EP0127635A1 - Verfahren zur entfernung von manganhaltigen inkrustationen aus zur wasserversorgung betriebenen einrichtungen, behandlungslösung und deren verwendung - Google Patents
Verfahren zur entfernung von manganhaltigen inkrustationen aus zur wasserversorgung betriebenen einrichtungen, behandlungslösung und deren verwendungInfo
- Publication number
- EP0127635A1 EP0127635A1 EP83903530A EP83903530A EP0127635A1 EP 0127635 A1 EP0127635 A1 EP 0127635A1 EP 83903530 A EP83903530 A EP 83903530A EP 83903530 A EP83903530 A EP 83903530A EP 0127635 A1 EP0127635 A1 EP 0127635A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- solution
- weight
- hydrogen peroxide
- incrustations
- manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
- C02F1/62—Heavy metal compounds
- C02F1/64—Heavy metal compounds of iron or manganese
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
Definitions
- the invention relates to a method for removing in particular calcium, iron and manganese-containing incrustations from water supply facilities, a treatment solution and the new use of the basic components of the treatment solution.
- lactic acid or formic acid noticeably better, but still not ausich ⁇ de cleaning effects services were achieved with heated to about 60 ° C ⁇ itronen yarnrefiten in many cases relatively satisfactory cleaning results'.
- heated solutions for cleaning wells, pipes or walls of drinking water reservoirs, for example is not very practical because the heat from the cleaning solution is constantly lost through the environment.
- DE-A-25 20 988 also discloses a method for removing scale and / or sludge.
- D These deposits differ in character from the sintering and sintering to be treated according to the present invention in that they have hardly any iron content and no manganese content.
- a two-stage treatment takes place, in which rinsing or treatment with an acid solution is carried out for a relatively long time, after which treatment with a pure hydrogen peroxide solution is carried out.
- the treatment with acid serves to loosen up of the original coating, so that it becomes porous, and the subsequent treatment with hydrogen peroxide leads to a bursting of the coating because hydrogen peroxide penetrates into the pores and on the sharp-edged surfaces and / or through traces of
- the present invention further generally relates to
- the present invention thus relates generally to one
- the two steps of the method described can be carried out at different locations by different people, so that, for example, the manufacture of a solution intended for the method according to the invention by a pure manufacturer and the use of this solution by a specialist for the treatment of water supply devices as Implementation of the claimed method can be seen.
- Another, but very special advantage of the invention lies in the fact that the use of hydrogen peroxide, which ultimately forms water in the course of its reactions, means that no unnecessary foreign substances are introduced and thus unnecessary water pollution is avoided.
- treatment solutions which contain mineral-acidic, aqueous hydrogen peroxide solutions with a content of 0.05 to 20% by weight, preferably 0.1 to 3% by weight, H 2 ⁇ 2.
- the mineral acid concentration corresponds to a normality ( N) from 0.001 N to 6 N, preferably from 0.5 N to 4.5 N, for normal customary applications very particularly preferably from 0.5 N to 3 N, in each case based on the water content contained in the system.
- Suitable mineral acids are, for example, hydrochloric acid and optionally sulfuric acid.
- hydrochloric acid is preferred.
- aqueous mineral acidic hydrogen peroxide solutions according to the invention can, depending on the intended use, also be used with conventional solutions
- OMPI 1 emulsifiers for example, in amounts of between 0.5 to 3.0 each
- anionic and / or cationic and / or neutral detergent organic acids in the form of carboxylic acids, hydroxyl acids or sulfonic acids, wetting agents and / or lower aliphatic alcohols.
- a typical preferred treatment solution according to the invention thus consists of 6 to 50% by weight 30 to 33% hydrochloric acid, 0.05 to 20% by weight hydrogen peroxide, 0.5 to 3.0% by weight anionic and / or cationic and / or neutral detergents, 0.5 to 3.0% by weight of organic carboxylic acids and / or organic hydroxy acids 15 and / or organic sulfonic acids, 0.5 to 3.0% by weight of one or more lower aliphatic alcohols and a balance up to 100% by weight water.
- the invention is explained in more detail below on the basis of exemplary embodiments.
- a scratch-resistant black coating on the walls of a drinking water container which had not been treated since 1968 and which was hardly attacked by semi-concentrated hydrochloric acid, consisting of a high content of
- Iron was sprayed per square meter with about 0.7 liters of a 0.9% by weight hydrogen peroxide and 0.5% by weight of a wetting agent based on polyethylene glycol in a treatment solution containing 2N hydrochloric acid.
- Such a solution can be prefabricated industrially and is stable in large quantities.
- a hydrochloric acid content of 30 to 35% by weight, it is particularly well suited for the treatment of normal incrustations, while higher acid contents can be chosen if particularly stubborn, strongly aged incrustations are to be treated.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
- Removal Of Specific Substances (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3244443A DE3244443C2 (de) | 1982-12-01 | 1982-12-01 | Verfahren zur Entfernung von eisen-, calcium- und manganhaltigen Verockerungen und/oder Versinterungen aus zur Wasserversorgung betriebenen Einrichtungen |
DE3244443 | 1982-12-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0127635A1 true EP0127635A1 (de) | 1984-12-12 |
Family
ID=6179542
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP83112059A Expired EP0113060B2 (de) | 1982-12-01 | 1983-12-01 | Verfahren zur Entfernung von manganhaltigen Inkrustationen aus zur Wasserversorgung betriebenen Einrichtungen |
EP83903530A Pending EP0127635A1 (de) | 1982-12-01 | 1983-12-01 | Verfahren zur entfernung von manganhaltigen inkrustationen aus zur wasserversorgung betriebenen einrichtungen, behandlungslösung und deren verwendung |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP83112059A Expired EP0113060B2 (de) | 1982-12-01 | 1983-12-01 | Verfahren zur Entfernung von manganhaltigen Inkrustationen aus zur Wasserversorgung betriebenen Einrichtungen |
Country Status (7)
Country | Link |
---|---|
US (1) | US4806169A (es) |
EP (2) | EP0113060B2 (es) |
AT (1) | ATE23143T1 (es) |
CA (1) | CA1245955A (es) |
DE (2) | DE3244443C2 (es) |
ES (1) | ES8504634A1 (es) |
WO (1) | WO1984002125A1 (es) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3431101A1 (de) * | 1984-08-24 | 1986-03-06 | Hubert F. 6000 Frankfurt Neuhausen | Flusssaeure - enthaltende waessrige organische saeuremischungen mit eventuellem zusatz von anorganischen saeuren und korrisionsinhibitoren |
EP0183894B1 (de) * | 1984-11-30 | 1991-07-24 | Feldmann-Chemie GmbH | Verwendung von Mischung aus organischen und/oder anorganischen Säuren und/oder sauren Salzen zur Entfernung von eisen- und manganhaltigen Ablagerungen und Verockerungen |
DE3625280A1 (de) * | 1986-07-25 | 1988-02-04 | Feldmann Hagen | Reiniger fuer trinkwasseranlagen |
US5022926A (en) * | 1988-06-10 | 1991-06-11 | W. R. Grace & Co.-Conn. | Corrosion control |
US5885364A (en) * | 1991-05-16 | 1999-03-23 | H.E.R.C. Products Incorporated | Method of cleaning and maintaining potable water distribution pipe systems |
US5360488A (en) * | 1993-03-23 | 1994-11-01 | H.E.R.C. Products Incorporated | Method of cleaning and maintaining water distribution pipe systems |
US5527395A (en) * | 1991-05-16 | 1996-06-18 | H.E.R.C. Products Incorporated | Method of cleaning and maintaining potable water distribution pipe systems with a heated cleaning solution |
DE4243303C1 (de) * | 1992-12-21 | 1994-09-01 | Aquaplus Brunnensanierung Kaet | Verfahren zum Reinigen eines Brunnenschachtes |
WO1994021865A1 (en) * | 1993-03-23 | 1994-09-29 | H.E.R.C. Incorporated | Method of cleaning and maintaining potable water distribution pipe systems |
GB2281742A (en) * | 1993-09-09 | 1995-03-15 | Grace W R & Co | Biocidal composition |
WO1995035419A1 (en) * | 1994-06-20 | 1995-12-28 | H.E.R.C. Products Incorporated | Method of cleaning and maintaining potable water distribution pipe systems with a heated cleaning solution |
DE4428027A1 (de) * | 1994-08-08 | 1996-02-15 | Spaene Kg R | Verwendung von Hydrogensulfat als Säurekomponente in Verbindung mit Wasserstoffperoxid zur Reinigung von Trinkwasserversorgungseinrichtungen |
GB2297976A (en) * | 1995-02-01 | 1996-08-21 | Reckitt & Colmann Prod Ltd | Improvements in or relating to a bleaching process |
JP3747504B2 (ja) * | 1996-02-23 | 2006-02-22 | 栗田工業株式会社 | 銅の孔食防止方法 |
US5800629A (en) * | 1997-03-06 | 1998-09-01 | H.E.R.C. Products Incorporated | Pipe system cleaning and in-line treatment of spent cleaning solution |
US6076536A (en) | 1998-10-07 | 2000-06-20 | H.E.R.C. Products Incorporated | Cleaning and passivating water distribution systems |
US6346217B1 (en) | 1999-06-02 | 2002-02-12 | Water Whole International, Inc. | Composition and method for cleaning drink water tanks |
DK1150923T3 (da) | 1999-12-10 | 2007-07-02 | Spaene Kg R | Fremgangsmåde til fjernelse af aflejringer fra vandoverföringssystemer og indretninger til vandtilförsel |
DE102012109099A1 (de) | 2012-09-26 | 2014-03-27 | Carela Gmbh | Desinfektionsreiniger für Trinkwasserversorgungsanlagen und seine Verwendungen |
DE102013203156A1 (de) | 2013-02-26 | 2014-08-28 | Carela Gmbh | Verfahren zur Entfernung von Biofilmen aus Anlagen zur Bereitstellung und Verteilung von Trink- und Brauchwasser |
MY194306A (en) * | 2014-07-28 | 2022-11-27 | Nat Univ Singapore | Rapid cleaning method for ultrapure water piping system |
ES2607234B1 (es) * | 2015-09-29 | 2018-03-07 | Universidad De Sevilla | Procedimiento de limpieza de Fe y Mn en redes de distribución de aguas |
DE202015105583U1 (de) | 2015-10-21 | 2017-01-27 | Witty Gmbh & Co. Kg | Reinigungsmittel |
DE102015117955B4 (de) | 2015-10-21 | 2019-05-09 | Witty Gmbh & Co. Kg | Verfahren zur Reinigung und Desinfektion von Trinkwasserbehältern |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE974400C (de) * | 1952-11-16 | 1960-12-15 | Henkel & Cie Gmbh | Beize fuer Buntmetalle |
US3085929A (en) * | 1961-03-16 | 1963-04-16 | Du Pont | Hydroxyacetate pesticide |
LU60299A1 (es) * | 1969-02-07 | 1970-04-06 | ||
BE758162A (fr) * | 1969-10-28 | 1971-04-01 | Fmc Corp | Stabilisation de solutions acidifiees d'eau |
US3682702A (en) * | 1970-09-02 | 1972-08-08 | Ethyl Corp | Method of removing manganese oxide deposits |
US3817859A (en) * | 1972-03-29 | 1974-06-18 | Texaco Inc | Waste water treatment method |
JPS526853B2 (es) * | 1972-12-22 | 1977-02-25 | ||
US4009115A (en) * | 1974-02-14 | 1977-02-22 | Amchem Products, Inc. | Composition and method for cleaning aluminum at low temperatures |
JPS576997B2 (es) * | 1974-05-16 | 1982-02-08 | ||
FR2297906A1 (fr) * | 1975-01-14 | 1976-08-13 | Ugine Kuhlmann | Stabilisation du peroxyde d'hydrogene dans les bains acides pour le decapage des metaux |
JPS5525754A (en) * | 1978-08-15 | 1980-02-23 | Kurita Kasen Kk | Method of cleaning scale |
-
1982
- 1982-12-01 DE DE3244443A patent/DE3244443C2/de not_active Expired
-
1983
- 1983-12-01 EP EP83112059A patent/EP0113060B2/de not_active Expired
- 1983-12-01 EP EP83903530A patent/EP0127635A1/de active Pending
- 1983-12-01 ES ES527721A patent/ES8504634A1/es not_active Expired
- 1983-12-01 DE DE8383112059T patent/DE3367204D1/de not_active Expired
- 1983-12-01 AT AT83112059T patent/ATE23143T1/de not_active IP Right Cessation
- 1983-12-01 WO PCT/EP1983/000320 patent/WO1984002125A1/de not_active Application Discontinuation
-
1985
- 1985-05-29 CA CA000482720A patent/CA1245955A/en not_active Expired
- 1985-06-04 US US06/741,245 patent/US4806169A/en not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO8402125A1 * |
Also Published As
Publication number | Publication date |
---|---|
US4806169A (en) | 1989-02-21 |
DE3244443C2 (de) | 1986-11-06 |
EP0113060B2 (de) | 1989-04-12 |
EP0113060B1 (de) | 1986-10-29 |
ATE23143T1 (de) | 1986-11-15 |
DE3244443A1 (de) | 1984-06-07 |
ES527721A0 (es) | 1985-05-01 |
EP0113060A1 (de) | 1984-07-11 |
DE3367204D1 (en) | 1986-12-04 |
WO1984002125A1 (en) | 1984-06-07 |
ES8504634A1 (es) | 1985-05-01 |
CA1245955A (en) | 1988-12-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
AK | Designated contracting states |
Designated state(s): AT BE CH DE FR LI LU NL |
|
17P | Request for examination filed |
Effective date: 19841019 |
|
XX | Miscellaneous (additional remarks) |
Free format text: VERFAHREN ABGESCHLOSSEN INFOLGE VERBINDUNG MIT 83112059.7/0113060 (EUROPAEISCHE ANMELDENUMMER/VEROEFFENTLICHUNGSNUMMER) VOM 06.08.85. |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: KOETZSCH, THOMAS Inventor name: SPAENE, RAINER |