l'agent lubrifiant selon les revendications 1 à 5, pour le formage à froid de l'acier, de l'acier fin, du cuivre ou du zinc.
EP84110944A 1983-09-17 1984-09-13 Lubrifiant pour le traitement de métal Expired EP0135193B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT84110944T ATE34998T1 (de) 1983-09-17 1984-09-13 Schmiermittel fuer die metallbearbeitung.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP58170580A JPS6063295A (ja) 1983-09-17 1983-09-17 金属材料の冷間加工用潤滑剤
JP170580/83 1983-09-17

Publications (3)

Publication Number Publication Date
EP0135193A2 EP0135193A2 (fr) 1985-03-27
EP0135193A3 EP0135193A3 (en) 1986-02-19
EP0135193B1 true EP0135193B1 (fr) 1988-06-08

Family

ID=15907465

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84110944A Expired EP0135193B1 (fr) 1983-09-17 1984-09-13 Lubrifiant pour le traitement de métal

Country Status (4)

Country Link
EP (1) EP0135193B1 (fr)
JP (1) JPS6063295A (fr)
AT (1) ATE34998T1 (fr)
DE (2) DE3471952D1 (fr)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2697072A (en) * 1951-06-08 1954-12-14 Texas Co Emulsion type drawing compounds containing carboxyalkyl cellulose salts
US2977300A (en) * 1958-08-21 1961-03-28 Continental Oil Co Method of producing heat-stable greases
US3372117A (en) * 1965-11-26 1968-03-05 Hooker Chemical Corp Cold forming lubricant
US3879305A (en) * 1973-03-26 1975-04-22 Mobil Oil Corp Grease thickened with oxygen-linked or sulfur-linked polyureas

Also Published As

Publication number Publication date
ATE34998T1 (de) 1988-06-15
EP0135193A2 (fr) 1985-03-27
EP0135193A3 (en) 1986-02-19
JPS6126957B2 (fr) 1986-06-23
DE3471952D1 (en) 1988-07-14
DE3433597A1 (de) 1985-04-18
JPS6063295A (ja) 1985-04-11

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